Nanoparticle treated stainless steel filters for metal vapor sequestration
Abstract
The ability to sequester vapor phase radioactive compounds during industrial processes reduces the exposure of workers and the environment to dangerous radioactive materials. Nanomaterials have a lot of potential in this area because they typically demonstrate size- and shape-dependent properties with higher reactivity than bulk. This is due to the increased surface area-to-volume ratio and quantum size effects. In this report, we developed a gold nanomaterial-treated stainless steel filter, namely wools and coupons, that can be efficiently used for zinc vapor sequestration. Without nanoparticle modification, stainless steel coupons do not react or alloy with Zn. Gold nanomaterials were grown onto various stainless steel filters using solution chemistry that is amenable to scaling up. Materials were characterized by electron microscopy, inductively coupled plasma mass spectroscopy and dynamic light scattering before and after exposure to zinc vapors. X-ray diffraction, high-resolution transmission electron microscopy, energy dispersive x-ray spectroscopy mapping and ultraviolet-visible spectroscopy confirm the formation of gold-zinc alloys after Zn vapor exposure. Furthermore, the effect of surface topography on nanoparticle morphology, size and loading density were also investigated, and stainless steel surface defects were found to have an impact on the Au NP growth and subsequently Zn sequestration.
- Authors:
-
- Savannah River National Lab., Aiken, SC (United States); The Univ. of Georgia, Athens, GA (United States)
- Savannah River National Lab., Aiken, SC (United States)
- Publication Date:
- Research Org.:
- Savannah River Site (SRS), Aiken, SC (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1352524
- Report Number(s):
- SRNL-STI-2016-00507
Journal ID: ISSN 1047-4838; PII: 2206
- Grant/Contract Number:
- AC09-08SR22470
- Resource Type:
- Accepted Manuscript
- Journal Name:
- JOM. Journal of the Minerals, Metals & Materials Society
- Additional Journal Information:
- Journal Volume: 69; Journal Issue: 2; Journal ID: ISSN 1047-4838
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; zinc; vapor; nanoparticles; characterization; sequestration
Citation Formats
Murph, Simona E. Hunyadi, Larsen, George K., Korinko, Paul, Coopersmith, Kaitlin J., Summer, Ansley J., and Lewis, Rebecca. Nanoparticle treated stainless steel filters for metal vapor sequestration. United States: N. p., 2016.
Web. doi:10.1007/s11837-016-2206-5.
Murph, Simona E. Hunyadi, Larsen, George K., Korinko, Paul, Coopersmith, Kaitlin J., Summer, Ansley J., & Lewis, Rebecca. Nanoparticle treated stainless steel filters for metal vapor sequestration. United States. https://doi.org/10.1007/s11837-016-2206-5
Murph, Simona E. Hunyadi, Larsen, George K., Korinko, Paul, Coopersmith, Kaitlin J., Summer, Ansley J., and Lewis, Rebecca. Wed .
"Nanoparticle treated stainless steel filters for metal vapor sequestration". United States. https://doi.org/10.1007/s11837-016-2206-5. https://www.osti.gov/servlets/purl/1352524.
@article{osti_1352524,
title = {Nanoparticle treated stainless steel filters for metal vapor sequestration},
author = {Murph, Simona E. Hunyadi and Larsen, George K. and Korinko, Paul and Coopersmith, Kaitlin J. and Summer, Ansley J. and Lewis, Rebecca},
abstractNote = {The ability to sequester vapor phase radioactive compounds during industrial processes reduces the exposure of workers and the environment to dangerous radioactive materials. Nanomaterials have a lot of potential in this area because they typically demonstrate size- and shape-dependent properties with higher reactivity than bulk. This is due to the increased surface area-to-volume ratio and quantum size effects. In this report, we developed a gold nanomaterial-treated stainless steel filter, namely wools and coupons, that can be efficiently used for zinc vapor sequestration. Without nanoparticle modification, stainless steel coupons do not react or alloy with Zn. Gold nanomaterials were grown onto various stainless steel filters using solution chemistry that is amenable to scaling up. Materials were characterized by electron microscopy, inductively coupled plasma mass spectroscopy and dynamic light scattering before and after exposure to zinc vapors. X-ray diffraction, high-resolution transmission electron microscopy, energy dispersive x-ray spectroscopy mapping and ultraviolet-visible spectroscopy confirm the formation of gold-zinc alloys after Zn vapor exposure. Furthermore, the effect of surface topography on nanoparticle morphology, size and loading density were also investigated, and stainless steel surface defects were found to have an impact on the Au NP growth and subsequently Zn sequestration.},
doi = {10.1007/s11837-016-2206-5},
journal = {JOM. Journal of the Minerals, Metals & Materials Society},
number = 2,
volume = 69,
place = {United States},
year = {Wed Dec 07 00:00:00 EST 2016},
month = {Wed Dec 07 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Turkevich in New Robes: Key Questions Answered for the Most Common Gold Nanoparticle Synthesis
journal, June 2015
- Wuithschick, Maria; Birnbaum, Alexander; Witte, Steffen
- ACS Nano, Vol. 9, Issue 7
Role of Defects in the Nucleation and Growth of Au Nanoclusters on SiO 2 Thin Films
journal, October 2004
- Min, B. K.; Wallace, W. T.; Santra, A. K.
