Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F

Sanjeewa, Liurukara D.; McGuire, Michael A.; Smith Pellizzeri, Tiffany M.; McMillen, Colin D.; Ovidiu Garlea, V.; Willett, Daniel; Chumanov, George; Kolis, Joseph W.

doi:10.1016/j.jssc.2016.05.008

Title: Synthesis and characterization of new fluoride-containing manganese vanadates A₂Mn₂V₂O₇F₂ (A=Rb, Cs) and Mn₂VO₄F

Abstract

In large single crystals of A₂Mn₂V₂O₇F₂ (A=Rb, Cs) and Mn₂VO₄F were grown using a high-temperature (~600 °C) hydrothermal technique. We utilized single crystal X-ray diffraction and powder X-ray diffraction in order to characterize the structures, which both possess MnO₄F₂ building blocks. The A₂Mn₂V₂O₇F₂ series crystallizes as a new structure type in space group Pbcn (No. 60), Z=4 (Rb₂Mn₂V₂O₇F₂: a=7.4389(17) Å, b=11.574(3) Å, c=10.914(2) Å; Cs₂Mn₂V₂O₇F₂: a=7.5615(15) Å, b=11.745(2) Å, c=11.127(2) Å). The structure is composed of zigzag chains of edge-sharing MnO₄F₂ units running along the a-axis, and interconnected through V₂O₇ pyrovanadate groups. Temperature dependent magnetic susceptibility measurements on this interesting one-dimensional structural feature based on Mn²⁺ indicated that Cs₂Mn₂V₂O₇F₂ is antiferromagnetic with a Neél temperature, TN=~3 K and a Weiss constant, θ, of -11.7(1) K. Raman and infrared spectra were also analyzed to identify the fundamental V–O vibrational modes in Cs₂Mn₂V₂O₇F₂. Mn₂(VO₄)F crystalizes in the monoclinic space group of C2/c (no. 15), Z=8 with unit cell parameters of a=13.559(2) Å, b=6.8036(7) Å, c=10.1408(13) Å and β=116.16(3)°. The structure is associated with those of triplite and wagnerite. Dynamic fluorine disorder gives rise to complex alternating chains of five-and six-coordinate Mn²⁺. Our interpenetrating chains are additionally connected through isolated VO₄ tetrahedra tomore » form the condensed structure.« less

Authors:

Sanjeewa, Liurukara D. ^[1]; McGuire, Michael A. ^[2]; Smith Pellizzeri, Tiffany M. ^[1]; McMillen, Colin D. ^[1]; Ovidiu Garlea, V. ^[3]; Willett, Daniel ^[1]; Chumanov, George ^[1]; Kolis, Joseph W. ^[1]

Clemson Univ., SC (United States). Dept. of Chemistry and Center for Optical Materials Science and Engineering Technologies
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division

Publication Date:: Tue May 10 00:00:00 EDT 2016

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE; National Science Foundation (NSF)

OSTI Identifier:: 1352766

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Solid State Chemistry

Additional Journal Information:: Journal Volume: 241; Journal Issue: C; Journal ID: ISSN 0022-4596

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; Hydrothermal; Vanadate; Manganese(II); Antiferromagnetism

Citation Formats


                    Sanjeewa, Liurukara D., McGuire, Michael A., Smith Pellizzeri, Tiffany M., McMillen, Colin D., Ovidiu Garlea, V., Willett, Daniel, Chumanov, George, and Kolis, Joseph W. Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F.  United States: N. p., 2016. 
Web.  doi:10.1016/j.jssc.2016.05.008.

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                    Sanjeewa, Liurukara D., McGuire, Michael A., Smith Pellizzeri, Tiffany M., McMillen, Colin D., Ovidiu Garlea, V., Willett, Daniel, Chumanov, George, & Kolis, Joseph W. Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F.  United States.  https://doi.org/10.1016/j.jssc.2016.05.008

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                    Sanjeewa, Liurukara D., McGuire, Michael A., Smith Pellizzeri, Tiffany M., McMillen, Colin D., Ovidiu Garlea, V., Willett, Daniel, Chumanov, George, and Kolis, Joseph W. Tue .  
"Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F".  United States.  https://doi.org/10.1016/j.jssc.2016.05.008.  https://www.osti.gov/servlets/purl/1352766.

