Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides
Abstract
Materials composed of two dimensional layers bonded to one another through weak van der Waals interactions often exhibit strongly anisotropic behaviors and can be cleaved into very thin specimens and sometimes into monolayer crystals. Interest in such materials is driven by the study of low dimensional physics and the design of functional heterostructures. Binary compounds with the compositions MX2 and MX3 where M is a metal cation and X is a halogen anion often form such structures. Magnetism can be incorporated by choosing a transition metal with a partially filled d-shell for M, enabling ferroic responses for enhanced functionality. Here we give a brief overview of binary transition metal dihalides and trihalides, summarizing their crystallographic properties and long-range-ordered magnetic structures, focusing on those materials with layered crystal structures and partially filled d-shells required for combining low dimensionality and cleavability with magnetism.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1356933
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Crystals
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 5; Journal ID: ISSN 2073-4352
- Publisher:
- MDPI
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; layered materials; van der Waals; monolayer; transition metal compounds; halides; crystal structure; magnetism; magnetic structure
Citation Formats
McGuire, Michael A. Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides. United States: N. p., 2017.
Web. doi:10.3390/cryst7050121.
McGuire, Michael A. Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides. United States. https://doi.org/10.3390/cryst7050121
McGuire, Michael A. Thu .
"Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides". United States. https://doi.org/10.3390/cryst7050121. https://www.osti.gov/servlets/purl/1356933.
@article{osti_1356933,
title = {Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides},
author = {McGuire, Michael A.},
abstractNote = {Materials composed of two dimensional layers bonded to one another through weak van der Waals interactions often exhibit strongly anisotropic behaviors and can be cleaved into very thin specimens and sometimes into monolayer crystals. Interest in such materials is driven by the study of low dimensional physics and the design of functional heterostructures. Binary compounds with the compositions MX2 and MX3 where M is a metal cation and X is a halogen anion often form such structures. Magnetism can be incorporated by choosing a transition metal with a partially filled d-shell for M, enabling ferroic responses for enhanced functionality. Here we give a brief overview of binary transition metal dihalides and trihalides, summarizing their crystallographic properties and long-range-ordered magnetic structures, focusing on those materials with layered crystal structures and partially filled d-shells required for combining low dimensionality and cleavability with magnetism.},
doi = {10.3390/cryst7050121},
journal = {Crystals},
number = 5,
volume = 7,
place = {United States},
year = {Thu Apr 27 00:00:00 EDT 2017},
month = {Thu Apr 27 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Darstellung und Kristallstruktur von Titandibromid
journal, October 1961
- Ehrlich, Paul; Gutsche, Walter; Seifert, Hans-Joachim
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 312, Issue 1-2
Optical and neutron diffraction study of the magnetic phase diagram of NiBr 2
journal, July 1976
- Day, P.; Dinsdale, A.; Krausz, E. R.
- Journal of Physics C: Solid State Physics, Vol. 9, Issue 13
Dynamics of a Two-Dimensional Quantum Spin Liquid: Signatures of Emergent Majorana Fermions and Fluxes
journal, May 2014
- Knolle, J.; Kovrizhin, D. L.; Chalker, J. T.
- Physical Review Letters, Vol. 112, Issue 20
X‐Ray Diffraction and Nuclear Quadrupole Resonance Studies of Chromium Trichloride
journal, April 1964
- Morosin, Bruno; Narath, Albert
- The Journal of Chemical Physics, Vol. 40, Issue 7
Neutron Scattering Study of the Triangular-Lattice Antiferromagnet VBr 2
journal, January 1985
- Kadowaki, Hiroaki; Ubukoshi, Koji; Hirakawa, Kinshiro
- Journal of the Physical Society of Japan, Vol. 54, Issue 1
Rearrangement of van der Waals stacking and formation of a singlet state at T = 90 K in a cluster magnet
journal, January 2017
- Sheckelton, John P.; Plumb, Kemp W.; Trump, Benjamin A.
- Inorganic Chemistry Frontiers, Vol. 4, Issue 3
Neue Untersuchungen �ber die Chloride des Molybd�ns
journal, September 1967
- Sch�fer, H.; Schnering, H. -G. V.; Tillack, J.
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 353, Issue 5-6
Strukturuntersuchungen an Rhodiumhalogeniden
journal, January 1968
- Brodersen, K.; Thiele, G.; Recke, I.
- Journal of the Less Common Metals, Vol. 14, Issue 1
Magnetic ordering and multiferroicity in MnI
journal, October 2012
- Wu, Xianxin; Cai, Yingxiang; Xie, Qing
- Physical Review B, Vol. 86, Issue 13
β-Technetium Trichloride: Formation, Structure, and First-Principles Calculations
journal, April 2012
- Poineau, Frederic; Johnstone, Erik V.; Weck, Philippe F.
- Inorganic Chemistry, Vol. 51, Issue 9
Magnetic-Field Induced Competition of Two Multiferroic Orders in a Triangular-Lattice Helimagnet
journal, April 2011
- Kurumaji, T.; Seki, S.; Ishiwata, S.
- Physical Review Letters, Vol. 106, Issue 16
Coupling of Crystal Structure and Magnetism in the Layered, Ferromagnetic Insulator CrI 3
journal, January 2015
- McGuire, Michael A.; Dixit, Hemant; Cooper, Valentino R.
- Chemistry of Materials, Vol. 27, Issue 2
Electronic and magnetic properties of metal diiodides MI 2 (M=V, Cr, Mn, Fe, Co, Ni, and Cd) from 129 I Mössbauer spectroscopy
journal, December 1976
- Friedt, J. M.; Sanchez, J. P.; Shenoy, G. K.
