Hydrothermal transport, deposition, and fractionation of the REE: Experimental data and thermodynamic calculations

Migdisov, Artaches; Williams-Jones, A. E.; Brugger, J.; Caporuscio, Florie Andre

doi:10.1016/j.chemgeo.2016.06.005

Title: Hydrothermal transport, deposition, and fractionation of the REE: Experimental data and thermodynamic calculations

Abstract

For many years, our understanding of the behavior of the REE in hydrothermal systems was based on semi-empirical estimates involving extrapolation of thermodynamic data obtained at 25 °C. Since then, a substantial body of experimental data has accumulated on the stability of aqueous complexes of the REE. These data have shown that some of the predictions of Haas et al. (1995) are accurate, but others may be in error by several orders of magnitude. However, application of the data in modeling hydrothermal transport and deposition of the REE has been severely hampered by the lack of data on the thermodynamic properties of even the most common REE minerals. The discrepancies between the predictions and experimental determinations of the thermodynamic properties of aqueous REE species, together with the paucity of data on the stability of REE minerals, raise serious questions about the reliability of some models that have been proposed for the hydrothermal mobility of these critical metals. In this contribution, we review a body of high-temperature experimental data collected over the past 15 years on the stability of REE aqueous species and minerals. Using this new thermodynamic dataset, we re-evaluate the mechanisms responsible for hydrothermal transport and deposition of themore »« less

Authors:

^[1]; Williams-Jones, A. E. ^[2]; Brugger, J. ^[3];

^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
McGill Univ., Montreal, QC (Canada)
Monash Univ., Melbourne, VIC (Australia)

Publication Date:: Sat Jun 11 00:00:00 EDT 2016

Research Org.:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: Natural Sciences and Engineering Research Council of Canada (NSERC); USDOE

OSTI Identifier:: 1351190

Report Number(s):: LA-UR-16-21989
Journal ID: ISSN 0009-2541

Grant/Contract Number:: AC52-06NA25396

Resource Type:: Accepted Manuscript

Journal Name:: Chemical Geology

Additional Journal Information:: Journal Volume: 439; Journal Issue: C; Journal ID: ISSN 0009-2541

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 58 GEOSCIENCES; earth sciences; hydrothermal; REE; transport; deposition; fractionation; rare earth elements

Citation Formats


                    Migdisov, Artaches, Williams-Jones, A. E., Brugger, J., and Caporuscio, Florie Andre. Hydrothermal transport, deposition, and fractionation of the REE: Experimental data and thermodynamic calculations.  United States: N. p., 2016. 
Web.  doi:10.1016/j.chemgeo.2016.06.005.

Copy to clipboard


                    Migdisov, Artaches, Williams-Jones, A. E., Brugger, J., & Caporuscio, Florie Andre. Hydrothermal transport, deposition, and fractionation of the REE: Experimental data and thermodynamic calculations.  United States.  https://doi.org/10.1016/j.chemgeo.2016.06.005

Copy to clipboard


                    Migdisov, Artaches, Williams-Jones, A. E., Brugger, J., and Caporuscio, Florie Andre. Sat .  
"Hydrothermal transport, deposition, and fractionation of the REE: Experimental data and thermodynamic calculations".  United States.  https://doi.org/10.1016/j.chemgeo.2016.06.005.  https://www.osti.gov/servlets/purl/1351190.

Copy to clipboard


                    
@article{osti_1351190,

  title        = {Hydrothermal transport, deposition, and fractionation of the REE: Experimental data and thermodynamic calculations},

  author       = {Migdisov, Artaches and Williams-Jones, A. E. and Brugger, J. and Caporuscio, Florie Andre},

  abstractNote = {For many years, our understanding of the behavior of the REE in hydrothermal systems was based on semi-empirical estimates involving extrapolation of thermodynamic data obtained at 25 °C. Since then, a substantial body of experimental data has accumulated on the stability of aqueous complexes of the REE. These data have shown that some of the predictions of Haas et al. (1995) are accurate, but others may be in error by several orders of magnitude. However, application of the data in modeling hydrothermal transport and deposition of the REE has been severely hampered by the lack of data on the thermodynamic properties of even the most common REE minerals. The discrepancies between the predictions and experimental determinations of the thermodynamic properties of aqueous REE species, together with the paucity of data on the stability of REE minerals, raise serious questions about the reliability of some models that have been proposed for the hydrothermal mobility of these critical metals. In this contribution, we review a body of high-temperature experimental data collected over the past 15 years on the stability of REE aqueous species and minerals. Using this new thermodynamic dataset, we re-evaluate the mechanisms responsible for hydrothermal transport and deposition of the REE. We also discuss the mechanisms that can result in REE fractionation during their hydrothermal transport and deposition. Here, our calculations suggest that in hydrothermal solutions, the main REE transporting ligands are chloride and sulfate, whereas fluoride, carbonate, and phosphate likely play an important role as depositional ligands. In addition to crystallographic fractionation, which is based on the differing affinity of mineral structures for the REE, our models suggest that the REE can be fractionated hydrothermally due to the differences in the stability of the LREE and HREE as aqueous chloride complexes.},

  doi          = {10.1016/j.chemgeo.2016.06.005},

  journal      = {Chemical Geology},

  number       = C,

  volume       = 439,

  place        = {United States},

  year         = {Sat Jun 11 00:00:00 EDT 2016},

  month        = {Sat Jun 11 00:00:00 EDT 2016}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1016/j.chemgeo.2016.06.005

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 268 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

The role of fluorine in the concentration and transport of lithophile trace elements in felsic magmas: Insights from the Gawler Range Volcanics, South Australia
journal, May 2010

Agangi, Andrea; Kamenetsky, Vadim S.; McPhie, Jocelyn
Chemical Geology, Vol. 273, Issue 3-4
DOI: 10.1016/j.chemgeo.2010.03.008

Rare earth elements in seawater: particle association, shale-normalization, and Ce oxidation
journal, February 1999

Alibo, Dia Sotto; Nozaki, Yoshiyuki
Geochimica et Cosmochimica Acta, Vol. 63, Issue 3-4
DOI: 10.1016/S0016-7037(98)00279-8

Solubility of Lanthanide Fluorides in Nitric Acid Solution in the Dissolution Process of FLUOREX Reprocessing System
journal, January 2004

Amano, Osamu; Sasahira, Akira; Kani, Yuko
Journal of Nuclear Science and Technology, Vol. 41, Issue 1
DOI: 10.1080/18811248.2004.9715457

REE composition of an aqueous magmatic fluid: A fluid inclusion study from the Capitan Pluton, New Mexico, U.S.A.
journal, April 1994

Banks, D. A.; Yardley, B. W. D.; Campbell, A. R.
Chemical Geology, Vol. 113, Issue 3-4
DOI: 10.1016/0009-2541(94)90070-1

Fluid Evolution and Origins of Iron Oxide Cu-Au Prospects in the Olympic Dam District, Gawler Craton, South Australia
journal, December 2007

Bastrakov, E. N.; Skirrow, R. G.; Davidson, G. J.
Economic Geology, Vol. 102, Issue 8
DOI: 10.2113/gsecongeo.102.8.1415

Rare-earth element mobility during hydrothermal and metamorphic fluid-rock interaction and the significance of the oxidation state of europium
journal, December 1991

Bau, Michael
Chemical Geology, Vol. 93, Issue 3-4
DOI: 10.1016/0009-2541(91)90115-8

Complex formation of trace elements in geochemical systems: stability constants of fluorocomplexes of the lanthanides in a fluorite bearing model system up to 200 °C and 1000 bar
journal, December 1987

Bilal, B. A.; Langer, P.
Inorganica Chimica Acta, Vol. 140
DOI: 10.1016/S0020-1693(00)81108-1

Thermodynamics of rare earth element partitioning between clinopyroxene and melt in the system CaO-MgO-Al2O3-SiO2
journal, January 1996

Blundy, Jon D.; Wood, Bernard J.; Davies, Alastair
Geochimica et Cosmochimica Acta, Vol. 60, Issue 2
DOI: 10.1016/0016-7037(95)00416-5

The Oxidation State of Europium in Hydrothermal Scheelite: in situ Measurement by Xanes Spectroscopy
journal, October 2006

Brugger, J.; Etschmann, B.; Chu, Y. S.
The Canadian Mineralogist, Vol. 44, Issue 5
DOI: 10.2113/gscanmin.44.5.1079

Oxidation state of europium in scheelite: Tracking fluid–rock interaction in gold deposits
journal, November 2008

Brugger, Joël; Etschmann, Barbara; Pownceby, Mark
Chemical Geology, Vol. 257, Issue 1-2
DOI: 10.1016/j.chemgeo.2008.08.003

Inhomogeneous distribution of REE in scheelite and dynamics of Archaean hydrothermal systems (Mt. Charlotte and Drysdale gold deposits, Western Australia)
journal, July 2000