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@article{osti_1352766,

  title        = {Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F},

  author       = {Sanjeewa, Liurukara D. and McGuire, Michael A. and Smith Pellizzeri, Tiffany M. and McMillen, Colin D. and Ovidiu Garlea, V. and Willett, Daniel and Chumanov, George and Kolis, Joseph W.},

  abstractNote = {In large single crystals of A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F were grown using a high-temperature (~600 °C) hydrothermal technique. We utilized single crystal X-ray diffraction and powder X-ray diffraction in order to characterize the structures, which both possess MnO4F2 building blocks. The A2Mn2V2O7F2 series crystallizes as a new structure type in space group Pbcn (No. 60), Z=4 (Rb2Mn2V2O7F2: a=7.4389(17) Å, b=11.574(3) Å, c=10.914(2) Å; Cs2Mn2V2O7F2: a=7.5615(15) Å, b=11.745(2) Å, c=11.127(2) Å). The structure is composed of zigzag chains of edge-sharing MnO4F2 units running along the a-axis, and interconnected through V2O7 pyrovanadate groups. Temperature dependent magnetic susceptibility measurements on this interesting one-dimensional structural feature based on Mn2+ indicated that Cs2Mn2V2O7F2 is antiferromagnetic with a Neél temperature, TN=~3 K and a Weiss constant, θ, of -11.7(1) K. Raman and infrared spectra were also analyzed to identify the fundamental V–O vibrational modes in Cs2Mn2V2O7F2. Mn2(VO4)F crystalizes in the monoclinic space group of C2/c (no. 15), Z=8 with unit cell parameters of a=13.559(2) Å, b=6.8036(7) Å, c=10.1408(13) Å and β=116.16(3)°. The structure is associated with those of triplite and wagnerite. Dynamic fluorine disorder gives rise to complex alternating chains of five-and six-coordinate Mn2+. Our interpenetrating chains are additionally connected through isolated VO4 tetrahedra to form the condensed structure.},

  doi          = {10.1016/j.jssc.2016.05.008},

  journal      = {Journal of Solid State Chemistry},

  number       = C,

  volume       = 241,

  place        = {United States},

  year         = {Tue May 10 00:00:00 EDT 2016},

  month        = {Tue May 10 00:00:00 EDT 2016}

}

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Works referenced in this record:

Bulk single crystal growth from hydrothermal solutions
journal, July 2012

McMillen, Colin D.; Kolis, Joseph W.
Philosophical Magazine, Vol. 92, Issue 19-21
DOI: 10.1080/14786435.2012.685772

Hydrothermal synthesis as a route to mineralogically-inspired structures
journal, January 2016

McMillen, Colin D.; Kolis, Joseph W.
Dalton Transactions, Vol. 45, Issue 7
DOI: 10.1039/C5DT03424H

Hydrothermal Synthesis and Spectroscopic Properties of a New Glaserite Material, K ₃ RE(VO ₄ ) ₂ (RE = Sc, Y, Dy, Ho, Er, Yb, Lu, or Tm) with Potential Lasing and Optical Properties
journal, November 2012

Kimani, Martin M.; Thompson, Lindsey; Snider, Whitney
Inorganic Chemistry, Vol. 51, Issue 24
DOI: 10.1021/ic301922e

Hydrothermal Synthesis and Characterization of Novel Brackebuschite-Type Transition Metal Vanadates: Ba ₂ M(VO ₄ ) ₂ (OH), M = V ³⁺ , Mn ³⁺ , and Fe ³⁺ , with Interesting Jahn–Teller and Spin-Liquid Behavior
journal, July 2015

Sanjeewa, Liurukara D.; McGuire, Michael A.; Garlea, Vasile O.
Inorganic Chemistry, Vol. 54, Issue 14
DOI: 10.1021/acs.inorgchem.5b01037

$A$ Ag $_{2} M$ [VO $_{4}]_{2}$ ( $A = Ba, Sr$ ; $M = Co, Ni$ ): A series of ferromagnetic insulators
journal, June 2012

Möller, Angela; Amuneke, Ngozi E.; Daniel, Phillip
Physical Review B, Vol. 85, Issue 21
DOI: 10.1103/PhysRevB.85.214422

Experimental Realization of a Unique Class of Compounds: XY -Antiferromagnetic Triangular Lattices, KAg ₂ Fe[VO ₄ ] ₂ and RbAg ₂ Fe[VO ₄ ] ₂ , with Ferroelectric Ground States
journal, October 2014