- The Journal of Chemical Physics, Vol. 65, Issue 12
First-order magnetic transition in CoI2
journal, February 1992
- Mekata, M.; Kuriyama, H.; Ajiro, Y.
- Journal of Magnetism and Magnetic Materials, Vol. 104-107
Specific Heat of Single-Crystal Mn in Applied Magnetic Fields
journal, November 1962
- Murray, R. B.
- Physical Review, Vol. 128, Issue 4
The preparation and crystallographic properties of certain lanthanide and actinide tribromides and tribromide hexahydrates
journal, January 1968
- Brown, D.; Fletcher, S.; Holah, D. G.
- Journal of the Chemical Society A: Inorganic, Physical, Theoretical
Sublattice magnetization in Fe below the critical region
journal, December 1974
- Oosterhuis, W. T.; Window, B.; Spartalian, K.
- Physical Review B, Vol. 10, Issue 11
: A spin-orbit assisted Mott insulator on a honeycomb lattice
journal, July 2014
- Plumb, K. W.; Clancy, J. P.; Sandilands, L. J.
- Physical Review B, Vol. 90, Issue 4
Note on the Crystal Structure of Vanadium Dichloride.
journal, January 1959
- Villadsen, Jørgen; Hauge, Sverre; Jørgensen, Peer Møller
- Acta Chemica Scandinavica, Vol. 13
Single crystal x-ray study of structural polytypism in cadmium bromide
journal, November 1962
- Mitchell, Richard S.
- Zeitschrift für Kristallographie, Vol. 117, Issue 4
Neutron-scattering studies of a phase transition in the metamagnet under external magnetic fields
journal, May 1997
- Katsumata, K.; Katori, H. Aruga; Shapiro, S. M.
- Physical Review B, Vol. 55, Issue 17
Exact Results for Spin Dynamics and Fractionalization in the Kitaev Model
journal, June 2007
- Baskaran, G.; Mandal, Saptarshi; Shankar, R.
- Physical Review Letters, Vol. 98, Issue 24
On the Magnetic Properties of a CrBr 3 Single Crystal
journal, September 1960
- Tsubokawa, Ichiro
- Journal of the Physical Society of Japan, Vol. 15, Issue 9
Crystal structure and magnetism in : An ab initio study
journal, April 2016
- Kim, Heung-Sik; Kee, Hae-Young
- Physical Review B, Vol. 93, Issue 15
Synthesis and structure of an infinite-chain form of ZrI2 (α)
journal, April 1981
- Guthrie, Dennis H.; Corbett, John D.
- Journal of Solid State Chemistry, Vol. 37, Issue 2
Effect of Hydrostatic Pressure on the Metamagnetic Transitions in FeCl 2 ·2H 2 O, CoCl 2 ·2H 2 O, FeCl 2 , and FeBr 2
journal, March 1966
- Narath, Albert; Schirber, J. E.
- Journal of Applied Physics, Vol. 37, Issue 3
The structure of TiCl2
journal, November 1948
- Baenziger, N. C.; Rundle, R. E.
- Acta Crystallographica, Vol. 1, Issue 5
Low-temperature crystal and magnetic structure of
journal, April 2016
- Cao, H. B.; Banerjee, A.; Yan, J. -Q.
- Physical Review B, Vol. 93, Issue 13
Exploration of new ferromagnetic, semiconducting and biocompatible Nb 3 X 8 (X = Cl, Br or I) monolayers with considerable visible and infrared light absorption
journal, January 2017
- Jiang, Junke; Liang, Qiuhua; Meng, Ruishen
- Nanoscale, Vol. 9, Issue 9
Proximate Kitaev quantum spin liquid behaviour in a honeycomb magnet
journal, April 2016
- Banerjee, A.; Bridges, C. A.; Yan, J. -Q.
- Nature Materials, Vol. 15, Issue 7
Exfoliating biocompatible ferromagnetic Cr-trihalide monolayers
journal, January 2016
- Liu, Junyi; Sun, Qiang; Kawazoe, Yoshiyuki
- Physical Chemistry Chemical Physics, Vol. 18, Issue 13
Anyons in an exactly solved model and beyond
journal, January 2006
- Kitaev, Alexei
- Annals of Physics, Vol. 321, Issue 1
Successive phase transitions in the hexagonal-layered Heisenberg antiferromagnets MnX2 (X = Br, I)
journal, August 1995
- Sato, T.; Kadowaki, H.; Iio, K.
- Physica B: Condensed Matter, Vol. 213-214
Magnetic order in : A honeycomb-lattice quantum magnet with strong spin-orbit coupling
journal, April 2015
- Sears, J. A.; Songvilay, M.; Plumb, K. W.
- Physical Review B, Vol. 91, Issue 14
Neutron Diffraction Investigation of the Magnetic Order in Mn
journal, March 1962
- Cable, J. W.; Wilkinson, M. K.; Wollan, E. O.
- Physical Review, Vol. 125, Issue 6
Die Kristallstrukturen von ScCl3, TiCl3 und VCl3
journal, May 1947
- Klemm, Wilhelm; Krose, Ehrhard
- Zeitschrift f�r anorganische Chemie, Vol. 253, Issue 3-4
Magnetoelectric responses induced by domain rearrangement and spin structural change in triangular-lattice helimagnets NiI and CoI
journal, January 2013
- Kurumaji, T.; Seki, S.; Ishiwata, S.
