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Title: NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery

Abstract

Sodium ion batteries are being considered as an alternative to lithium ion batteries in large-scale energy storage applications owing to the low cost. A novel titanate compound, NaAlTi3O8, was successfully synthesized and tested as a promising anode material for sodium ion batteries. Powder X-ray Diffraction (XRD) and refinement were used to analyze the crystal structure. Electrochemical cycling tests under a C/10 rate between 0.01 - 2.5 V showed that ~83 mAh/g capacity could be achieved in the second cycle, with ~75% of which retained after 100 cycles, which corresponds to 0.75 Na+ insertion and extraction. The influence of synthesis conditions on electrochemical performances was investigated and discussed. In conclusion, NaAlTi3O8 not only presents a new anode material with low average voltage of ~0.5 V, but also provides a new type of intercalation anode with a crystal structure that differentiates from the anodes that have been reported.

Authors:
 [1]; ORCiD logo [2];  [3];  [1]
  1. Georgia Inst. of Technology, Atlanta, GA (United States). The Woodruff School of Mechanical Engineering
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Division
  3. Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II
Publication Date:
Research Org.:
Georgia Institute of Technology, Atlanta, GA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
Contributing Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
OSTI Identifier:
1352810
Alternate Identifier(s):
OSTI ID: 1376120
Report Number(s):
BNL-114010-2017-JA
Journal ID: ISSN 2045-2322; KC0402010; ERKCSNX
Grant/Contract Number:  
AC05-00OR22725; 1410936; SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 25 ENERGY STORAGE; batteries

Citation Formats

Ma, Xuetian, An, Ke, Bai, Jianmin, and Chen, Hailong. NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery. United States: N. p., 2017. Web. doi:10.1038/s41598-017-00202-y.
Ma, Xuetian, An, Ke, Bai, Jianmin, & Chen, Hailong. NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery. United States. doi:https://doi.org/10.1038/s41598-017-00202-y
Ma, Xuetian, An, Ke, Bai, Jianmin, and Chen, Hailong. Mon . "NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery". United States. doi:https://doi.org/10.1038/s41598-017-00202-y. https://www.osti.gov/servlets/purl/1352810.
@article{osti_1352810,
title = {NaAlTi3O8, A Novel Anode Material for Sodium Ion Battery},
author = {Ma, Xuetian and An, Ke and Bai, Jianmin and Chen, Hailong},
abstractNote = {Sodium ion batteries are being considered as an alternative to lithium ion batteries in large-scale energy storage applications owing to the low cost. A novel titanate compound, NaAlTi3O8, was successfully synthesized and tested as a promising anode material for sodium ion batteries. Powder X-ray Diffraction (XRD) and refinement were used to analyze the crystal structure. Electrochemical cycling tests under a C/10 rate between 0.01 - 2.5 V showed that ~83 mAh/g capacity could be achieved in the second cycle, with ~75% of which retained after 100 cycles, which corresponds to 0.75 Na+ insertion and extraction. The influence of synthesis conditions on electrochemical performances was investigated and discussed. In conclusion, NaAlTi3O8 not only presents a new anode material with low average voltage of ~0.5 V, but also provides a new type of intercalation anode with a crystal structure that differentiates from the anodes that have been reported.},
doi = {10.1038/s41598-017-00202-y},
journal = {Scientific Reports},
number = ,
volume = 7,
place = {United States},
year = {2017},
month = {3}
}

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Works referenced in this record:

Understanding Na 2 Ti 3 O 7 as an ultra-low voltage anode material for a Na-ion battery
journal, January 2014

  • Xu, Jing; Ma, Chuze; Balasubramanian, Mahalingam
  • Chem. Commun., Vol. 50, Issue 83
  • DOI: 10.1039/c4cc03973d

Lithium ion secondary batteries; past 10 years and the future
journal, November 2001


Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries
journal, August 2011

  • Komaba, Shinichi; Murata, Wataru; Ishikawa, Toru
  • Advanced Functional Materials, Vol. 21, Issue 20
  • DOI: 10.1002/adfm.201100854

Rationalization of Intercalation Potential and Redox Mechanism for A 2 Ti 3 O 7 (A = Li, Na)
journal, December 2013

  • Rousse, Gwenaelle; Arroyo-de Dompablo, M. Elena; Senguttuvan, Premkumar
  • Chemistry of Materials, Vol. 25, Issue 24
  • DOI: 10.1021/cm4032336

Assessment of world lithium resources and consequences of their geographic distribution on the expected development of the electric vehicle industry
journal, April 2012

  • Grosjean, Camille; Miranda, Pamela Herrera; Perrin, Marion
  • Renewable and Sustainable Energy Reviews, Vol. 16, Issue 3
  • DOI: 10.1016/j.rser.2011.11.023

Vanadium based materials as electrode materials for high performance supercapacitors
journal, October 2016


Electrochemical Alloying of Lithium in Organic Electrolytes
journal, January 1971

  • Dey, A. N.
  • Journal of The Electrochemical Society, Vol. 118, Issue 10
  • DOI: 10.1149/1.2407783

Nanostructures and lithium electrochemical reactivity of lithium titanites and titanium oxides: A review
journal, July 2009


Facile synthesis of amorphous aluminum vanadate hierarchical microspheres for supercapacitors
journal, January 2016

  • Yan, Yan; Xu, Hao; Guo, Wei
  • Inorganic Chemistry Frontiers, Vol. 3, Issue 6
  • DOI: 10.1039/c6qi00089d

First In Situ Lattice Strains Measurements Under Load at VULCAN
journal, October 2010

  • An, Ke; Skorpenske, Harley D.; Stoica, Alexandru D.
  • Metallurgical and Materials Transactions A, Vol. 42, Issue 1
  • DOI: 10.1007/s11661-010-0495-9

Better Cycling Performances of Bulk Sb in Na-Ion Batteries Compared to Li-Ion Systems: An Unexpected Electrochemical Mechanism
journal, December 2012

  • Darwiche, Ali; Marino, Cyril; Sougrati, Moulay T.
  • Journal of the American Chemical Society, Vol. 134, Issue 51
  • DOI: 10.1021/ja310347x

High performance electrochemical capacitor materials focusing on nickel based materials
journal, January 2016

  • Li, Bing; Zheng, Mingbo; Xue, Huaiguo
  • Inorganic Chemistry Frontiers, Vol. 3, Issue 2
  • DOI: 10.1039/c5qi00187k

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

  • Chan, Candace K.; Peng, Hailin; Liu, Gao
  • Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35
  • DOI: 10.1038/nnano.2007.411

Challenges for Na-ion Negative Electrodes
journal, January 2011

  • Chevrier, V. L.; Ceder, G.
  • Journal of The Electrochemical Society, Vol. 158, Issue 9
  • DOI: 10.1149/1.3607983

Redox reaction of Sn-polyacrylate electrodes in aprotic Na cell
journal, July 2012


Na-ion batteries, recent advances and present challenges to become low cost energy storage systems
journal, January 2012

  • Palomares, Verónica; Serras, Paula; Villaluenga, Irune
  • Energy & Environmental Science, Vol. 5, Issue 3
  • DOI: 10.1039/c2ee02781j

Challenges and Prospects of Lithium–Sulfur Batteries
journal, June 2012

  • Manthiram, Arumugam; Fu, Yongzhu; Su, Yu-Sheng
  • Accounts of Chemical Research, Vol. 46, Issue 5
  • DOI: 10.1021/ar300179v

Spinel lithium titanate (Li 4 Ti 5 O 12 ) as novel anode material for room-temperature sodium-ion battery
journal, February 2012


Demonstrating the Feasibility of Al as Anode Current Collector in Li-Ion Batteries via In Situ Neutron Depth Profiling
journal, January 2016


Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013

  • Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
  • Energy & Environmental Science, Vol. 6, Issue 8
  • DOI: 10.1039/c3ee40847g

EXPGUI , a graphical user interface for GSAS
journal, April 2001


Materials Challenges Facing Electrical Energy Storage
journal, April 2008


Sodium-Ion Batteries
journal, June 2018

  • Rojo, Teofilo; Hu, Yong-Sheng; Forsyth, Maria
  • Advanced Energy Materials, Vol. 8, Issue 17
  • DOI: 10.1002/aenm.201800880

Characterization of a P2-type chelating-agent-assisted Na 2/3 Fe 1/2 Mn 1/2 O 2 cathode material for sodium-ion batteries
journal, January 2014

  • Park, Kwangjin; Han, Dongwook; Kim, Hyunjin
  • RSC Adv., Vol. 4, Issue 43
  • DOI: 10.1039/c4ra01391c

Na2Ti6O13: a potential anode for grid-storage sodium-ion batteries
journal, January 2013

  • Rudola, Ashish; Saravanan, Kuppan; Devaraj, Sappani
  • Chemical Communications, Vol. 49, Issue 67
  • DOI: 10.1039/c3cc44381g

Characterization of salt-adapted secreted lignocellulolytic enzymes from the mangrove fungus Pestalotiopsis sp.
journal, May 2013

  • Arfi, Yonathan; Chevret, Didier; Henrissat, Bernard
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2850

Cohesion and structure in stage-1 graphite intercalation compounds
journal, August 1985


Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012

  • Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
  • Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
  • DOI: 10.1002/aenm.201200026

Na 2 Ti 3 O 7 : Lowest Voltage Ever Reported Oxide Insertion Electrode for Sodium Ion Batteries
journal, September 2011

  • Senguttuvan, Premkumar; Rousse, Gwenaëlle; Seznec, Vincent
  • Chemistry of Materials, Vol. 23, Issue 18
  • DOI: 10.1021/cm202076g

LiFePO 4 Nanocrystals: Liquid-Phase Reduction Synthesis and Their Electrochemical Performance
journal, June 2012

  • Jiang, Jie; Liu, Wen; Chen, Jitao
  • ACS Applied Materials & Interfaces, Vol. 4, Issue 6
  • DOI: 10.1021/am300418p

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Lithium ion secondary batteries; past 10 years and the future
journal, November 2001


Sodium-Ion Batteries
journal, May 2012

  • Slater, Michael D.; Kim, Donghan; Lee, Eungje
  • Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
  • DOI: 10.1002/adfm.201200691

High performance electrochemical capacitor materials focusing on nickel based materials
journal, January 2016

  • Li, Bing; Zheng, Mingbo; Xue, Huaiguo
  • Inorganic Chemistry Frontiers, Vol. 3, Issue 2
  • DOI: 10.1039/C5QI00187K

Facile synthesis of amorphous aluminum vanadate hierarchical microspheres for supercapacitors
journal, January 2016

  • Yan, Yan; Xu, Hao; Guo, Wei
  • Inorganic Chemistry Frontiers, Vol. 3, Issue 6
  • DOI: 10.1039/C6QI00089D

Characterization of a P2-type chelating-agent-assisted Na 2/3 Fe 1/2 Mn 1/2 O 2 cathode material for sodium-ion batteries
journal, January 2014

  • Park, Kwangjin; Han, Dongwook; Kim, Hyunjin
  • RSC Adv., Vol. 4, Issue 43
  • DOI: 10.1039/C4RA01391C

Cohesion and structure in stage-1 graphite intercalation compounds
journal, August 1985


Understanding Na 2 Ti 3 O 7 as an ultra-low voltage anode material for a Na-ion battery
journal, January 2014

  • Xu, Jing; Ma, Chuze; Balasubramanian, Mahalingam
  • Chem. Commun., Vol. 50, Issue 83
  • DOI: 10.1039/C4CC03973D

EXPGUI , a graphical user interface for GSAS
journal, April 2001