Brugger, Joël; Lahaye, Yann; Costa, Sylvie
Contributions to Mineralogy and Petrology, Vol. 139, Issue 3
DOI: 10.1007/s004100000135

Origins of Nd–Sr–Pb isotopic variations in single scheelite grains from Archaean gold deposits, Western Australia
journal, February 2002

Brugger, Joël; Maas, Roland; Lahaye, Yann
Chemical Geology, Vol. 182, Issue 2-4
DOI: 10.1016/S0009-2541(01)00290-X

The effect of oxygen fugacity, melt composition, temperature and pressure on the oxidation state of cerium in silicate melts
journal, February 2014

Burnham, A. D.; Berry, A. J.
Chemical Geology, Vol. 366
DOI: 10.1016/j.chemgeo.2013.12.015

The hydration properties of Eu(II) and Eu(III): An ab initio quantum mechanical molecular dynamics study
journal, January 2015

Canaval, Lorenz R.; Rode, Bernd M.
Chemical Physics Letters, Vol. 618
DOI: 10.1016/j.cplett.2014.10.060

The aqueous geochemistry of the rare earth elements. Part XIV. The solubility of rare earth element phosphates from 23 to 150 °C
journal, April 2005

Cetiner, Ziya S.; Wood, Scott A.; Gammons, Christopher H.
Chemical Geology, Vol. 217, Issue 1-2
DOI: 10.1016/j.chemgeo.2005.01.001

Host-rock controlled epigenetic, hydrothermal metasomatic origin of the Bayan Obo REEFe-Nb ore deposit, Inner Mongolia, P.R.C.
journal, September 1992

Chao, E. C. T.; Back, J. M.; Minkin, J. A.
Applied Geochemistry, Vol. 7, Issue 5
DOI: 10.1016/0883-2927(92)90005-N

Mineral chemistry of Rare Earth Element (REE) mineralization, Browns Ranges, Western Australia
journal, July 2013

Cook, Nigel J.; Ciobanu, Cristiana L.; O'Rielly, Daniel
Lithos, Vol. 172-173
DOI: 10.1016/j.lithos.2013.04.012

Hydration of Lanthanoids(III) and Actinoids(III): An Experimental/Theoretical Saga
journal, August 2012

D'Angelo, Paola; Spezia, Riccardo
Chemistry - A European Journal, Vol. 18, Issue 36
DOI: 10.1002/chem.201200572

Experimental study of La(OH)3 and Gd(OH)3 solubilities (25 to 150°C), and La–acetate complexing (25 to 80°C)
journal, October 1998

Deberdt, Samuel; Castet, Sylvie; Dandurand, Jean-Louis
Chemical Geology, Vol. 151, Issue 1-4
DOI: 10.1016/S0009-2541(98)00089-8

Standard thermodynamic properties and heat capacity equations of rare earth hydroxides:
journal, October 1998

Diakonov, I. I.; Ragnarsdottir, K. V.; Tagirov, B. R.
Chemical Geology, Vol. 151, Issue 1-4
DOI: 10.1016/S0009-2541(98)00088-6

REE Daughter Minerals Trapped in Fluid Inclusions in the Giant Bayan Obo REE-Nb-Fe Deposit, Inner Mongolia, China
journal, July 2004

Fan, Hong-Rui; Xie, Yi-Han; Wang, Kai-Yi
International Geology Review, Vol. 46, Issue 7
DOI: 10.2747/0020-6814.46.7.638

The aqueous geochemistry of the rare earth elements and yttrium: VI. Stability of neodymium chloride complexes from 25 to 300°C
journal, December 1996

Gammons, C. H.; Wood, S. A.; Williams-Jones, A. E.
Geochimica et Cosmochimica Acta, Vol. 60, Issue 23
DOI: 10.1016/S0016-7037(96)00262-1

Thermodynamic functions of erbium orthophosphate ErPO4 in the temperature range of 0–1600K
journal, May 2012

Gavrichev, K. S.; Ryumin, M. A.; Tyurin, A. V.
Thermochimica Acta, Vol. 535
DOI: 10.1016/j.tca.2012.02.002

Heat capacity and thermodynamic functions of xenotime YPO4(c) at 0–1600 K
journal, September 2010

Gavrichev, K. S.; Ryumin, M. A.; Tyurin, A. V.
Geochemistry International, Vol. 48, Issue 9
DOI: 10.1134/S0016702910090065

Heat capacity and thermodynamic functions of YbPO4 from 0 to 1800 K
journal, June 2013

Gavrichev, K. S.; Ryumin, M. A.; Tyurin, A. V.
Inorganic Materials, Vol. 49, Issue 7
DOI: 10.1134/S0020168513070042

Heat capacity and thermodynamic functions of LuPO4 in the range 0–320K
journal, September 2006

Gavrichev, K. S.; Smirnova, N. N.; Gurevich, V. M.
Thermochimica Acta, Vol. 448, Issue 1
DOI: 10.1016/j.tca.2006.05.019

Geology, mineralogy and fluid inclusion data of the Kizilcaören fluorite–barite–REE deposit, Eskisehir, Turkey
journal, January 2003

Gültekin, Ali Haydar; Örgün, Yüksel; Suner, Fikret
Journal of Asian Earth Sciences, Vol. 21, Issue 4
DOI: 10.1016/S1367-9120(02)00019-6

Hydrothermal mobilization of pegmatite-hosted REE and Zr at Strange Lake, Canada: A reaction path model
journal, December 2013

Gysi, Alexander P.; Williams-Jones, Anthony E.
Geochimica et Cosmochimica Acta, Vol. 122
DOI: 10.1016/j.gca.2013.08.031

The thermodynamic properties of bastnäsite-(Ce) and parisite-(Ce)
journal, January 2015

Gysi, Alexander P.; Williams-Jones, Anthony E.
Chemical Geology, Vol. 392
DOI: 10.1016/j.chemgeo.2014.11.001

Experimental determination of the high temperature heat capacity of a natural xenotime-(Y) solid solution and synthetic DyPO4 and ErPO4 endmembers
journal, March 2016

Gysi, Alexander P.; Harlov, Daniel; Filho, Deusavan Costa
Thermochimica Acta, Vol. 627-629
DOI: 10.1016/j.tca.2016.01.016

The solubility of xenotime-(Y) and other HREE phosphates (DyPO 4 , ErPO 4 and YbPO 4 ) in aqueous solutions from 100 to 250 °C and p sat
journal, April 2015

Gysi, Alexander P.; Williams-Jones, Anthony E.; Harlov, Daniel
Chemical Geology, Vol. 401
DOI: 10.1016/j.chemgeo.2015.02.023

Rare earth elements in hydrothermal systems: Estimates of standard partial molal thermodynamic properties of aqueous complexes of the rare earth elements at high pressures and temperatures
journal, November 1995

Haas, Johnson R.; Shock, Everett L.; Sassani, David C.
Geochimica et Cosmochimica Acta, Vol. 59, Issue 21
DOI: 10.1016/0016-7037(95)00314-P

The lanthanum hydroxide fluoride carbonate system: The preparation of synthetic bastnaesite
journal, January 1975

Haschke, John M.
Journal of Solid State Chemistry, Vol. 12, Issue 1-2
DOI: 10.1016/0022-4596(75)90186-3

Acidity constant of hydrofluoric acid
journal, July 1984

Hefter, G. T.
Journal of Solution Chemistry, Vol. 13, Issue 7
DOI: 10.1007/BF00647171

Theoretical prediction of the thermodynamic behavior of aqueous electrolytes by high pressures and temperatures; IV, Calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600 degrees C and 5kb
journal, December 1981

Helgeson, H. C.; Kirkham, D. H.; Flowers, G. C.
American Journal of Science, Vol. 281, Issue 10
DOI: 10.2475/ajs.281.10.1249

Geological characteristics and tectonic setting of proterozoic iron oxide (CuUAuREE) deposits
journal, October 1992

Hitzman, Murray W.; Oreskes, Naomi; Einaudi, Marco T.
Precambrian Research, Vol. 58, Issue 1-4
DOI: 10.1016/0301-9268(92)90121-4

The ree Minerals of the Bastnas-Type Deposits, South-Central Sweden
journal, October 2007

Holtstam, D.; Andersson, U. B.
The Canadian Mineralogist, Vol. 45, Issue 5
DOI: 10.2113/gscanmin.45.5.1073

Synthesis and stability of bastnaesites in a part of the system (Ce,La)-F-H-C-O
journal, January 1992

Hsu, L. C.
Mineralogy and Petrology, Vol. 47, Issue 1
DOI: 10.1007/BF01165299

Determination of Solubility Products of Rare Earth Fluorides by Fluoride Ion-selective Electrode
journal, June 1984

Itoh, Hisako; Hachiya, Hiromitsu; Tsuchiya, Masashi
Bulletin of the Chemical Society of Japan, Vol. 57, Issue 6
DOI: 10.1246/bcsj.57.1689

