Investigation of a diabase-derived regolith profile from Pennsylvania: Mineralogy, chemistry and Fe isotope fractionation

Yesavage, Tiffany; Stinchcomb, Gary E.; Fantle, Matthew S.; Sak, Peter B.; Kasznel, Alexander; Brantley, Susan L.

doi:10.1016/j.geoderma.2016.03.004

Title: Investigation of a diabase-derived regolith profile from Pennsylvania: Mineralogy, chemistry and Fe isotope fractionation

Journal Article · 30 June 2016 · Geoderma

DOI: https://doi.org/10.1016/j.geoderma.2016.03.004 · OSTI ID:1359159

; Stinchcomb, Gary E.; Fantle, Matthew S.; Sak, Peter B.;

; Brantley, Susan L.

Not Available

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI ID:: 1359159

Journal Information:: Geoderma, Journal Name: Geoderma Journal Issue: C Vol. 273; ISSN 0016-7061

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

References (76)

Where fast weathering creates thin regolith and slow weathering creates thick regolith: FAST WEATHERING - THIN REGOLITH, SLOW WEATHERING - THICK REGOLITH Bazilevskaya, Ekaterina; Lebedeva, Marina; Pavich, Milan Earth Surface Processes and Landforms, Vol. 38, Issue 8 https://doi.org/10.1002/esp.3369	journal	December 2012
Probing deep weathering in the Shale Hills Critical Zone Observatory, Pennsylvania (USA): the hypothesis of nested chemical reaction fronts in the subsurface: NESTED REACTION FRONTS Brantley, Susan L.; Holleran, Molly E.; Jin, Lixin Earth Surface Processes and Landforms, Vol. 38, Issue 11 https://doi.org/10.1002/esp.3415	journal	April 2013
Mass spectrometry and natural variations of iron isotopes Dauphas, Nicolas; Rouxel, Olivier Mass Spectrometry Reviews, Vol. 25, Issue 4 https://doi.org/10.1002/mas.20078	journal	January 2006
Vertical transport of dissolved organic C and N under long-term N amendments in pine and hardwood forests Currie, William S.; Aber, John D.; McDowell, William H. Biogeochemistry, Vol. 35, Issue 3 https://doi.org/10.1007/BF02183037	journal	December 1996
Redox-controlled iron isotope fractionation during magmatic differentiation: an example from the Red Hill intrusion, S. Tasmania Sossi, Paolo A.; Foden, John D.; Halverson, Galen P. Contributions to Mineralogy and Petrology, Vol. 164, Issue 5 https://doi.org/10.1007/s00410-012-0769-x	journal	June 2012
Iron oxide mineralogy and stable iron isotope composition in a Gleysol with petrogleyic properties Mansfeldt, Tim; Schuth, Stephan; Häusler, Werner Journal of Soils and Sediments, Vol. 12, Issue 1 https://doi.org/10.1007/s11368-011-0402-z	journal	August 2011
Determination of ferrous iron in silicate rocks Goldich, Samuel S. Chemical Geology, Vol. 42, Issue 1-4 https://doi.org/10.1016/0009-2541(84)90027-5	journal	January 1984
Isovolumetric geochemical investigation of a buried granite saprolite near Columbia, SC, U.S.A. Gardner, L. R.; Kheoruenromne, I.; Chen, H. S. Geochimica et Cosmochimica Acta, Vol. 42, Issue 4 https://doi.org/10.1016/0016-7037(78)90273-9	journal	April 1978
Constitutive mass balance relations between chemical composition, volume, density, porosity, and strain in metasomatic hydrochemical systems: Results on weathering and pedogenesis Brimhall, George H.; Dietrich, William E. Geochimica et Cosmochimica Acta, Vol. 51, Issue 3 https://doi.org/10.1016/0016-7037(87)90070-6	journal	March 1987
Formation and evolution of soils from an acidified watershed: Plastic Lake, Ontario, Canada Kirkwood, D. E.; Nesbitt, H. W. Geochimica et Cosmochimica Acta, Vol. 55, Issue 5 https://doi.org/10.1016/0016-7037(91)90308-R	journal	May 1991
