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Title: Domain wall and interphase boundary motion in (1–x)Bi(Mg0.5Ti0.5)O3–xPbTiO3 near the morphotropic phase boundary

Abstract

In this work, electric field-induced changes in the domain wall motion of (1-x)Bi(Mg0.5Ti0.5)O3–xPbTiO3 (BMT-xPT) near the morphotropic phase boundary (MPB) where x = 0.37 (BMT-37PT) and x =0.38 (BMT-38PT), are studied by means of synchrotron x-ray diffraction. Through Rietveld analysis and profile fitting, a mixture of coexisting monoclinic (Cm) and tetragonal (P4mm) phases is identified at room temperature. Extrinsic contributions to the property coefficients are evident from electric-field-induced domain wall motion in both the tetragonal and monoclinic phases, as well as through the interphase boundary motion between the two phases. Domain wall motion in the tetragonal and monoclinic phases for BMT-37PT is larger than that of BMT-38PT, possibly due to this composition's closer proximity to the MPB. Increased interphase boundary motion was also observed in BMT-37PT. Lattice strain, which is a function of both intrinsic piezoelectric strain and elastic interactions of the grains (the latter originating from domain wall and interphase boundary motion), is similar for the respective tetragonal and monoclinic phases.

Authors:
 [1];  [2];  [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [3];  [4]
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  1. Univ. of Florida, Gainesville, FL (United States)
  2. Univ. of Science and Technology Beijing (China)
  3. North Carolina State Univ., Raleigh, NC (United States)
  4. Univ. of Florida, Gainesville, FL (United States); North Carolina State Univ., Raleigh, NC (United States)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); US Army; National Natural Science Foundation of China (NSFC); National Science Foundation (NSF)
OSTI Identifier:
1353230
Alternate Identifier(s):
OSTI ID: 1273669
Grant/Contract Number:  
AC02-06CH11357; W911NF-09-1-0435; 91022016; 21031005; IIP-1361571; IIP-1361503; ECCS-1542015
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 120; Journal Issue: 4; Journal ID: ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
ENGLISH
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Tutuncu, Goknur, Chen, Jun, Fan, Longlong, Fancher, Chris M., Forrester, Jennifer S., Zhao, Jianwei, and Jones, Jacob L. Domain wall and interphase boundary motion in (1–x)Bi(Mg0.5Ti0.5)O3–xPbTiO3 near the morphotropic phase boundary. United States: N. p., 2016. Web. doi:10.1063/1.4959820.
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Tutuncu, Goknur, Chen, Jun, Fan, Longlong, Fancher, Chris M., Forrester, Jennifer S., Zhao, Jianwei, & Jones, Jacob L. Domain wall and interphase boundary motion in (1–x)Bi(Mg0.5Ti0.5)O3–xPbTiO3 near the morphotropic phase boundary. United States. https://doi.org/10.1063/1.4959820
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Tutuncu, Goknur, Chen, Jun, Fan, Longlong, Fancher, Chris M., Forrester, Jennifer S., Zhao, Jianwei, and Jones, Jacob L. Wed . "Domain wall and interphase boundary motion in (1–x)Bi(Mg0.5Ti0.5)O3–xPbTiO3 near the morphotropic phase boundary". United States. https://doi.org/10.1063/1.4959820. https://www.osti.gov/servlets/purl/1353230.
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@article{osti_1353230,
title = {Domain wall and interphase boundary motion in (1–x)Bi(Mg0.5Ti0.5)O3–xPbTiO3 near the morphotropic phase boundary},
author = {Tutuncu, Goknur and Chen, Jun and Fan, Longlong and Fancher, Chris M. and Forrester, Jennifer S. and Zhao, Jianwei and Jones, Jacob L.},
abstractNote = {In this work, electric field-induced changes in the domain wall motion of (1-x)Bi(Mg0.5Ti0.5)O3–xPbTiO3 (BMT-xPT) near the morphotropic phase boundary (MPB) where x = 0.37 (BMT-37PT) and x =0.38 (BMT-38PT), are studied by means of synchrotron x-ray diffraction. Through Rietveld analysis and profile fitting, a mixture of coexisting monoclinic (Cm) and tetragonal (P4mm) phases is identified at room temperature. Extrinsic contributions to the property coefficients are evident from electric-field-induced domain wall motion in both the tetragonal and monoclinic phases, as well as through the interphase boundary motion between the two phases. Domain wall motion in the tetragonal and monoclinic phases for BMT-37PT is larger than that of BMT-38PT, possibly due to this composition's closer proximity to the MPB. Increased interphase boundary motion was also observed in BMT-37PT. Lattice strain, which is a function of both intrinsic piezoelectric strain and elastic interactions of the grains (the latter originating from domain wall and interphase boundary motion), is similar for the respective tetragonal and monoclinic phases.},
doi = {10.1063/1.4959820},
journal = {Journal of Applied Physics},
number = 4,
volume = 120,
place = {United States},
year = {Wed Jul 27 00:00:00 EDT 2016},
month = {Wed Jul 27 00:00:00 EDT 2016}
}
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    Works referencing / citing this record:

    Unexpectedly high piezoelectricity of Sm-doped lead zirconate titanate in the Curie point region
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    Role of Reversible Phase Transformation for Strong Piezoelectric Performance at the Morphotropic Phase Boundary
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    Unexpectedly high piezoelectricity of Sm-doped lead zirconate titanate in the Curie point region
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