SUPCRT92: A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000°C
journal, August 1992

Johnson, James W.; Oelkers, Eric H.; Helgeson, Harold C.
Computers & Geosciences, Vol. 18, Issue 7
DOI: 10.1016/0098-3004(92)90029-Q

Comparative hydrolysis behavior of the rare earths and yttrium: the influence of temperature and ionic strength
journal, January 2000

Klungness, Greta D.; Byrne, Robert H.
Polyhedron, Vol. 19, Issue 1
DOI: 10.1016/S0277-5387(99)00332-0

Thermodynamic properties of the lanthanide(III) halides
book, January 2003

Konings, R. J. M.; Kovács, A.
Handbook on the Physics and Chemistry of Rare Earths
DOI: 10.1016/S0168-1273(02)33003-4

The Thermodynamic Properties of the f -Elements and their Compounds. Part 2. The Lanthanide and Actinide Oxides
journal, March 2014

Konings, Rudy J. M.; Beneš, Ondrej; Kovács, Attila
Journal of Physical and Chemical Reference Data, Vol. 43, Issue 1
DOI: 10.1063/1.4825256

REE mineralization at Gakara, Burundi: Evidence for anomalous upper mantle in the western Rift Valley
journal, January 1994

Lehmann, Bernd; Nakai, Shun'ichi; Höhndorf, Axel
Geochimica et Cosmochimica Acta, Vol. 58, Issue 2
DOI: 10.1016/0016-7037(94)90520-7

Rare Earth Element Speciation in Geothermal Fluids from Yellowstone National Park, Wyoming, USA
journal, February 1998

Lewis, A. J.; Komninou, A.; Yardley, B. W. D.
Geochimica et Cosmochimica Acta, Vol. 62, Issue 4
DOI: 10.1016/S0016-7037(97)00367-0

Re-Os dating of pyrite from Giant Bayan Obo REE-Nb-Fe deposit
journal, January 2004

Liu, Yulong
Chinese Science Bulletin, Vol. 49, Issue 24
DOI: 10.1360/04wd0185

Comparative carbonate complexation of yttrium and gadolinium at 25 °C and 0.7 mol dm−3 ionic strength
journal, December 1995

Liu, Xuewu; Byrne, Robert H.
Marine Chemistry, Vol. 51, Issue 3
DOI: 10.1016/0304-4203(95)00067-4

Rare earth and yttrium phosphate solubilities in aqueous solution
journal, April 1997

Liu, Xuewu; Byrne, Robert H.
Geochimica et Cosmochimica Acta, Vol. 61, Issue 8
DOI: 10.1016/S0016-7037(97)00037-9

An experimental study of the aqueous solubility and speciation of Y(III) fluoride at temperatures up to 250°C
journal, December 2013

Loges, Anselm; Migdisov, Artas A.; Wagner, Thomas
Geochimica et Cosmochimica Acta, Vol. 123
DOI: 10.1016/j.gca.2013.07.031

Hydrothermal controls on the genesis of REE deposits: Insights from an in situ XAS study of Yb solubility and speciation in high temperature fluids (T < 400 °C)
journal, December 2015

Louvel, Marion; Bordage, Amélie; Testemale, Denis
Chemical Geology, Vol. 417
DOI: 10.1016/j.chemgeo.2015.10.011

Structural Study of the N,N′ -Dimethylpropyleneurea Solvated Lanthanoid(III) Ions in Solution and Solid State with an Analysis of the Ionic Radii of Lanthanoid(III) Ions
journal, May 2010

Lundberg, Daniel; Persson, Ingmar; Eriksson, Lars
Inorganic Chemistry, Vol. 49, Issue 10
DOI: 10.1021/ic100034q

Carbonate complexation of yttrium and the rare earth elements in natural waters
journal, February 2004

Luo, Yu-Ran; Byrne, Robert H.
Geochimica et Cosmochimica Acta, Vol. 68, Issue 4
DOI: 10.1016/S0016-7037(03)00495-2

The Influence of Ionic Strength on Yttrium and Rare Earth Element Complexation by Fluoride Ions in NaClO4, NaNO3 and NaCl Solutions at 25 °C
journal, May 2007

Luo, Yu-Ran; Byrne, Robert H.
Journal of Solution Chemistry, Vol. 36, Issue 6
DOI: 10.1007/s10953-007-9141-6

Effects of temperature and ionic strength on the stabilities of the first and second fluoride complexes of yttrium and the rare earth elements
journal, November 2004

Luo, Yanxin; Millero, F. J.
Geochimica et Cosmochimica Acta, Vol. 68, Issue 21
DOI: 10.1016/j.gca.2004.05.025

On the formation and structure of rare-earth element complexes in aqueous solutions under hydrothermal conditions with new data on gadolinium aqua and chloro complexes
journal, April 2007

Mayanovic, Robert A.; Anderson, Alan J.; Bassett, William A.
Chemical Geology, Vol. 239, Issue 3-4
DOI: 10.1016/j.chemgeo.2006.10.004

Steric hindrance and the enhanced stability of light rare-earth elements in hydrothermal fluids
journal, October 2009

Mayanovic, R. A.; Anderson, A. J.; Bassett, W. A.
American Mineralogist, Vol. 94, Issue 10
DOI: 10.2138/am.2009.3250

The structure and stability of aqueous rare-earth elements in hydrothermal fluids: New results on neodymium(III) aqua and chloroaqua complexes in aqueous solutions to 500 °C and 520 MPa
journal, February 2009

Mayanovic, Robert A.; Anderson, Alan J.; Bassett, William A.
Chemical Geology, Vol. 259, Issue 1-2
DOI: 10.1016/j.chemgeo.2008.08.011

The Structure of Yb ³⁺ Aquo Ion and Chloro Complexes in Aqueous Solutions at Up to 500 °C and 270 MPa
journal, June 2002

Mayanovic, Robert A.; Jayanetti, Sumedha; Anderson, Alan J.
The Journal of Physical Chemistry A, Vol. 106, Issue 28
DOI: 10.1021/jp020140q

Ab initio molecular dynamics simulation and free energy exploration of copper(I) complexation by chloride and bisulfide in hydrothermal fluids
journal, February 2013

Mei, Yuan; Sherman, David M.; Liu, Weihua
Geochimica et Cosmochimica Acta, Vol. 102
DOI: 10.1016/j.gca.2012.10.027

Solubilities, solubility products and solution chemistry of lanthanon trifluoride–water systems
journal, January 1989

Menon, Manchery P.; James, Jeffrey
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 85, Issue 9
DOI: 10.1039/f19898502683

Geology and geochemistry of the Snowbird Deposit, Mineral County, Montana
journal, April 1985

Metz, Michael C.; Brookins, Douglas G.; Rosenberg, P. E.
Economic Geology, Vol. 80, Issue 2
DOI: 10.2113/gsecongeo.80.2.394

A spectrophotometric study of neodymium(III) complexation in chloride solutions
journal, December 2002

Migdisov, Art A.; Williams-Jones, A. E.
Geochimica et Cosmochimica Acta, Vol. 66, Issue 24
DOI: 10.1016/S0016-7037(02)00995-X

A spectrophotometric study of erbium (III) speciation in chloride solutions at elevated temperatures
journal, October 2006

Migdisov, Art. A.; Williams-Jones, A. E.
Chemical Geology, Vol. 234, Issue 1-2
DOI: 10.1016/j.chemgeo.2006.04.002

An experimental study of the solubility and speciation of neodymium (III) fluoride in F-bearing aqueous solutions
journal, June 2007

Migdisov, Art A.; Williams-Jones, A. E.
Geochimica et Cosmochimica Acta, Vol. 71, Issue 12
DOI: 10.1016/j.gca.2007.04.004

A spectrophotometric study of Nd(III), Sm(III) and Er(III) complexation in sulfate-bearing solutions at elevated temperatures
journal, November 2008

Migdisov, Art. A.; Williams-Jones, A. E.
Geochimica et Cosmochimica Acta, Vol. 72, Issue 21
DOI: 10.1016/j.gca.2008.08.002

Hydrothermal transport and deposition of the rare earth elements by fluorine-bearing aqueous liquids
journal, August 2014

Migdisov, Art A.; Williams-Jones, A. E.
Mineralium Deposita, Vol. 49, Issue 8
DOI: 10.1007/s00126-014-0554-z

A spectrophotometric study of neodymium(III) complexation in sulfate solutions at elevated temperatures
journal, February 2006

Migdisov, Art. A.; Reukov, V. V.; Williams-Jones, A. E.
Geochimica et Cosmochimica Acta, Vol. 70, Issue 4
DOI: 10.1016/j.gca.2005.11.001

A spectrophotometric study of samarium (III) speciation in chloride solutions at elevated temperatures
journal, March 2008

Migdisov, Art. A.; Williams-Jones, A. E.; Normand, C.
Geochimica et Cosmochimica Acta, Vol. 72, Issue 6
DOI: 10.1016/j.gca.2008.01.007

