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Title: Metallic Borides, La 2 Re 3 B 7 and La 3 Re 2 B 5 , Featuring Extensive Boron–Boron Bonding

Authors:
 [1];  [2];  [1];  [2]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Emergent Superconductivity (CES); Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1356849
Alternate Identifier(s):
OSTI ID: 1371271
Grant/Contract Number:  
AC02-06CH11357; AC02-98CH10886
Resource Type:
Accepted Manuscript
Journal Name:
Inorganic Chemistry
Additional Journal Information:
Journal Volume: 55; Journal Issue: 4; Journal ID: ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Bugaris, Daniel E., Malliakas, Christos D., Chung, Duck Young, and Kanatzidis, Mercouri G.. Metallic Borides, La 2 Re 3 B 7 and La 3 Re 2 B 5 , Featuring Extensive Boron–Boron Bonding. United States: N. p., 2016. Web. https://doi.org/10.1021/acs.inorgchem.5b02599.
Bugaris, Daniel E., Malliakas, Christos D., Chung, Duck Young, & Kanatzidis, Mercouri G.. Metallic Borides, La 2 Re 3 B 7 and La 3 Re 2 B 5 , Featuring Extensive Boron–Boron Bonding. United States. https://doi.org/10.1021/acs.inorgchem.5b02599
Bugaris, Daniel E., Malliakas, Christos D., Chung, Duck Young, and Kanatzidis, Mercouri G.. Tue . "Metallic Borides, La 2 Re 3 B 7 and La 3 Re 2 B 5 , Featuring Extensive Boron–Boron Bonding". United States. https://doi.org/10.1021/acs.inorgchem.5b02599. https://www.osti.gov/servlets/purl/1356849.
@article{osti_1356849,
title = {Metallic Borides, La 2 Re 3 B 7 and La 3 Re 2 B 5 , Featuring Extensive Boron–Boron Bonding},
author = {Bugaris, Daniel E. and Malliakas, Christos D. and Chung, Duck Young and Kanatzidis, Mercouri G.},
abstractNote = {},
doi = {10.1021/acs.inorgchem.5b02599},
journal = {Inorganic Chemistry},
number = 4,
volume = 55,
place = {United States},
year = {2016},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
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Citation Metrics:
Cited by: 6 works
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Figures / Tables:

Table 1 Table 1: Structure Refinement Details from Single-Crystal X-ray Diffraction a

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Works referenced in this record:

High superconducting transition temperatures of new rare earth ternary borides
journal, April 1977

  • Matthias, B. T.; Corenzwit, E.; Vandenberg, J. M.
  • Proceedings of the National Academy of Sciences, Vol. 74, Issue 4
  • DOI: 10.1073/pnas.74.4.1334

Superconducting and magnetic properties of new ternary borides with the CeCo3B2-type structure
journal, July 1980


LaCo 2 B 2 : A Co-Based Layered Superconductor with a ThCr 2 Si 2 -Type Structure
journal, June 2011


Superconductivity and physical properties of strongly electron correlated compounds La n Ru 3n−1 B 2n (n = 1, 2, and 3)
journal, October 2013


Study of Coexistence of Ferromagnetism and Superconductivity in Single-Crystal Er Rh 4 B 4
journal, April 1982


Structural and Physical Properties Diversity of New CaCu 5 -Type Related Europium Platinum Borides
journal, March 2013

  • Salamakha, Leonid; Bauer, Ernst; Hilscher, Gerfried
  • Inorganic Chemistry, Vol. 52, Issue 8
  • DOI: 10.1021/ic301548w

Magnetic behavior and structural chemistry of RERu3B2 borides
journal, November 1980


Intermediate valence behavior of ternary cerium and uranium transition metal borides
journal, September 1984

  • Yang, K. N.; Torikachvili, M. S.; Maple, M. B.
  • Journal of Low Temperature Physics, Vol. 56, Issue 5-6
  • DOI: 10.1007/BF00681814

The nature of 4f electron magnetism in the diluted ferromagnetic Kondo lattice, CeIr 2 B 2
journal, June 2012


