Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy

Rosales, Bryan A.; Hanrahan, Michael P.; Boote, Brett W.; Rossini, Aaron J.; Smith, Emily A.; Vela, Javier

doi:10.1021/acsenergylett.6b00674

Title: Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy

Abstract

Hybrid lead perovskites containing a mixture of organic and inorganic cations and anions have lead to solar cell devices with better performance and stability than their single halide analogs. Here, 207Pb solid-state nuclear magnetic resonance and single particle photoluminescence spectroscopies show that the structure and composition of mixed-halide and—likely—other hybrid lead perovskites is much more complex than previously thought and is highly dependent on their synthesis. While a majority of reports in the area focus on the construction of photovoltaic devices, this perspective focuses instead on achieving a better understanding of the fundamental chemistry and photophysics of these materials, as this will aid not only in constructing improved devices, but also in generating new uses for these unique materials.

Authors:

Rosales, Bryan A. ^[1]; Hanrahan, Michael P. ^[2]; Boote, Brett W. ^[2]; Rossini, Aaron J. ^[2]; Smith, Emily A. ^[2];

^[2]

Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States
Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States, US DOE Ames Laboratory, Ames, Iowa 50011, United States

Publication Date:: Tue Mar 28 00:00:00 EDT 2017

Research Org.:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1352099

Alternate Identifier(s):: OSTI ID: 1347410; OSTI ID: 1508006

Report Number(s):: IS-J-9164
Journal ID: ISSN 2380-8195

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Published Article

Journal Name:: ACS Energy Letters

Additional Journal Information:: Journal Name: ACS Energy Letters Journal Volume: 2 Journal Issue: 4; Journal ID: ISSN 2380-8195

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 14 SOLAR ENERGY; 36 MATERIALS SCIENCE

Citation Formats


                    Rosales, Bryan A., Hanrahan, Michael P., Boote, Brett W., Rossini, Aaron J., Smith, Emily A., and Vela, Javier. Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy.  United States: N. p., 2017. 
Web.  doi:10.1021/acsenergylett.6b00674.

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                    Rosales, Bryan A., Hanrahan, Michael P., Boote, Brett W., Rossini, Aaron J., Smith, Emily A., & Vela, Javier. Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy.  United States.  https://doi.org/10.1021/acsenergylett.6b00674

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                    Rosales, Bryan A., Hanrahan, Michael P., Boote, Brett W., Rossini, Aaron J., Smith, Emily A., and Vela, Javier. Tue .  
"Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy".  United States.  https://doi.org/10.1021/acsenergylett.6b00674.

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@article{osti_1352099,

  title        = {Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy},

  author       = {Rosales, Bryan A. and Hanrahan, Michael P. and Boote, Brett W. and Rossini, Aaron J. and Smith, Emily A. and Vela, Javier},

  abstractNote = {Hybrid lead perovskites containing a mixture of organic and inorganic cations and anions have lead to solar cell devices with better performance and stability than their single halide analogs. Here, 207Pb solid-state nuclear magnetic resonance and single particle photoluminescence spectroscopies show that the structure and composition of mixed-halide and—likely—other hybrid lead perovskites is much more complex than previously thought and is highly dependent on their synthesis. While a majority of reports in the area focus on the construction of photovoltaic devices, this perspective focuses instead on achieving a better understanding of the fundamental chemistry and photophysics of these materials, as this will aid not only in constructing improved devices, but also in generating new uses for these unique materials.},

  doi          = {10.1021/acsenergylett.6b00674},

  journal      = {ACS Energy Letters},

  number       = 4,

  volume       = 2,

  place        = {United States},

  year         = {Tue Mar 28 00:00:00 EDT 2017},

  month        = {Tue Mar 28 00:00:00 EDT 2017}

}

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Cited by: 75 works

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Figures / Tables:

Figure 1: Films of CH₃NH₃PbX₃ (X = I, Br, Cl) are typically fabricated through (a) spin-coating by either a one-step (PbX₂ and CH₃NH₃X deposited at same time) or two-step (PbX₂ deposited first then dipped in CH₃NH₃X solution) process followed by annealing between 80 and 100 °C, or (b) vapor depositionmore »

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Figures / Tables found in this record:

Figure 1 (p. 2)

Figure 2 (p. 3)

Figure 3 (p. 3)

Table 1. Properties of NMR Active Nuclei Found in Perovskite Materials (p. 4)

Figure 4 (p. 5)

Figure 5 (p. 6)

