Nonicosahedral boron allotrope synthesized at high pressure and high temperature
Abstract
Theoretical predictions of pressure-induced phase transformations often become long-standing enigmas because of limitations of contemporary available experimental possibilities. Hitherto the existence of a nonicosahedral boron allotrope has been one of them. Here we report on a nonicosahedral boron allotrope, which we denoted as ζ -B, with the orthorhombic α-Ga-type structure (space group Cmce) synthesized in a diamond-anvil cell at extreme high-pressure high-temperature conditions (115 GPa and 2100 K). The structure of ζ -B was solved using single-crystal synchrotron x-ray diffraction and its compressional behavior was studied in the range of very high pressures (115–135 GPa). Here,experimental validation of theoretical predictions reveals the degree of our up-to-date comprehension of condensed matter and promotes further development of solid-state physics and chemistry.
- Authors:
-
- Univ. of Bayreuth (Germany)
- Univ. of Chicago, Argonne, IL (United States)
- Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
- European Synchrotron Radiation Facility, Grenoble Cedex (France)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Science Foundation (NSF); German Research Foundation (DFG)
- OSTI Identifier:
- 1357640
- Alternate Identifier(s):
- OSTI ID: 1357309
- Grant/Contract Number:
- AC02-06CH11357; FG02-94ER14466; EAR-1128799; 5K13WC3; DU 954-6/1; DU 954-6/2; DU 954-8/1; DU 393-9/1; DU 393-10/1
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 95; Journal Issue: 18; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 36 MATERIALS SCIENCE; zeta-boron; gamma-boron; betta-boron; single crystal X-ray diffraction; alfa-Ga structural type; high-pressure high-temperature phase transition; pressure effects; structural properties; crystal structures; polycrystalline materials; single crystal materials; pressure techniques; X-ray diffraction; X-ray powder diffraction
Citation Formats
Chuvashova, Irina, Bykova, Elena, Bykov, Maxim, Prakapenka, Vitali, Glazyrin, Konstantin, Mezouar, Mohamed, Dubrovinsky, Leonid, and Dubrovinskaia, Natalia. Nonicosahedral boron allotrope synthesized at high pressure and high temperature. United States: N. p., 2017.
Web. doi:10.1103/PhysRevB.95.180102.
Chuvashova, Irina, Bykova, Elena, Bykov, Maxim, Prakapenka, Vitali, Glazyrin, Konstantin, Mezouar, Mohamed, Dubrovinsky, Leonid, & Dubrovinskaia, Natalia. Nonicosahedral boron allotrope synthesized at high pressure and high temperature. United States. https://doi.org/10.1103/PhysRevB.95.180102
Chuvashova, Irina, Bykova, Elena, Bykov, Maxim, Prakapenka, Vitali, Glazyrin, Konstantin, Mezouar, Mohamed, Dubrovinsky, Leonid, and Dubrovinskaia, Natalia. Tue .
"Nonicosahedral boron allotrope synthesized at high pressure and high temperature". United States. https://doi.org/10.1103/PhysRevB.95.180102. https://www.osti.gov/servlets/purl/1357640.
@article{osti_1357640,
title = {Nonicosahedral boron allotrope synthesized at high pressure and high temperature},
author = {Chuvashova, Irina and Bykova, Elena and Bykov, Maxim and Prakapenka, Vitali and Glazyrin, Konstantin and Mezouar, Mohamed and Dubrovinsky, Leonid and Dubrovinskaia, Natalia},
abstractNote = {Theoretical predictions of pressure-induced phase transformations often become long-standing enigmas because of limitations of contemporary available experimental possibilities. Hitherto the existence of a nonicosahedral boron allotrope has been one of them. Here we report on a nonicosahedral boron allotrope, which we denoted as ζ -B, with the orthorhombic α-Ga-type structure (space group Cmce) synthesized in a diamond-anvil cell at extreme high-pressure high-temperature conditions (115 GPa and 2100 K). The structure of ζ -B was solved using single-crystal synchrotron x-ray diffraction and its compressional behavior was studied in the range of very high pressures (115–135 GPa). Here,experimental validation of theoretical predictions reveals the degree of our up-to-date comprehension of condensed matter and promotes further development of solid-state physics and chemistry.},
doi = {10.1103/PhysRevB.95.180102},
journal = {Physical Review B},
number = 18,
volume = 95,
place = {United States},
year = {Tue May 16 00:00:00 EDT 2017},
month = {Tue May 16 00:00:00 EDT 2017}
}
Web of Science
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