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Title: Charge transfer in iridate-manganite superlattices

Charge transfer in superlattices consisting of SrIrO$$_3$$ and SrMnO$$_3$$ is investigated using density functional theory. Despite the nearly identical work function and non-polar interfaces between SrIrO$$_3$$ and SrMnO$$_3$$, rather large charge transfer was experimentally reported between them. Our results provide a qualitative understanding to such experimental reports. We further develop a microscopic model that captures the mechanism behind this phenomenon. This leads to unique strain dependence of such charge transfer in iridate-manganite superlattices. The predicted behavior is consistently verified by experiment. Lastly, our work thus demonstrates a new route to control electronic states in non-polar oxide heterostructures.
Authors:
ORCiD logo [1] ;  [1] ;  [1] ;  [2] ;  [2] ; ORCiD logo [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Institute for Basic Science (IBS), Seoul (Republic of Korea); Seoul National Univ., Seoul (Republic of Korea)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
Nano Letters
Additional Journal Information:
Journal Volume: 17; Journal Issue: 4; Journal ID: ISSN 1530-6984
Publisher:
American Chemical Society
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; density functional theory; electronic reconstruction; modeling; oxide heterostructures; x-ray and optical measurements
OSTI Identifier:
1351768

Okamoto, Satoshi, Nichols, John, Sohn, Changhee, Kim, So Yeun, Noh, Tae Won, and Lee, Ho Nyung. Charge transfer in iridate-manganite superlattices. United States: N. p., Web. doi:10.1021/acs.nanolett.6b04107.
Okamoto, Satoshi, Nichols, John, Sohn, Changhee, Kim, So Yeun, Noh, Tae Won, & Lee, Ho Nyung. Charge transfer in iridate-manganite superlattices. United States. doi:10.1021/acs.nanolett.6b04107.
Okamoto, Satoshi, Nichols, John, Sohn, Changhee, Kim, So Yeun, Noh, Tae Won, and Lee, Ho Nyung. 2017. "Charge transfer in iridate-manganite superlattices". United States. doi:10.1021/acs.nanolett.6b04107. https://www.osti.gov/servlets/purl/1351768.
@article{osti_1351768,
title = {Charge transfer in iridate-manganite superlattices},
author = {Okamoto, Satoshi and Nichols, John and Sohn, Changhee and Kim, So Yeun and Noh, Tae Won and Lee, Ho Nyung},
abstractNote = {Charge transfer in superlattices consisting of SrIrO$_3$ and SrMnO$_3$ is investigated using density functional theory. Despite the nearly identical work function and non-polar interfaces between SrIrO$_3$ and SrMnO$_3$, rather large charge transfer was experimentally reported between them. Our results provide a qualitative understanding to such experimental reports. We further develop a microscopic model that captures the mechanism behind this phenomenon. This leads to unique strain dependence of such charge transfer in iridate-manganite superlattices. The predicted behavior is consistently verified by experiment. Lastly, our work thus demonstrates a new route to control electronic states in non-polar oxide heterostructures.},
doi = {10.1021/acs.nanolett.6b04107},
journal = {Nano Letters},
number = 4,
volume = 17,
place = {United States},
year = {2017},
month = {3}
}