- Physical Review B, Vol. 87, Issue 1
Multiferroicity in NiBr with long-wavelength cycloidal spin structure on a triangular lattice
journal, August 2011
- Tokunaga, Y.; Okuyama, D.; Kurumaji, T.
- Physical Review B, Vol. 84, Issue 6
Transition De Phase Metamagnetique Du Bromure Ferreux
journal, January 1973
- Fert, A. R.; Carrara, P.; Lanusse, M. C.
- Journal of Physics and Chemistry of Solids, Vol. 34, Issue 2
Heat Capacity and Entropy of CoCl 2 and MnCl 2 from 11° to 300°K. Thermal Anomaly Associated with Antiferromagnetic Ordering in CoCl 2
journal, February 1962
- Chisholm, R. C.; Stout, J. W.
- The Journal of Chemical Physics, Vol. 36, Issue 4
Neutron diffraction study of the commensurate and incommensurate magnetic structures of NiBr2
journal, July 1980
- Adam, A.; Billerey, D.; Terrier, C.
- Solid State Communications, Vol. 35, Issue 1
Low‐Temperature Magnetic Susceptibility of FeCl 3
journal, June 1969
- Jones, Edwin R.; Morton, O. B.; Cathey, L.
- The Journal of Chemical Physics, Vol. 50, Issue 11
Single crystal structure refinement of MnCl2
journal, January 1990
- Tornero, J. D.; Fayos, J.
- Zeitschrift für Kristallographie - Crystalline Materials, Vol. 192, Issue 1-4
Yttrium triiodide, YI 3
journal, July 2005
- Jongen, Liesbet; Meyer, Gerd
- Acta Crystallographica Section E Structure Reports Online, Vol. 61, Issue 8
Mössbauer-Effect Measurements in Antiferromagnetic Fe
journal, November 1973
- Stampfel, J. P.; Oosterhuis, W. T.; Window, B.
- Physical Review B, Vol. 8, Issue 9
Neutron Scattering Investigation of the Magnetic Excitations in CoBr 2
journal, January 1980
- Yoshizawa, Hideki; Ubukoshi, Koji; Hirakawa, Kinshiro
- Journal of the Physical Society of Japan, Vol. 48, Issue 1
Electronic structure and magnetic ordering of the semiconducting chromium trihalides CrCl 3 , CrBr 3 , and CrI 3
journal, March 2011
- Wang, H.; Eyert, V.; Schwingenschlögl, U.
- Journal of Physics: Condensed Matter, Vol. 23, Issue 11
Antiferromagnetic spintronics
journal, March 2016
- Jungwirth, T.; Marti, X.; Wadley, P.
- Nature Nanotechnology, Vol. 11, Issue 3
Die Kristallstruktur der Verbindung Nb3Cl8
journal, January 1961
- v. Schnering, H. -G.; Wöhrle, H.; Schäfer, H.
- Naturwissenschaften, Vol. 48, Issue 6
Pressure-induced magnetic and electronic transitions in the layered Mott insulator
journal, December 2001
- Pasternak, M. P.; Xu, W. M.; Rozenberg, G. Kh.
- Physical Review B, Vol. 65, Issue 3
Neutron diffraction investigation of antiferromagnetism in CrCl3
journal, April 1961
- Cable, J. W.; Wilkinson, M. K.; Wollan, E. O.
- Journal of Physics and Chemistry of Solids, Vol. 19, Issue 1-2
Anhydrous Ruthenium Chlorides
journal, September 1963
- Fletcher, J. M.; Gardner, W. E.; Hooper, E. W.
- Nature, Vol. 199, Issue 4898
Robust intrinsic ferromagnetism and half semiconductivity in stable two-dimensional single-layer chromium trihalides
journal, January 2015
- Zhang, Wei-Bing; Qu, Qian; Zhu, Peng
- Journal of Materials Chemistry C, Vol. 3, Issue 48
The Crystal Structures of Yttrium Trichloride and Similar Compounds
journal, November 1954
- Templeton, D. H.; Carter, Giles F.
- The Journal of Physical Chemistry, Vol. 58, Issue 11
Manifestation of long-range ordered state in layered VX 2 (X = Cl, Br, I) systems
journal, October 2013
- Abdul Wasey, A. H. M.; Karmakar, Debjani; Das, G. P.
- Journal of Physics: Condensed Matter, Vol. 25, Issue 47
Zur Struktur des Iridium(III)- und des Ruthenium(III)-chlorids
journal, January 1965
- Brodersen, K.; Moers, F.; Schnering, H. G.
- Die Naturwissenschaften, Vol. 52, Issue 9
The Magnetic Properties of the Iron Group Anhydrous Chlorides at Low Temperatures. I. Experimental
journal, December 1940
- Starr, C.; Bitter, F.; Kaufmann, A. R.
- Physical Review, Vol. 58, Issue 11
Novel high-temperature polymorphs of MgBr2 and MnBr2 - limits of powder diffraction for structure determination
journal, December 1992
- Schneider, M.; Kuske, P.; Lutz, H. D.
- Acta Crystallographica Section B Structural Science, Vol. 48, Issue 6
Magnetic neutron-scattering investigation of the field-induced Griffiths phase in
journal, October 1996
- Binek, Ch.; Bertrand, D.; Regnault, L. P.
- Physical Review B, Vol. 54, Issue 13
Structural Properties of Chromium(III) Iodide and Some Chromium(III) Mixed Halides
journal, February 1952
- Handy, L. L.; Gregory, N. W.
- Journal of the American Chemical Society, Vol. 74, Issue 4
Some Magnetic Properties of the Chromium ( III ) Halides at 4.2°K
journal, April 1959
- Hansen, Wilford N.
