X-ray absorption spectroscopy characterization of embedded and extracted nano-oxides
Abstract
Here, the chemistries and structures of both embedded and extracted Ysingle bondTisingle bondO nanometer-scale oxides in a nanostructured ferritic alloy (NFA) were probed by x-ray absorption spectroscopy (XAS). Y2Ti2O7 is the primary embedded phase, while the slightly larger extracted oxides are primarily Y2TiO5. Analysis of the embedded nano-oxides is difficult partly due to the multiple Ti environments associated with different oxides and those still residing in matrix lattice sites. Thus, bulk extraction followed by selective filtration was used to isolate the larger Y2TiO5 oxides for XAS, while the smaller predominant embedded phase Y2Ti2O7 oxides passed through the filters and were analyzed using the log-ratio method.
- Authors:
-
- Univ. of California, Santa Barbara, CA (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Univ. of Idaho, Moscow, ID (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Nuclear Physics (NP); USDOE Office of Science (SC), Fusion Energy Sciences (FES); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1357955
- Alternate Identifier(s):
- OSTI ID: 1416775
- Report Number(s):
- BNL-113799-2017-JA
Journal ID: ISSN 0925-8388
- Grant/Contract Number:
- SC00112704; FG03-94ER54275; AC02-98CH10886; SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Alloys and Compounds
- Additional Journal Information:
- Journal Volume: 699; Journal Issue: C; Journal ID: ISSN 0925-8388
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 73 NUCLEAR PHYSICS AND RADIATION PHYSICS; nanostructured materials; nuclear reactor materials; synchrotron radiation; EXAFS
Citation Formats
Stan, Tiberiu, Sprouster, David J., Ofan, Avishai, Odette, G. Robert, Ecker, Lynne E., and Charit, Indrajit. X-ray absorption spectroscopy characterization of embedded and extracted nano-oxides. United States: N. p., 2016.
Web. doi:10.1016/j.jallcom.2016.12.350.
Stan, Tiberiu, Sprouster, David J., Ofan, Avishai, Odette, G. Robert, Ecker, Lynne E., & Charit, Indrajit. X-ray absorption spectroscopy characterization of embedded and extracted nano-oxides. United States. https://doi.org/10.1016/j.jallcom.2016.12.350
Stan, Tiberiu, Sprouster, David J., Ofan, Avishai, Odette, G. Robert, Ecker, Lynne E., and Charit, Indrajit. Thu .
"X-ray absorption spectroscopy characterization of embedded and extracted nano-oxides". United States. https://doi.org/10.1016/j.jallcom.2016.12.350. https://www.osti.gov/servlets/purl/1357955.
@article{osti_1357955,
title = {X-ray absorption spectroscopy characterization of embedded and extracted nano-oxides},
author = {Stan, Tiberiu and Sprouster, David J. and Ofan, Avishai and Odette, G. Robert and Ecker, Lynne E. and Charit, Indrajit},
abstractNote = {Here, the chemistries and structures of both embedded and extracted Ysingle bondTisingle bondO nanometer-scale oxides in a nanostructured ferritic alloy (NFA) were probed by x-ray absorption spectroscopy (XAS). Y2Ti2O7 is the primary embedded phase, while the slightly larger extracted oxides are primarily Y2TiO5. Analysis of the embedded nano-oxides is difficult partly due to the multiple Ti environments associated with different oxides and those still residing in matrix lattice sites. Thus, bulk extraction followed by selective filtration was used to isolate the larger Y2TiO5 oxides for XAS, while the smaller predominant embedded phase Y2Ti2O7 oxides passed through the filters and were analyzed using the log-ratio method.},
doi = {10.1016/j.jallcom.2016.12.350},
journal = {Journal of Alloys and Compounds},
number = C,
volume = 699,
place = {United States},
year = {Thu Dec 29 00:00:00 EST 2016},
month = {Thu Dec 29 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Recent Progress in Developing and Qualifying Nanostructured Ferritic Alloys for Advanced Fission and Fusion Applications
journal, November 2014
- Odette, G. R.
- JOM, Vol. 66, Issue 12
Irradiation-tolerant nanostructured ferritic alloys: Transforming helium from a liability to an asset
journal, September 2010
- Odette, G. R.; Hoelzer, D. T.
- JOM, Vol. 62, Issue 9
Structural materials for fission & fusion energy
journal, November 2009
- Zinkle, Steven J.; Busby, Jeremy T.
- Materials Today, Vol. 12, Issue 11
On the remarkable thermal stability of nanostructured ferritic alloys
journal, September 2014
- Cunningham, N.; Wu, Y.; Klingensmith, D.
- Materials Science and Engineering: A, Vol. 613
Effect of bulk oxygen on 14YWT nanostructured ferritic alloys
journal, January 2014
- Cunningham, N. J.; Wu, Y.; Etienne, A.
- Journal of Nuclear Materials, Vol. 444, Issue 1-3
Core/shell structures of oxygen-rich nanofeatures in oxide-dispersion strengthened Fe–Cr alloys
journal, November 2008
- Marquis, Emmanuelle A.