Amuneke, Ngozi E.; Tapp, Joshua; de la Cruz, Clarina R.
Chemistry of Materials, Vol. 26, Issue 20
DOI: 10.1021/cm5025712

Magnetically Driven Ferroelectric Order in ${Ni}_{3} V_{2} O_{8}$
journal, August 2005

Lawes, G.; Harris, A. B.; Kimura, T.
Physical Review Letters, Vol. 95, Issue 8
DOI: 10.1103/PhysRevLett.95.087205

Synthesis and Characterization of the Crystal Structure and Magnetic Properties of the Ternary Manganese Vanadate NaMnVO ₄
journal, September 2010

Ben Yahia, Hamdi; Gaudin, Etienne; Boulahya, Khalid
Inorganic Chemistry, Vol. 49, Issue 18
DOI: 10.1021/ic101180h

Synthesis, structures and magnetic properties of the new vanadates AgMnVO4 and RbMnVO4
journal, November 2008

Ben Yahia, Hamdi; Gaudin, Etienne; Darriet, Jacques
Journal of Solid State Chemistry, Vol. 181, Issue 11
DOI: 10.1016/j.jssc.2008.08.001

BaMn ₉ [VO ₄ ] ₆ (OH) ₂ : A Unique Canted Antiferromagnet with a Chiral “Paddle-Wheel” Structural Feature
journal, November 2014

Sun, Kewen; Litvinchuk, Alexander P.; Tapp, Joshua
Inorganic Chemistry, Vol. 54, Issue 3
DOI: 10.1021/ic502266k

Magnetic structures of the low temperature phase of Mn ₃ (VO ₄ ) ₂ – towards understanding magnetic ordering between adjacent Kagomé layers
journal, January 2016

Clemens, Oliver; Rohrer, Jochen; Nénert, Gwilherm
Dalton Transactions, Vol. 45, Issue 1
DOI: 10.1039/C5DT03141A

Influence of side groups on 90° superexchange: A modification of the Goodenough-Kanamori-Anderson rules
journal, August 1996

Geertsma, Wiebe; Khomskii, D.
Physical Review B, Vol. 54, Issue 5
DOI: 10.1103/PhysRevB.54.3011

Spin dimer, electronic band structure and classical spin analyses of spin exchange interactions and ordered magnetic structures of magnetic solids
journal, July 2005

Whangbo, M. -H.; Dai, D.; Koo, H. -J.
Solid State Sciences, Vol. 7, Issue 7
DOI: 10.1016/j.solidstatesciences.2005.02.009

Two Novel Acentric Borate Fluorides: M ₃ B ₆ O ₁₁ F ₂ (M = Sr, Ba)
journal, March 2012

McMillen, Colin D.; Stritzinger, Jared T.; Kolis, Joseph W.
Inorganic Chemistry, Vol. 51, Issue 7
DOI: 10.1021/ic202318b

Hydrothermal synthesis of new rare earth silicate fluorides: A novel class of polar materials
journal, November 2012

McMillen, Colin D.; Emirdag-Eanes, Mehtap; Stritzinger, Jared T.
Journal of Solid State Chemistry, Vol. 195
DOI: 10.1016/j.jssc.2012.02.057

The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic Structures
journal, February 2012

Donakowski, Martin D.; Gautier, Romain; Yeon, Jeongho
Journal of the American Chemical Society, Vol. 134, Issue 18
DOI: 10.1021/ja210984k

On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MO _x F _{6– x} ] ^2– ( x = 1, 2) Building Units
journal, January 2015

Gautier, Romain; Gautier, Régis; Chang, Kelvin B.
Inorganic Chemistry, Vol. 54, Issue 4
DOI: 10.1021/ic5026735

Crystal Chemistry and Selected Physical Properties of Inorganic Fluorides and Oxide-Fluorides
journal, August 2014

Leblanc, Marc; Maisonneuve, Vincent; Tressaud, Alain
Chemical Reviews, Vol. 115, Issue 2
DOI: 10.1021/cr500173c

Fluoride-Rich, Hydrofluorothermal Routes to Functional Transition Metal (Mn, Fe, Co, Cu) Fluorophosphates
journal, June 2011

Armstrong, Jennifer A.; Williams, Edward R.; Weller, Mark T.
Journal of the American Chemical Society, Vol. 133, Issue 21
DOI: 10.1021/ja201096b