- Journal of Applied Physics, Vol. 30, Issue 4
Phase transition of a triangular lattice Ising antiferromagnet
journal, September 2010
- Katsumata, K.; Katori, H. Aruga; Kimura, S.
- Physical Review B, Vol. 82, Issue 10
Röntgenographische Untersuchungen an ZnCl2
journal, January 1959
- Brehzer, Bruno
- The Science of Nature, Vol. 46, Issue 3
On the Crystal Structure of the Chlorides of Certain Bivalent Elements
journal, September 1929
- Pauling, L.
- Proceedings of the National Academy of Sciences, Vol. 15, Issue 9
Domainlike antiferromagnetic correlations of paramagnetic : A field-induced Griffiths phase?
journal, February 1994
- Binek, C.; Kleemann, W.
- Physical Review Letters, Vol. 72, Issue 8
Die Kristallstruktur von Rhodium(III)-chlorid
journal, March 1964
- Bärnighausen, H.; Handa, B. K.
- Journal of the Less Common Metals, Vol. 6, Issue 3
Incommensurate spin structure in the low-temperature magnetic phase of NiBr 2
journal, July 1980
- Day, P.; Ziebeck, K. R. A.
- Journal of Physics C: Solid State Physics, Vol. 13, Issue 21
Anisotropic magnetism in the honeycomb system: Susceptibility, specific heat, and zero-field NMR
journal, May 2015
- Majumder, M.; Schmidt, M.; Rosner, H.
- Physical Review B, Vol. 91, Issue 18
Study of Frustration Effects in Two-Dimensional Triangular Lattice Antiferromagnets–Neutron Powder Diffraction Study of VX 2 , X≡Cl, Br and I
journal, May 1983
- Hirakawa, Kinshiro; Kadowaki, Hiroaki; Ubukoshi, Koji
- Journal of the Physical Society of Japan, Vol. 52, Issue 5
Review / Synthèse : Triangular antiferromagnets
journal, September 1997
- Collins, M. F.; Petrenko, O. A.
- Canadian Journal of Physics, Vol. 75, Issue 9
The zirconium dichloride phase region. Synthesis, structure, and photoelectron spectral studies of 3R-ZrCl2, 6T-Zr1.05Cl2, and related phases
journal, March 1979
- Cisar, Alan; Corbett, John D.; Daake, Richard L.
- Inorganic Chemistry, Vol. 18, Issue 3
Die Kristallstruktur des Nickelbromids und -jodids.
journal, January 1934
- Ketelaar, J. Α. A.
- Zeitschrift für Kristallographie - Crystalline Materials, Vol. 88, Issue 1-6
Magnetic Transition in TiCl 3
journal, October 1960
- Ogawa, Shinji
- Journal of the Physical Society of Japan, Vol. 15, Issue 10
Doping enhanced ferromagnetism and induced half-metallicity in CrI 3 monolayer
journal, May 2016
- Wang, Hongbo; Fan, Fengren; Zhu, Shasha
- EPL (Europhysics Letters), Vol. 114, Issue 4
Determination of Anomalous Superexchange in MnC and Its Graphite Intercalation Compound
journal, July 1995
- Wiesler, David G.; Suzuki, Masatsugu; Suzuki, Itsuko S.
- Physical Review Letters, Vol. 75, Issue 5
Neutron Diffraction Study of the Magnetic Properties of Mn
journal, May 1958
- Wollan, E. O.; Koehler, W. C.; Wilkinson, M. K.
- Physical Review, Vol. 110, Issue 3
Unusual Dirac half-metallicity with intrinsic ferromagnetism in vanadium trihalide monolayers
journal, January 2016
- He, Junjie; Ma, Shuangying; Lyu, Pengbo
- Journal of Materials Chemistry C, Vol. 4, Issue 13
X-Ray, infrared, and magnetic studies of α- and β-ruthenium trichloride
journal, January 1967
- Fletcher, J. M.; Gardner, W. E.; Fox, A. C.
- J. Chem. Soc. A, Vol. 0, Issue 0
Neutron diffraction study and specific heat of antiferromagnetic NiI2
journal, April 1977
- Billerey, D.; Terrier, C.; Ciret, N.
- Physics Letters A, Vol. 61, Issue 2
The Heat Capacity of Anhydrous NiCl 2 from 15 to 300°K. The Antiferromagnetic Anomaly near 52°K. Entropy and Free Energy 1
journal, September 1952
- Busey, R. H.; Giauque, W. F.
- Journal of the American Chemical Society, Vol. 74, Issue 17
Transport Reactions of Some Vanadium(III) Halides. Mixed Halide Formation
journal, January 1964
- McCarley, Robert E.; Roddy, James W.; Berry, Keith O.
- Inorganic Chemistry, Vol. 3, Issue 1
Die struktur des IrBr3 und über die ursachen der fehlordnungserscheinungen bei den in schichtenstrukturen kristallisierenden edelmetalltrihalogeniden
journal, July 1968
- Brodersen, K.; Thiele, G.; Ohnsorge, H.
- Journal of the Less Common Metals, Vol. 15, Issue 3
Structure refinement of an FeCl 3 crystal using a thin plate sample
journal, April 1989
- Hashimoto, S.; Forster, K.; Moss, S. C.
- Journal of Applied Crystallography, Vol. 22, Issue 2
Neutron Diffraction Investigations of the Magnetic Ordering in Fe , Co , Fe , and Co
journal, January 1959
- Wilkinson, M. K.; Cable, J. W.; Wollan, E. O.
