A water activity based model of heterogeneous ice nucleation kinetics for freezing of water and aqueous solution droplets
Abstract
Immersion freezing of water and aqueous solutions by particles acting as ice nuclei (IN) is a common process of heterogeneous ice nucleation which occurs in many environments, especially in the atmosphere where it results in the glaciation of clouds. Here we experimentally show, using a variety of IN types suspended in various aqueous solutions, that immersion freezing temperatures and kinetics can be described solely by temperature, T, and solution water activity, aw, which is the ratio of the vapour pressure of the solution and the saturation water vapour pressure under the same conditions and, in equilibrium, equivalent to relative humidity (RH). This allows the freezing point and corresponding heterogeneous ice nucleation rate coefficient, Jhet, to be uniquely expressed by T and aw, a result we term the aw based immersion freezing model (ABIFM). This method is independent of the nature of the solute and accounts for several varying parameters, including cooling rate and IN surface area, while providing a holistic description of immersion freezing and allowing prediction of freezing temperatures, Jhet, frozen fractions, ice particle production rates and numbers. Our findings are based on experimental freezing data collected for various IN surface areas, A, and cooling rates, r, of dropletsmore »
- Authors:
-
- Stony Brook Univ., Stony Brook, NY (United States)
- Publication Date:
- Research Org.:
- Stony Brook Univ., NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1349435
- Grant/Contract Number:
- SC0008613
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Faraday Discussions
- Additional Journal Information:
- Journal Volume: 165; Journal ID: ISSN 1359-6640
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES
Citation Formats
Knopf, Daniel A., and Alpert, Peter A. A water activity based model of heterogeneous ice nucleation kinetics for freezing of water and aqueous solution droplets. United States: N. p., 2013.
Web. doi:10.1039/C3FD00035D.
Knopf, Daniel A., & Alpert, Peter A. A water activity based model of heterogeneous ice nucleation kinetics for freezing of water and aqueous solution droplets. United States. https://doi.org/10.1039/C3FD00035D
Knopf, Daniel A., and Alpert, Peter A. Wed .
"A water activity based model of heterogeneous ice nucleation kinetics for freezing of water and aqueous solution droplets". United States. https://doi.org/10.1039/C3FD00035D. https://www.osti.gov/servlets/purl/1349435.
@article{osti_1349435,
title = {A water activity based model of heterogeneous ice nucleation kinetics for freezing of water and aqueous solution droplets},
author = {Knopf, Daniel A. and Alpert, Peter A.},
abstractNote = {Immersion freezing of water and aqueous solutions by particles acting as ice nuclei (IN) is a common process of heterogeneous ice nucleation which occurs in many environments, especially in the atmosphere where it results in the glaciation of clouds. Here we experimentally show, using a variety of IN types suspended in various aqueous solutions, that immersion freezing temperatures and kinetics can be described solely by temperature, T, and solution water activity, aw, which is the ratio of the vapour pressure of the solution and the saturation water vapour pressure under the same conditions and, in equilibrium, equivalent to relative humidity (RH). This allows the freezing point and corresponding heterogeneous ice nucleation rate coefficient, Jhet, to be uniquely expressed by T and aw, a result we term the aw based immersion freezing model (ABIFM). This method is independent of the nature of the solute and accounts for several varying parameters, including cooling rate and IN surface area, while providing a holistic description of immersion freezing and allowing prediction of freezing temperatures, Jhet, frozen fractions, ice particle production rates and numbers. Our findings are based on experimental freezing data collected for various IN surface areas, A, and cooling rates, r, of droplets variously containing marine biogenic material, two soil humic acids, four mineral dusts, and one organic monolayer acting as IN. For all investigated IN types we demonstrate that droplet freezing temperatures increase as A increases. Similarly, droplet freezing temperatures increase as the cooling rate decreases. The log10(Jhet) values for the various IN types derived exclusively by T and aw, provide a complete description of the heterogeneous ice nucleation kinetics. Thus, the ABIFM can be applied over the entire range of T, RH, total particulate surface area, and cloud activation timescales typical of atmospheric conditions. Finally, we demonstrate that ABIFM can be used to derive frozen fractions of droplets and ice particle production for atmospheric models of cirrus and mixed phase cloud conditions.},
doi = {10.1039/C3FD00035D},
journal = {Faraday Discussions},
number = ,
volume = 165,
place = {United States},
year = {Wed Apr 24 00:00:00 EDT 2013},
month = {Wed Apr 24 00:00:00 EDT 2013}
}
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Works referenced in this record:
Eight Years of High Cloud Statistics Using HIRS
journal, January 1999
- Wylie, Donald P.; Menzel, W. Paul
- Journal of Climate, Vol. 12, Issue 1
Trends in Global Cloud Cover in Two Decades of HIRS Observations
journal, August 2005
- Wylie, Donald; Jackson, Darren L.; Menzel, W. Paul
- Journal of Climate, Vol. 18, Issue 15
Small-scale cloud processes and climate
journal, January 2008
- Baker, Marcia B.; Peter, Thomas
- Nature, Vol. 451, Issue 7176
Advances in Understanding Clouds from ISCCP
journal, November 1999
- Rossow, William B.; Schiffer, Robert A.