Partitioning and speciation of solid phase iron in saltmarsh sediments Kostka, Joel E.; Luther, George W. Geochimica et Cosmochimica Acta, Vol. 58, Issue 7 https://doi.org/10.1016/0016-7037(94)90531-2	journal	April 1994
Saprolite-soil transformations in the Piedmont and Mountains of North Carolina Buol, S. W.; Weed, S. B. Geoderma, Vol. 51, Issue 1-4 https://doi.org/10.1016/0016-7061(91)90064-Z	journal	November 1991
Determining mineral weathering rates based on solid and solute weathering gradients and velocities: application to biotite weathering in saprolites White, Art F. Chemical Geology, Vol. 190, Issue 1-4 https://doi.org/10.1016/S0009-2541(02)00111-0	journal	October 2002
Application of Fe isotopes to tracing the geochemical and biological cycling of Fe Beard, Brian L.; Johnson, Clark M.; Skulan, Joseph L. Chemical Geology, Vol. 195, Issue 1-4 https://doi.org/10.1016/S0009-2541(02)00390-X	journal	April 2003
Mechanism and effect of chemical weathering of sedimentary rocks Chigira, M.; Oyama, T. Engineering Geology, Vol. 55, Issue 1-2 https://doi.org/10.1016/S0013-7952(99)00102-7	journal	January 2000
Kinetic and equilibrium Fe isotope fractionation between aqueous Fe(III) and hematite Skulan, Joseph L.; Beard, Brian L.; Johnson, Clark M. Geochimica et Cosmochimica Acta, Vol. 66, Issue 17 https://doi.org/10.1016/S0016-7037(02)00902-X	journal	September 2002
Chemical Weathering in a Tropical Watershed, Luquillo Mountains, Puerto Rico: I. Long-Term Versus Short-Term Weathering Fluxes White, Art F.; Blum, Alex E.; Schulz, Marjorie S. Geochimica et Cosmochimica Acta, Vol. 62, Issue 2 https://doi.org/10.1016/S0016-7037(97)00335-9	journal	January 1998
Aluminum solubility and mobility in relation to organic carbon in surface soils affected by six tree species of the northeastern United States Dijkstra, Feike A.; Fitzhugh, Ross D. Geoderma, Vol. 114, Issue 1-2 https://doi.org/10.1016/S0016-7061(02)00340-3	journal	May 2003
Aluminium, iron and manganese in near-surface waters of a tropical rainforest ecosystem Lorieri, Daniel; Elsenbeer, Helmut Science of The Total Environment, Vol. 205, Issue 1 https://doi.org/10.1016/S0048-9697(97)00089-2	journal	October 1997
Past and present weathering rates in northern Sweden Land, Magnus; Ingri, Johan; Öhlander, Björn Applied Geochemistry, Vol. 14, Issue 6 https://doi.org/10.1016/S0883-2927(98)00098-5	journal	August 1999
Detecting the near-surface redox front in crystalline bedrock using fracture mineral distribution, geochemistry and U-series disequilibrium Drake, Henrik; Tullborg, Eva-Lena; MacKenzie, Angus B. Applied Geochemistry, Vol. 24, Issue 5 https://doi.org/10.1016/j.apgeochem.2009.03.004	journal	May 2009
Seasonal dynamics of CO2 profiles across a soil chronosequence, Santa Cruz, California Schulz, Marjorie; Stonestrom, David; Von Kiparski, Guntram Applied Geochemistry, Vol. 26 https://doi.org/10.1016/j.apgeochem.2011.03.048	journal	June 2011
A preliminary mixing model for Fe isotopes in soils Emmanuel, Simon; Erel, Yigal; Matthews, Alan Chemical Geology, Vol. 222, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2005.07.002	journal	October 2005
Rayleigh fractionation of iron isotopes during pedogenesis along a climate sequence of Hawaiian basalt Thompson, Aaron; Ruiz, Joaquin; Chadwick, Oliver A. Chemical Geology, Vol. 238, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2006.11.005	journal	March 2007