- Physical Review, Vol. 113, Issue 2
Magnetization, Resonance, and Optical Properties of the Ferromagnet CrI 3
journal, March 1965
- Dillon, J. F.; Olson, C. E.
- Journal of Applied Physics, Vol. 36, Issue 3
Monoclinic crystal structure of and the zigzag antiferromagnetic ground state
journal, December 2015
- Johnson, R. D.; Williams, S. C.; Haghighirad, A. A.
- Physical Review B, Vol. 92, Issue 23
Neutron-Diffraction Study of Antiferromagnetic Fe
journal, August 1962
- Cable, J. W.; Wilkinson, M. K.; Wollan, E. O.
- Physical Review, Vol. 127, Issue 3
Refinement of the crystal structure of iron dibromide, FeBr2
journal, January 2001
- Haberecht, J.; Borrmann, Η.; Kniep, R.
- Zeitschrift für Kristallographie - New Crystal Structures, Vol. 216, Issue 1-4
Magnetic Ordering in CrCl3 at the Phase Transition
journal, July 1982
- Kuhlow, B.
- physica status solidi (a), Vol. 72, Issue 1
The Crystal Structure of Cadmium Iodide
journal, October 1922
- Bozorth, Richard M.
- Journal of the American Chemical Society, Vol. 44, Issue 10
Moessbauer spectroscopy and magnetization studies of .alpha.- and .beta.-ruthenium trichloride
journal, October 1992
- Kobayashi, Y.; Okada, T.; Asai, K.
- Inorganic Chemistry, Vol. 31, Issue 22
Novel Mott State Induced by Relativistic Spin-Orbit Coupling in
journal, August 2008
- Kim, B. J.; Jin, Hosub; Moon, S. J.
- Physical Review Letters, Vol. 101, Issue 7
Opportunities and challenges of 2D magnetic van der Waals materials: magnetic graphene?
journal, June 2016
- Park, Je-Geun
- Journal of Physics: Condensed Matter, Vol. 28, Issue 30
Zur Kenntnis der Dihalogenide des Titans und Vanadins
journal, March 1942
- Klemm, Wilhelm; Grimm, Ludwig
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 249, Issue 2
Van der Waals heterostructures
journal, July 2013
- Geim, A. K.; Grigorieva, I. V.
- Nature, Vol. 499, Issue 7459, p. 419-425
The different crystalline modifications of TiCl3, a catalyst component for the polymerization of α-olefins. I: α-, β-, γ-TiCl3. II: δ-TiCl3
journal, June 1961
- Natta, G.; Corradini, P.; Allegra, G.
- Journal of Polymer Science, Vol. 51, Issue 156
The Structure and Colour of Anhydrous Cobalt Chloride, CoCl2, at Room and very Low Temperatures.
journal, January 1934
- Grime, H.; Santos, J. A.
- Zeitschrift für Kristallographie - Crystalline Materials, Vol. 88, Issue 1-6
X-ray investigation of magnetostriction in NiBr2
journal, April 1992
- Nasser, J. A.; Kiat, J. M.; Gabilly, R.
- Solid State Communications, Vol. 82, Issue 1
Magnetic and structural investigations on NiI2 and CoI2
journal, November 1981
- Kuindersma, S. R.; Sanchez, J. P.; Haas, C.
- Physica B+C, Vol. 111, Issue 2-3
Evidencing the existence of exciting half-metallicity in two-dimensional TiCl3 and VCl3 sheets
journal, January 2016
- Zhou, Yungang; Lu, Haifeng; Zu, Xiaotao
- Scientific Reports, Vol. 6, Issue 1
A second infinite-chain form of zirconium diiodide (.beta.) and its coherent intergrowth with .alpha.-zirconium diiodide
journal, May 1982
- Corbett, John D.; Guthrie, Dennis H.
- Inorganic Chemistry, Vol. 21, Issue 5
Kitaev magnetism in honeycomb with intermediate spin-orbit coupling
journal, June 2015
- Kim, Heung-Sik; V., Vijay Shankar; Catuneanu, Andrei
- Physical Review B, Vol. 91, Issue 24
Susceptibilité magnétique des halogénures ferreux FeCl2, FeBr2, Fel2
journal, January 1974
- Bertrand, Y.; Fert, A. R.; Gélard, J.
- Journal de Physique, Vol. 35, Issue 4
Experimental Study of New Type Phase Transition in Triangular Lattice Antiferromagnet VCl 2
journal, November 1987
- Kadowaki, Hiroaki; Ubukoshi, Koji; Hirakawa, Kinshiro
- Journal of the Physical Society of Japan, Vol. 56, Issue 11
Spintronics of antiferromagnetic systems (Review Article)
journal, January 2014
- Gomonay, E. V.; Loktev, V. M.
- Low Temperature Physics, Vol. 40, Issue 1
Magnetic behaviour of vanadium +II in one- and two-dimensional systems
journal, January 1977
- Niel, M.; Cros, C.; Le Flem, G.
- Physica B+C, Vol. 86-88
Antiferromagnetic metal spintronics
journal, August 2011
- MacDonald, A. H.; Tsoi, M.
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 369, Issue 1948
Magnetic structures and properties of VI2
journal, May 1979
- Kuindersma, S. R.; Haas, C.; Sanchez, J. P.
- Solid State Communications, Vol. 30, Issue 6
The structure of FeCl2 at high pressures
journal, May 1975
- Vettier, C.; Yelon, W. B.
