High-capacity, low-tortuosity, and channel-guided lithium metal anode
Abstract
Lithium metal anode with the highest capacity and lowest anode potential is extremely attractive to battery technologies, but infinite volume change during the Li stripping/plating process results in cracks and fractures of the solid electrolyte interphase, low Coulombic efficiency, and dendritic growth of Li. Here, we use a carbonized wood (C-wood) as a 3D, highly porous (73% porosity) conductive framework with well-aligned channels as Li host material. We discovered that molten Li metal can infuse into the straight channels of C-wood to form a Li/C-wood electrode after surface treatment. The C-wood channels function as excellent guides in which the Li stripping/plating process can take place and effectively confine the volume change that occurs. Moreover, the local current density can be minimized due to the 3D C-wood framework. Therefore, in symmetric cells, the as-prepared Li/C-wood electrode presents a lower overpotential (90 mV at 3 mA•cm-2), more-stable stripping/plating profiles, and better cycling performance (~150 h at 3 mA•cm-2) compared with bare Li metal electrode. Lastly, our findings may open up a solution for fabricating stable Li metal anode, which further facilitates future application of high-energy-density Li metal batteries.
- Authors:
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC), College Park, MD (United States). Nanostructures for Electrical Energy Storage (NEES)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1347464
- Alternate Identifier(s):
- OSTI ID: 1388493
- Grant/Contract Number:
- SC0001160
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 114 Journal Issue: 14; Journal ID: ISSN 0027-8424
- Publisher:
- National Academy of Sciences, Washington, DC (United States)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; bio-inspired; energy storage (including batteries and capacitors); defects; charge transport; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing); lithium metal batteries; wood channels; low tortuosity
Citation Formats
Zhang, Ying, Luo, Wei, Wang, Chengwei, Li, Yiju, Chen, Chaoji, Song, Jianwei, Dai, Jiaqi, Hitz, Emily M., Xu, Shaomao, Yang, Chunpeng, Wang, Yanbin, and Hu, Liangbing. High-capacity, low-tortuosity, and channel-guided lithium metal anode. United States: N. p., 2017.
Web. doi:10.1073/pnas.1618871114.
Zhang, Ying, Luo, Wei, Wang, Chengwei, Li, Yiju, Chen, Chaoji, Song, Jianwei, Dai, Jiaqi, Hitz, Emily M., Xu, Shaomao, Yang, Chunpeng, Wang, Yanbin, & Hu, Liangbing. High-capacity, low-tortuosity, and channel-guided lithium metal anode. United States. https://doi.org/10.1073/pnas.1618871114
Zhang, Ying, Luo, Wei, Wang, Chengwei, Li, Yiju, Chen, Chaoji, Song, Jianwei, Dai, Jiaqi, Hitz, Emily M., Xu, Shaomao, Yang, Chunpeng, Wang, Yanbin, and Hu, Liangbing. Mon .
"High-capacity, low-tortuosity, and channel-guided lithium metal anode". United States. https://doi.org/10.1073/pnas.1618871114.
