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Title: Use of Carbon Steel for Construction of Post-combustion CO 2 Capture Facilities: A Pilot-Scale Corrosion Study

Abstract

Corrosion studies were carried out on metal coated and noncoated carbon steel as well as stainless steel in a pilot-scale post-combustion CO2 capture process. Aqueous 30 wt % monoethanolamine (MEA) solvent was used without any chemical additive for antioxidation to examine a worst-case scenario where corrosion is not mitigated. The corrosion rate of all carbon steels was almost zero in the absorber column and CO2 lean amine piping except for Ni-coated carbon steel (<1.8 mm/yr). Ni2Al3/Al2O3 precoated carbon steels showed initial protection but lost their integrity in the stripping column and CO2 rich amine piping, and severe corrosion was eventually observed for all carbon steels at these two locations. Stainless steel was found to be stable and corrosion resistant in all of the sampling locations throughout the experiment. This study provides an initial framework for the use of carbon steel as a potential construction material for process units with relatively mild operating conditions (temperature less than 80 °C), such as the absorber and CO2 lean amine piping of a post-combustion CO2 capture process. As a result, it also warrants further investigation of using carbon steel with more effective corrosion mitigation strategies for process units where harsh environments are expected (suchmore » as temperatures greater than 100 °C).« less

Authors:
ORCiD logo; ; ; ORCiD logo; ; ORCiD logo; ; ; ; ; ; ORCiD logo
Publication Date:
Research Org.:
Univ. of Kentucky, Lexington, KY (United States)
Sponsoring Org.:
USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1352138
Grant/Contract Number:  
FE0007395
Resource Type:
Accepted Manuscript
Journal Name:
Industrial and Engineering Chemistry Research
Additional Journal Information:
Journal Volume: 56; Journal Issue: 16; Journal ID: ISSN 0888-5885
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; CO2 capture; pilot-scale; carbon steel; corrosion; massloss; SEM; XRD

Citation Formats

Li, Wei, Landon, James, Irvin, Bradley, Zheng, Liangfu, Ruh, Keith, Kong, Liang, Pelgen, Jonathan, Link, David, Figueroa, Jose D., Thompson, Jesse, Nikolic, Heather, and Liu, Kunlei. Use of Carbon Steel for Construction of Post-combustion CO 2 Capture Facilities: A Pilot-Scale Corrosion Study. United States: N. p., 2017. Web. https://doi.org/10.1021/acs.iecr.7b00697.
Li, Wei, Landon, James, Irvin, Bradley, Zheng, Liangfu, Ruh, Keith, Kong, Liang, Pelgen, Jonathan, Link, David, Figueroa, Jose D., Thompson, Jesse, Nikolic, Heather, & Liu, Kunlei. Use of Carbon Steel for Construction of Post-combustion CO 2 Capture Facilities: A Pilot-Scale Corrosion Study. United States. https://doi.org/10.1021/acs.iecr.7b00697
Li, Wei, Landon, James, Irvin, Bradley, Zheng, Liangfu, Ruh, Keith, Kong, Liang, Pelgen, Jonathan, Link, David, Figueroa, Jose D., Thompson, Jesse, Nikolic, Heather, and Liu, Kunlei. Thu . "Use of Carbon Steel for Construction of Post-combustion CO 2 Capture Facilities: A Pilot-Scale Corrosion Study". United States. https://doi.org/10.1021/acs.iecr.7b00697. https://www.osti.gov/servlets/purl/1352138.
@article{osti_1352138,
title = {Use of Carbon Steel for Construction of Post-combustion CO 2 Capture Facilities: A Pilot-Scale Corrosion Study},
author = {Li, Wei and Landon, James and Irvin, Bradley and Zheng, Liangfu and Ruh, Keith and Kong, Liang and Pelgen, Jonathan and Link, David and Figueroa, Jose D. and Thompson, Jesse and Nikolic, Heather and Liu, Kunlei},
abstractNote = {Corrosion studies were carried out on metal coated and noncoated carbon steel as well as stainless steel in a pilot-scale post-combustion CO2 capture process. Aqueous 30 wt % monoethanolamine (MEA) solvent was used without any chemical additive for antioxidation to examine a worst-case scenario where corrosion is not mitigated. The corrosion rate of all carbon steels was almost zero in the absorber column and CO2 lean amine piping except for Ni-coated carbon steel (<1.8 mm/yr). Ni2Al3/Al2O3 precoated carbon steels showed initial protection but lost their integrity in the stripping column and CO2 rich amine piping, and severe corrosion was eventually observed for all carbon steels at these two locations. Stainless steel was found to be stable and corrosion resistant in all of the sampling locations throughout the experiment. This study provides an initial framework for the use of carbon steel as a potential construction material for process units with relatively mild operating conditions (temperature less than 80 °C), such as the absorber and CO2 lean amine piping of a post-combustion CO2 capture process. As a result, it also warrants further investigation of using carbon steel with more effective corrosion mitigation strategies for process units where harsh environments are expected (such as temperatures greater than 100 °C).},
doi = {10.1021/acs.iecr.7b00697},
journal = {Industrial and Engineering Chemistry Research},
number = 16,
volume = 56,
place = {United States},
year = {2017},
month = {4}
}

