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Title: Stabilizing hybrid perovskites against moisture and temperature via non-hydrolytic atomic layer deposited overlayers

We utilized a novel non-hydrolytic (nh) surface chemistry to allow the direct synthesis of pinhole-fee oxide overlayers directly on conventional hybrid perovskite halide absorbers without damage. By utilizing water- free ALD Al 2O 3 passivation, a minimum of ten-fold increase in stability against relative humidity (RH) 85% was achieved along with a dramatically improved thermal resistance (up to 250 °C). We extend this approach to synthesize nh-TiO 2 directly on hybrid perovskites to establish its potential in inverted photovoltaic devices as a dual stabilizing and electron accepting layer, as evidenced by photoluminescence (PL) quenching.
Authors:
 [1] ;  [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Argonne Northwestern Solar Energy Research (ANSER) Center, Evanston, IL (United States)
Publication Date:
Grant/Contract Number:
AC02-06CH11357
Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 3; Journal Issue: 40; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Research Org:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1356852

Kim, In Soo, and Martinson, Alex B. F.. Stabilizing hybrid perovskites against moisture and temperature via non-hydrolytic atomic layer deposited overlayers. United States: N. p., Web. doi:10.1039/C5TA07186k.
Kim, In Soo, & Martinson, Alex B. F.. Stabilizing hybrid perovskites against moisture and temperature via non-hydrolytic atomic layer deposited overlayers. United States. doi:10.1039/C5TA07186k.
Kim, In Soo, and Martinson, Alex B. F.. 2015. "Stabilizing hybrid perovskites against moisture and temperature via non-hydrolytic atomic layer deposited overlayers". United States. doi:10.1039/C5TA07186k. https://www.osti.gov/servlets/purl/1356852.
@article{osti_1356852,
title = {Stabilizing hybrid perovskites against moisture and temperature via non-hydrolytic atomic layer deposited overlayers},
author = {Kim, In Soo and Martinson, Alex B. F.},
abstractNote = {We utilized a novel non-hydrolytic (nh) surface chemistry to allow the direct synthesis of pinhole-fee oxide overlayers directly on conventional hybrid perovskite halide absorbers without damage. By utilizing water- free ALD Al2O3 passivation, a minimum of ten-fold increase in stability against relative humidity (RH) 85% was achieved along with a dramatically improved thermal resistance (up to 250 °C). We extend this approach to synthesize nh-TiO2 directly on hybrid perovskites to establish its potential in inverted photovoltaic devices as a dual stabilizing and electron accepting layer, as evidenced by photoluminescence (PL) quenching.},
doi = {10.1039/C5TA07186k},
journal = {Journal of Materials Chemistry. A},
number = 40,
volume = 3,
place = {United States},
year = {2015},
month = {9}
}