An experimental study of the solubility and speciation of the Rare Earth Elements (III) in fluoride- and chloride-bearing aqueous solutions at temperatures up to 300°C
journal, December 2009

Migdisov, Art. A.; Williams-Jones, A. E.; Wagner, T.
Geochimica et Cosmochimica Acta, Vol. 73, Issue 23
DOI: 10.1016/j.gca.2009.08.023

IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 1. Scandium Group (Sc, Y, La)
journal, December 2008

Mioduski, Tomasz; Gumiński, Cezary; Zeng, Dewen
Journal of Physical and Chemical Reference Data, Vol. 37, Issue 4
DOI: 10.1063/1.2956740

IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 2. Light Lanthanides (Ce–Eu)
journal, June 2009

Mioduski, Tomasz; Gumiński, Cezary; Zeng, Dewen
Journal of Physical and Chemical Reference Data, Vol. 38, Issue 2
DOI: 10.1063/1.3112775

IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (Gd–Lu)
journal, December 2009

Mioduski, Tomasz; Gumiński, Cezary; Zeng, Dewen
Journal of Physical and Chemical Reference Data, Vol. 38, Issue 4
DOI: 10.1063/1.3212962

Microbially mediated cerium oxidation in sea water
journal, May 1990

Moffett, James W.
Nature, Vol. 345, Issue 6274
DOI: 10.1038/345421a0

Structural Investigation of the Aqueous Eu ²⁺ Ion: Comparison with Sr ²⁺ Using the XAFS Technique
journal, March 2002

Moreau, Gilles; Helm, Lothar; Purans, Juris
The Journal of Physical Chemistry A, Vol. 106, Issue 12
DOI: 10.1021/jp0139639

Thermodynamics of solid phases containing rare earth oxides
journal, September 2015

Navrotsky, Alexandra; Lee, Wingyee; Mielewczyk-Gryn, Aleksandra
The Journal of Chemical Thermodynamics, Vol. 88
DOI: 10.1016/j.jct.2015.04.008

Calculation of activity coefficients and degrees of formation of neutral ion pairs in supercritical electrolyte solutions
journal, May 1991

Oelkers, Eric H.; Helgeson, Harold C.
Geochimica et Cosmochimica Acta, Vol. 55, Issue 5
DOI: 10.1016/0016-7037(91)90303-M

² H and ¹³⁹ La NMR Spectroscopy in Aqueous Solutions at Geochemical Pressures
journal, September 2015

Ochoa, Gerardo; Pilgrim, Corey D.; Martin, Michele N.
Angewandte Chemie International Edition, Vol. 54, Issue 51
DOI: 10.1002/anie.201507773

Origin of hydrothermal fluids at Olympic Dam; preliminary results from fluid inclusions and stable isotopes
journal, February 1992

Oreskes, Naomi; Einaudi, Marco T.
Economic Geology, Vol. 87, Issue 1
DOI: 10.2113/gsecongeo.87.1.64

Hydrated metal ions in aqueous solution: How regular are their structures?
journal, August 2010

Persson, Ingmar
Pure and Applied Chemistry, Vol. 82, Issue 10
DOI: 10.1351/PAC-CON-09-10-22

Hydration of Lanthanoid(III) Ions in Aqueous Solution and Crystalline Hydrates Studied by EXAFS Spectroscopy and Crystallography: The Myth of the “Gadolinium Break”
journal, March 2008

Persson, Ingmar; D'Angelo, Paola; De Panfilis, Simone
Chemistry - A European Journal, Vol. 14, Issue 10
DOI: 10.1002/chem.200701281

Ab Initio Molecular Dynamics Study of a Highly Concentrated LiCl Aqueous Solution
journal, May 2008

Petit, L.; Vuilleumier, R.; Maldivi, P.
Journal of Chemical Theory and Computation, Vol. 4, Issue 7
DOI: 10.1021/ct800007v

Experimental determination of synthetic NdPO4 monazite end-member solubility in water from 21°C to 300°C: implications for rare earth element mobility in crustal fluids
journal, May 2004

Poitrasson, Franck; Oelkers, Eric; Schott, Jacques
Geochimica et Cosmochimica Acta, Vol. 68, Issue 10
DOI: 10.1016/j.gca.2003.12.010

High-temperature heat capacities of EuPO4 and SmPO4 synthetic monazites
journal, June 2006

Popa, K.; Konings, R. J. M.
Thermochimica Acta, Vol. 445, Issue 1
DOI: 10.1016/j.tca.2006.03.023

Solubility measurements of synthetic neodymium monazite as a function of temperature at 2kbars, and aqueous neodymium speciation in equilibrium with monazite
journal, March 2010

Pourtier, Emilie; Devidal, Jean-Luc; Gibert, François
Geochimica et Cosmochimica Acta, Vol. 74, Issue 6
DOI: 10.1016/j.gca.2009.12.023

Aqueous speciation of yttrium at temperatures from 25 to 340°C at Psat: an in situ EXAFS study
journal, October 1998

Vala Ragnarsdottir, K.; Oelkers, Eric H.; Sherman, David M.
Chemical Geology, Vol. 151, Issue 1-4
DOI: 10.1016/S0009-2541(98)00068-0

Intracrystalline rare earth element distributions in apatite: Surface structural influences on incorporation during growth
journal, November 1996

Rakovan, John; Reeder, Richard J.
Geochimica et Cosmochimica Acta, Vol. 60, Issue 22
DOI: 10.1016/S0016-7037(96)00244-X

Evidence of heterovalent europium in zoned Llallagua apatite using wavelength dispersive XANES
journal, May 2001

Rakovan, John; Newville, Matthew; Sutton, Steve
American Mineralogist, Vol. 86, Issue 5-6
DOI: 10.2138/am-2001-5-610

Hydrothermal ree Fluorocarbonate Mineralization at Barra do Itapirapua, a Multiple Stockwork Carbonatite, Southern Brazil
journal, August 2008

Ruberti, E.; Enrich, G. E. R.; Gomes, C. B.
The Canadian Mineralogist, Vol. 46, Issue 4
DOI: 10.3749/canmin.46.4.901

Lanthanide(III) halides: Thermodynamic properties and their correlation with crystal structure
journal, February 2008

Rycerz, L.; Gaune-Escard, M.
Journal of Alloys and Compounds, Vol. 450, Issue 1-2
DOI: 10.1016/j.jallcom.2006.12.096

The role of hydrothermal processes in concentrating high-field strength elements in the Strange Lake peralkaline complex, northeastern Canada
journal, June 1996

Salvi, Stefano; Williams-Jones, Anthony E.
Geochimica et Cosmochimica Acta, Vol. 60, Issue 11
DOI: 10.1016/0016-7037(96)00071-3

Determination of stability constants for the mono- and difluoro-complexes of Y and the REE, using a cation-exchange resin and ICP-MS
journal, September 1999

Schijf, Johan; Byrne, Robert H.
Polyhedron, Vol. 18, Issue 22
DOI: 10.1016/S0277-5387(99)00205-3

Determination of SO4β1 for yttrium and the rare earth elements at I = 0.66 m and t = 25°C—implications for YREE solution speciation in sulfate-rich waters
journal, July 2004

Schijf, Johan; Byrne, Robert H.
Geochimica et Cosmochimica Acta, Vol. 68, Issue 13
DOI: 10.1016/j.gca.2003.12.003

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Shannon, R. D.
Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
DOI: 10.1107/S0567739476001551

Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Correlation algorithms for ionic species and equation of state predictions to 5 kb and 1000°C
journal, August 1988

Shock, Everett L.; Helgeson, Harold C.
Geochimica et Cosmochimica Acta, Vol. 52, Issue 8
DOI: 10.1016/0016-7037(88)90181-0

Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes
journal, March 1997

Shock, Everett L.; Sassani, David C.; Willis, Marc
Geochimica et Cosmochimica Acta, Vol. 61, Issue 5
DOI: 10.1016/S0016-7037(96)00339-0

Coordination of ions in aqueous solutions of erbium chloride from X-ray diffraction data
journal, August 2013

Smirnov, P. R.; Grechin, O. V.
Russian Journal of Coordination Chemistry, Vol. 39, Issue 9
DOI: 10.1134/S1070328413090078

Preliminary Fluid Inclusion Constraints on Fluid Evolution in the Bayan Obo Fe-REE-Nb Deposit, Inner Mongolia, China
journal, November 2000

Smith, M. P.; Henderson, P.
Economic Geology, Vol. 95, Issue 7
DOI: 10.2113/gsecongeo.95.7.1371

Fractionation of the REE during hydrothermal processes: constraints from the Bayan Obo Fe-REE-Nb deposit, Inner Mongolia, China.
journal, September 2000

Smith, M. P.; Henderson, P.; Campbell, L. S.
Geochimica et Cosmochimica Acta, Vol. 64, Issue 18
DOI: 10.1016/S0016-7037(00)00416-6