- Journal of Physics and Chemistry of Solids, Vol. 36, Issue 5
Electronic and magnetic properties of 57 Fe in NiCl 2 , NiBr 2 , NiI 2 and CoI 2 from Mossbauer spectroscopy
journal, November 1982
- Pollard, R. J.; McCann, V. H.; Ward, J. B.
- Journal of Physics C: Solid State Physics, Vol. 15, Issue 33
Pressure-induced structural, electronic, and magnetic phase transitions in studied by x-ray diffraction and resistivity measurements
journal, June 2009
- Rozenberg, G. Kh.; Pasternak, M. P.; Gorodetsky, P.
- Physical Review B, Vol. 79, Issue 21
380. The magnetic properties of some halides of titanium and zirconium
journal, January 1962
- Lewis, J.; Machin, D. J.; Newnham, I. E.
- Journal of the Chemical Society (Resumed)
Two-dimensional van der Waals materials
journal, September 2016
- Ajayan, Pulickel; Kim, Philip; Banerjee, Kaustav
- Physics Today, Vol. 69, Issue 9
Synthesis by hydrogen-driven disproportionation reactions. Synthesis and structure of the hexazirconium dodecahalide clusters Zr6Cl12 and Zr6Br12 and the double salt Zr6Cl12.M2ZrCl6 (M = sodium, potassium, cesium)
journal, January 1981
- Imoto, Hideo.; Corbett, John D.; Cisar, Alan.
- Inorganic Chemistry, Vol. 20, Issue 1
Magnetic structure of FeI2 by neutron diffraction experiments
journal, January 1974
- Gelard, J.; Fert, A. R.; Meriel, P.
- Solid State Communications, Vol. 14, Issue 2
Phase Transitions of Fel2 in high magnetic field parallel to the spin direction, static field up to 150 kOe, pulsed field up to 250 kOe
journal, October 1973
- Fert, A. R.; Gelard, J.; Carrara, P.
- Solid State Communications, Vol. 13, Issue 8
Metamagnetic Phase Transitions and Hysteresis in
journal, December 1967
- Jacobs, I. S.; Lawrence, P. E.
- Physical Review, Vol. 164, Issue 2
Field‐induced magnetic phase transitions in FeCl3
journal, March 1981
- Johnson, P. B.; Friedberg, S. A.; Rayne, J. A.
- Journal of Applied Physics, Vol. 52, Issue 3
Strongly Geometrically Frustrated Magnets
journal, August 1994
- Ramirez, A. P.
- Annual Review of Materials Science, Vol. 24, Issue 1
Die Kristallstruktur von ?-Iridium(III)-Chlorid
journal, September 1965
- Meisel, A.; Leonhardt, G.
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 339, Issue 1-2
Recent Advances in Technetium Halide Chemistry
journal, December 2013
- Poineau, Frederic; Johnstone, Erik V.; Czerwinski, Kenneth R.
- Accounts of Chemical Research, Vol. 47, Issue 2
Strongly Geometrically Frustrated Magnets
journal, January 1994
- Ramirez, A.
- Annual Review of Materials Research, Vol. 24, Issue 1
Single crystal x-ray study of structural polytypism in cadmium bromide
journal, January 1962
- Mitchell, Richard S.
- Zeitschrift für Kristallographie - Crystalline Materials, Vol. 117, Issue 1-6
The structure of FeCl2 at high pressures
journal, November 1974
- Vettier, C.; Yelon, W. B.
- Solid State Communications, Vol. 15, Issue 9
Robust Intrinsic Ferromagnetism and Half Semiconductivity in Stable Two-Dimensional Single-Layer Chromium Trihalides
text, January 2015
- Zhang, Wei-Bing; Qu, Qian; Zhu, Peng
- arXiv
β-Technetium Trichloride: Formation, Structure, and First-Principles Calculations
journal, April 2012
- Poineau, Frederic; Johnstone, Erik V.; Weck, Philippe F.
- Inorganic Chemistry, Vol. 51, Issue 9
Lanthanum and neodymium diiodide hydride phases and their hydrogen dissociation pressures
journal, February 1981
- Imoto, Hideo; Corbett, John D.
- Inorganic Chemistry, Vol. 20, Issue 2
Truth and Logic
journal, September 1940
- Kaufmann, Felix
- Philosophy and Phenomenological Research, Vol. 1, Issue 1
Works referencing / citing this record:
Synthesis and Characterization of the New Manganese Hydroxide Chloride γ-Mn(OH)Cl: Synthesis and Characterization of the New Manganese Hydroxide Chloride γ-Mn(OH)Cl
journal, November 2018
- Falkowski, Viktoria; Zeugner, Alexander; Isaeva, Anna
- European Journal of Inorganic Chemistry, Vol. 2018, Issue 42
The emerging ferroic orderings in two dimensions
journal, November 2019
- Zhang, Yupeng; Wang, Hanwen; Li, Feng
- Science China Information Sciences, Vol. 62, Issue 12
Magnetic 2D materials and heterostructures
journal, May 2019
- Gibertini, M.; Koperski, M.; Morpurgo, A. F.
- Nature Nanotechnology, Vol. 14, Issue 5
Spin tunnel field-effect transistors based on two-dimensional van der Waals heterostructures
journal, April 2019
- Jiang, Shengwei; Li, Lizhong; Wang, Zefang
- Nature Electronics, Vol. 2, Issue 4
Micromagnetometry of two-dimensional ferromagnets
journal, September 2019
- Kim, M.; Kumaravadivel, P.; Birkbeck, J.