- Bulletin of the American Meteorological Society, Vol. 80, Issue 11
Global modeling of mixed-phase clouds: The albedo and lifetime effects of aerosols
journal, January 2011
- Storelvmo, T.; Hoose, C.; Eriksson, P.
- Journal of Geophysical Research, Vol. 116, Issue D5
Predicting global atmospheric ice nuclei distributions and their impacts on climate
journal, June 2010
- DeMott, P. J.; Prenni, A. J.; Liu, X.
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 25
Long-term impacts of aerosols on the vertical development of clouds and precipitation
journal, November 2011
- Li, Zhanqing; Niu, Feng; Fan, Jiwen
- Nature Geoscience, Vol. 4, Issue 12
Impact of aerosols on convective clouds and precipitation: AEROSOL IMPACT ON CONVECTIVE CLOUDS
journal, April 2012
- Tao, Wei-Kuo; Chen, Jen-Ping; Li, Zhanqing
- Reviews of Geophysics, Vol. 50, Issue 2
Nucleation in the atmosphere
journal, April 2009
- Hegg, D. A.; Baker, M. B.
- Reports on Progress in Physics, Vol. 72, Issue 5
Heterogeneous freezing of ammonium sulfate and sodium chloride solutions by long chain alcohols
journal, January 2006
- Cantrell, Will; Robinson, Carly
- Geophysical Research Letters, Vol. 33, Issue 7
Nucleation terminology
journal, January 1985
- ,
- Journal of Aerosol Science, Vol. 16, Issue 6, p. 575-576
Upper-tropospheric relative humidity observations and implications for cirrus ice nucleation
journal, May 1998
- Heymsfield, Andrew J.; Miloshevich, Larry M.; Twohy, Cynthia
- Geophysical Research Letters, Vol. 25, Issue 9
The role of heterogeneous freezing nucleation in upper tropospheric clouds: Inferences from SUCCESS
journal, May 1998
- DeMott, Paul J.; Rogers, David C.; Kreidenweis, Sonia M.
- Geophysical Research Letters, Vol. 25, Issue 9
African dust aerosols as atmospheric ice nuclei: AFRICAN DUST AEROSOLS AS ICE NUCLEI
journal, July 2003
- DeMott, Paul J.; Sassen, Kenneth; Poellot, Michael R.
- Geophysical Research Letters, Vol. 30, Issue 14
In-situ observations of aerosol particles remaining from evaporated cirrus crystals: Comparing clean and polluted air masses
journal, January 2003
- Seifert, M.; Ström, J.; Krejci, R.
- Atmospheric Chemistry and Physics, Vol. 3, Issue 4
Freezing thresholds and cirrus cloud formation mechanisms inferred from in situ measurements of relative humidity
journal, January 2003
- Haag, W.; Kärcher, B.; Ström, J.
- Atmospheric Chemistry and Physics, Vol. 3, Issue 5
Single particle measurements of the chemical composition of cirrus ice residue during CRYSTAL-FACE: CHEMICAL COMPOSITION OF ICE RESIDUE
journal, February 2004
- Cziczo, D. J.; Murphy, D. M.; Hudson, P. K.