- Applied Physics Letters, Vol. 93, Issue 18, Article No. 181904
The formation and evolution of oxide particles in oxide-dispersion-strengthened ferritic steels during processing
journal, April 2013
- Williams, Ceri A.; Unifantowicz, Paulina; Baluc, Nadine
- Acta Materialia, Vol. 61, Issue 6
Three-dimensional atom probe observation of nanoscale titanium-oxygen clustering in an oxide-dispersion-strengthened Fe-12Cr-3W-0.4Ti + Y2O3 ferritic alloy
journal, February 2001
- Larson, D. J.; Maziasz, P. J.; Kim, I-S
- Scripta Materialia, Vol. 44, Issue 2
Atom probe tomography of nanoscale particles in ODS ferritic alloys
journal, July 2003
- Miller, M. K.; Kenik, E. A.; Russell, K. F.
- Materials Science and Engineering: A, Vol. 353, Issue 1-2
The crystal structure, orientation relationships and interfaces of the nanoscale oxides in nanostructured ferritic alloys
journal, June 2016
- Wu, Yuan; Ciston, Jim; Kräemer, Stephan
- Acta Materialia, Vol. 111
Transmission electron microscopy characterization of the nanofeatures in nanostructured ferritic alloy MA957
journal, May 2012
- Wu, Y.; Haney, E. M.; Cunningham, N. J.
- Acta Materialia, Vol. 60, Issue 8
Comparison of the neutron and ion irradiation response of nano-oxides in oxide dispersion strengthened materials
journal, July 2015
- Ribis, Joël; Bordas, Eric; Trocellier, Patrick
- Journal of Materials Research, Vol. 30, Issue 14
Influence of nano-particle coherency degree on the coarsening resistivity of the nano-oxide particles of Fe–14Cr–1W ODS alloys
journal, December 2014
- Zhong, S. Y.; Ribis, J.; Lochet, N.
- Journal of Nuclear Materials, Vol. 455, Issue 1-3
Interfacial strained structure and orientation relationships of the nanosized oxide particles deduced from elasticity-driven morphology in oxide dispersion strengthened materials
journal, January 2012
- Ribis, J.; de Carlan, Y.
- Acta Materialia, Vol. 60, Issue 1
New insights into the chemical structure of Y2Ti2O7−δ nanoparticles in oxide dispersion-strengthened steels designed for sodium fast reactors by electron energy-loss spectroscopy
journal, January 2015
- Badjeck, V.; Walls, M. G.; Chaffron, L.
- Journal of Nuclear Materials, Vol. 456
Characterisation of nanosized oxides in ODM401 oxide dispersion strengthened steel
journal, January 2014
- Dawson, Karl; Tatlock, Gordon J.
- Journal of Nuclear Materials, Vol. 444, Issue 1-3
A new method for the quantitative analysis of the scale and composition of nanosized oxide in 9Cr-ODS steel
journal, October 2009
- Ohnuma, M.; Suzuki, J.; Ohtsuka, S.
- Acta Materialia, Vol. 57, Issue 18
Chemical composition of nano-phases studied by anomalous small-angle X-ray scattering: Application to oxide nano-particles in ODS steels
journal, January 2014
- Dumont, Myriam; Commin, Lorelei; Morfin, Isabelle
- Materials Characterization, Vol. 87
On the role of alloy composition and processing parameters in nanocluster formation and dispersion strengthening in nanostuctured ferritic alloys
journal, January 2009
- Alinger, M. J.; Odette, G. R.; Hoelzer, D. T.
- Acta Materialia, Vol. 57, Issue 2
Evidence for core–shell nanoclusters in oxygen dispersion strengthened steels measured using X-ray absorption spectroscopy
journal, February 2014
- Liu, S.; Odette, G. R.; Segre, C. U.
- Journal of Nuclear Materials, Vol. 445, Issue 1-3
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Application of the ratio method of EXAFS analysis to disordered systems
journal, April 1983
- Bunker, Grant
- Nuclear Instruments and Methods in Physics Research, Vol. 207, Issue 3
Extended x-ray-absorption fine-structure measurements of copper: Local dynamics, anharmonicity, and thermal expansion
journal, November 2004
- Fornasini, P.; a. Beccara, S.; Dalba, G.
- Physical Review B, Vol. 70, Issue 17
Study of the edges of transition metals in pure and oxide form by x-ray-absorption spectroscopy
journal, February 1983
- Grunes, L. A.
- Physical Review B, Vol. 27, Issue 4
Ti -edge XANES studies of Ti coordination and disorder in oxide compounds: Comparison between theory and experiment
journal, July 1997
- Farges, François; Brown, Gordon E.; Rehr, J. J.
- Physical Review B, Vol. 56, Issue 4
Size-dependent characterization of embedded Ge nanocrystals: Structural and thermal properties
journal, September 2008
- Araujo, L. L.; Giulian, R.; Sprouster, D. J.
- Physical Review B, Vol. 78, Issue 9
A View from the Inside: Complexity in the Atomic Scale Ordering of Supported Metal Nanoparticles
journal, December 2001
- Frenkel, Anatoly I.; Hills, Charles W.; Nuzzo, Ralph G.
- The Journal of Physical Chemistry B, Vol. 105, Issue 51