Structures and Energetics of Erbium Chloride Complexes in Aqueous Solution
journal, June 2009

Soderholm, L.; Skanthakumar, S.; Wilson, Richard E.
The Journal of Physical Chemistry A, Vol. 113, Issue 22
DOI: 10.1021/jp9012366

Spectrophotometric study of Nd, Sm, and Ho complexation in chloride solutions at 100–250°C
journal, March 2005

Stepanchikova, S. A.; Kolonin, G. R.
Russian Journal of Coordination Chemistry, Vol. 31, Issue 3
DOI: 10.1007/s11173-005-0076-4

An experimental study of hydroxo complex formation in basic and near-neutral solutions of rare-earth elements and yttrium at 25 ºC
journal, August 2014

Stepanchikova, S. A.; Biteikina, R. P.; Shironosova, G. P.
Russian Geology and Geophysics, Vol. 55, Issue 8
DOI: 10.1016/j.rgg.2014.07.002

Europium redox equilibria in aqueous solution
journal, January 1984

Sverjensky, Dimitri A.
Earth and Planetary Science Letters, Vol. 67, Issue 1
DOI: 10.1016/0012-821X(84)90039-6

Prediction of the thermodynamic properties of aqueous metal complexes to 1000°C and 5 kb
journal, April 1997

Sverjensky, D. A.; Shock, E. L.; Helgeson, H. C.
Geochimica et Cosmochimica Acta, Vol. 61, Issue 7
DOI: 10.1016/S0016-7037(97)00009-4

Experimental study of dissociation of HCl from 350 to 500°C and from 500 to 2500 bars: Thermodynamic properties of HCl°(aq)
journal, October 1997

Tagirov, B. R.; Zotov, A. V.; Akinfiev, N. N.
Geochimica et Cosmochimica Acta, Vol. 61, Issue 20
DOI: 10.1016/S0016-7037(97)00274-3

Determination of the Eu(II)/Eu(III) ratios in minerals by X-ray absorption near-edge structure (XANES) and its application to hydrothermal deposits
journal, April 2005

Takahashi, Y.; Kolonin, G. R.; Shironosova, G. P.
Mineralogical Magazine, Vol. 69, Issue 2
DOI: 10.1180/0026461056920245

Density functional theory based molecular dynamics study of hydration and electronic properties of aqueous La3+
journal, July 2010

Terrier, Cyril; Vitorge, Pierre; Gaigeot, Marie-Pierre
The Journal of Chemical Physics, Vol. 133, Issue 4
DOI: 10.1063/1.3460813

In-situ X-ray absorption study of Iron(II) speciation in brines up to supercritical conditions
journal, June 2009

Testemale, Denis; Brugger, Joël; Liu, Weihua
Chemical Geology, Vol. 264, Issue 1-4
DOI: 10.1016/j.chemgeo.2009.03.014

The Nature and Origin of the REE Mineralization in the Wicheeda Carbonatite, British Columbia, Canada
journal, January 2016

Trofanenko, J.; Williams-Jones, A. E.; Simandl, G. J.
Economic Geology, Vol. 111, Issue 1
DOI: 10.2113/econgeo.111.1.199

Reading the mineral record of fluid composition from element partitioning
journal, September 2010

van Hinsberg, Vincent J.; Migdisov, Artasches A.; Williams-Jones, Anthony E.
Geology, Vol. 38, Issue 9
DOI: 10.1130/G31112.1

The Karonge rare earth deposits, Republic of Burundi: New mineralogical-geochemical data and origin of the mineralization
journal, November 1977

Van Wambeke, L.
Mineralium Deposita, Vol. 12, Issue 3
DOI: 10.1007/BF00206173

A Special Orogenic-type Rare Earth Element Deposit in Maoniuping, Sichuan, China: Geology and Geochemistry
journal, September 2001

Wang, Denghong; Yang, Jianmin; Yan, Shenghao
Resource Geology, Vol. 51, Issue 3
DOI: 10.1111/j.1751-3928.2001.tb00090.x

A Detailed Assessment of Global Rare Earth Element Resources: Opportunities and Challenges
journal, November 2015

Weng, Zhehan; Jowitt, Simon M.; Mudd, Gavin M.
Economic Geology, Vol. 110, Issue 8
DOI: 10.2113/econgeo.110.8.1925

A preliminary petrogenetic grid for REE fluorocarbonates and associated minerals
journal, February 1992

Williams-Jones, Anthony E.; Wood, Scott A.
Geochimica et Cosmochimica Acta, Vol. 56, Issue 2
DOI: 10.1016/0016-7037(92)90093-X

Hydrothermal Mobilisation of the Rare Earth Elements - a Tale of "Ceria" and "Yttria"
journal, October 2012

Williams-Jones, A. E.; Migdisov, A. A.; Samson, I. M.
Elements, Vol. 8, Issue 5
DOI: 10.2113/gselements.8.5.355

The Genesis of Hydrothermal Fluorite-REE Deposits in the Gallinas Mountains, New Mexico
journal, March 2000

Williams-Jones, A. E.; Samson, I. M.; Olivo, G. R.
Economic Geology, Vol. 95, Issue 2
DOI: 10.2113/gsecongeo.95.2.327

The aqueous geochemistry of the rare-earth elements and yttrium
journal, October 1990

Wood, Scott A.
Chemical Geology, Vol. 88, Issue 1-2
DOI: 10.1016/0009-2541(90)90106-H

The aqueous geochemistry of the rare-earth elements and yttrium
journal, January 1990

Wood, Scott A.
Chemical Geology, Vol. 82
DOI: 10.1016/0009-2541(90)90080-Q

Trace-element modeling of the magmatic evolution of rare-earth-rich carbonatite from the Miaoya deposit, Central China
journal, July 2010

Xu, Cheng; Kynicky, Jindrich; Chakhmouradian, Anton R.
Lithos, Vol. 118, Issue 1-2
DOI: 10.1016/j.lithos.2010.04.003

Works referencing / citing this record:

Numerical Modeling of REE Fractionation Patterns in Fluorapatite from the Olympic Dam Deposit (South Australia)
journal, August 2018

Krneta, Sasha; Ciobanu, Cristiana; Cook, Nigel
Minerals, Vol. 8, Issue 8
DOI: 10.3390/min8080342

The Petyayan-Vara Carbonatite-Hosted Rare Earth Deposit (Vuoriyarvi, NW Russia): Mineralogy and Geochemistry
journal, January 2020

Kozlov, Evgeniy; Fomina, Ekaterina; Sidorov, Mikhail
Minerals, Vol. 10, Issue 1
DOI: 10.3390/min10010073

Uranium Transport in F-Cl-Bearing Fluids and Hydrothermal Upgrading of U-Cu Ores in IOCG Deposits
journal, August 2018

Xing, Yanlu; Mei, Yuan; Etschmann, Barbara
Geofluids, Vol. 2018
DOI: 10.1155/2018/6835346

Crystal chemistry of titanite from the Roxby Downs Granite, South Australia: insights into petrogenesis, subsolidus evolution and hydrothermal alteration
journal, June 2019

Kontonikas-Charos, Alkiviadis; Ehrig, Kathy; Cook, Nigel J.
Contributions to Mineralogy and Petrology, Vol. 174, Issue 7
DOI: 10.1007/s00410-019-1594-2

Open Apatite Sr Isotopic System in Low‐Temperature Hydrous Regimes
journal, November 2019

Cao, Mingjian; Evans, Noreen J.; Qin, Kezhang
Journal of Geophysical Research: Solid Earth, Vol. 124, Issue 11
DOI: 10.1029/2019jb018085

REY and Trace Element Chemistry of Fluorite from Post-Variscan Hydrothermal Veins in Paleozoic Units of the North German Basin
journal, July 2018

Nadoll, Patrick; Rehm, Meike; Duschl, Florian
Geosciences, Vol. 8, Issue 8
DOI: 10.3390/geosciences8080283

Ion Association in Lanthanide Chloride Solutions
journal, May 2019

Finney, Aaron R.; Lectez, Sébastien; Freeman, Colin L.
Chemistry – A European Journal
DOI: 10.1002/chem.201900945

Mineralogical constraints on Nb–REE mineralization of the Zhujiayuan Nb (−REE) deposit in the North Daba Mountain, South Qinling, China
journal, December 2019

Nie, Xiao; Wang, Zongqi; Chen, Lei
Geological Journal, Vol. 55, Issue 6
DOI: 10.1002/gj.3710

Rare Earth Elements in Mineral Deposits: Speciation in Hydrothermal Fluids and Partitioning in Calcite
journal, January 2018

Perry, Emily P.; Gysi, Alexander P.
Geofluids, Vol. 2018
DOI: 10.1155/2018/5382480

The s in Hydrothermal Systems
book, January 2019

Migdisov, Artaches (Artas); Xu, Hongwu; Williams‐Jones, Anthony E.
Encyclopedia of Water: Science, Technology, and Society
DOI: 10.1002/9781119300762.wsts0079

