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Title: Electrochemical ammonia synthesis—The selectivity challenge

Here, the N 2 molecule is particularly inert; the N–N triple bond is one of the most stable in all of chemistry, and in addition, the molecule has no dipole moment and a very low polarizability.
Authors:
ORCiD logo [1] ;  [1] ;  [1] ;  [1] ;  [2] ; ORCiD logo [2] ;  [3] ;  [2]
  1. Stanford Univ., Stanford, CA (United States)
  2. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
  3. Technical Univ. of Denmark, Lyngby (Denmark)
Publication Date:
Grant/Contract Number:
AC02-76SF00515
Type:
Accepted Manuscript
Journal Name:
ACS Catalysis
Additional Journal Information:
Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Research Org:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1349282

Singh, Aayush R., Rohr, Brian A., Schwalbe, Jay A., Cargnello, Matteo, Chan, Karen, Jaramillo, Thomas F., Chorkendorff, Ib, and Nørskov, Jens K.. Electrochemical ammonia synthesis—The selectivity challenge. United States: N. p., Web. doi:10.1021/acscatal.6b03035.
Singh, Aayush R., Rohr, Brian A., Schwalbe, Jay A., Cargnello, Matteo, Chan, Karen, Jaramillo, Thomas F., Chorkendorff, Ib, & Nørskov, Jens K.. Electrochemical ammonia synthesis—The selectivity challenge. United States. doi:10.1021/acscatal.6b03035.
Singh, Aayush R., Rohr, Brian A., Schwalbe, Jay A., Cargnello, Matteo, Chan, Karen, Jaramillo, Thomas F., Chorkendorff, Ib, and Nørskov, Jens K.. 2016. "Electrochemical ammonia synthesis—The selectivity challenge". United States. doi:10.1021/acscatal.6b03035. https://www.osti.gov/servlets/purl/1349282.
@article{osti_1349282,
title = {Electrochemical ammonia synthesis—The selectivity challenge},
author = {Singh, Aayush R. and Rohr, Brian A. and Schwalbe, Jay A. and Cargnello, Matteo and Chan, Karen and Jaramillo, Thomas F. and Chorkendorff, Ib and Nørskov, Jens K.},
abstractNote = {Here, the N2 molecule is particularly inert; the N–N triple bond is one of the most stable in all of chemistry, and in addition, the molecule has no dipole moment and a very low polarizability.},
doi = {10.1021/acscatal.6b03035},
journal = {ACS Catalysis},
number = 1,
volume = 7,
place = {United States},
year = {2016},
month = {12}
}