Figure 6 (p. 6)

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

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Title: Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy

Abstract

Citation Formats

Figures / Tables:

Organometal halide perovskite thin films and solar cells by vapor deposition journal, January 2016

Fast magic-angle sample spinning solid-state NMR at 60–100 kHz for natural abundance samples journal, September 2016

Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells journal, March 2013

Sensitivity Enhancement in Solid State 15N NMR by Indirect Detection with High-Speed Magic Angle Spinning journal, January 2000

Mesoporous Silica Particles Integrated with All-Inorganic CsPbBr 3 Perovskite Quantum-Dot Nanocomposites (MP-PQDs) with High Stability and Wide Color Gamut Used for Backlight Display journal, May 2016

Photoluminescence Blinking of Single-Crystal Methylammonium Lead Iodide Perovskite Nanorods Induced by Surface Traps journal, July 2016

Raman Spectroscopy of Organic–Inorganic Halide Perovskites journal, January 2015

Multinuclear Magnetic Resonance Tracking of Hydro, Thermal, and Hydrothermal Decomposition of CH 3 NH 3 PbI 3 journal, January 2017

Inorganic caesium lead iodide perovskite solar cells journal, January 2015

NMR longitudinal relaxation enhancement in metal halides by heteronuclear polarization exchange during magic-angle spinning journal, June 2016

Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics journal, January 2015

Reversible Halide Exchange Reaction of Organometal Trihalide Perovskite Colloidal Nanocrystals for Full-Range Band Gap Tuning journal, July 2015

Cation rotation in methylammonium lead halides journal, November 1985

Perovskite solar cells: film formation and properties journal, January 2015

Photophysical properties of wavelength-tunable methylammonium lead halide perovskite nanocrystals journal, January 2017

Super-Resolution Luminescence Microspectroscopy Reveals the Mechanism of Photoinduced Degradation in CH 3 NH 3 PbI 3 Perovskite Nanocrystals journal, May 2016

Molecular Motions and Phase Transitions in Solid CH3NH3PbX3 (X = C1, Br, I) as Studied by NMR and NQR journal, January 1991

Organohalide Perovskites for Solar Energy Conversion journal, February 2016

Perovskite energy funnels for efficient light-emitting diodes journal, June 2016

Bandgap-Tunable Cesium Lead Halide Perovskites with High Thermal Stability for Efficient Solar Cells journal, February 2016

Cesium Enhances Long-Term Stability of Lead Bromide Perovskite-Based Solar Cells journal, December 2015

Hybrid Organic–Inorganic Perovskites on the Move journal, February 2016

Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency journal, January 2016

Ion Migration in Organometal Trihalide Perovskite and Its Impact on Photovoltaic Efficiency and Stability journal, January 2016

NMR nomenclature. Nuclear spin properties and conventions for chemical shifts(IUPAC Recommendations 2001) journal, January 2001

A combined single crystal neutron/X-ray diffraction and solid-state nuclear magnetic resonance study of the hybrid perovskites CH 3 NH 3 PbX 3 (X = I, Br and Cl) journal, January 2015

Making and Breaking of Lead Halide Perovskites journal, January 2016

Enhanced Organo-Metal Halide Perovskite Photoluminescence from Nanosized Defect-Free Crystallites and Emitting Sites journal, September 2015

Symmetry, Dynamics, and Defects in Methylammonium Lead Halide Perovskites journal, December 2016

Thermodynamic Origin of Photoinstability in the CH 3 NH 3 Pb(I 1– x Br x ) 3 Hybrid Halide Perovskite Alloy journal, March 2016

Shape Evolution and Single Particle Luminescence of Organometal Halide Perovskite Nanocrystals journal, February 2015

Organometal halide perovskite solar cells: degradation and stability journal, January 2016

Highly Tunable Colloidal Perovskite Nanoplatelets through Variable Cation, Metal, and Halide Composition journal, July 2016

Alkylammonium lead halides. Part 2. CH 3 NH 3 PbX 3 (X = Cl, Br, I) perovskites: cuboctahedral halide cages with isotropic cation reorientation journal, March 1990

Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells journal, April 2014

Perovskite-perovskite tandem photovoltaics with optimized band gaps journal, October 2016

Dynamic nuclear polarization at high magnetic fields journal, February 2008

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Persistent Dopants and Phase Segregation in Organolead Mixed-Halide Perovskites journal, August 2016