Hydrothermal Alteration of Eudialyte-Hosted Critical Metal Deposits: Fluid Source and Implications for Deposit Grade
journal, July 2019

van de Ven, Mathijs A. J.; Borst, Anouk M.; Davies, Gareth R.
Minerals, Vol. 9, Issue 7
DOI: 10.3390/min9070422

Carbonatites: related ore deposits, resources, footprint, and exploration methods
journal, October 2018

Simandl, George J.; Paradis, Suzanne
Applied Earth Science, Vol. 127, Issue 4
DOI: 10.1080/25726838.2018.1516935

Hydrothermal formation of heavy rare earth element (HREE)–xenotime deposits at 100 °C in a sedimentary basin
journal, January 2018

Richter, Lisa; Diamond, Larryn W.; Atanasova, Petya
Geology, Vol. 46, Issue 3
DOI: 10.1130/g39871.1

Critical Elements in Supergene Phosphates: The Example of the Weathering Profile at the Gavà Neolithic Mines, Catalonia, Spain
journal, December 2019

Díaz-Acha, Yael; Campeny, Marc; Tauler, Esperança
Minerals, Vol. 10, Issue 1
DOI: 10.3390/min10010003

Fractionation of Rare Earth Elements in Greisen and Hydrothermal Veins Related to A-Type Magmatism
journal, August 2019

Tillberg, Mikael; Maskenskaya, Olga M.; Drake, Henrik
Geofluids, Vol. 2019
DOI: 10.1155/2019/4523214

Hydrothermal formation of heavy rare earth element (HREE)–xenotime deposits at 100 °C in a sedimentary basin
text, January 2018

Richter, Lisa; Diamond, Larryn William; Atanasova, Petya
Geological Society of America
DOI: 10.7892/boris.112805

Similar Records in DOE PAGES and OSTI.GOV collections:

Fractionation of REE, U, and Th in natural ore-forming hydrothermal systems: Thermodynamic modeling

Journal Article Migdissov, Artaches ; Guo, Xiaofeng ; Nisbet, Haylea Dawn ; ... - Journal of Chemical Thermodynamics

This contribution presents a thermodynamic model revealing the mechanisms responsible for separation of Heavy and Light Rare Earth (HREE and LREE) phosphates in natural hydrothermal systems at temperatures of 250–350 °C. Our calculations were performed for an isothermal column of rock containing 0.5 wt% of apatite (Ca phosphate), which served as an immobilizing agent for REE dissolved in the solution. REE were transported by 10 wt% NaCl acidic solution. The model accounted for formation of REE phosphate solid solutions through a regular mixing model. It demonstrates that hydrothermal flushing can efficiently separate REE forming xenotime (HREE phosphate solid solutions) atmore »« less
Cited by 25
https://doi.org/10.1016/j.jct.2018.08.032

Full Text Available
Optimized thermodynamic properties of REE aqueous species (REE³⁺ and REEOH²⁺) and experimental database for modeling the solubility of REE phosphate minerals (monazite, xenotime, and rhabdophane) from 25 to 300 °C

Journal Article Pan, Ruiguang ; Gysi, Alexander P. ; Miron, George D. ; ... - Chemical Geology

Rare earth elements (REE) are critical elements found in monazite, xenotime, and hydrated REE phosphates which typically form in hydrothermal mineral deposits. Accurate predictions of the solubility of these REE phosphates and the speciation of REE in aqueous fluids are both key to understanding the controls on the transport, fractionation, and deposition of REE in natural systems. Previous monazite and xenotime solubility experiments indicate the presence of large discrepancies between experimentally derived solubility constants versus calculated solubilities by combining different data sources for the thermodynamic properties of minerals and aqueous species at hydrothermal conditions. In this study, these discrepancies weremore »« less
https://doi.org/10.1016/j.chemgeo.2023.121817
Yttrium and rare earth elements in fluids from various deep-sea hydrothermal systems

Journal Article Douville, E ; IFREMER Centre de Brest, Plouzane ; Appriou, P ; ... - Geochimica et Cosmochimica Acta

Rare earth element (REE) and yttrium (Y) concentrations were measured in fluids collected from deep-sea hydrothermal systems including the Mid-Atlantic Ridge (MAR), i.e., Menez Gwen, Lucky Strike, TAG, and Snakepit; the East Pacific Rise (EPR), i.e., 13{degree}N and 17--19{degree}S; and the Lau (Vai Lili) and Manus (Vienna Woods, PacManus, Desmos) Back-arc Basins (BAB) in the South-West Pacific. In most fluids, Y is trivalent and behaves like Ho. Chondrite normalized Y-REE (Y-REE{sub N}) concentrations of fluids from MAR, EPR, and two BAB sites, i.e., Vai Lili and Vienna Woods, showed common patterns with LREE enrichment and positive Eu anomalies. REE analysismore »« less
https://doi.org/10.1016/S0016-7037(99)00024-1
Mineralogical, Chemical, and Isotopic Characterization of Fracture-Coating Minerals in Borehole Samples from Western Pahute Mesa and Oasis Valley, Nevada

Technical Report Benedict, F C ; Rose, T P ; Zhou, X

This report summarizes the results of a mineralogical and geochemical investigation of fracture-coating phases obtained from archived borehole core and cuttings samples from the western Pahute Mesa-Oasis Valley region. The objective is to provide data needed to validate UGTA flow and transport models for this region. Fracture-lining minerals were characterized using micrographic techniques (SEM-EDS), and selected calcite samples were analyzed for their stable isotope ({sup 13}C/{sup 12}C and {sup 18}O/{sup 16}O) and rare earth element (REE) abundances. The main conclusions are as follows: (1) The distribution of fracture-lining mineral phases is a function of primary rock type, the style andmore »« less
https://doi.org/10.2172/15006451

Full Text Available
The solubility of thorium in carbonate-bearing solutions at hydrothermal conditions

Journal Article Nisbet, Haylea Dawn ; Migdissov, Artaches ; Williams-Jones, A. E. ; ... - Geochimica et Cosmochimica Acta

Thorium mineralization is frequently hosted in carbonate-bearing rocks, and thorium commonly substitutes into the structures of carbonate-bearing minerals that have precipitated from or been modified by hydrothermal fluids. Given this common association, it is reasonable to consider the hypothesis that the presence of carbonate ligands in hydrothermal solutions promotes the transport of Th through the formation of stable aqueous complexes. Our ability to evaluate this hypothesis, however, is hindered by the lack of experimental data for Th-carbonate species at conditions beyond ambient. The low-temperature data indicate that carbonate is a strong complexing agent for Th. In this contribution, we investigatemore »« less
https://doi.org/10.1016/j.gca.2021.04.035

Full Text Available

Similar Records

Title: Hydrothermal transport, deposition, and fractionation of the REE: Experimental data and thermodynamic calculations

Abstract

Citation Formats

The role of fluorine in the concentration and transport of lithophile trace elements in felsic magmas: Insights from the Gawler Range Volcanics, South Australia journal, May 2010

Rare earth elements in seawater: particle association, shale-normalization, and Ce oxidation journal, February 1999

Solubility of Lanthanide Fluorides in Nitric Acid Solution in the Dissolution Process of FLUOREX Reprocessing System journal, January 2004

REE composition of an aqueous magmatic fluid: A fluid inclusion study from the Capitan Pluton, New Mexico, U.S.A. journal, April 1994

Fluid Evolution and Origins of Iron Oxide Cu-Au Prospects in the Olympic Dam District, Gawler Craton, South Australia journal, December 2007

Rare-earth element mobility during hydrothermal and metamorphic fluid-rock interaction and the significance of the oxidation state of europium journal, December 1991

Complex formation of trace elements in geochemical systems: stability constants of fluorocomplexes of the lanthanides in a fluorite bearing model system up to 200 °C and 1000 bar journal, December 1987

Thermodynamics of rare earth element partitioning between clinopyroxene and melt in the system CaO-MgO-Al2O3-SiO2 journal, January 1996

The Oxidation State of Europium in Hydrothermal Scheelite: in situ Measurement by Xanes Spectroscopy journal, October 2006

Oxidation state of europium in scheelite: Tracking fluid–rock interaction in gold deposits journal, November 2008

Inhomogeneous distribution of REE in scheelite and dynamics of Archaean hydrothermal systems (Mt. Charlotte and Drysdale gold deposits, Western Australia) journal, July 2000

Origins of Nd–Sr–Pb isotopic variations in single scheelite grains from Archaean gold deposits, Western Australia journal, February 2002

The effect of oxygen fugacity, melt composition, temperature and pressure on the oxidation state of cerium in silicate melts journal, February 2014

The hydration properties of Eu(II) and Eu(III): An ab initio quantum mechanical molecular dynamics study journal, January 2015