Limited iron isotope variations in recent lateritic soils from Nsimi, Cameroon: Implications for the global Fe geochemical cycle Poitrasson, Franck; Viers, Jérôme; Martin, François Chemical Geology, Vol. 253, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2008.04.011	journal	July 2008
Phosphorus and iron cycling in deep saprolite, Luquillo Mountains, Puerto Rico Buss, Heather L.; Mathur, Ryan; White, Arthur F. Chemical Geology, Vol. 269, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2009.08.001	journal	January 2010
Determining the stable Fe isotope signature of plant-available iron in soils Guelke, Monika; von Blanckenburg, Friedhelm; Schoenberg, Ronny Chemical Geology, Vol. 277, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2010.08.010	journal	October 2010
Extent and isotopic composition of Fe and Mo release from two Pennsylvania shales in the presence of organic ligands and bacteria Liermann, Laura J.; Mathur, Ryan; Wasylenki, Laura E. Chemical Geology, Vol. 281, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2010.12.005	journal	February 2011
Soil profiles as indicators of mineral weathering rates and organic interactions for a Pennsylvania diabase Hausrath, E. M.; Navarre-Sitchler, A. K.; Sak, P. B. Chemical Geology, Vol. 290, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2011.08.014	journal	November 2011
The isotopic fingerprint of Fe cycling in an equatorial soil–plant–water system: The Nsimi watershed, South Cameroon Akerman, Alisson; Poitrasson, Franck; Oliva, Priscia Chemical Geology, Vol. 385 https://doi.org/10.1016/j.chemgeo.2014.07.003	journal	October 2014
Iron isotopic fractionation during continental weathering Fantle, Matthew S.; DePaolo, Donald J. Earth and Planetary Science Letters, Vol. 228, Issue 3-4 https://doi.org/10.1016/j.epsl.2004.10.013	journal	December 2004
A spheroidal weathering model coupling porewater chemistry to soil thicknesses during steady-state denudation Fletcher, R.; Buss, H.; Brantley, S. Earth and Planetary Science Letters, Vol. 244, Issue 1-2 https://doi.org/10.1016/j.epsl.2006.01.055	journal	April 2006
Fe isotopic fractionation during mineral dissolution with and without bacteria Brantley, Susan L.; Liermann, Laura J.; Guynn, Robin L. Geochimica et Cosmochimica Acta, Vol. 68, Issue 15 https://doi.org/10.1016/j.gca.2004.01.023	journal	August 2004
Inter-mineral Fe isotope variations in mantle-derived rocks and implications for the Fe geochemical cycle Beard, Brian L.; Johnson, Clark M. Geochimica et Cosmochimica Acta, Vol. 68, Issue 22 https://doi.org/10.1016/j.gca.2004.04.023	journal	November 2004
Iron isotope fractionation in oxic soils by mineral weathering and podzolization Wiederhold, Jan G.; Teutsch, Nadya; Kraemer, Stephan M. Geochimica et Cosmochimica Acta, Vol. 71, Issue 23 https://doi.org/10.1016/j.gca.2007.07.023	journal	December 2007
Iron isotope fractionation during leaching of granite and basalt by hydrochloric and oxalic acids Chapman, John B.; Weiss, Dominik J.; Shan, Yao Geochimica et Cosmochimica Acta, Vol. 73, Issue 5 https://doi.org/10.1016/j.gca.2008.11.037	journal	March 2009
Evidence for equilibrium iron isotope fractionation by nitrate-reducing iron(II)-oxidizing bacteria Kappler, A.; Johnson, C. M.; Crosby, H. A. Geochimica et Cosmochimica Acta, Vol. 74, Issue 10 https://doi.org/10.1016/j.gca.2010.02.017	journal	May 2010
Iron isotope fractionation during proton- and ligand-promoted dissolution of primary phyllosilicates Kiczka, Mirjam; Wiederhold, Jan G.; Frommer, Jakob Geochimica et Cosmochimica Acta, Vol. 74, Issue 11 https://doi.org/10.1016/j.gca.2010.02.018	journal	June 2010