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Works referenced in this record:

Corrosion and materials selection issues in carbon capture plants
journal, January 2011


Mechanistic Modeling of Carbon Steel Corrosion in a Methyldiethanolamine (MDEA)-Based Carbon Dioxide Capture Process
journal, January 2013

  • Choi, Yoon-Seok; Duan, Deli; Jiang, Shengli
  • Corrosion, Vol. 69, Issue 6
  • DOI: 10.5006/0695

Recent progress and new developments in post-combustion carbon-capture technology with amine based solvents
journal, September 2015

  • Liang, Zhiwu (Henry); Rongwong, Wichitpan; Liu, Helei
  • International Journal of Greenhouse Gas Control, Vol. 40
  • DOI: 10.1016/j.ijggc.2015.06.017

Towards Commercial Scale Postcombustion Capture of CO 2 with Monoethanolamine Solvent: Key Considerations for Solvent Management and Environmental Impacts
journal, March 2012

  • Reynolds, Alicia J.; Verheyen, T. Vincent; Adeloju, Samuel B.
  • Environmental Science & Technology, Vol. 46, Issue 7
  • DOI: 10.1021/es204051s

Corrosion in MEA units for CO2 capture: Pilot plant studies
journal, February 2009


Using carbon steel in the stripper and reboiler for post-Combustion CO2 capture with aqueous amine blends
journal, August 2016

  • Yu, Louis C. Y.; Sedransk Campbell, Kyra L.; Williams, Daryl R.
  • International Journal of Greenhouse Gas Control, Vol. 51
  • DOI: 10.1016/j.ijggc.2016.04.031

Effects of flue gas composition on carbon steel (1020) corrosion in MEA-based CO2 capture process
journal, November 2013

  • Wattanaphan, Pathamaporn; Sema, Teerawat; Idem, Raphael
  • International Journal of Greenhouse Gas Control, Vol. 19
  • DOI: 10.1016/j.ijggc.2013.08.021

Time-dependent electrochemical behavior of carbon steel in MEA-based CO 2 capture process
journal, November 2014

  • Xiang, Yong; Yan, Maocheng; Choi, Yoon-Seok
  • International Journal of Greenhouse Gas Control, Vol. 30
  • DOI: 10.1016/j.ijggc.2014.09.003

Investigation of Pseudo-Passivation of Mild Steel in CO 2 Corrosion
journal, March 2014

  • Li, Wei; Brown, Bruce; Young, David
  • CORROSION, Vol. 70, Issue 3
  • DOI: 10.5006/0950

Degradation and corrosion inhibitors for MEA-based CO2 capture plants
journal, July 2016

  • Fytianos, Georgios; Vevelstad, Solrun J.; Knuutila, Hanna K.
  • International Journal of Greenhouse Gas Control, Vol. 50
  • DOI: 10.1016/j.ijggc.2016.05.003

Suitability and Stability of 2-Mercaptobenzimidazole as a Corrosion Inhibitor in a Post-Combustion CO 2 Capture System
journal, June 2015

  • Zheng, Liangfu; Landon, James; Koebcke, Neal C.
  • CORROSION, Vol. 71, Issue 6
  • DOI: 10.5006/1524

Enhanced Carbon Capture through Incorporation of Surfactant Additives
journal, June 2016

  • Bryant, Jonathan J.; Lippert, Cameron; Qi, Guojie
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 27
  • DOI: 10.1021/acs.iecr.5b04906

Corrosion behaviour of an aluminized nickel coating in a carbon dioxide capture process using aqueous monoethanolamine
journal, November 2011


Comparison of the dry and wet oxidation at 900°C of η-Fe2Al5 and δ-Ni2Al3 coatings
journal, February 2011


High-temperature oxidation of pure Fe and the ferritic steel 2.25Cr1Mo
journal, December 2005


XPS characterization of passive films formed on Type 304 stainless steel in humid atmosphere
journal, May 2012


Simplified Calculation of CACO3 Saturation at High Temperatures and Pressures in Brine Solutions
journal, July 1982

  • Oddo, John E.; Tomson, Mason B.
  • Journal of Petroleum Technology, Vol. 34, Issue 07
  • DOI: 10.2118/10352-PA

Corrosion Behavior of Alumina Ceramics in Caustic Alkaline Solutions at High Temperatures
journal, December 1991


Corrosion mitigation via a pH stabilization method in monoethanolamine-based solutions for post-combustion CO2 capture
journal, May 2016


FeCO 3 Coating Process toward the Corrosion Protection of Carbon Steel in a Postcombustion CO 2 Capture System
journal, March 2016

  • Zheng, Liangfu; Landon, James; Matin, Naser S.
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 14
  • DOI: 10.1021/acs.iecr.5b04145

    Works referencing / citing this record:

    The corrosion behavior in CO 2 medium of 20# steel under the (CO 2 /aqueous solution) gas-liquid two-phase stratified flow condition
    journal, October 2018

    • Gui-rong, Yang; Wen-ming, Song; Fu-qiang, Wang
    • Materials Research Express, Vol. 6, Issue 1
    • DOI: 10.1088/2053-1591/aae667