Manganese Vanadate Chemistry in Hydrothermal BaF 2 Brines: Ba 3 Mn 2 (V 2 O 7 ) 2 F 2 and Ba 7 Mn 8 O 2 (VO 4 ) 2 F 23

Sanjeewa, Liurukara D.; McMillen, Colin D.; McGuire, Michael A.; Kolis, Joseph W.

doi:10.1021/acs.inorgchem.6b02355

Title: Manganese Vanadate Chemistry in Hydrothermal BaF ₂ Brines: Ba ₃ Mn ₂ (V ₂ O ₇ ) ₂ F ₂ and Ba ₇ Mn ₈ O ₂ (VO ₄ ) ₂ F ₂₃

Abstract

We synthesized manganese vanadate fluorides using high-temperature hydrothermal techniques with BaF₂ as a mineralizer. Ba₃Mn₂(V₂O₇)₂F₂ crystallizes in space group C2/c and consists of dimers built from edge-sharing MnO₄F₂ trigonal prisms with linking V₂O₇ groups. Ba₇Mn₈O₂(VO₄)₂F₂₃ crystallizes in space group Cmmm, with a manganese oxyfluoride network built from edge- and corner-sharing Mn^2+/3+(O,F)₆ octahedra. The resulting octahedra form alternating Mn²⁺ and Mn^2+/3+ layers separated by VO₄ tetrahedra. This latter compound exhibits a canted antiferromagnetic order below TN = 25 K.

Authors:

Sanjeewa, Liurukara D. ^[1];

^[1]; McGuire, Michael A. ^[2]; Kolis, Joseph W. ^[1]

Clemson Univ., SC (United States). Dept. of Chemistry and Center for Optical Materials Science and Engineering Technologies
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division

Publication Date:: Mon Dec 05 00:00:00 EST 2016

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1352776

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Inorganic Chemistry

Additional Journal Information:: Journal Volume: 55; Journal Issue: 24; Journal ID: ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Sanjeewa, Liurukara D., McMillen, Colin D., McGuire, Michael A., and Kolis, Joseph W. Manganese Vanadate Chemistry in Hydrothermal BaF 2 Brines: Ba 3 Mn 2 (V 2 O 7 ) 2 F 2 and Ba 7 Mn 8 O 2 (VO 4 ) 2 F 23.  United States: N. p., 2016. 
Web.  doi:10.1021/acs.inorgchem.6b02355.

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                    Sanjeewa, Liurukara D., McMillen, Colin D., McGuire, Michael A., & Kolis, Joseph W. Manganese Vanadate Chemistry in Hydrothermal BaF 2 Brines: Ba 3 Mn 2 (V 2 O 7 ) 2 F 2 and Ba 7 Mn 8 O 2 (VO 4 ) 2 F 23.  United States.  https://doi.org/10.1021/acs.inorgchem.6b02355

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                    Sanjeewa, Liurukara D., McMillen, Colin D., McGuire, Michael A., and Kolis, Joseph W. Mon .  
"Manganese Vanadate Chemistry in Hydrothermal BaF 2 Brines: Ba 3 Mn 2 (V 2 O 7 ) 2 F 2 and Ba 7 Mn 8 O 2 (VO 4 ) 2 F 23".  United States.  https://doi.org/10.1021/acs.inorgchem.6b02355.  https://www.osti.gov/servlets/purl/1352776.

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@article{osti_1352776,

  title        = {Manganese Vanadate Chemistry in Hydrothermal BaF 2 Brines: Ba 3 Mn 2 (V 2 O 7 ) 2 F 2 and Ba 7 Mn 8 O 2 (VO 4 ) 2 F 23},

  author       = {Sanjeewa, Liurukara D. and McMillen, Colin D. and McGuire, Michael A. and Kolis, Joseph W.},

  abstractNote = {We synthesized manganese vanadate fluorides using high-temperature hydrothermal techniques with BaF2 as a mineralizer. Ba3Mn2(V2O7)2F2 crystallizes in space group C2/c and consists of dimers built from edge-sharing MnO4F2 trigonal prisms with linking V2O7 groups. Ba7Mn8O2(VO4)2F23 crystallizes in space group Cmmm, with a manganese oxyfluoride network built from edge- and corner-sharing Mn2+/3+(O,F)6 octahedra. The resulting octahedra form alternating Mn2+ and Mn2+/3+ layers separated by VO4 tetrahedra. This latter compound exhibits a canted antiferromagnetic order below TN = 25 K.},

  doi          = {10.1021/acs.inorgchem.6b02355},

  journal      = {Inorganic Chemistry},

  number       = 24,

  volume       = 55,

  place        = {United States},

  year         = {Mon Dec 05 00:00:00 EST 2016},

  month        = {Mon Dec 05 00:00:00 EST 2016}

}

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Citation Formats

From simple building blocks to structures with increasing size and complexity journal, February 1999

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Strongly Geometrically Frustrated Magnets
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Hydrothermal synthesis of single crystals of transition metal vanadates in the glaserite phase
journal, April 2016

Hydrothermal Synthesis and Characterization of Novel Brackebuschite-Type Transition Metal Vanadates: Ba ₂ M(VO ₄ ) ₂ (OH), M = V ³⁺ , Mn ³⁺ , and Fe ³⁺ , with Interesting Jahn–Teller and Spin-Liquid Behavior
journal, July 2015

Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F
journal, September 2016

Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates
journal, May 2016

The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt-Inclusion Vanadate Hybrids
journal, May 2008

Trigonal-prismatic coordination in solid compounds of transition metals
journal, February 1971

Trigonal prismatic vs. octahedral stereochemistry in complexes derived from innocent ligands
journal, December 1972

Mononuclear Iron(II), Manganese(II), and Nickel(II) and Tetranuclear Iron(III) Complexes of a New Hexadentate Ligand
journal, July 1994

A novel bipyridine-based hexadentate tripodal framework with a strong preference for trigonal prismatic co-ordination geometries
journal, January 2010

A Cyano-Bridged Single-Molecule Magnet: Slow Magnetic Relaxation in a Trigonal Prismatic MnMo ₆ (CN) ₁₈ Cluster
journal, June 2002

Synthesis and Structural Characterization of Manganese(II) Complexes with N , N ′-Bis(2-pyridylmethylene)-1,3-diaminopropan-2-ol or N , N ′-Bis(2-pyridylmethylene)-1,3-propanediamine
journal, October 1997

Trigonal prismatic versus octahedral co-ordination. Part 2. X-Ray structure determinations of manganese(II), cobalt(II), and nickel(II) complexes of intermediate geometry derived from the ligand 1,1,1-tris-(pyridine-2-aldiminomethyl)ethane
journal, January 1977

Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties
journal, January 2018

Crystal Structure and Preferential Site Occupancy in Cs6Mn(H2O)2(VO3)8 and Cs5KMn(H2O)2(VO3)8
journal, May 2019