- Nature Electronics, Vol. 2, Issue 10
Electronic and magnetic properties of monolayer α-RuCl 3 : a first-principles and Monte Carlo study
journal, January 2018
- Sarikurt, S.; Kadioglu, Y.; Ersan, F.
- Physical Chemistry Chemical Physics, Vol. 20, Issue 2
Atomically thin p–n junctions based on two-dimensional materials
journal, January 2018
- Frisenda, Riccardo; Molina-Mendoza, Aday J.; Mueller, Thomas
- Chemical Society Reviews, Vol. 47, Issue 9
Distinct spin–lattice and spin–phonon interactions in monolayer magnetic CrI 3
journal, January 2018
- Webster, Lucas; Liang, Liangbo; Yan, Jia-An
- Physical Chemistry Chemical Physics, Vol. 20, Issue 36
The enhanced ferromagnetism of single-layer CrX 3 (X = Br and I) via van der Waals engineering
journal, January 2019
- Li, Hongxing; Xu, Yuan-Kai; Lai, Kang
- Physical Chemistry Chemical Physics, Vol. 21, Issue 22
Organic molecule stabilized bismuth iodide nanoparticles: a hybrid system with multifunctional physical properties
journal, January 2020
- Ghosh, Sarit K.; Perla, Venkata K.; Mallick, Kaushik
- Physical Chemistry Chemical Physics, Vol. 22, Issue 6
Lanthanide f 7 metalloxenes – a class of intrinsic 2D ferromagnets
journal, January 2019
- Tokmachev, Andrey M.; Averyanov, Dmitry V.; Taldenkov, Alexander N.
- Materials Horizons, Vol. 6, Issue 7
High throughput study on magnetic ground states with Hubbard U corrections in transition metal dihalide monolayers
journal, January 2020
- Li, Xinru; Zhang, Zeying; Zhang, Hongbin
- Nanoscale Advances, Vol. 2, Issue 1
Microwave absorption properties of heterostructure composites of two dimensional layered magnetic materials and graphene nanosheets
journal, July 2019
- Mu, Congpu; Du, Xia; Nie, Anmin
- Applied Physics Letters, Vol. 115, Issue 4
High tunnel magnetoresistance based on 2D Dirac spin gapless semiconductor VCl 3
journal, January 2020
- Feng, Yulin; Wu, Xuming; Gao, Guoying
- Applied Physics Letters, Vol. 116, Issue 2
Pressure-induced ferromagnetism and enhanced perpendicular magnetic anisotropy of bilayer CrI 3
journal, June 2019
- Subhan, Fazle; Khan, Imran; Hong, Jisang
- Journal of Physics: Condensed Matter, Vol. 31, Issue 35
Calculating critical temperatures for ferromagnetic order in two-dimensional materials
journal, December 2018
- Torelli, Daniele; Olsen, Thomas
- 2D Materials, Vol. 6, Issue 1
High throughput computational screening for 2D ferromagnetic materials: the critical role of anisotropy and local correlations
journal, July 2019
- Torelli, Daniele; Thygesen, Kristian S.; Olsen, Thomas
- 2D Materials, Vol. 6, Issue 4
Growth and stabilization of two-dimensional multiferroics MnI 2
journal, May 2019
- Zhuo, La; Li, Yongkai; Wang, Xiangzhuo
- Materials Research Express, Vol. 6, Issue 8
Proximity exchange effects in and heterostructures with : Twist angle, layer, and gate dependence
journal, August 2019
- Zollner, Klaus; Faria Junior, Paulo E.; Fabian, Jaroslav
- Physical Review B, Vol. 100, Issue 8
Anisotropic magnetic entropy change in the hard ferromagnetic semiconductor V I 3
journal, September 2019
- Yan, J.; Luo, X.; Chen, F. C.
- Physical Review B, Vol. 100, Issue 9
Multiple ferromagnetic transitions and structural distortion in the van der Waals ferromagnet VI 3 at ambient and finite pressures
journal, September 2019
- Gati, Elena; Inagaki, Yuji; Kong, Tai
- Physical Review B, Vol. 100, Issue 9
Bulk properties of the van der Waals hard ferromagnet
journal, January 2019
- Son, Suhan; Coak, Matthew J.; Lee, Nahyun
- Physical Review B, Vol. 99, Issue 4
Microscopic Mechanism for a Higher-Spin Kitaev Model
journal, July 2019
- Stavropoulos, P. Peter; Pereira, D.; Kee, Hae-Young
- Physical Review Letters, Vol. 123, Issue 3
Spin-glass behavior and vacancy order in van der Waals layered
journal, July 2018
- McGuire, Michael A.; Sales, Brian C.
- Physical Review Materials, Vol. 2, Issue 7
Electronic structure and magnetism of transition metal dihalides: Bulk to monolayer
journal, April 2019
- Botana, A. S.; Norman, M. R.
- Physical Review Materials, Vol. 3, Issue 4
Defect chemistry of Eu dopants in NaI scintillators studied by atomically resolved force microscopy
journal, July 2019
- Ulreich, Manuel; Boatner, Lynn A.; Sokolović, Igor
- Physical Review Materials, Vol. 3, Issue 7
Topological Spin Excitations in Honeycomb Ferromagnet
journal, November 2018
- Chen, Lebing; Chung, Jae-Ho; Gao, Bin
- Physical Review X, Vol. 8, Issue 4
Probing magnetism in 2D van der Waals crystalline insulators via electron tunneling
journal, May 2018
- Klein, D. R.; MacNeill, D.; Lado, J. L.