- Journal of Geophysical Research: Atmospheres, Vol. 109, Issue D4
A Continuous-Flow Diffusion Chamber for Airborne Measurements of Ice Nuclei
journal, May 2001
- Rogers, David C.; DeMott, Paul J.; Kreidenweis, Sonia M.
- Journal of Atmospheric and Oceanic Technology, Vol. 18, Issue 5
Black carbon enrichment in atmospheric ice particle residuals observed in lower tropospheric mixed phase clouds
journal, January 2008
- Cozic, J.; Mertes, S.; Verheggen, B.
- Journal of Geophysical Research, Vol. 113, Issue D15
Chemical composition of ambient aerosol, ice residues and cloud droplet residues in mixed-phase clouds: single particle analysis during the Cloud and Aerosol Characterization Experiment (CLACE 6)
journal, January 2010
- Kamphus, M.; Ettner-Mahl, M.; Klimach, T.
- Atmospheric Chemistry and Physics, Vol. 10, Issue 16
A large-eddy model for cirrus clouds with explicit aerosol and ice microphysics and Lagrangian ice particle tracking
journal, September 2010
- Sölch, Ingo; Kärcher, Bernd
- Quarterly Journal of the Royal Meteorological Society, Vol. 136, Issue 653
Ice in Clouds Experiment–Layer Clouds. Part II: Testing Characteristics of Heterogeneous Ice Formation in Lee Wave Clouds
journal, March 2012
- Field, P. R.; Heymsfield, A. J.; Shipway, B. J.
- Journal of the Atmospheric Sciences, Vol. 69, Issue 3
New Primary Ice-Nucleation Parameterizations in an Explicit Cloud Model
journal, July 1992
- Meyers, Michael P.; DeMott, Paul J.; Cotton, William R.
- Journal of Applied Meteorology, Vol. 31, Issue 7
Nucleation Processes in Deep Convection Simulated by a Cloud-System-Resolving Model with Double-Moment Bulk Microphysics
journal, March 2007
- Phillips, Vaughan T. J.; Donner, Leo J.; Garner, Stephen T.
- Journal of the Atmospheric Sciences, Vol. 64, Issue 3
Evolution of the ice phase in tropical altocumulus: SAMUM lidar observations over Cape Verde
journal, January 2009
- Ansmann, A.; Tesche, M.; Seifert, P.
- Journal of Geophysical Research, Vol. 114, Issue D17
A Classical-Theory-Based Parameterization of Heterogeneous Ice Nucleation by Mineral Dust, Soot, and Biological Particles in a Global Climate Model
journal, August 2010
- Hoose, Corinna; Kristjánsson, Jón Egill; Chen, Jen-Ping
- Journal of the Atmospheric Sciences, Vol. 67, Issue 8
Evidence that ice forms primarily in supercooled liquid clouds at temperatures > −27°C: ICE NUCLEATION IN MID-LEVEL CLOUDS
journal, July 2011
- Westbrook, C. D.; Illingworth, A. J.
- Geophysical Research Letters, Vol. 38, Issue 14
Water activity as the determinant for homogeneous ice nucleation in aqueous solutions
journal, August 2000
- Koop, Thomas; Luo, Beiping; Tsias, Athanasios
- Nature, Vol. 406, Issue 6796
Freezing of HNO 3 /H 2 SO 4 /H 2 O Solutions at Stratospheric Temperatures: Nucleation Statistics and Experiments
journal, February 1997
- Koop, Thomas; Luo, Beiping; Biermann, Uta M.