Fe cycling in the Shale Hills Critical Zone Observatory, Pennsylvania: An analysis of biogeochemical weathering and Fe isotope fractionation Yesavage, Tiffany; Fantle, Matthew S.; Vervoort, Jeffrey Geochimica et Cosmochimica Acta, Vol. 99 https://doi.org/10.1016/j.gca.2012.09.029	journal	December 2012
Elemental translocation and loss from three highly weathered soil–bedrock profiles in the southeastern United States Oh, Neung-Hwan; Richter, Daniel D. Geoderma, Vol. 126, Issue 1-2 https://doi.org/10.1016/j.geoderma.2004.11.005	journal	May 2005
Inferences from the vertical distribution of Fe isotopic compositions on pedogenetic processes in soils Fekiacova, Z.; Pichat, S.; Cornu, S. Geoderma, Vol. 209-210 https://doi.org/10.1016/j.geoderma.2013.06.007	journal	November 2013
Controls on soil pore water solutes: An approach for distinguishing between biogenic and lithogenic processes White, Art F.; Schulz, Marjorie S.; Vivit, Davison V. Journal of Geochemical Exploration, Vol. 88, Issue 1-3 https://doi.org/10.1016/j.gexplo.2005.08.076	journal	January 2006
Iron Isotope Fractionation during Proton-Promoted, Ligand-Controlled, and Reductive Dissolution of Goethite Wiederhold, Jan G.; Kraemer, Stephan M.; Teutsch, Nadya Environmental Science & Technology, Vol. 40, Issue 12 https://doi.org/10.1021/es052228y	journal	June 2006
Fractionation of Stable Iron Isotopes in Higher Plants Guelke, Monika; von Blanckenburg, Friedhelm Environmental Science & Technology, Vol. 41, Issue 6 https://doi.org/10.1021/es062288j	journal	March 2007
Iron Isotope Fractionation during Fe Uptake and Translocation in Alpine Plants Kiczka, Mirjam; Wiederhold, Jan G.; Kraemer, Stephan M. Environmental Science & Technology, Vol. 44, Issue 16 https://doi.org/10.1021/es100863b	journal	August 2010
Bacterial Associations with Weathering Minerals at the Regolith-Bedrock Interface, Luquillo Experimental Forest, Puerto Rico Minyard, Morgan L.; Bruns, Mary Ann; Liermann, Laura J. Geomicrobiology Journal, Vol. 29, Issue 9 https://doi.org/10.1080/01490451.2011.619640	journal	April 2012
The coupling of biological iron cycling and mineral weathering during saprolite formation, Luquillo Mountains, Puerto Rico Buss, H. L.; Bruns, M. A.; Schultz, M. J. Geobiology, Vol. 3, Issue 4 https://doi.org/10.1111/j.1472-4669.2006.00058.x	journal	October 2005
Estimation of Evapotranspiration Across the Conterminous United States Using a Regression With Climate and Land-Cover Data ¹ Sanford, Ward E.; Selnick, David L. JAWRA Journal of the American Water Resources Association, Vol. 49, Issue 1 https://doi.org/10.1111/jawr.12010	journal	December 2012
Deformational Mass Transport and Invasive Processes in Soil Evolution Brimhall, G. H.; Chadwick, O. A.; Lewis, C. J. Science, Vol. 255, Issue 5045 https://doi.org/10.1126/science.255.5045.695	journal	February 1992
Iron Isotope Biosignatures Beard, B. L. Science, Vol. 285, Issue 5435 https://doi.org/10.1126/science.285.5435.1889	journal	September 1999
Geology and Geochemistry of Triassic Diabase in Pennsylvania Smith, Robert C.; Rose, Arthur W.; Lanning, Robert M. Geological Society of America Bulletin, Vol. 86, Issue 7 https://doi.org/10.1130/0016-7606(1975)86<943:GAGOTD>2.0.CO;2	journal	January 1975
Chemical weathering in two Adirondack watersheds: Past and present-day rates April, Richard; Newton, Robert; Coles, Laura Truettner Geological Society of America Bulletin, Vol. 97, Issue 10 https://doi.org/10.1130/0016-7606(1986)97<1232:CWITAW>2.0.CO;2	journal	January 1986