On the physical properties of RPd 8 B 2 − x and R 3 Pd 25 − x B 8 − y (R = La, Ce)
journal, October 2010


Signatures of spin-glass behaviour in PrIr 2 B 2 and heavy fermion behaviour in PrIr 2 B 2 C
journal, August 2011


Magnetic properties and large reversible magnetocaloric effect in PrCo2B2 compound
journal, July 2009

  • Li, Lingwei; Nishimura, Katsuhiko
  • Journal of Applied Physics, Vol. 106, Issue 2
  • DOI: 10.1063/1.3173565

Synthesis of Ultra-Incompressible Superhard Rhenium Diboride at Ambient Pressure
journal, April 2007


The Superconductivity in Re–B System
journal, July 2003

  • Kawano, Akihiko; Mizuta, Yukiko; Takagiwa, Hiroyuki
  • Journal of the Physical Society of Japan, Vol. 72, Issue 7
  • DOI: 10.1143/JPSJ.72.1724

Yttrium-rhenium-boron and lanthanum-rhenium-boron systems
journal, January 1977

  • Mikhalenko, S. I.; Kuz'ma, Yu. B.; Sobolev, A. S.
  • Soviet Powder Metallurgy and Metal Ceramics, Vol. 16, Issue 1
  • DOI: 10.1007/BF01129707

A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

La 3 Cl 3 BC – Structure, Bonding and Electrical Conductivity
journal, May 2005

  • Zeng, Hui-Yi; Okudera, Hiroki; Zheng, Chong
  • Zeitschrift für Naturforschung B, Vol. 60, Issue 5
  • DOI: 10.1515/znb-2005-0504

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965


Inhomogeneous Electron Gas
journal, November 1964


Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

A technique for relativistic spin-polarised calculations
journal, August 1977


The crystal structure of rhenium diboride
journal, February 1962


Crystal Structures of the Metal Diborides ReB2, RuB2, and OsB2 from Neutron Powder Diffraction 
journal, June 2010

  • Frotscher, Michael; Hölzel, Markus; Albert, Barbara
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 636, Issue 9-10
  • DOI: 10.1002/zaac.201000101

New incommensurate structures of the borides Pr41(Mn4B4)35 and Pr7(Re4B4)6
journal, January 1994


Preparation of ReB2 single crystals by the floating zone method
journal, May 1997


Preparation and Properties of Metallic, Superhard Rhenium Diboride Crystals
journal, December 2008

  • Levine, Jonathan B.; Nguyen, Sandy L.; Rasool, Haider I.
  • Journal of the American Chemical Society, Vol. 130, Issue 50
  • DOI: 10.1021/ja804989q

Crystal structure, chemical bonding, electrical transport, and magnetic behavior of Tm Al B 4
journal, August 2007


Growth and physical properties of Sc 2 AlB 6 crystals
journal, June 2009


The crystal structure of MoCoB and related compounds
journal, July 1968

  • Jeitschko, W.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 24, Issue 7
  • DOI: 10.1107/S0567740868003432

Growth of Single Crystals in the Systems withR–Rh–B andR–Rh–B–C (R=Rare Earth Element) from Molten Copper Flux
journal, October 1997

  • Shishido, Toetsu; Ye, Jinhua; Sasaki, Takahiko
  • Journal of Solid State Chemistry, Vol. 133, Issue 1
  • DOI: 10.1006/jssc.1997.7319

Darstellung und kristallstrukturen der Zink-Iridiumboride ZnIr4B3, Zn6Ir11B6−x, ZnIr2B2 und Zn2Ir2B
journal, May 1992


Synthesis, structure and properties of Li2Rh3B2
journal, April 2007

  • Bailey, Mark S.; Lobkovsky, Emil B.; Hinks, David G.
  • Journal of Solid State Chemistry, Vol. 180, Issue 4
  • DOI: 10.1016/j.jssc.2007.02.006

The ternary alkali metal platinum borides LiPt3B, NaPt3B1+x and Na3Pt9B5 — new structure variants of the CeCo3B2 type
journal, November 1988


Synthesis and crystal structures of the new metal-rich ternary borides Ni12AlB8, Ni12GaB8 and Ni10.6Ga0.4B6—examples for the first B5 zig-zag chain fragment
journal, August 2010