- The Journal of Physical Chemistry A, Vol. 101, Issue 6
Homogeneous Ice Nucleation in Water and Aqueous Solutions
journal, November 2004
- Koop, Thomas
- Zeitschrift für Physikalische Chemie, Vol. 218, Issue 11-2004
The homogeneous ice nucleation rate of water droplets produced in a microfluidic device and the role of temperature uncertainty
journal, January 2013
- Riechers, Birte; Wittbracht, Frank; Hütten, Andreas
- Physical Chemistry Chemical Physics, Vol. 15, Issue 16
Parameterizations for ice nucleation in biological and atmospheric systems
journal, January 2009
- Koop, Thomas; Zobrist, Bernhard
- Physical Chemistry Chemical Physics, Vol. 11, Issue 46
Ice nucleation in aqueous solutions of poly[ethylene glycol] with different molar mass
journal, June 2003
- Zobrist, Bernhard; Weers, Uwe; Koop, Thomas
- The Journal of Chemical Physics, Vol. 118, Issue 22
Ice nucleation from aqueous NaCl droplets with and without marine diatoms
journal, January 2011
- Alpert, P. A.; Aller, J. Y.; Knopf, D. A.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 12
Homogeneous ice freezing temperatures and ice nucleation rates of aqueous ammonium sulfate and aqueous levoglucosan particles for relevant atmospheric conditions
journal, January 2009
- Knopf, Daniel Alexander; Lopez, Miguel David
- Physical Chemistry Chemical Physics, Vol. 11, Issue 36
Stimulation of ice nucleation by marine diatoms
journal, December 2010
- Knopf, D. A.; Alpert, P. A.; Wang, B.
- Nature Geoscience, Vol. 4, Issue 2
Homogeneous Ice Nucleation From Aqueous Inorganic/Organic Particles Representative of Biomass Burning: Water Activity, Freezing Temperatures, Nucleation Rates
journal, February 2011
- Knopf, Daniel A.; Rigg, Yannick J.
- The Journal of Physical Chemistry A, Vol. 115, Issue 5
A parameterization of cirrus cloud formation: Homogeneous freezing of supercooled aerosols
journal, January 2002
- Kärcher, B.
- Journal of Geophysical Research, Vol. 107, Issue D2
A Parameterization of cirrus cloud formation: Homogeneous freezing including effects of aerosol size: CIRRUS PARAMETERIZATION
journal, December 2002
- Kärcher, B.; Lohmann, U.
- Journal of Geophysical Research: Atmospheres, Vol. 107, Issue D23
Physically based parameterization of cirrus cloud formation for use in global atmospheric models
journal, January 2006
- Kärcher, B.; Hendricks, J.; Lohmann, U.
- Journal of Geophysical Research, Vol. 111, Issue D1
Effects of ice nuclei on cirrus clouds in a global climate model
journal, January 2011
- Hendricks, J.; Kärcher, B.; Lohmann, U.
- Journal of Geophysical Research, Vol. 116, Issue D18
Inferring ice formation processes from global-scale black carbon profiles observed in the remote atmosphere and model simulations: INFERRING CLOUD ICE FORMATION PROCESSES
journal, December 2012
- Fan, S. -M.; Schwarz, J. P.; Liu, J.
- Journal of Geophysical Research: Atmospheres, Vol. 117, Issue D23
Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures
journal, April 2003
- Knopf, D. A.; Luo, B. P.; Krieger, U. K.
- The Journal of Physical Chemistry A, Vol. 107, Issue 21
Reply to “Comment on the ‘Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures'”
journal, March 2005
- Knopf, D. A.; Luo, B. P.; Krieger, U. K.
- The Journal of Physical Chemistry A, Vol. 109, Issue 11
A Thermodynamic Model of the System HCl-HNO3-H2SO4-H2O, Including Solubilities of HBr, from <200 to 328 K
journal, July 1995
- Carslaw, Kenneth S.; Clegg, Simon L.; Brimblecombe, Peter
- The Journal of Physical Chemistry, Vol. 99, Issue 29
Equilibrium Partial Pressures, Thermodynamic Properties of Aqueous and Solid Phases, and Cl 2 Production from Aqueous HCl and HNO 3 and Their Mixtures
journal, May 1999
- Massucci, Mario; Clegg, Simon L.; Brimblecombe, Peter
- The Journal of Physical Chemistry A, Vol. 103, Issue 21
Comment on the “Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures”
journal, March 2005
- Clegg, Simon L.; Brimblecombe, Peter
- The Journal of Physical Chemistry A, Vol. 109, Issue 11
Thermodynamic Model of the System H + −NH 4 + −SO 4 2- −NO 3 - −H 2 O at Tropospheric Temperatures
journal, March 1998
- Clegg, Simon L.; Brimblecombe, Peter; Wexler, Anthony S.