The aqueous geochemistry of the rare earth elements. Part XIV. The solubility of rare earth element phosphates from 23 to 150 °C journal, April 2005

Host-rock controlled epigenetic, hydrothermal metasomatic origin of the Bayan Obo REEFe-Nb ore deposit, Inner Mongolia, P.R.C. journal, September 1992

Mineral chemistry of Rare Earth Element (REE) mineralization, Browns Ranges, Western Australia journal, July 2013

Hydration of Lanthanoids(III) and Actinoids(III): An Experimental/Theoretical Saga journal, August 2012

Experimental study of La(OH)3 and Gd(OH)3 solubilities (25 to 150°C), and La–acetate complexing (25 to 80°C) journal, October 1998

Standard thermodynamic properties and heat capacity equations of rare earth hydroxides: journal, October 1998

REE Daughter Minerals Trapped in Fluid Inclusions in the Giant Bayan Obo REE-Nb-Fe Deposit, Inner Mongolia, China journal, July 2004

The aqueous geochemistry of the rare earth elements and yttrium: VI. Stability of neodymium chloride complexes from 25 to 300°C journal, December 1996

Thermodynamic functions of erbium orthophosphate ErPO4 in the temperature range of 0–1600K journal, May 2012

Heat capacity and thermodynamic functions of xenotime YPO4(c) at 0–1600 K journal, September 2010

Heat capacity and thermodynamic functions of YbPO4 from 0 to 1800 K journal, June 2013

Heat capacity and thermodynamic functions of LuPO4 in the range 0–320K journal, September 2006

Geology, mineralogy and fluid inclusion data of the Kizilcaören fluorite–barite–REE deposit, Eskisehir, Turkey journal, January 2003

Hydrothermal mobilization of pegmatite-hosted REE and Zr at Strange Lake, Canada: A reaction path model journal, December 2013

The thermodynamic properties of bastnäsite-(Ce) and parisite-(Ce) journal, January 2015

Experimental determination of the high temperature heat capacity of a natural xenotime-(Y) solid solution and synthetic DyPO4 and ErPO4 endmembers journal, March 2016

The solubility of xenotime-(Y) and other HREE phosphates (DyPO 4 , ErPO 4 and YbPO 4 ) in aqueous solutions from 100 to 250 °C and p sat journal, April 2015

Rare earth elements in hydrothermal systems: Estimates of standard partial molal thermodynamic properties of aqueous complexes of the rare earth elements at high pressures and temperatures journal, November 1995

The lanthanum hydroxide fluoride carbonate system: The preparation of synthetic bastnaesite journal, January 1975

Acidity constant of hydrofluoric acid journal, July 1984

Theoretical prediction of the thermodynamic behavior of aqueous electrolytes by high pressures and temperatures; IV, Calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600 degrees C and 5kb journal, December 1981

Geological characteristics and tectonic setting of proterozoic iron oxide (CuUAuREE) deposits journal, October 1992

The ree Minerals of the Bastnas-Type Deposits, South-Central Sweden journal, October 2007

Synthesis and stability of bastnaesites in a part of the system (Ce,La)-F-H-C-O journal, January 1992

Determination of Solubility Products of Rare Earth Fluorides by Fluoride Ion-selective Electrode journal, June 1984

SUPCRT92: A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000°C journal, August 1992

Comparative hydrolysis behavior of the rare earths and yttrium: the influence of temperature and ionic strength journal, January 2000

Thermodynamic properties of the lanthanide(III) halides book, January 2003

The Thermodynamic Properties of the f -Elements and their Compounds. Part 2. The Lanthanide and Actinide Oxides journal, March 2014

REE mineralization at Gakara, Burundi: Evidence for anomalous upper mantle in the western Rift Valley journal, January 1994

Rare Earth Element Speciation in Geothermal Fluids from Yellowstone National Park, Wyoming, USA journal, February 1998

Re-Os dating of pyrite from Giant Bayan Obo REE-Nb-Fe deposit journal, January 2004

Comparative carbonate complexation of yttrium and gadolinium at 25 °C and 0.7 mol dm−3 ionic strength journal, December 1995

Rare earth and yttrium phosphate solubilities in aqueous solution journal, April 1997

An experimental study of the aqueous solubility and speciation of Y(III) fluoride at temperatures up to 250°C journal, December 2013

Hydrothermal controls on the genesis of REE deposits: Insights from an in situ XAS study of Yb solubility and speciation in high temperature fluids (T < 400 °C) journal, December 2015

Structural Study of the N,N′ -Dimethylpropyleneurea Solvated Lanthanoid(III) Ions in Solution and Solid State with an Analysis of the Ionic Radii of Lanthanoid(III) Ions journal, May 2010

Carbonate complexation of yttrium and the rare earth elements in natural waters journal, February 2004

The Influence of Ionic Strength on Yttrium and Rare Earth Element Complexation by Fluoride Ions in NaClO4, NaNO3 and NaCl Solutions at 25 °C journal, May 2007

Effects of temperature and ionic strength on the stabilities of the first and second fluoride complexes of yttrium and the rare earth elements journal, November 2004

On the formation and structure of rare-earth element complexes in aqueous solutions under hydrothermal conditions with new data on gadolinium aqua and chloro complexes journal, April 2007

Steric hindrance and the enhanced stability of light rare-earth elements in hydrothermal fluids journal, October 2009

The structure and stability of aqueous rare-earth elements in hydrothermal fluids: New results on neodymium(III) aqua and chloroaqua complexes in aqueous solutions to 500 °C and 520 MPa journal, February 2009

The Structure of Yb 3+ Aquo Ion and Chloro Complexes in Aqueous Solutions at Up to 500 °C and 270 MPa journal, June 2002

Ab initio molecular dynamics simulation and free energy exploration of copper(I) complexation by chloride and bisulfide in hydrothermal fluids journal, February 2013

Solubilities, solubility products and solution chemistry of lanthanon trifluoride–water systems journal, January 1989

Geology and geochemistry of the Snowbird Deposit, Mineral County, Montana journal, April 1985

A spectrophotometric study of neodymium(III) complexation in chloride solutions journal, December 2002

A spectrophotometric study of erbium (III) speciation in chloride solutions at elevated temperatures journal, October 2006

An experimental study of the solubility and speciation of neodymium (III) fluoride in F-bearing aqueous solutions journal, June 2007

A spectrophotometric study of Nd(III), Sm(III) and Er(III) complexation in sulfate-bearing solutions at elevated temperatures journal, November 2008

Hydrothermal transport and deposition of the rare earth elements by fluorine-bearing aqueous liquids journal, August 2014

A spectrophotometric study of neodymium(III) complexation in sulfate solutions at elevated temperatures journal, February 2006

A spectrophotometric study of samarium (III) speciation in chloride solutions at elevated temperatures journal, March 2008

An experimental study of the solubility and speciation of the Rare Earth Elements (III) in fluoride- and chloride-bearing aqueous solutions at temperatures up to 300°C journal, December 2009

IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 1. Scandium Group (Sc, Y, La) journal, December 2008

IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 2. Light Lanthanides (Ce–Eu) journal, June 2009

IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (Gd–Lu) journal, December 2009

Microbially mediated cerium oxidation in sea water journal, May 1990

Structural Investigation of the Aqueous Eu 2+ Ion: Comparison with Sr 2+ Using the XAFS Technique journal, March 2002

Thermodynamics of solid phases containing rare earth oxides journal, September 2015

Calculation of activity coefficients and degrees of formation of neutral ion pairs in supercritical electrolyte solutions journal, May 1991

2 H and 139 La NMR Spectroscopy in Aqueous Solutions at Geochemical Pressures journal, September 2015

The role of fluorine in the concentration and transport of lithophile trace elements in felsic magmas: Insights from the Gawler Range Volcanics, South Australia
journal, May 2010

Rare earth elements in seawater: particle association, shale-normalization, and Ce oxidation
journal, February 1999

Solubility of Lanthanide Fluorides in Nitric Acid Solution in the Dissolution Process of FLUOREX Reprocessing System
journal, January 2004

REE composition of an aqueous magmatic fluid: A fluid inclusion study from the Capitan Pluton, New Mexico, U.S.A.
journal, April 1994

Fluid Evolution and Origins of Iron Oxide Cu-Au Prospects in the Olympic Dam District, Gawler Craton, South Australia
journal, December 2007

Rare-earth element mobility during hydrothermal and metamorphic fluid-rock interaction and the significance of the oxidation state of europium
journal, December 1991

Complex formation of trace elements in geochemical systems: stability constants of fluorocomplexes of the lanthanides in a fluorite bearing model system up to 200 °C and 1000 bar
journal, December 1987

Thermodynamics of rare earth element partitioning between clinopyroxene and melt in the system CaO-MgO-Al2O3-SiO2
journal, January 1996

The Oxidation State of Europium in Hydrothermal Scheelite: in situ Measurement by Xanes Spectroscopy
journal, October 2006

