Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix

Lin, Dingchang; Zhao, Jie; Sun, Jie; Yao, Hongbin; Liu, Yayuan; Yan, Kai; Cui, Yi

doi:10.1073/pnas.1619489114

Title: Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix

Abstract

Significance Lithium metal anode holds great promises for next-generation high-energy lithium battery systems. This work introduces an electrolyte-proof design of three-dimensional lithium metal anode where most of the lithium domains are embedded in a lithium-ion conductive matrix. In this architecture, the lithium-ion conductive matrix can isolate the embedded lithium domains from liquid electrolyte and thus prevent severe initial side reactions, while the matrix can simultaneously transport lithium ion and maintain the electrochemical activity of the embedded lithium. The design principle enables highly stable, high-power, and safe lithium metal anodes with minimal side reactions and negligible volume variation during cycling, which paves the way for viable lithium metal batteries in the future.

Authors:

Lin, Dingchang ^[1]; Zhao, Jie ^[1]; Sun, Jie ^[1]; Yao, Hongbin ^[1]; Liu, Yayuan ^[1]; Yan, Kai ^[1]; Cui, Yi ^[2]

Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305,
Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305,, Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, Menlo Park, CA 94025

Publication Date:: Mon Apr 17 00:00:00 EDT 2017

Sponsoring Org.:: USDOE

OSTI Identifier:: 1351924

Grant/Contract Number:: EE0006828

Resource Type:: Published Article

Journal Name:: Proceedings of the National Academy of Sciences of the United States of America

Additional Journal Information:: Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 114 Journal Issue: 18; Journal ID: ISSN 0027-8424

Publisher:: Proceedings of the National Academy of Sciences

Country of Publication:: United States

Language:: English

Citation Formats


                    Lin, Dingchang, Zhao, Jie, Sun, Jie, Yao, Hongbin, Liu, Yayuan, Yan, Kai, and Cui, Yi. Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix.  United States: N. p., 2017. 
Web.  doi:10.1073/pnas.1619489114.

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                    Lin, Dingchang, Zhao, Jie, Sun, Jie, Yao, Hongbin, Liu, Yayuan, Yan, Kai, & Cui, Yi. Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix.  United States.  https://doi.org/10.1073/pnas.1619489114

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                    Lin, Dingchang, Zhao, Jie, Sun, Jie, Yao, Hongbin, Liu, Yayuan, Yan, Kai, and Cui, Yi. Mon .  
"Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix".  United States.  https://doi.org/10.1073/pnas.1619489114.

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@article{osti_1351924,

  title        = {Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix},

  author       = {Lin, Dingchang and Zhao, Jie and Sun, Jie and Yao, Hongbin and Liu, Yayuan and Yan, Kai and Cui, Yi},

  abstractNote = {Significance Lithium metal anode holds great promises for next-generation high-energy lithium battery systems. This work introduces an electrolyte-proof design of three-dimensional lithium metal anode where most of the lithium domains are embedded in a lithium-ion conductive matrix. In this architecture, the lithium-ion conductive matrix can isolate the embedded lithium domains from liquid electrolyte and thus prevent severe initial side reactions, while the matrix can simultaneously transport lithium ion and maintain the electrochemical activity of the embedded lithium. The design principle enables highly stable, high-power, and safe lithium metal anodes with minimal side reactions and negligible volume variation during cycling, which paves the way for viable lithium metal batteries in the future.},

  doi          = {10.1073/pnas.1619489114},

  journal      = {Proceedings of the National Academy of Sciences of the United States of America},

  number       = 18,

  volume       = 114,

  place        = {United States},

  year         = {Mon Apr 17 00:00:00 EDT 2017},

  month        = {Mon Apr 17 00:00:00 EDT 2017}

}

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Title: Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix

Abstract

Citation Formats

In situ NMR observation of the formation of metallic lithium microstructures in lithium batteries journal, May 2010

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7Li MRI of Li batteries reveals location of microstructural lithium journal, February 2012

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Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating journal, February 2016

A consideration of the morphology of electrochemically deposited lithium in an organic electrolyte journal, August 1998

Dry-air-stable lithium silicide–lithium oxide core–shell nanoparticles as high-capacity prelithiation reagents journal, October 2014

Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes journal, August 2015

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Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth journal, February 2016

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High rate and stable cycling of lithium metal anode journal, February 2015

In situ NMR observation of the formation of metallic lithium microstructures in lithium batteries
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High-performance lithium-ion anodes using a hierarchical bottom-up approach
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High-capacity battery cathode prelithiation to offset initial lithium loss
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Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries
journal, August 2000

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Metallurgically lithiated SiO _x anode with high capacity and ambient air compatibility
journal, June 2016

Single-ion BAB triblock copolymers as highly efficient electrolytes for lithium-metal batteries
journal, March 2013

Spatially heterogeneous carbon-fiber papers as surface dendrite-free current collectors for lithium deposition
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journal, October 2004

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journal, September 1996

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journal, October 2014

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journal, March 2016

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journal, January 2011

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journal, October 2007

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journal, January 2015

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journal, January 2004

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journal, June 2015

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journal, January 2012

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journal, September 1999

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journal, June 2002

Effect of Electrolyte Composition on Lithium Dendrite Growth
journal, January 2008

Systematical electrochemical study on the parasitic shuttle-effect in lithium-sulfur-cells at different temperatures and different rates
journal, August 2014

Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode
journal, March 2016

Reviving the lithium metal anode for high-energy batteries
journal, March 2017

Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating
journal, February 2016

A consideration of the morphology of electrochemically deposited lithium in an organic electrolyte
journal, August 1998

Dry-air-stable lithium silicide–lithium oxide core–shell nanoparticles as high-capacity prelithiation reagents
journal, October 2014

Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes
journal, August 2015

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013

Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth
journal, February 2016

A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes
journal, February 2014

High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO ₂ Nanospheres in Poly(ethylene oxide)
journal, December 2015

Li–O₂ and Li–S batteries with high energy storage
journal, January 2012

A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles
journal, December 2015

A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009

A high tap density secondary silicon particle anode fabricated by scalable mechanical pressing for lithium-ion batteries
journal, January 2015

The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model
journal, January 1979

Stable lithium electrodeposition in liquid and nanoporous solid electrolytes
journal, August 2014

Thin-film lithium and lithium-ion batteries
journal, November 2000

High rate and stable cycling of lithium metal anode
journal, February 2015