- Science, Vol. 360, Issue 6394
Direct observation of van der Waals stacking–dependent interlayer magnetism
journal, November 2019
- Chen, Weijong; Sun, Zeyuan; Wang, Zhongjie
- Science, Vol. 366, Issue 6468
Introducing Magnetism into 2D Nonmagnetic Inorganic Layered Crystals: A Brief Review from First-Principles Aspects
journal, January 2018
- Shi, Xinying; Huang, Zhongjia; Huttula, Marko
- Crystals, Vol. 8, Issue 1
VI 3 —a New Layered Ferromagnetic Semiconductor
journal, March 2019
- Kong, Tai; Stolze, Karoline; Timmons, Erik I.
- Advanced Materials, Vol. 31, Issue 17
Enhancement of interlayer exchange in an ultrathin two-dimensional magnet
journal, September 2019
- Klein, Dahlia R.; MacNeill, David; Song, Qian
- Nature Physics, Vol. 15, Issue 12
Probing and controlling magnetic states in 2D layered magnetic materials
journal, September 2019
- Mak, Kin Fai; Shan, Jie; Ralph, Daniel C.
- Nature Reviews Physics, Vol. 1, Issue 11
K 2 MnII2(H 2 O) 2 C 2 O 4 (HPO 3 ) 2 : a new 2D manganese( ii ) oxalatophosphite with double-layered honeycomb sheets stabilized by potassium ions
journal, January 2018
- Orive, Joseba; Sivasamy, Ramesh; Fernández de Luis, Roberto
- CrystEngComm, Vol. 20, Issue 3
The intrinsic magnetism, quantum anomalous Hall effect and Curie temperature in 2D transition metal trihalides
journal, January 2020
- Sun, Jiaxiang; Zhong, Xin; Cui, Wenwen
- Physical Chemistry Chemical Physics, Vol. 22, Issue 4
High-efficiency spin polarization in electron transport through the graphene nanoribbon coupled to chromium triiodide
journal, August 2019
- Han, Xiao; Zheng, Tian-Fang; Jiang, Cui
- Journal of Physics D: Applied Physics, Vol. 52, Issue 43
Chemical disorder and spin-liquid-like magnetism in the van der Waals layered transition metal halide
journal, June 2019
- McGuire, Michael A.; Zheng, Qiang; Yan, Jiaqiang
- Physical Review B, Vol. 99, Issue 21
Fundamental Spin Interactions Underlying the Magnetic Anisotropy in the Kitaev Ferromagnet
journal, January 2020
- Lee, Inhee; Utermohlen, Franz G.; Weber, Daniel
- Physical Review Letters, Vol. 124, Issue 1
High-temperature magnetostructural transition in van der Waals-layered
journal, November 2017
- McGuire, Michael A.; Yan, Jiaqiang; Lampen-Kelley, Paula
- Physical Review Materials, Vol. 1, Issue 6
Crystal structure and magnetic properties of the layered van der Waals compound VB r 3
journal, August 2019
- Kong, Tai; Guo, Shu; Ni, Danrui
- Physical Review Materials, Vol. 3, Issue 8
Two-dimensional magnetic crystals and emergent heterostructure devices
journal, February 2019
- Gong, Cheng; Zhang, Xiang
- Science, Vol. 363, Issue 6428
Intrinsic Van Der Waals Magnetic Materials from Bulk to the 2D Limit: New Frontiers of Spintronics
journal, May 2019
- Li, Hui; Ruan, Shuangchen; Zeng, Yu‐Jia
- Advanced Materials, Vol. 31, Issue 27
Electric-field switching of two-dimensional van der Waals magnets
journal, March 2018
- Jiang, Shengwei; Shan, Jie; Mak, Kin Fai
- Nature Materials, Vol. 17, Issue 5
Spiral spin structures and skyrmions in multiferroics
journal, September 2019
- Kurumaji, Takashi
- Physical Sciences Reviews, Vol. 5, Issue 1
CrAs Monolayer: Low Buckled 2D Half‐Metal Ferromagnet
journal, October 2019
- Rahman, Gul; Jahangirli, Zakir
- physica status solidi (RRL) – Rapid Research Letters, Vol. 14, Issue 1
Strain-tunable magnetic anisotropy in monolayer , , and
journal, October 2018
- Webster, Lucas; Yan, Jia-An
- Physical Review B, Vol. 98, Issue 14
Flux growth in a horizontal configuration: An analog to vapor transport growth
journal, July 2017
- Yan, J. -Q.; Sales, B. C.; Susner, M. A.
- Physical Review Materials, Vol. 1, Issue 2
A 2D ferromagnetic semiconductor in monolayer Cr-trihalide and its Janus structures
journal, January 2018
- Moaied, Mohammed; Lee, Jiyoul; Hong, Jisang
- Physical Chemistry Chemical Physics, Vol. 20, Issue 33
Crystal structures and phase transitions of the van der Waals ferromagnet V I 3
journal, December 2019
- Doležal, P.; Kratochvílová, M.; Holý, V.
- Physical Review Materials, Vol. 3, Issue 12
Flux growth in a horizontal configuration: an analogue to vapor transport growth
text, January 2017
- Yan, J. -Q.; Sales, B. C.; Susner, M. A.
- arXiv
Atomically thin p-n junctions based on two-dimensional materials
text, January 2018
- Frisenda, Riccardo; Molina-Mendoza, Aday J.; Mueller, Thomas
- arXiv
Direct observation of van der Waals stacking dependent interlayer magnetism
text, January 2019
- Chen, Weijong; Sun, Zeyuan; Gu, Lehua
- arXiv