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Title: Effect of the size-selective silver clusters on lithium peroxide morphology in lithium–oxygen batteries

Journal Article · · Nature Communications
DOI: https://doi.org/10.1038/ncomms5895 · OSTI ID:1356644
 [1];  [2];  [2];  [2];  [1];  [3];  [3];  [2];  [2];  [1];  [1];  [4];  [4];  [5];  [1];  [6]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Electron Microscopy Center
  4. Hanyang Univ., Seoul (Korea, Republic of). Dept. of Energy Engineering
  5. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division. Nanoscience and Technology Division; Yale Univ., New Haven, CT (United States). Dept. of Chemical and Environmental Engineering; Univ. of Chicago, IL (United States). Inst. for Molecular Engineering
  6. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division. Nanoscience and Technology Division
+ Show Author Affiliations

Lithium–oxygen batteries have the potential needed for long-range electric vehicles, but the charge and discharge chemistries are complex and not well understood. The active sites on cathode surfaces and their role in electrochemical reactions in aprotic lithium–oxygen cells are difficult to ascertain because the exact nature of the sites is unknown. In this paper, we report the deposition of subnanometre silver clusters of exact size and number of atoms on passivated carbon to study the discharge process in lithium–oxygen cells. The results reveal dramatically different morphologies of the electrochemically grown lithium peroxide dependent on the size of the clusters. This dependence is found to be due to the influence of the cluster size on the formation mechanism, which also affects the charge process. Finally, the results of this study suggest that precise control of subnanometre surface structure on cathodes can be used as a means to improve the performance of lithium–oxygen cells.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States); Hanyang Univ., Seoul (Korea, Republic of)
Sponsoring Organization:
Ministry of Knowledge Economy (Korea, Republic of); National Research Foundation (NRF) (Korea, Republic of); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1356644
Journal Information:
Nature Communications, Journal Name: Nature Communications Vol. 5; ISSN 2041-1723
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

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Cited By (33)

Realizing the Embedded Growth of Large Li 2 O 2 Aggregations by Matching Different Metal Oxides for High-Capacity and High-Rate Lithium Oxygen Batteries journal July 2017
Subnanometer cobalt oxide clusters as selective low temperature oxidative dehydrogenation catalysts journal February 2019
Graphene-Modified 3D Copper Foam Current Collector for Dendrite-Free Lithium Deposition journal November 2019
Platinum-Coated Hollow Graphene Nanocages as Cathode Used in Lithium-Oxygen Batteries journal August 2016
Advances in Manganese-Based Oxides Cathodic Electrocatalysts for Li-Air Batteries journal February 2018
Realizing the Embedded Growth of Large Li 2 O 2 Aggregations by Matching Different Metal Oxides for High-Capacity and High-Rate Lithium Oxygen Batteries journal July 2017
Effect of Componential Proportion in Bimetallic Electrocatalysts on the Aprotic Lithium-Oxygen Battery Performance journal April 2018
Highly Stable Oxygen Electrodes Enabled by Catalyst Redistribution through an In Situ Electrochemical Method journal February 2019
Insights into Structural Evolution of Lithium Peroxides with Reduced Charge Overpotential in Li−O 2 System journal June 2019
Von isolierten Ionen zu mehrschichtigen funktionellen Materialien durch sanfte Landung von Ionen journal November 2018
From Isolated Ions to Multilayer Functional Materials Using Ion Soft Landing journal November 2018
Raman Spectroscopy in Lithium-Oxygen Battery Systems journal August 2015
A lithium–oxygen battery based on lithium superoxide journal January 2016
State-of-the-art characterization techniques for advanced lithium-ion batteries journal March 2017
Catalysis by clusters with precise numbers of atoms journal July 2015
Subnanometer cobalt oxide clusters as selective low temperature oxidative dehydrogenation catalysts journal February 2019
Electrochemical behaviour of naked sub-nanometre sized copper clusters and effect of CO 2 journal January 2016
A 3D porous nitrogen-doped carbon-nanofiber-supported palladium composite as an efficient catalytic cathode for lithium–oxygen batteries journal January 2017
Recent advances in understanding of the mechanism and control of Li 2 O 2 formation in aprotic Li–O 2 batteries journal January 2017
Enhancing oxygen adsorption capabilities in Li–O 2 battery cathodes through solid perfluorocarbons journal January 2017
Pd-Impregnated NiCo 2 O 4 nanosheets/porous carbon composites as a free-standing and binder-free catalyst for a high energy lithium–oxygen battery journal January 2017
A free standing Ru–TiC nanowire array/carbon textile cathode with enhanced stability for Li–O 2 batteries journal January 2018
A lithium ion/oxygen hybrid battery with high energy and high power journal January 2018
Functional and stability orientation synthesis of materials and structures in aprotic Li–O 2 batteries journal January 2018
Hydrogen evolution reaction (HER) on Au@Ag ultrananoclusters as electro-catalysts journal January 2018
Urchin-like NiO–NiCo 2 O 4 heterostructure microsphere catalysts for enhanced rechargeable non-aqueous Li–O 2 batteries journal January 2019
Ruthenium oxide modified hierarchically porous boron-doped graphene aerogels as oxygen electrodes for lithium–oxygen batteries journal January 2018
PdNi alloy decorated 3D hierarchically N, S co-doped macro–mesoporous carbon composites as efficient free-standing and binder-free catalysts for Li–O 2 batteries journal January 2018
Electron microscopy and its role in advanced lithium-ion battery research journal January 2019
Biomass-derived hierarchically porous carbon skeletons with in situ decorated IrCo nanoparticles as high-performance cathode catalysts for Li–O 2 batteries journal January 2019
Perspective: Size selected clusters for catalysis and electrochemistry journal March 2018
Transient High-Power Output of Aprotic Li-O 2 Batteries Based on Cathode Capacitance Behavior journal January 2018
A High Voltage Organic Redox Flow Battery with Redox Couples O 2 /Tetrabutylammonium Complex and Tris(4-bromophenyl)amine as Redox Active Species journal January 2018

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