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Multinuclear Magnetic Resonance Tracking of Hydro, Thermal, and Hydrothermal Decomposition of CH ₃ NH ₃ PbI ₃
journal, January 2017

Inorganic caesium lead iodide perovskite solar cells
journal, January 2015

NMR longitudinal relaxation enhancement in metal halides by heteronuclear polarization exchange during magic-angle spinning
journal, June 2016

Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics
journal, January 2015

Reversible Halide Exchange Reaction of Organometal Trihalide Perovskite Colloidal Nanocrystals for Full-Range Band Gap Tuning
journal, July 2015

Cation rotation in methylammonium lead halides
journal, November 1985

Perovskite solar cells: film formation and properties
journal, January 2015

Photophysical properties of wavelength-tunable methylammonium lead halide perovskite nanocrystals
journal, January 2017

Super-Resolution Luminescence Microspectroscopy Reveals the Mechanism of Photoinduced Degradation in CH ₃ NH ₃ PbI ₃ Perovskite Nanocrystals
journal, May 2016

Molecular Motions and Phase Transitions in Solid CH₃NH₃PbX₃ (X = C1, Br, I) as Studied by NMR and NQR
journal, January 1991

Organohalide Perovskites for Solar Energy Conversion
journal, February 2016

Perovskite energy funnels for efficient light-emitting diodes
journal, June 2016

Bandgap-Tunable Cesium Lead Halide Perovskites with High Thermal Stability for Efficient Solar Cells
journal, February 2016

Cesium Enhances Long-Term Stability of Lead Bromide Perovskite-Based Solar Cells
journal, December 2015

Hybrid Organic–Inorganic Perovskites on the Move
journal, February 2016

Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
journal, January 2016

Ion Migration in Organometal Trihalide Perovskite and Its Impact on Photovoltaic Efficiency and Stability
journal, January 2016

NMR nomenclature. Nuclear spin properties and conventions for chemical shifts(IUPAC Recommendations 2001)
journal, January 2001

A combined single crystal neutron/X-ray diffraction and solid-state nuclear magnetic resonance study of the hybrid perovskites CH ₃ NH ₃ PbX ₃ (X = I, Br and Cl)
journal, January 2015

Making and Breaking of Lead Halide Perovskites
journal, January 2016

Enhanced Organo-Metal Halide Perovskite Photoluminescence from Nanosized Defect-Free Crystallites and Emitting Sites
journal, September 2015

Symmetry, Dynamics, and Defects in Methylammonium Lead Halide Perovskites
journal, December 2016

Thermodynamic Origin of Photoinstability in the CH ₃ NH ₃ Pb(I _{1– x} Br _x ) ₃ Hybrid Halide Perovskite Alloy
journal, March 2016

Shape Evolution and Single Particle Luminescence of Organometal Halide Perovskite Nanocrystals
journal, February 2015

Organometal halide perovskite solar cells: degradation and stability
journal, January 2016

Highly Tunable Colloidal Perovskite Nanoplatelets through Variable Cation, Metal, and Halide Composition
journal, July 2016

Alkylammonium lead halides. Part 2. CH ₃ NH ₃ PbX ₃ (X = Cl, Br, I) perovskites: cuboctahedral halide cages with isotropic cation reorientation
journal, March 1990

Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells
journal, April 2014

Perovskite-perovskite tandem photovoltaics with optimized band gaps
journal, October 2016

Dynamic nuclear polarization at high magnetic fields
journal, February 2008

Toward Lead-Free Perovskite Solar Cells
journal, November 2016

Pathways toward high-performance perovskite solar cells: review of recent advances in organo-metal halide perovskites for photovoltaic applications
journal, April 2016

Persistent Dopants and Phase Segregation in Organolead Mixed-Halide Perovskites
journal, August 2016

Multinuclear NMR as a tool for studying local order and dynamics in CH ₃ NH ₃ PbX ₃ (X = Cl, Br, I) hybrid perovskites
journal, January 2016

Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
journal, February 2015

Nanowires of Methylammonium Lead Iodide (CH ₃ NH ₃ PbI ₃ ) Prepared by Low Temperature Solution-Mediated Crystallization
journal, November 2014

The Raman Spectrum of the CH ₃ NH ₃ PbI ₃ Hybrid Perovskite: Interplay of Theory and Experiment
journal, December 2013

Compositionally Dependent Phase Identity of Colloidal CsPbBr _{3– x} I _x Quantum Dots
journal, October 2016