Cobalt(ii) fluorophosphate frameworks
journal, January 2012

Armstrong, Jennifer A.; Williams, Edward R.; Weller, Mark T.
Dalton Transactions, Vol. 41, Issue 46
DOI: 10.1039/c2dt31734f

Novel phosphate halides BaMnIII[PO4]FCl and BaMnIII[PO4]F2: Effects of mixed halides on crystal structures and magnetic properties
journal, February 2016

Pei, Da-Ting; Sun, Wei; Huang, Ya-Xi
Journal of Solid State Chemistry, Vol. 234
DOI: 10.1016/j.jssc.2015.11.023

Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr ₄ V ₃ O ₅ F ₁₃ , Pb ₇ V ₄ O ₈ F ₁₈ , Pb ₂ VO ₂ F ₅ , and Pb ₂ VOF ₆
journal, January 2015

Yeon, Jeongho; Felder, Justin B.; Smith, Mark D.
CrystEngComm, Vol. 17, Issue 44
DOI: 10.1039/C5CE01464F

Calcium–lead fluoro-vanadinite apatites. II. Equilibrium structures
journal, March 2004

Dong, ZhiLi; White, T. J.
Acta Crystallographica Section B Structural Science, Vol. 60, Issue 2
DOI: 10.1107/S0108768104001843

Triclinic apatites
journal, March 2007

Baikie, Tom; Mercier, Patrick H. J.; Elcombe, Margaret M.
Acta Crystallographica Section B Structural Science, Vol. 63, Issue 2
DOI: 10.1107/S0108768106053316

Apatite-structured compounds: Synthesis and high-temperature investigation
journal, February 2012

Knyazev, Alexander V.; Chernorukov, Nikolai G.; Bulanov, Evgeny N.
Materials Chemistry and Physics, Vol. 132, Issue 2-3
DOI: 10.1016/j.matchemphys.2011.12.011

Crystal chemistry of the tsumcorite-group minerals. New data on ferrilotharmeyerite, tsumcorite, thometzekite, mounanaite, helmutwinklerite, and a redefinition of gartrellite [Crystal chemistry of the tsumcorite-group minerals. New data on ferrilotharmeyerite, tsumcorite, thometzekite, mounanaite, helmutwinklerite, and a redefinition of gartrellite]
journal, March 1998

Krause, Werner; Belendorff, Klaus; Bernhardt, Heinz-Jürgen
European Journal of Mineralogy, Vol. 10, Issue 2
DOI: 10.1127/ejm/10/2/0179

A short history of SHELX
journal, December 2007

Sheldrick, George M.
Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
DOI: 10.1107/S0108767307043930

The pathobiology of isolated systolic hypertension
journal, January 2010

Franklin, S. S.
Hipertensión y Riesgo Vascular, Vol. 27, Issue 1
DOI: 10.1016/j.hipert.2009.02.004

Synthesis and Characterization of a Novel Sodium Transition Metal Oxyfluoride: NaMnMoO ₃ F ₃ ·H ₂ O
journal, August 2013

Nava-Avendaño, Jessica; Frontera, Carlos; Ayllón, José A.
Inorganic Chemistry, Vol. 52, Issue 17
DOI: 10.1021/ic401447p

Crystal structure of triplite
journal, April 1968

Waldrop, L.
Die Naturwissenschaften, Vol. 55, Issue 4
DOI: 10.1007/BF00591017

The crystal structure of manganese fluorophosphate, Mn ₂ (PO ₄ )F
journal, August 1972

Rea, J. R.; Kostiner, E.
Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 8
DOI: 10.1107/S0567740872006417

Fe2(AsO4)F: A new three-dimensional condensed fluoro-arsenate iron(II) compound with antiferromagnetic interactions
journal, June 2006

Berrocal, Teresa; Mesa, José L.; Pizarro, José L.
Journal of Solid State Chemistry, Vol. 179, Issue 6
DOI: 10.1016/j.jssc.2006.02.029

Cadmium fluorophosphate, Cd ₂ (PO ₄ )F
journal, December 1974

Rea, J. R.; Kostiner, E.
Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 30, Issue 12
DOI: 10.1107/S0567740874008430

Sodium manganese fluorosulfate with a triplite structure
journal, November 2013

Barpanda, Prabeer; Ling, Chris D.; Oyama, Gosuke
Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 69, Issue 6
DOI: 10.1107/S2052519213024093