- The Journal of Physical Chemistry A, Vol. 102, Issue 12
Oxalic acid as a heterogeneous ice nucleus in the upper troposphere and its indirect aerosol effect
journal, January 2006
- Zobrist, B.; Marcolli, C.; Koop, T.
- Atmospheric Chemistry and Physics, Vol. 6, Issue 10
Freezing of Water and Aqueous NaCl Droplets Coated by Organic Monolayers as a Function of Surfactant Properties and Water Activity
journal, June 2011
- Knopf, Daniel A.; Forrester, Seanna M.
- The Journal of Physical Chemistry A, Vol. 115, Issue 22
Microbiology and atmospheric processes: the role of biological particles in cloud physics
journal, January 2007
- Möhler, O.; DeMott, P. J.; Vali, G.
- Biogeosciences, Vol. 4, Issue 6
Heterogeneous ice nucleation on atmospheric aerosols: a review of results from laboratory experiments
journal, January 2012
- Hoose, C.; Möhler, O.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 20
Ice nucleation by particles immersed in supercooled cloud droplets
journal, January 2012
- Murray, B. J.; O'Sullivan, D.; Atkinson, J. D.
- Chemical Society Reviews, Vol. 41, Issue 19
Phase Transitions of Aqueous Atmospheric Particles
journal, September 2000
- Martin, Scot T.
- Chemical Reviews, Vol. 100, Issue 9
Ice nucleation by surrogates for atmospheric mineral dust and mineral dust/sulfate particles at cirrus temperatures
journal, January 2005
- Archuleta, C. M.; DeMott, P. J.; Kreidenweis, S. M.
- Atmospheric Chemistry and Physics, Vol. 5, Issue 10
Heterogeneous nucleation of ice on surrogates of mineral dust
journal, January 2006
- Knopf, Daniel A.; Koop, Thomas
- Journal of Geophysical Research, Vol. 111, Issue D12
Heterogeneous freezing of droplets with immersed mineral dust particles – measurements and parameterization
journal, January 2010
- Niedermeier, D.; Hartmann, S.; Shaw, R. A.
- Atmospheric Chemistry and Physics, Vol. 10, Issue 8
Time dependence of immersion freezing: an experimental study on size selected kaolinite particles
journal, January 2012
- Welti, A.; Lüönd, F.; Kanji, Z. A.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 20
Ice nucleation efficiency of clay minerals in the immersion mode
journal, January 2012
- Pinti, V.; Marcolli, C.; Zobrist, B.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 13
Heterogeneous freezing of ice on atmospheric aerosols containing ash, soot, and soil
journal, January 2009
- Fornea, Adam P.; Brooks, Sarah D.; Dooley, Jeffrey B.
- Journal of Geophysical Research, Vol. 114, Issue D13
Immersion freezing of water and aqueous ammonium sulfate droplets initiated by humic-like substances as a function of water activity
journal, January 2013
- Rigg, Y. J.; Alpert, P. A.; Knopf, D. A.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 13
Initiation of the ice phase by marine biogenic surfaces in supersaturated gas and supercooled aqueous phases
journal, January 2011
- Alpert, Peter A.; Aller, Josephine Y.; Knopf, Daniel A.
- Physical Chemistry Chemical Physics, Vol. 13, Issue 44
Ice Nucleation by Alcohols Arranged in Monolayers at the Surface of Water Drops
journal, November 1990
- Gavish, M.; Popovitz-Biro, R.; Lahav, M.
- Science, Vol. 250, Issue 4983
Preactivation in the nucleation of ice by Langmuir films of aliphatic alcohols
journal, June 2001
- Seeley, L. H.; Seidler, G. T.
- The Journal of Chemical Physics, Vol. 114, Issue 23
Internally mixed sulfate and organic particles as potential ice nuclei in the tropical tropopause region
journal, April 2010
- Wise, M. E.; Baustian, K. J.; Tolbert, M. A.