Oxidation state of europium in scheelite: Tracking fluid–rock interaction in gold deposits
journal, November 2008

Inhomogeneous distribution of REE in scheelite and dynamics of Archaean hydrothermal systems (Mt. Charlotte and Drysdale gold deposits, Western Australia)
journal, July 2000

Origins of Nd–Sr–Pb isotopic variations in single scheelite grains from Archaean gold deposits, Western Australia
journal, February 2002

The effect of oxygen fugacity, melt composition, temperature and pressure on the oxidation state of cerium in silicate melts
journal, February 2014

The hydration properties of Eu(II) and Eu(III): An ab initio quantum mechanical molecular dynamics study
journal, January 2015

The aqueous geochemistry of the rare earth elements. Part XIV. The solubility of rare earth element phosphates from 23 to 150 °C
journal, April 2005

Host-rock controlled epigenetic, hydrothermal metasomatic origin of the Bayan Obo REEFe-Nb ore deposit, Inner Mongolia, P.R.C.
journal, September 1992

Mineral chemistry of Rare Earth Element (REE) mineralization, Browns Ranges, Western Australia
journal, July 2013

Hydration of Lanthanoids(III) and Actinoids(III): An Experimental/Theoretical Saga
journal, August 2012

Experimental study of La(OH)3 and Gd(OH)3 solubilities (25 to 150°C), and La–acetate complexing (25 to 80°C)
journal, October 1998

Standard thermodynamic properties and heat capacity equations of rare earth hydroxides:
journal, October 1998

REE Daughter Minerals Trapped in Fluid Inclusions in the Giant Bayan Obo REE-Nb-Fe Deposit, Inner Mongolia, China
journal, July 2004

The aqueous geochemistry of the rare earth elements and yttrium: VI. Stability of neodymium chloride complexes from 25 to 300°C
journal, December 1996

Thermodynamic functions of erbium orthophosphate ErPO4 in the temperature range of 0–1600K
journal, May 2012

Heat capacity and thermodynamic functions of xenotime YPO4(c) at 0–1600 K
journal, September 2010

Heat capacity and thermodynamic functions of YbPO4 from 0 to 1800 K
journal, June 2013

Heat capacity and thermodynamic functions of LuPO4 in the range 0–320K
journal, September 2006

Geology, mineralogy and fluid inclusion data of the Kizilcaören fluorite–barite–REE deposit, Eskisehir, Turkey
journal, January 2003

Hydrothermal mobilization of pegmatite-hosted REE and Zr at Strange Lake, Canada: A reaction path model
journal, December 2013

The thermodynamic properties of bastnäsite-(Ce) and parisite-(Ce)
journal, January 2015

Experimental determination of the high temperature heat capacity of a natural xenotime-(Y) solid solution and synthetic DyPO4 and ErPO4 endmembers
journal, March 2016

The solubility of xenotime-(Y) and other HREE phosphates (DyPO 4 , ErPO 4 and YbPO 4 ) in aqueous solutions from 100 to 250 °C and p sat
journal, April 2015

Rare earth elements in hydrothermal systems: Estimates of standard partial molal thermodynamic properties of aqueous complexes of the rare earth elements at high pressures and temperatures
journal, November 1995

The lanthanum hydroxide fluoride carbonate system: The preparation of synthetic bastnaesite
journal, January 1975

Acidity constant of hydrofluoric acid
journal, July 1984

Theoretical prediction of the thermodynamic behavior of aqueous electrolytes by high pressures and temperatures; IV, Calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600 degrees C and 5kb
journal, December 1981

Geological characteristics and tectonic setting of proterozoic iron oxide (CuUAuREE) deposits
journal, October 1992

The ree Minerals of the Bastnas-Type Deposits, South-Central Sweden
journal, October 2007

Synthesis and stability of bastnaesites in a part of the system (Ce,La)-F-H-C-O
journal, January 1992

Determination of Solubility Products of Rare Earth Fluorides by Fluoride Ion-selective Electrode
journal, June 1984

SUPCRT92: A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000°C
journal, August 1992

Comparative hydrolysis behavior of the rare earths and yttrium: the influence of temperature and ionic strength
journal, January 2000

Thermodynamic properties of the lanthanide(III) halides
book, January 2003

The Thermodynamic Properties of the f -Elements and their Compounds. Part 2. The Lanthanide and Actinide Oxides
journal, March 2014

REE mineralization at Gakara, Burundi: Evidence for anomalous upper mantle in the western Rift Valley
journal, January 1994

Rare Earth Element Speciation in Geothermal Fluids from Yellowstone National Park, Wyoming, USA
journal, February 1998

Re-Os dating of pyrite from Giant Bayan Obo REE-Nb-Fe deposit
journal, January 2004

Comparative carbonate complexation of yttrium and gadolinium at 25 °C and 0.7 mol dm−3 ionic strength
journal, December 1995

Rare earth and yttrium phosphate solubilities in aqueous solution
journal, April 1997

An experimental study of the aqueous solubility and speciation of Y(III) fluoride at temperatures up to 250°C
journal, December 2013

Hydrothermal controls on the genesis of REE deposits: Insights from an in situ XAS study of Yb solubility and speciation in high temperature fluids (T < 400 °C)
journal, December 2015

Structural Study of the N,N′ -Dimethylpropyleneurea Solvated Lanthanoid(III) Ions in Solution and Solid State with an Analysis of the Ionic Radii of Lanthanoid(III) Ions
journal, May 2010

Carbonate complexation of yttrium and the rare earth elements in natural waters
journal, February 2004

The Influence of Ionic Strength on Yttrium and Rare Earth Element Complexation by Fluoride Ions in NaClO4, NaNO3 and NaCl Solutions at 25 °C
journal, May 2007

Effects of temperature and ionic strength on the stabilities of the first and second fluoride complexes of yttrium and the rare earth elements
journal, November 2004

On the formation and structure of rare-earth element complexes in aqueous solutions under hydrothermal conditions with new data on gadolinium aqua and chloro complexes
journal, April 2007

Steric hindrance and the enhanced stability of light rare-earth elements in hydrothermal fluids
journal, October 2009

The structure and stability of aqueous rare-earth elements in hydrothermal fluids: New results on neodymium(III) aqua and chloroaqua complexes in aqueous solutions to 500 °C and 520 MPa
journal, February 2009

The Structure of Yb ³⁺ Aquo Ion and Chloro Complexes in Aqueous Solutions at Up to 500 °C and 270 MPa
journal, June 2002

Ab initio molecular dynamics simulation and free energy exploration of copper(I) complexation by chloride and bisulfide in hydrothermal fluids
journal, February 2013

Solubilities, solubility products and solution chemistry of lanthanon trifluoride–water systems
journal, January 1989

Geology and geochemistry of the Snowbird Deposit, Mineral County, Montana
journal, April 1985

A spectrophotometric study of neodymium(III) complexation in chloride solutions
journal, December 2002

A spectrophotometric study of erbium (III) speciation in chloride solutions at elevated temperatures
journal, October 2006

An experimental study of the solubility and speciation of neodymium (III) fluoride in F-bearing aqueous solutions
journal, June 2007

A spectrophotometric study of Nd(III), Sm(III) and Er(III) complexation in sulfate-bearing solutions at elevated temperatures
journal, November 2008

Hydrothermal transport and deposition of the rare earth elements by fluorine-bearing aqueous liquids
journal, August 2014

A spectrophotometric study of neodymium(III) complexation in sulfate solutions at elevated temperatures
journal, February 2006

A spectrophotometric study of samarium (III) speciation in chloride solutions at elevated temperatures
journal, March 2008

An experimental study of the solubility and speciation of the Rare Earth Elements (III) in fluoride- and chloride-bearing aqueous solutions at temperatures up to 300°C
journal, December 2009

IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 1. Scandium Group (Sc, Y, La)
journal, December 2008

IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 2. Light Lanthanides (Ce–Eu)
journal, June 2009

IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (Gd–Lu)
journal, December 2009

Microbially mediated cerium oxidation in sea water
journal, May 1990

Structural Investigation of the Aqueous Eu ²⁺ Ion: Comparison with Sr ²⁺ Using the XAFS Technique
journal, March 2002

Thermodynamics of solid phases containing rare earth oxides
journal, September 2015

Calculation of activity coefficients and degrees of formation of neutral ion pairs in supercritical electrolyte solutions
journal, May 1991

² H and ¹³⁹ La NMR Spectroscopy in Aqueous Solutions at Geochemical Pressures
journal, September 2015

Origin of hydrothermal fluids at Olympic Dam; preliminary results from fluid inclusions and stable isotopes
journal, February 1992

Hydrated metal ions in aqueous solution: How regular are their structures?
journal, August 2010

Hydration of Lanthanoid(III) Ions in Aqueous Solution and Crystalline Hydrates Studied by EXAFS Spectroscopy and Crystallography: The Myth of the “Gadolinium Break”
journal, March 2008