Lu ₂ SiO ₅ by single-crystal X-ray and neutron diffraction
journal, June 2001

Gustafsson, T.; Klintenberg, M.; Derenzo, S. E.
Acta Crystallographica Section C Crystal Structure Communications, Vol. 57, Issue 6
DOI: 10.1107/S0108270101005352

Crystal Structure of the B-type Dierbium Oxide ortho -Oxosilicate Er ₂ O[SiO ₄ ]
journal, September 2008

Phanon, Delphine; Černý, Radovan
Zeitschrift für anorganische und allgemeine Chemie, Vol. 634, Issue 11
DOI: 10.1002/zaac.200800218

Structure and luminescence of Gd2GeO5 and Dy2GeO5
journal, August 1985

Brixner, L.; Calabrese, J.; Chen, H. Y.
Journal of the Less Common Metals, Vol. 110, Issue 1-2
DOI: 10.1016/0022-5088(85)90349-2

Hydrothermal Synthesis and Comparative Coordination Chemistry of New Rare-Earth V ⁴⁺ Compounds
journal, March 2012

Kimani, Martin M.; McMillen, Colin D.; Kolis, Joseph W.
Inorganic Chemistry, Vol. 51, Issue 6
DOI: 10.1021/ic2024132

Superspace description of wagnerite-group minerals (Mg,Fe,Mn) ₂ (PO ₄ )(F,OH)
journal, March 2014

Lazic, Biljana; Armbruster, Thomas; Chopin, Christian
Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 70, Issue 2
DOI: 10.1107/S2052520613031247

Structural and Magnetic Properties of a New Type of Ordered Oxygen-Deficient Perovskite, KMnVO ₄
journal, October 2007

Yahia, H. Ben; Gaudin, E.; Lee, C.
Chemistry of Materials, Vol. 19, Issue 23
DOI: 10.1021/cm070452b

Raman and infrared spectroscopy of selected vanadates
journal, March 2005

Frost, Ray L.; Erickson, Kristy L.; Weier, Matt L.
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 61, Issue 5
DOI: 10.1016/j.saa.2004.06.006

A Raman spectroscopic study of the different vanadate groups in solid-state compounds-model case: mineral phases vésigniéite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2·2H2O]
journal, April 2011

Frost, Ray L.; Palmer, Sara J.; Čejka, Jiří
Journal of Raman Spectroscopy, Vol. 42, Issue 8
DOI: 10.1002/jrs.2906

AAg ₂ (M′ _1/3 M _2/3 )[VO ₄ ] ₂ : Synthesis, Magnetic Properties, and Lattice Dynamics of Honeycomb-Type Lattices
journal, May 2014

Bratsch, Michaela; Tapp, Joshua; Litvinchuk, Alexander P.
Inorganic Chemistry, Vol. 53, Issue 10
DOI: 10.1021/ic500028b

Works referencing / citing this record:

Low temperature synthesis, structure and magnetic properties of Mn ₂ [VO ₄ ]F
journal, December 2017

Mori, Daisuke; Ben Yahia, Hamdi; Shikano, Masahiro
Journal of Asian Ceramic Societies, Vol. 5, Issue 4
DOI: 10.1016/j.jascer.2017.10.002

Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties
journal, January 2018

Smith Pellizzeri, Tiffany M.; McGuire, Michael A.; McMillen, Colin D.
Dalton Transactions, Vol. 47, Issue 8
DOI: 10.1039/c7dt04642a

Alkali Transition‐Metal Molybdates: A Stepwise Approach to Geometrically Frustrated Systems
journal, November 2019

Smith Pellizzeri, Tiffany M.; McMillen, Colin D.; Kolis, Joseph W.
Chemistry – A European Journal, Vol. 26, Issue 3
DOI: 10.1002/chem.201904193

Single crystal neutron and magnetic measurements of Rb ₂ Mn ₃ (VO ₄ ) ₂ CO ₃ and K ₂ Co ₃ (VO ₄ ) ₂ CO ₃ with mixed honeycomb and triangular magnetic lattices
journal, January 2020

Smith Pellizzeri, Tiffany M.; Sanjeewa, Liurukara D.; Pellizzeri, Steven
Dalton Transactions, Vol. 49, Issue 14
DOI: 10.1039/c9dt03389k