  • Ade, Martin; Kotzott, Dominik; Hillebrecht, Harald
  • Journal of Solid State Chemistry, Vol. 183, Issue 8
  • DOI: 10.1016/j.jssc.2010.05.009

Crystal structure of the rare earth borosilicide Er8Si17B3
journal, April 2003


Superconducting state magnetization and critical fields of single- crystal YNi2B2C
journal, July 1994


Ruthenium Intermetallics Grown from La−Ni Flux: Synthesis, Structure, and Physical Properties
journal, March 2010

  • Zaikina, Julia V.; Jo, Young-Jung; Latturner, Susan E.
  • Inorganic Chemistry, Vol. 49, Issue 6
  • DOI: 10.1021/ic902151d

Crystal Growth, Structures, and Properties of the Complex Borides, LaOs 2 Al 2 B and La 2 Os 2 AlB 2
journal, August 2015


A Tale of Two Metals: New Cerium Iron Borocarbide Intermetallics Grown from Rare-Earth/Transition Metal Eutectic Fluxes
journal, July 2012

  • Tucker, Patricia C.; Nyffeler, Jason; Chen, Banghao
  • Journal of the American Chemical Society, Vol. 134, Issue 29
  • DOI: 10.1021/ja303370j

Spin Glass Behavior of Isolated, Geometrically Frustrated Tetrahedra of Iron Atoms in the Intermetallic La 21 Fe 8 Sn 7 C 12
journal, March 2009

  • Benbow, Evan M.; Dalal, Naresh S.; Latturner, Susan E.
  • Journal of the American Chemical Society, Vol. 131, Issue 9
  • DOI: 10.1021/ja809084n

Structural relationships between new carbide La14Sn(MnC6)3 and fully ordered La11(MnC6)3
journal, December 2010

  • Zaikina, Julia V.; Zhou, Haidong; Latturner, Susan E.
  • Journal of Solid State Chemistry, Vol. 183, Issue 12
  • DOI: 10.1016/j.jssc.2010.10.004

Borides of Rhenium and the Platinum Metals. The Crystal Structure of Re7B3, ReB3, Rh7B3, RhB~1.1, IrB~1.1 and PtB.
journal, January 1960


Preparation and lattice parameters of the rare earth tetraborides
journal, April 1972


New borides of Pr5−xCo2+xB6-type structure containing iron and cobalt
journal, March 1986


Synthesis and crystal structure of MgB12
journal, September 2006

  • Adasch, Volker; Hess, Kai-Uwe; Ludwig, Thilo
  • Journal of Solid State Chemistry, Vol. 179, Issue 9
  • DOI: 10.1016/j.jssc.2006.03.045

Single crystal investigations on ScB15 and Sc2Cu1−xB45 – Two new representatives of boron-rich borides related to tetragonal boron II (t-B192)
journal, August 2011


Superconductivity in a new ternary structure class of boride compounds
journal, December 1977


Die Kristallstruktur von Mo2FeB2: Kurze Mitteilung
journal, November 1964

  • Rieger, W.; Nowotny, H.; Benesovsky, F.
  • Monatshefte für Chemie und verwandte Teile anderer Wissenschaften, Vol. 95, Issue 6
  • DOI: 10.1007/BF00901704

�ber einige Komplexboride von �bergangsmetallen
journal, January 1965

  • Rieger, W.; Nowotny, H.; Benesovsky, F.
  • Monatshefte f�r Chemie, Vol. 96, Issue 3
  • DOI: 10.1007/BF00919158

�ber einige Komplexboride mit Platinmetallen
journal, January 1972

  • Rogl, P.; Benesovsky, F.; Nowotny, H.
  • Monatshefte f�r Chemie, Vol. 103, Issue 4
  • DOI: 10.1007/BF00905170

Crystal Structure of Novel Ni–Zn Borides: First Observation of a Boron–Metal Nested Cage Unit: B 20 Ni 6
journal, August 2011

  • Malik, Zahida P.; Sologub, Oksana; Grytsiv, Andriy
  • Inorganic Chemistry, Vol. 50, Issue 16
  • DOI: 10.1021/ic2007167