- The Journal of Physical Chemistry B, Vol. 108, Issue 42
Analysis of Zinc 65 Contamination After Vacuum Thermal Process
journal, June 2013
- Korinko, Paul S.; Tosten, Michael H.
- Journal of Failure Analysis and Prevention, Vol. 13, Issue 4
Remediation of Cr(VI) and Pb(II) Aqueous Solutions Using Supported, Nanoscale Zero-valent Iron
journal, June 2000
- Ponder, Sherman M.; Darab, John G.; Mallouk, Thomas E.
- Environmental Science & Technology, Vol. 34, Issue 12
Mechanism of Gold Nanoparticle Formation in the Classical Citrate Synthesis Method Derived from Coupled In Situ XANES and SAXS Evaluation
journal, February 2010
- Polte, Jörg; Ahner, T. Torsten; Delissen, Friedmar
- Journal of the American Chemical Society, Vol. 132, Issue 4
Tuning of size and shape of Au–Pt nanocatalysts for direct methanol fuel cells
journal, July 2011
- Hunyadi Murph, Simona E.; Murphy, Catherine J.; Colon-Mercado, Hector R.
- Journal of Nanoparticle Research, Vol. 13, Issue 12
Multifunctional Fe2O3–Au Nanoparticles with Different Shapes: Enhanced Catalysis, Photothermal Effects, and Magnetic Recyclability
journal, July 2016
- Larsen, George K.; Farr, Will; Hunyadi Murph, Simona E.
- The Journal of Physical Chemistry C, Vol. 120, Issue 28, p. 15162-15172
Functionalized paramagnetic nanoparticles for waste water treatment
journal, January 2010
- Urban, Ilona; Ratcliffe, Norman M.; Duffield, John R.
- Chemical Communications, Vol. 46, Issue 25
Iron Nanoparticles: the Core−Shell Structure and Unique Properties for Ni(II) Sequestration
journal, May 2006
- Li, Xiao-qin; Zhang, Wei-xian
- Langmuir, Vol. 22, Issue 10
Recovery of 65Zn from waste solutions from gallium targets at Brookhaven Linac Isotope Producer
journal, March 2009
- Medvedev, D. G.; Mausner, L. F.; Meinken, G. E.
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 280, Issue 1
Trichloroethene Hydrodechlorination in Water by Highly Disordered Monometallic Nanoiron
journal, October 2005
- Liu, Yueqiang; Choi, Hyeok; Dionysiou, Dionysios
- Chemistry of Materials, Vol. 17, Issue 21
Sequestration of Metal Cations with Zerovalent Iron NanoparticlesA Study with High Resolution X-ray Photoelectron Spectroscopy (HR-XPS)
journal, May 2007
- Li, Xiao-qin; Zhang, Wei-xian
- The Journal of Physical Chemistry C, Vol. 111, Issue 19
Synthesis of Poly- l -glutamic Acid Grafted Silica Nanoparticles and Their Assembly into Macroporous Structures
journal, September 2011
- Kar, Mrityunjoy; Pauline, Minois; Sharma, Kamendra
- Langmuir, Vol. 27, Issue 19
Patchy silica-coated silver nanowires as SERS substrates
journal, May 2013
- Hunyadi Murph, Simona E.; Murphy, Catherine J.
- Journal of Nanoparticle Research, Vol. 15, Issue 6
Fundamental growth principles of colloidal metal nanoparticles – a new perspective
journal, January 2015
- Polte, Jörg
- CrystEngComm, Vol. 17, Issue 36
Actinides and radiation effects: impact on the back-end of the nuclear fuel cycle
journal, August 2011
- Ewing, R. C.
- Mineralogical Magazine, Vol. 75, Issue 4
As(III) Sequestration by Iron Nanoparticles: Study of Solid-Phase Redox Transformations with X-ray Photoelectron Spectroscopy
journal, February 2012
- Yan, Weile; Ramos, Mauricio A. V.; Koel, Bruce E.
- The Journal of Physical Chemistry C, Vol. 116, Issue 9
Anisotropic Metal Nanoparticles: Synthesis, Assembly, and Optical Applications
journal, July 2005
- Murphy, Catherine J.; Sau, Tapan K.; Gole, Anand M.
- The Journal of Physical Chemistry B, Vol. 109, Issue 29
Methods of Preventing the Spread of Zinc Contamination During Vacuum Processing
journal, December 2013
- Korinko, Paul S.; Duncan, Andrew J.; Stoner, Kevin J.
- Journal of Failure Analysis and Prevention, Vol. 14, Issue 1