Crystal Structure and Preferential Site Occupancy in Cs6Mn(H2O)2(VO3)8 and Cs5KMn(H2O)2(VO3)8
journal, May 2019

Pellizzeri, Tiffany M. Smith; McMillen, Colin D.; Ivey, Kimberly
Journal of Chemical Crystallography, Vol. 49, Issue 3
DOI: 10.1007/s10870-019-00787-4

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Honeycomb-like S = 5/2 Spin–Lattices in Manganese(II) Vanadates

Journal Article Sanjeewa, Liurukara. D. ; McGuire, Michael A. ; McMillen, Colin D. ; ... - Inorganic Chemistry

We synthesized new complex manganese vanadate materials as high-quality single crystals in multi-millimeter lengths using a high-temperature, high-pressure hydrothermal method. We grew one compound, Mn₅(VO₄)₂(OH)₄, from Mn₂O₃ and V₂O₅ in 3 M CsOH at 580 °C and 1.5 kbar. Changing the mineralizer to 1 M CsOH/3MCsCl leads to the formation of another product, Mn₆O(VO₄)₂(OH). Both compounds were structurally characterized by single-crystal X-ray diffraction (Mn₅(VO₄)₂(OH)₄: C2/m, Z = 2, a = 9.6568(9) Å, b = 9.5627(9) Å, c = 5.4139(6) Å, β = 98.529(8)°; Mn₆O(VO₄)₂(OH): P21/m, Z = 2, a = 8.9363(12) Å, b = 6.4678(8) Å, c = 10.4478(13) Å,more »« less
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https://doi.org/10.1021/acs.inorgchem.6b01286

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A Ag 2 M [VO 4 ] 2 ( A = Ba , Sr ; M = Co , Ni ): A series of ferromagnetic insulators journal, June 2012

Experimental Realization of a Unique Class of Compounds: XY -Antiferromagnetic Triangular Lattices, KAg 2 Fe[VO 4 ] 2 and RbAg 2 Fe[VO 4 ] 2 , with Ferroelectric Ground States journal, October 2014

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Synthesis and Characterization of the Crystal Structure and Magnetic Properties of the Ternary Manganese Vanadate NaMnVO 4 journal, September 2010

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Title: Synthesis and characterization of new fluoride-containing manganese vanadates A₂Mn₂V₂O₇F₂ (A=Rb, Cs) and Mn₂VO₄F

Bulk single crystal growth from hydrothermal solutions
journal, July 2012

Hydrothermal synthesis as a route to mineralogically-inspired structures
journal, January 2016

Hydrothermal Synthesis and Spectroscopic Properties of a New Glaserite Material, K ₃ RE(VO ₄ ) ₂ (RE = Sc, Y, Dy, Ho, Er, Yb, Lu, or Tm) with Potential Lasing and Optical Properties
journal, November 2012

Hydrothermal Synthesis and Characterization of Novel Brackebuschite-Type Transition Metal Vanadates: Ba ₂ M(VO ₄ ) ₂ (OH), M = V ³⁺ , Mn ³⁺ , and Fe ³⁺ , with Interesting Jahn–Teller and Spin-Liquid Behavior
journal, July 2015

$A$ Ag $_{2} M$ [VO $_{4}]_{2}$ ( $A = Ba, Sr$ ; $M = Co, Ni$ ): A series of ferromagnetic insulators
journal, June 2012

Experimental Realization of a Unique Class of Compounds: XY -Antiferromagnetic Triangular Lattices, KAg ₂ Fe[VO ₄ ] ₂ and RbAg ₂ Fe[VO ₄ ] ₂ , with Ferroelectric Ground States
journal, October 2014

Magnetically Driven Ferroelectric Order in ${Ni}_{3} V_{2} O_{8}$
journal, August 2005

Synthesis and Characterization of the Crystal Structure and Magnetic Properties of the Ternary Manganese Vanadate NaMnVO ₄
journal, September 2010

Synthesis, structures and magnetic properties of the new vanadates AgMnVO4 and RbMnVO4
journal, November 2008

BaMn ₉ [VO ₄ ] ₆ (OH) ₂ : A Unique Canted Antiferromagnet with a Chiral “Paddle-Wheel” Structural Feature
journal, November 2014

Magnetic structures of the low temperature phase of Mn ₃ (VO ₄ ) ₂ – towards understanding magnetic ordering between adjacent Kagomé layers
journal, January 2016