The crystal structure of Rh5B4
journal, November 1981


Synthesis of a missing structural link: the first trigonal planar B 4 units in the novel complex boride Ti 1+x Os 2−x RuB 2 (x = 0.6)
journal, January 2006

  • Fokwa, Boniface P. T.; von Appen, Jörg; Dronskowski, Richard
  • Chem. Commun., Issue 42
  • DOI: 10.1039/b608903h

Rh3B2−x, new structure type of binary borides with triclinic symmetry
journal, November 2004


Unexpected Synergy between Magnetic Iron Chains and Stacked B 6 Rings in Nb 6 Fe 1− x Ir 6+ x B 8
journal, August 2014

  • Mbarki, Mohammed; St. Touzani, Rachid; Fokwa, Boniface P. T.
  • Angewandte Chemie International Edition, Vol. 53, Issue 48
  • DOI: 10.1002/anie.201406397

All-Boron Planar B6 Ring in the Solid-State Phase Ti7Rh4Ir2B8
journal, January 2012

  • Fokwa, Boniface P. T.; Hermus, Martin
  • Angewandte Chemie International Edition, Vol. 51, Issue 7
  • DOI: 10.1002/anie.201106798

Structure refinements of iron borides Fe2B and FeB
journal, January 2006

  • Kapfenberger, Christine; Albert, Barbara; Pöttgen, Rainer
  • Zeitschrift für Kristallographie - Crystalline Materials, Vol. 221, Issue 5-7
  • DOI: 10.1524/zkri.2006.221.5-7.477

The crystal structure of Fe2AlB2
journal, January 1969

  • Jeitschko, W.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 25, Issue 1
  • DOI: 10.1107/S0567740869001944

MgOs3B4 and ScOs3B4, Ternary Borides with a New Channel Structure
journal, October 2000

  • Schiffer, Joachim; Jung, Walter
  • Journal of Solid State Chemistry, Vol. 154, Issue 1
  • DOI: 10.1006/jssc.2000.8841

Der Strukturtyp von Aluminiumborid (AlB2)
journal, December 1935

  • Hofmann, Wilhelm; J�niche, Walter
  • Die Naturwissenschaften, Vol. 23, Issue 50
  • DOI: 10.1007/BF01491990

Synthesis, Structure, and Superconductivity in Be1.09B3
journal, February 2002

  • Chan, Julia Y.; Fronczek, Frank R.; Young, David P.
  • Journal of Solid State Chemistry, Vol. 163, Issue 2
  • DOI: 10.1006/jssc.2001.9374

Spatial Separation of Covalent, Ionic, and Metallic Interactions in Mg 11 Rh 18 B 8 and Mg 3 Rh 5 B 3
journal, December 2013

  • Alekseeva, Anastasia M.; Abakumov, Artem M.; Leither-Jasper, Andreas
  • Chemistry - A European Journal, Vol. 19, Issue 52
  • DOI: 10.1002/chem.201301512

Physical properties of the noncentrosymmetric superconductor Ru 7 B 3
journal, April 2009


Mg1?xRhB - a New Boridometallide with 2D Polyanion
journal, May 2005

  • Alekseeva, A. M.; Abakumov, A. M.; Leithe-Jasper, A.
  • Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 631, Issue 6-7
  • DOI: 10.1002/zaac.200400479

New scandium rhodium boride Sc4Rh17B12 with a framework structure: synthesis, crystal structure, and properties
journal, March 2008


    Works referencing / citing this record:

    Metal borohydride formation from aluminium boride and metal hydrides
    journal, January 2016

    • Møller, Kasper T.; Fogh, Alexander S.; Paskevicius, Mark
    • Physical Chemistry Chemical Physics, Vol. 18, Issue 39
    • DOI: 10.1039/c6cp05391b

    New cerium cobalt borocarbide synthesized from eutectic metal flux mixture
    journal, January 2017

    • Zhou, Sixuan; Mishra, Trinath; Lyman, Daniel
    • Inorganic Chemistry Frontiers, Vol. 4, Issue 3
    • DOI: 10.1039/c6qi00539j