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 15
Depositional ice nucleation on solid ammonium sulfate and glutaric acid particles
journal, January 2010
- Baustian, K. J.; Wise, M. E.; Tolbert, M. A.
- Atmospheric Chemistry and Physics, Vol. 10, Issue 5
Importance of aerosol composition, mixing state, and morphology for heterogeneous ice nucleation: A combined field and laboratory approach: HETEROGENEOUS ICE NUCLEATION
journal, March 2012
- Baustian, Kelly J.; Cziczo, Daniel J.; Wise, Matthew E.
- Journal of Geophysical Research: Atmospheres, Vol. 117, Issue D6
Depositional Ice Nucleation on Monocarboxylic Acids: Effect of the O:C Ratio
journal, May 2012
- Schill, Gregory P.; Tolbert, Margaret A.
- The Journal of Physical Chemistry A, Vol. 116, Issue 25
The deposition ice nucleation and immersion freezing potential of amorphous secondary organic aerosol: Pathways for ice and mixed-phase cloud formation: ICE NUCLEATION BY AMORPHOUS SOA
journal, August 2012
- Wang, Bingbing; Lambe, Andrew T.; Massoli, Paola
- Journal of Geophysical Research: Atmospheres, Vol. 117, Issue D16
Efficiency of immersion mode ice nucleation on surrogates of mineral dust
journal, January 2007
- Marcolli, C.; Gedamke, S.; Peter, T.
- Atmospheric Chemistry and Physics, Vol. 7, Issue 19
Influence of particle size on the ice nucleating ability of mineral dusts
journal, January 2009
- Welti, A.; Lüönd, F.; Stetzer, O.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 18
Heterogeneous ice nucleation: exploring the transition from stochastic to singular freezing behavior
journal, January 2011
- Niedermeier, D.; Shaw, R. A.; Hartmann, S.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 16
On the representation of immersion and condensation freezing in cloud models using different nucleation schemes
journal, January 2012
- Ervens, B.; Feingold, G.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 13
A parameterization of cirrus cloud formation: Heterogeneous freezing
journal, January 2003
- Kärcher, B.
- Journal of Geophysical Research, Vol. 108, Issue D14
Adsorption of Gases in Multimolecular Layers
journal, February 1938
- Brunauer, Stephen; Emmett, P. H.; Teller, Edward
- Journal of the American Chemical Society, Vol. 60, Issue 2, p. 309-319
Baseline studies of the Clay Minerals Society source clays: specific surface area by the Brunauer Emmett Teller (BET) method
journal, February 2006
- Dogan, A. Umran; Dogan, Meral; Onal, Muserref
- Clays and Clay Minerals, Vol. 54, Issue 1
Review of the vapour pressures of ice and supercooled water for atmospheric applications
journal, April 2005
- Murphy, D. M.; Koop, T.
- Quarterly Journal of the Royal Meteorological Society, Vol. 131, Issue 608
Do NAD and NAT Form in Liquid Stratospheric Aerosols by Pseudoheterogeneous Nucleation?
journal, May 2006
- Knopf, Daniel A.
- The Journal of Physical Chemistry A, Vol. 110, Issue 17
Homogeneous nucleation of NAD and NAT in liquid stratospheric aerosols: insufficient to explain denitrification
journal, January 2002
- Knopf, D. A.; Koop, T.; Luo, B. P.
- Atmospheric Chemistry and Physics, Vol. 2, Issue 3
Immersion mode heterogeneous ice nucleation by an illite rich powder representative of atmospheric mineral dust
journal, January 2012
- Broadley, S. L.; Murray, B. J.; Herbert, R. J.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 1
Heterogeneous freezing of water droplets containing kaolinite particles
journal, January 2011
- Murray, B. J.; Broadley, S. L.; Wilson, T. W.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 9
The ice nucleation ability of one of the most abundant types of fungal spores found in the atmosphere
journal, January 2011
- Iannone, R.; Chernoff, D. I.; Pringle, A.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 3
Do atmospheric aerosols form glasses?
journal, January 2008
- Zobrist, B.; Marcolli, C.; Pedernera, D. A.
