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Title: Development of a reactor with carbon catalysts for modular-scale, low-cost electrochemical generation of H 2O 2

The development of small-scale, decentralized reactors for H 2O 2 production that can couple to renewable energy sources would be of great benefit, particularly for water purification in the developing world. Herein, we describe our efforts to develop electrochemical reactors for H 2O 2 generation with high Faradaic efficiencies of >90%, requiring cell voltages of only ~1.6 V. The reactor employs a carbon-based catalyst that demonstrates excellent performance for H 2O 2 production under alkaline conditions, as demonstrated by fundamental studies involving rotating-ring disk electrode methods. Finally, the low-cost, membrane-free reactor design represents a step towards a continuous, modular-scale, de-centralized production of H 2O 2.
Authors:
 [1] ;  [1] ;  [2] ;  [2] ;  [1] ;  [3] ;  [3] ;  [1] ;  [1] ; ORCiD logo [1]
  1. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
  2. Stanford Univ., Stanford, CA (United States)
  3. SLAC National Accelerator Lab., Menlo Park, CA (United States)
Publication Date:
Grant/Contract Number:
SC0008685; AC02-76SF00515
Type:
Accepted Manuscript
Journal Name:
Reaction Chemistry & Engineering
Additional Journal Information:
Journal Volume: 2; Journal Issue: 2; Journal ID: ISSN 2058-9883
Publisher:
Royal Society of Chemistry
Research Org:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 42 ENGINEERING
OSTI Identifier:
1349279

Chen, Zhihua, Chen, Shucheng, Siahrostami, Samira, Chakthranont, Pongkarn, Hahn, Christopher, Nordlund, Dennis, Dimosthenis, Sokaras, Nørskov, Jens K., Bao, Zhenan, and Jaramillo, Thomas F.. Development of a reactor with carbon catalysts for modular-scale, low-cost electrochemical generation of H2O2. United States: N. p., Web. doi:10.1039/c6re00195e.
Chen, Zhihua, Chen, Shucheng, Siahrostami, Samira, Chakthranont, Pongkarn, Hahn, Christopher, Nordlund, Dennis, Dimosthenis, Sokaras, Nørskov, Jens K., Bao, Zhenan, & Jaramillo, Thomas F.. Development of a reactor with carbon catalysts for modular-scale, low-cost electrochemical generation of H2O2. United States. doi:10.1039/c6re00195e.
Chen, Zhihua, Chen, Shucheng, Siahrostami, Samira, Chakthranont, Pongkarn, Hahn, Christopher, Nordlund, Dennis, Dimosthenis, Sokaras, Nørskov, Jens K., Bao, Zhenan, and Jaramillo, Thomas F.. 2017. "Development of a reactor with carbon catalysts for modular-scale, low-cost electrochemical generation of H2O2". United States. doi:10.1039/c6re00195e. https://www.osti.gov/servlets/purl/1349279.
@article{osti_1349279,
title = {Development of a reactor with carbon catalysts for modular-scale, low-cost electrochemical generation of H2O2},
author = {Chen, Zhihua and Chen, Shucheng and Siahrostami, Samira and Chakthranont, Pongkarn and Hahn, Christopher and Nordlund, Dennis and Dimosthenis, Sokaras and Nørskov, Jens K. and Bao, Zhenan and Jaramillo, Thomas F.},
abstractNote = {The development of small-scale, decentralized reactors for H2O2 production that can couple to renewable energy sources would be of great benefit, particularly for water purification in the developing world. Herein, we describe our efforts to develop electrochemical reactors for H2O2 generation with high Faradaic efficiencies of >90%, requiring cell voltages of only ~1.6 V. The reactor employs a carbon-based catalyst that demonstrates excellent performance for H2O2 production under alkaline conditions, as demonstrated by fundamental studies involving rotating-ring disk electrode methods. Finally, the low-cost, membrane-free reactor design represents a step towards a continuous, modular-scale, de-centralized production of H2O2.},
doi = {10.1039/c6re00195e},
journal = {Reaction Chemistry & Engineering},
number = 2,
volume = 2,
place = {United States},
year = {2017},
month = {3}
}