Oxidation potentials of phenols and anilines: correlation analysis of electrochemical and theoretical values
Abstract
As described in the main text, we classified our voltammograms into four types. For phenols, most compounds were type I or type II, except four phenols that were type III (4-nitrophenol, 4-cyanophenol, DNOC, and 4-hydroxyacetphenone); and two phenols that were type IV (4-aminophenol and dopamine). Almost all of the compounds gave the same type by SCV and SWV, except for 2,4-dinitrophenol (whose current went up and down and therefore could be considered a type II or III), 4-cyanophenol (which fell into a type III for SCV, but whose current went up and down in SWV (type II or III)), and 4-hydroxyacetophenone (which was a type III in SCV, but a type II in SWV). The majority of the anilines were type I except for p-toluidine (type II) and 4-methyl-3-nitroaniline and 2-methoxy-5-nitroaniline (both were type I for SWV, but for SCV fell into type III and type II respectively).
- Authors:
-
[1];
[1]
- Oregon Health & Science Univ., Portland, OR (United States). Inst. of Environmental Health
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER); National Science Foundation (NSF)
- OSTI Identifier:
- 1356492
- Report Number(s):
- PNNL-SA-123390
Journal ID: ISSN 2050-7887; 49691; KP1704020
- Grant/Contract Number:
- AC05-76RL01830; ER-1735; 1506744
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Environmental Science: Processes & Impacts
- Additional Journal Information:
- Journal Volume: 19; Journal Issue: 3; Journal ID: ISSN 2050-7887
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Environmental Molecular Sciences Laboratory
Citation Formats
Pavitt, Ania S., Bylaska, Eric J., and Tratnyek, Paul G. Oxidation potentials of phenols and anilines: correlation analysis of electrochemical and theoretical values. United States: N. p., 2017.
Web. doi:10.1039/C6EM00694A.
Pavitt, Ania S., Bylaska, Eric J., & Tratnyek, Paul G. Oxidation potentials of phenols and anilines: correlation analysis of electrochemical and theoretical values. United States. https://doi.org/10.1039/C6EM00694A
Pavitt, Ania S., Bylaska, Eric J., and Tratnyek, Paul G. Fri .
"Oxidation potentials of phenols and anilines: correlation analysis of electrochemical and theoretical values". United States. https://doi.org/10.1039/C6EM00694A. https://www.osti.gov/servlets/purl/1356492.
@article{osti_1356492,
title = {Oxidation potentials of phenols and anilines: correlation analysis of electrochemical and theoretical values},
author = {Pavitt, Ania S. and Bylaska, Eric J. and Tratnyek, Paul G.},
abstractNote = {As described in the main text, we classified our voltammograms into four types. For phenols, most compounds were type I or type II, except four phenols that were type III (4-nitrophenol, 4-cyanophenol, DNOC, and 4-hydroxyacetphenone); and two phenols that were type IV (4-aminophenol and dopamine). Almost all of the compounds gave the same type by SCV and SWV, except for 2,4-dinitrophenol (whose current went up and down and therefore could be considered a type II or III), 4-cyanophenol (which fell into a type III for SCV, but whose current went up and down in SWV (type II or III)), and 4-hydroxyacetophenone (which was a type III in SCV, but a type II in SWV). The majority of the anilines were type I except for p-toluidine (type II) and 4-methyl-3-nitroaniline and 2-methoxy-5-nitroaniline (both were type I for SWV, but for SCV fell into type III and type II respectively).},
doi = {10.1039/C6EM00694A},
journal = {Environmental Science: Processes & Impacts},
number = 3,
volume = 19,
place = {United States},
year = {Fri Feb 10 00:00:00 EST 2017},
month = {Fri Feb 10 00:00:00 EST 2017}
}
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