- Atmospheric Chemistry and Physics, Vol. 8, Issue 17
A comparison of heterogeneous ice nucleation parameterizations using a parcel model framework
journal, January 2009
- Eidhammer, Trude; DeMott, Paul J.; Kreidenweis, Sonia M.
- Journal of Geophysical Research, Vol. 114, Issue D6
Measurements of the concentration and composition of nuclei for cirrus formation
journal, December 2003
- DeMott, P. J.; Cziczo, D. J.; Prenni, A. J.
- Proceedings of the National Academy of Sciences, Vol. 100, Issue 25
The susceptibility of ice formation in upper tropospheric clouds to insoluble aerosol components
journal, August 1997
- DeMott, Paul J.; Rogers, David C.; Kreidenweis, Sonia M.
- Journal of Geophysical Research: Atmospheres, Vol. 102, Issue D16
Prediction of the number of cloud droplets in the ECHAM GCM
journal, April 1999
- Lohmann, Ulrike; Feichter, Johann; Chuang, Catherine C.
- Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D8
Sensitivity studies of different aerosol indirect effects in mixed-phase clouds
journal, January 2009
- Lohmann, U.; Hoose, C.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 22
Influence of Saharan dust on cloud glaciation in southern Morocco during the Saharan Mineral Dust Experiment
journal, January 2008
- Ansmann, A.; Tesche, M.; Althausen, D.
- Journal of Geophysical Research, Vol. 113, Issue D4
Works referencing / citing this record:
Heterogeneous Ice Nucleation in the Tropical Tropopause Layer
journal, November 2018
- Jensen, Eric J.; Kärcher, Bernd; Ueyama, Rei
- Journal of Geophysical Research: Atmospheres, Vol. 123, Issue 21
Stochastic nucleation processes and substrate abundance explain time-dependent freezing in supercooled droplets
journal, January 2020
- Knopf, Daniel A.; Alpert, Peter A.; Zipori, Assaf
- npj Climate and Atmospheric Science, Vol. 3, Issue 1
Ice-nucleating bacteria control the order and dynamics of interfacial water
journal, April 2016
- Pandey, Ravindra; Usui, Kota; Livingstone, Ruth A.
- Science Advances, Vol. 2, Issue 4
Perspectives on the Future of Ice Nucleation Research: Research Needs and Unanswered Questions Identified from Two International Workshops
journal, July 2017
- Coluzza, Ivan; Creamean, Jessie; Rossi, Michel
- Atmosphere, Vol. 8, Issue 12
Immersion freezing of water and aqueous ammonium sulfate droplets initiated by humic-like substances as a function of water activity
journal, January 2013
- Rigg, Y. J.; Alpert, P. A.; Knopf, D. A.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 13
Laboratory studies of immersion and deposition mode ice nucleation of ozone aged mineral dust particles
journal, January 2013
- Kanji, Z. A.; Welti, A.; Chou, C.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 17
Contact freezing: a review of experimental studies
journal, January 2013
- Ladino Moreno, L. A.; Stetzer, O.; Lohmann, U.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 19
Kaolinite particles as ice nuclei: learning from the use of different kaolinite samples and different coatings
journal, January 2014
- Wex, H.; DeMott, P. J.; Tobo, Y.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 11
Organic matter matters for ice nuclei of agricultural soil origin
journal, January 2014
- Tobo, Y.; DeMott, P. J.; Hill, T. C. J.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 16
Technical Note: A proposal for ice nucleation terminology
journal, January 2015
- Vali, G.; DeMott, P. J.; Möhler, O.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 18
A comprehensive laboratory study on the immersion freezing behavior of illite NX particles: a comparison of 17 ice nucleation measurement techniques
journal, January 2015
- Hiranuma, N.; Augustin-Bauditz, S.; Bingemer, H.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 5
Integrating laboratory and field data to quantify the immersion freezing ice nucleation activity of mineral dust particles
journal, January 2015
- DeMott, P. J.; Prenni, A. J.; McMeeking, G. R.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 1
A laboratory investigation of the ice nucleation efficiency of three types of mineral and soil dust
journal, January 2018
- Paramonov, Mikhail; David, Robert O.; Kretzschmar, Ruben
- Atmospheric Chemistry and Physics, Vol. 18, Issue 22
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 1: The K-feldspar microcline
journal, January 2018
- Kumar, Anand; Marcolli, Claudia; Luo, Beiping
- Atmospheric Chemistry and Physics, Vol. 18, Issue 10
Mixed-phase orographic cloud microphysics during StormVEx and IFRACS
journal, January 2019
- Lowenthal, Douglas H.; Hallar, A. Gannet; David, Robert O.