Influence of side groups on 90° superexchange: A modification of the Goodenough-Kanamori-Anderson rules
journal, August 1996

Spin dimer, electronic band structure and classical spin analyses of spin exchange interactions and ordered magnetic structures of magnetic solids
journal, July 2005

Two Novel Acentric Borate Fluorides: M ₃ B ₆ O ₁₁ F ₂ (M = Sr, Ba)
journal, March 2012

Hydrothermal synthesis of new rare earth silicate fluorides: A novel class of polar materials
journal, November 2012

The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic Structures
journal, February 2012

On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MO _x F _{6– x} ] ^2– ( x = 1, 2) Building Units
journal, January 2015

Crystal Chemistry and Selected Physical Properties of Inorganic Fluorides and Oxide-Fluorides
journal, August 2014

Fluoride-Rich, Hydrofluorothermal Routes to Functional Transition Metal (Mn, Fe, Co, Cu) Fluorophosphates
journal, June 2011

Cobalt(ii) fluorophosphate frameworks
journal, January 2012

Novel phosphate halides BaMnIII[PO4]FCl and BaMnIII[PO4]F2: Effects of mixed halides on crystal structures and magnetic properties
journal, February 2016

Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr ₄ V ₃ O ₅ F ₁₃ , Pb ₇ V ₄ O ₈ F ₁₈ , Pb ₂ VO ₂ F ₅ , and Pb ₂ VOF ₆
journal, January 2015

Calcium–lead fluoro-vanadinite apatites. II. Equilibrium structures
journal, March 2004

Triclinic apatites
journal, March 2007

Apatite-structured compounds: Synthesis and high-temperature investigation
journal, February 2012

A short history of SHELX
journal, December 2007

The pathobiology of isolated systolic hypertension
journal, January 2010

Synthesis and Characterization of a Novel Sodium Transition Metal Oxyfluoride: NaMnMoO ₃ F ₃ ·H ₂ O
journal, August 2013

Crystal structure of triplite
journal, April 1968

The crystal structure of manganese fluorophosphate, Mn ₂ (PO ₄ )F
journal, August 1972

Fe2(AsO4)F: A new three-dimensional condensed fluoro-arsenate iron(II) compound with antiferromagnetic interactions
journal, June 2006

Cadmium fluorophosphate, Cd ₂ (PO ₄ )F
journal, December 1974

Sodium manganese fluorosulfate with a triplite structure
journal, November 2013

Lu ₂ SiO ₅ by single-crystal X-ray and neutron diffraction
journal, June 2001

Crystal Structure of the B-type Dierbium Oxide ortho -Oxosilicate Er ₂ O[SiO ₄ ]
journal, September 2008

Structure and luminescence of Gd2GeO5 and Dy2GeO5
journal, August 1985

Hydrothermal Synthesis and Comparative Coordination Chemistry of New Rare-Earth V ⁴⁺ Compounds
journal, March 2012

Superspace description of wagnerite-group minerals (Mg,Fe,Mn) ₂ (PO ₄ )(F,OH)
journal, March 2014

Structural and Magnetic Properties of a New Type of Ordered Oxygen-Deficient Perovskite, KMnVO ₄
journal, October 2007

Raman and infrared spectroscopy of selected vanadates
journal, March 2005

A Raman spectroscopic study of the different vanadate groups in solid-state compounds-model case: mineral phases vésigniéite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2·2H2O]
journal, April 2011

AAg ₂ (M′ _1/3 M _2/3 )[VO ₄ ] ₂ : Synthesis, Magnetic Properties, and Lattice Dynamics of Honeycomb-Type Lattices
journal, May 2014

Low temperature synthesis, structure and magnetic properties of Mn ₂ [VO ₄ ]F
journal, December 2017

Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties
journal, January 2018

Alkali Transition‐Metal Molybdates: A Stepwise Approach to Geometrically Frustrated Systems
journal, November 2019

Single crystal neutron and magnetic measurements of Rb ₂ Mn ₃ (VO ₄ ) ₂ CO ₃ and K ₂ Co ₃ (VO ₄ ) ₂ CO ₃ with mixed honeycomb and triangular magnetic lattices
journal, January 2020

Crystal Structure and Preferential Site Occupancy in Cs6Mn(H2O)2(VO3)8 and Cs5KMn(H2O)2(VO3)8
journal, May 2019