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Title: Elucidating the Phase Transformation of Li4Ti5O12 Lithiation at the Nanoscale

Abstract

Here this work provides insight regarding the fundamental lithiation and delithiation mechanism of the popular lithium ion battery anode material, Li4Ti5O12 (LTO). Our results quantify the extent of reaction between Li4Ti5O12 and Li7Ti5O12 at the nanoscale, during the first cycle. Lithium titanate’s discharge (lithiation) and charge (delithiation) reactions are notoriously difficult to characterize due to the zero-strain transition occurring between the end members Li4Ti5O12 and Li7Ti5O12. Interestingly, however, the latter compound is electronically conductive, while the former is an insulator. We take advantage of this critical property difference by using conductive atomic force microscopy (c-AFM) to locally monitor the phase transition between the two structures at various states of charge. To do so, we perform ex situ characterization on electrochemically cycled LTO thin-films that are never exposed to air. We provide direct confirmation of the manner in which the reaction occurs, which proceeds via percolation channels within single grains. We complement scanning probe analyses with an X-ray photoelectron spectroscopy (XPS) study that identifies and explains changes in the LTO surface structure and composition. Additionally, we provide a computational analysis to describe the unique electronic differences between LTO and its lithiated form.

Authors:
 [1];  [2];  [3];  [2];  [4];  [1];  [1]
  1. Univ. of California, San Diego, CA (United States). Dept. of NanoEngineering
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
  4. Univ. of California, San Diego, CA (United States). Materials Science & Engineering Program
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Univ. of California, San Diego, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
OSTI Identifier:
1352742
Alternate Identifier(s):
OSTI ID: 1595357
Grant/Contract Number:  
AC05-00OR22725; SC0002357; FG02-10ER46672; ACI-1053575
Resource Type:
Accepted Manuscript
Journal Name:
ACS Nano
Additional Journal Information:
Journal Volume: 10; Journal Issue: 4; Journal ID: ISSN 1936-0851
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; anode; c-AFM; Li-ion battery; Li4Ti5O12; LTO; thin-film; XPS

Citation Formats

Verde, Michael G., Baggetto, Loïc, Balke, Nina, Veith, Gabriel M., Seo, Joon Kyo, Wang, Ziying, and Meng, Ying Shirley. Elucidating the Phase Transformation of Li4Ti5O12 Lithiation at the Nanoscale. United States: N. p., 2016. Web. https://doi.org/10.1021/acsnano.5b07875.
Verde, Michael G., Baggetto, Loïc, Balke, Nina, Veith, Gabriel M., Seo, Joon Kyo, Wang, Ziying, & Meng, Ying Shirley. Elucidating the Phase Transformation of Li4Ti5O12 Lithiation at the Nanoscale. United States. https://doi.org/10.1021/acsnano.5b07875
Verde, Michael G., Baggetto, Loïc, Balke, Nina, Veith, Gabriel M., Seo, Joon Kyo, Wang, Ziying, and Meng, Ying Shirley. Tue . "Elucidating the Phase Transformation of Li4Ti5O12 Lithiation at the Nanoscale". United States. https://doi.org/10.1021/acsnano.5b07875. https://www.osti.gov/servlets/purl/1352742.
@article{osti_1352742,
title = {Elucidating the Phase Transformation of Li4Ti5O12 Lithiation at the Nanoscale},
author = {Verde, Michael G. and Baggetto, Loïc and Balke, Nina and Veith, Gabriel M. and Seo, Joon Kyo and Wang, Ziying and Meng, Ying Shirley},
abstractNote = {Here this work provides insight regarding the fundamental lithiation and delithiation mechanism of the popular lithium ion battery anode material, Li4Ti5O12 (LTO). Our results quantify the extent of reaction between Li4Ti5O12 and Li7Ti5O12 at the nanoscale, during the first cycle. Lithium titanate’s discharge (lithiation) and charge (delithiation) reactions are notoriously difficult to characterize due to the zero-strain transition occurring between the end members Li4Ti5O12 and Li7Ti5O12. Interestingly, however, the latter compound is electronically conductive, while the former is an insulator. We take advantage of this critical property difference by using conductive atomic force microscopy (c-AFM) to locally monitor the phase transition between the two structures at various states of charge. To do so, we perform ex situ characterization on electrochemically cycled LTO thin-films that are never exposed to air. We provide direct confirmation of the manner in which the reaction occurs, which proceeds via percolation channels within single grains. We complement scanning probe analyses with an X-ray photoelectron spectroscopy (XPS) study that identifies and explains changes in the LTO surface structure and composition. Additionally, we provide a computational analysis to describe the unique electronic differences between LTO and its lithiated form.},
doi = {10.1021/acsnano.5b07875},
journal = {ACS Nano},
number = 4,
volume = 10,
place = {United States},
year = {2016},
month = {3}
}

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Works referencing / citing this record:

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