- Atmospheric Chemistry and Physics, Vol. 19, Issue 8
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 2: Quartz and amorphous silica
journal, January 2019
- Kumar, Anand; Marcolli, Claudia; Peter, Thomas
- Atmospheric Chemistry and Physics, Vol. 19, Issue 9
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 3: Aluminosilicates
journal, January 2019
- Kumar, Anand; Marcolli, Claudia; Peter, Thomas
- Atmospheric Chemistry and Physics, Vol. 19, Issue 9
An instrument for quantifying heterogeneous ice nucleation in multiwell plates using infrared emissions to detect freezing
journal, January 2018
- Harrison, Alexander D.; Whale, Thomas F.; Rutledge, Rupert
- Atmospheric Measurement Techniques, Vol. 11, Issue 10
A technique for quantifying heterogeneous ice nucleation in microlitre supercooled water droplets
journal, January 2015
- Whale, T. F.; Murray, B. J.; O'Sullivan, D.
- Atmospheric Measurement Techniques, Vol. 8, Issue 6
BINARY: an optical freezing array for assessing temperature and time dependence of heterogeneous ice nucleation
journal, January 2014
- Budke, C.; Koop, T.
- Atmospheric Measurement Techniques Discussions, Vol. 7, Issue 9
Contact freezing: a review of experimental studies
text, January 2013
- A., Ladino Moreno, Luis; Olaf, Stetzer,; Ulrike, Lohmann,
- ETH Zurich
A comprehensive laboratory study on the immersion freezing behavior of illite NX particles: A comparison of 17 ice nucleation measurement techniques
text, January 2015
- Hiranuma, Naruki; Augustin-Bauditz, Stefanie; Bingemer, Heinz
- ETH Zurich
Perspectives on the Future of Ice Nucleation Research: Research Needs and Unanswered Questions Identified from Two International Workshops
text, January 2017
- Coluzza, Ivan; Creamean, Jessie; Rossi, Michel J.
- ETH Zurich
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions - Part 1: The K-feldspar microcline
text, January 2018
- Kumar, Anand; Marcolli, Claudia; Luo, Beiping
- ETH Zurich
A laboratory investigation of the ice nucleation efficiency of three types of mineral and soil dust
text, January 2018
- Mikhail, Paramonov,; O., David, Robert; Ruben, Kretzschmar,
- ETH Zurich
Mixed-phase orographic cloud microphysics during StormVEx and IFRACS
text, January 2019
- Lowenthal, Douglas H.; Hallar, A. Gannet; David, Robert O.
- ETH Zurich
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 2: Quartz and amorphous silica
text, January 2019
- Kumar, Anand; Marcolli, Claudia; Peter, Thomas
- ETH Zurich
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions - Part 3: Aluminosilicates
text, January 2019
- Anand, Kumar,; Claudia, Marcolli,; Thomas, Peter,
- ETH Zurich
Laboratory studies of immersion and deposition mode ice nucleation of ozone aged mineral dust particles
text, January 2013
- Kanji, Zamin A.; Welti, André; Chou, Cédric
- ETH Zurich
BINARY: an optical freezing array for assessing temperature and time dependence of heterogeneous ice nucleation
journal, January 2015
- Budke, C.; Koop, T.
- Atmospheric Measurement Techniques, Vol. 8, Issue 2
A technique for quantifying heterogeneous ice nucleation in microlitre supercooled water droplets
text, January 2015
- Whale, Thomas F.; Murray, Benjamin J.; O'Sullivan, Daniel
- ETH Zurich