Weathering profiles, mass-balance analysis, and rates of solute loss: Linkages between weathering and erosion in a small, steep catchment Anderson, Suzanne Prestrud; Dietrich, William E.; Brimhall, George H. GSA Bulletin, Vol. 114, Issue 9 https://doi.org/10.1130/0016-7606(2002)114<1143:WPMBAA>2.0.CO;2	journal	September 2002
Fractionation of Fe isotopes by soil microbes and organic acids Brantley, Susan L.; Liermann, Laura; Bullen, Thomas D. Geology, Vol. 29, Issue 6 https://doi.org/10.1130/0091-7613(2001)029<0535:FOFIBS>2.0.CO;2	journal	January 2001
Rates and time scales of clay-mineral formation by weathering in saprolitic regoliths of the southern Appalachians from geochemical mass balance Price, Jason R.; Velbel, Michael A.; Patino, Lina C. Geological Society of America Bulletin, Vol. 117, Issue 5 https://doi.org/10.1130/B25547.1	journal	January 2005
Iron isotope fractionation during microbial reduction of iron: The importance of adsorption Icopini, G. A.; Anbar, A. D.; Ruebush, S. S. Geology, Vol. 32, Issue 3 https://doi.org/10.1130/G20184.1	journal	January 2004
Aluminum compounds in soil solutions and their migration in podzolic soils on two-layered deposits Tolpeshta, I. I.; Sokolova, T. A. Eurasian Soil Science, Vol. 42, Issue 1 https://doi.org/10.1134/S1064229309010049	journal	January 2009
Iron-Oxidizing Bacteria: An Environmental and Genomic Perspective Emerson, David; Fleming, Emily J.; McBeth, Joyce M. Annual Review of Microbiology, Vol. 64, Issue 1 https://doi.org/10.1146/annurev.micro.112408.134208	journal	October 2010
A Statistical-Topographic Model for Mapping Climatological Precipitation over Mountainous Terrain Daly, Christopher; Neilson, Ronald P.; Phillips, Donald L. Journal of Applied Meteorology, Vol. 33, Issue 2 https://doi.org/10.1175/1520-0450(1994)033<0140:ASTMFM>2.0.CO;2	journal	February 1994
Biotite Alteration in Deeply Weathered Granite. I. Morphological, Mineralogical, and Chemical Properties Gilkes, R. J. Clays and Clay Minerals, Vol. 27, Issue 5 https://doi.org/10.1346/CCMN.1979.0270505	journal	January 1979
Weathering of Iron-Bearing Minerals in Soils and Saprolite on the North Carolina Blue Ridge Front: II. Clay Mineralogy Graham, R. C. Clays and Clay Minerals, Vol. 37, Issue 1 https://doi.org/10.1346/CCMN.1989.0370104	journal	January 1989
The Dependence of Localized Crystallization of Halloysite and Kaolinite on Primary Minerals in the Weathering Profile of Granite Jeong, Gi Young Clays and Clay Minerals, Vol. 48, Issue 2 https://doi.org/10.1346/CCMN.2000.0480205	journal	January 2000
Progressive Stages in the Formation of Kaolin Minerals of Different Morphologies in the Weathering of Plagioclase Papoulis, Dimitris; Tsolis-Katagas, Panayota; Katagas, Christos Clays and Clay Minerals, Vol. 52, Issue 3 https://doi.org/10.1346/CCMN.2004.0520303	journal	June 2004
Microbial formation of a halloysite-like mineral Tazaki, Kazue clays and clay minerals, Vol. 53, Issue 3 https://doi.org/10.1346/CCMN.2005.0530303	journal	June 2005
A Study of a Deep Weathering Profile on Granite in Peninsular Malaysia: III. Alteration of Feldspars Eswaran, H.; Bin, Wong Chaw Soil Science Society of America Journal, Vol. 42, Issue 1 https://doi.org/10.2136/sssaj1978.03615995004200010034x	journal	January 1978
Mineralogical Characteristics and Transformations of a Vertical Rock-Saprolite-Soil Sequence in the North Carolina Piedmont: I. Profile Morphology, Chemical Composition, and Mineralogy Calvert, C. S.; Buol, S. W.; Weed, S. B. Soil Science Society of America Journal, Vol. 44, Issue 5 https://doi.org/10.2136/sssaj1980.03615995004400050044x	journal	September 1980
