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Title: Pressure dependence of carbonate exchange with [NpO 2(CO 3) 3] 4– in aqueous solutions

Here, the rates of ligand exchange into the geochemically important [NpO 2(CO 3) 3] 4– aqueous complex are measured as a function of pressure in order to complement existing data on the isostructural [UO 2(CO 3) 3] 4– complex. Experiments are conducted at pH conditions where the rate of exchange is independent of the proton concentration. Unexpectedly, the experiments show a distinct difference in the pressure dependencies of rates of exchange for the uranyl and neptunyl complexes.
Authors:
 [1] ;  [2] ; ORCiD logo [1]
  1. Univ. of California, Davis, CA (United States)
  2. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Publication Date:
Report Number(s):
LLNL-JRNL-694411
Journal ID: ISSN 0020-1669
Grant/Contract Number:
AC52-07NA27344
Type:
Accepted Manuscript
Journal Name:
Inorganic Chemistry
Additional Journal Information:
Journal Volume: 56; Journal Issue: 1; Journal ID: ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Research Org:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; neptunium; carbonate; ligand exchange; high-pressure
OSTI Identifier:
1349784

Pilgrim, Corey D., Zavarin, Mavrik, and Casey, William H.. Pressure dependence of carbonate exchange with [NpO2(CO3)3]4– in aqueous solutions. United States: N. p., Web. doi:10.1021/acs.inorgchem.6b02604.
Pilgrim, Corey D., Zavarin, Mavrik, & Casey, William H.. Pressure dependence of carbonate exchange with [NpO2(CO3)3]4– in aqueous solutions. United States. doi:10.1021/acs.inorgchem.6b02604.
Pilgrim, Corey D., Zavarin, Mavrik, and Casey, William H.. 2016. "Pressure dependence of carbonate exchange with [NpO2(CO3)3]4– in aqueous solutions". United States. doi:10.1021/acs.inorgchem.6b02604. https://www.osti.gov/servlets/purl/1349784.
@article{osti_1349784,
title = {Pressure dependence of carbonate exchange with [NpO2(CO3)3]4– in aqueous solutions},
author = {Pilgrim, Corey D. and Zavarin, Mavrik and Casey, William H.},
abstractNote = {Here, the rates of ligand exchange into the geochemically important [NpO2(CO3)3]4– aqueous complex are measured as a function of pressure in order to complement existing data on the isostructural [UO2(CO3)3]4– complex. Experiments are conducted at pH conditions where the rate of exchange is independent of the proton concentration. Unexpectedly, the experiments show a distinct difference in the pressure dependencies of rates of exchange for the uranyl and neptunyl complexes.},
doi = {10.1021/acs.inorgchem.6b02604},
journal = {Inorganic Chemistry},
number = 1,
volume = 56,
place = {United States},
year = {2016},
month = {12}
}