Mineralogical Characteristics and Transformations of a Vertical Rock-Saprolite-Soil Sequence in the North Carolina Piedmont: II. Feldspar Alteration Products-Their Transformations Through the Profile Calvert, C. S.; Buol, S. W.; Weed, S. B. Soil Science Society of America Journal, Vol. 44, Issue 5 https://doi.org/10.2136/sssaj1980.03615995004400050045x	journal	September 1980
Soil-Saprolite Profiles Derived from Mafic Rocks in the North Carolina Piedmont: I. Chemical, Morphological, and Mineralogical Characteristics and Transformations Rice, T. J.; Buol, S. W.; Weed, S. B. Soil Science Society of America Journal, Vol. 49, Issue 1 https://doi.org/10.2136/sssaj1985.03615995004900010035x	journal	January 1985
Characterization and Genesis of Saprolite Derived from Gneissic Rocks of Virginia Stolt, M. H.; Baker, J. C.; Simpson, T. W. Soil Science Society of America Journal, Vol. 56, Issue 2 https://doi.org/10.2136/sssaj1992.03615995005600020030x	journal	March 1992
Iron Isotope Fractionation during Pedogenesis in Redoximorphic Soils Wiederhold, Jan G.; Teutsch, Nadya; Kraemer, Stephan M. Soil Science Society of America Journal, Vol. 71, Issue 6 https://doi.org/10.2136/sssaj2006.0379	journal	November 2007
Halloysite Nanotubes and Bacteria at the Saprolite-Bedrock Interface, Rio Icacos Watershed, Puerto Rico Minyard, Morgan L.; Bruns, Mary Ann; Martínez, Carmen E. Soil Science Society of America Journal, Vol. 75, Issue 2 https://doi.org/10.2136/sssaj2010.0126nps	journal	March 2011
Hot Spots and Hot Moments of Dissolved Organic Carbon Export and Soil Organic Carbon Storage in the Shale Hills Catchment Andrews, Danielle M.; Lin, Henry; Zhu, Qing Vadose Zone Journal, Vol. 10, Issue 3 https://doi.org/10.2136/vzj2010.0149	journal	January 2011
Characterization of deep weathering and nanoporosity development in shale--A neutron study Jin, L.; Rother, G.; Cole, D. R. American Mineralogist, Vol. 96, Issue 4 https://doi.org/10.2138/am.2011.3598	journal	March 2011
How Deep Is Soil? Richter, Daniel D.; Markewitz, Daniel BioScience, Vol. 45, Issue 9 https://doi.org/10.2307/1312764	journal	October 1995
Patterns of Nutrient Loss from Unpolluted, Old-Growth Temperate Forests: Evaluation of Biogeochemical Theory Hedin, Lars O.; Armesto, Juan J.; Johnson, Arthur H. Ecology, Vol. 76, Issue 2 https://doi.org/10.2307/1941208	journal	March 1995
The evolution of Appalachian fluviokarst White, William Journal of Cave and Karst Studies https://doi.org/10.4311/jcks2008es0046	journal	January 2009

Similar Records

CHEMISTRY OF ISOTOPE FRACTIONATION

Journal Article · 1958 · Chem. Weekblad · OSTI ID:4173170

de Vries, A E

Fractionation of Fe isotopes during Fe(II) oxidation by a marine photoferrotroph is controlled by the formation of organic Fe-complexes and colloidal Fe fractions

Journal Article · 2015 · Geochimica et Cosmochimica Acta · OSTI ID:1247754

Swanner, Elizabeth D.; Wu, Wenfang; Schoenberg, Ronny; +4 more

MINERALOGIC AND ISOTOPIC INVESTIGATIONS ON LUNAR ROCK 12013.

Journal Article · 1969 · Earth Planet. Sci. Lett. 9: 137-63(Sep 1970). · OSTI ID:4107425

Albee, A L; Burnett, D S; Chodos, A A

Title: Investigation of a diabase-derived regolith profile from Pennsylvania: Mineralogy, chemistry and Fe isotope fractionation

Citation Formats

References (76)

Similar Records

Related Subjects