@article{osti_1347464,
title = {High-capacity, low-tortuosity, and channel-guided lithium metal anode},
author = {Zhang, Ying and Luo, Wei and Wang, Chengwei and Li, Yiju and Chen, Chaoji and Song, Jianwei and Dai, Jiaqi and Hitz, Emily M. and Xu, Shaomao and Yang, Chunpeng and Wang, Yanbin and Hu, Liangbing},
abstractNote = {Lithium metal anode with the highest capacity and lowest anode potential is extremely attractive to battery technologies, but infinite volume change during the Li stripping/plating process results in cracks and fractures of the solid electrolyte interphase, low Coulombic efficiency, and dendritic growth of Li. Here, we use a carbonized wood (C-wood) as a 3D, highly porous (73% porosity) conductive framework with well-aligned channels as Li host material. We discovered that molten Li metal can infuse into the straight channels of C-wood to form a Li/C-wood electrode after surface treatment. The C-wood channels function as excellent guides in which the Li stripping/plating process can take place and effectively confine the volume change that occurs. Moreover, the local current density can be minimized due to the 3D C-wood framework. Therefore, in symmetric cells, the as-prepared Li/C-wood electrode presents a lower overpotential (90 mV at 3 mA•cm-2), more-stable stripping/plating profiles, and better cycling performance (~150 h at 3 mA•cm-2) compared with bare Li metal electrode. Lastly, our findings may open up a solution for fabricating stable Li metal anode, which further facilitates future application of high-energy-density Li metal batteries.},
doi = {10.1073/pnas.1618871114},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 14,
volume = 114,
place = {United States},
year = {Mon Mar 20 00:00:00 EDT 2017},
month = {Mon Mar 20 00:00:00 EDT 2017}
}
https://doi.org/10.1073/pnas.1618871114
Web of Science
Works referenced in this record:
Large-volume-change electrodes for Li-ion batteries of amorphous alloy particles held by elastomeric tethers
journal, November 2003
- Chen, Zonghai; Christensen, L.; Dahn, J. R.
- Electrochemistry Communications, Vol. 5, Issue 11
Resonant Raman spectroscopy of disordered, amorphous, and diamondlike carbon
journal, July 2001
- Ferrari, A. C.; Robertson, J.
- Physical Review B, Vol. 64, Issue 7
A Highly Ordered Meso@Microporous Carbon-Supported Sulfur@Smaller Sulfur Core–Shell Structured Cathode for Li–S Batteries
journal, August 2014
- Li, Zhen; Jiang, Yan; Yuan, Lixia
- ACS Nano, Vol. 8, Issue 9
Metal-Air Batteries with High Energy Density: Li-Air versus Zn-Air
journal, December 2010
- Lee, Jang-Soo; Tai Kim, Sun; Cao, Ruiguo
- Advanced Energy Materials, Vol. 1, Issue 1, p. 34-50
Recent Developments of the Lithium Metal Anode for Rechargeable Non-Aqueous Batteries
journal, July 2016
- Zhang, Kai; Lee, Gi-Hyeok; Park, Mihui
- Advanced Energy Materials, Vol. 6, Issue 20
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
journal, June 2015
- Li, Weiyang; Yao, Hongbin; Yan, Kai
- Nature Communications, Vol. 6, Issue 1
Size Effects in the Li 4+ x Ti 5 O 12 Spinel
journal, December 2009
- Borghols, W. J. H.; Wagemaker, M.; Lafont, U.
- Journal of the American Chemical Society, Vol. 131, Issue 49
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Dendrite-Free Lithium Deposition with Self-Aligned Nanorod Structure
journal, November 2014
- Zhang, Yaohui; Qian, Jiangfeng; Xu, Wu
- Nano Letters, Vol. 14, Issue 12
Ultrathin Two-Dimensional Atomic Crystals as Stable Interfacial Layer for Improvement of Lithium Metal Anode
journal, September 2014
- Yan, Kai; Lee, Hyun-Wook; Gao, Teng
- Nano Letters, Vol. 14, Issue 10
Engineering three-dimensional hybrid supercapacitors and microsupercapacitors for high-performance integrated energy storage
journal, March 2015
- El-Kady, Maher F.; Ihns, Melanie; Li, Mengping
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 14
Three-Dimensional Battery Architectures
journal, October 2004
- Long, Jeffrey W.; Dunn, Bruce; Rolison, Debra R.
- Chemical Reviews, Vol. 104, Issue 10, p. 4463-4492
Assessing the improved performance of freestanding, flexible graphene and carbon nanotube hybrid foams for lithium ion battery anodes
journal, January 2014
- Cohn, Adam P.; Oakes, Landon; Carter, Rachel
- Nanoscale, Vol. 6, Issue 9
Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries
journal, January 2013
- Wei Seh, Zhi; Li, Weiyang; Cha, Judy J.
- Nature Communications, Vol. 4, Article No. 1331
Compliant glass–polymer hybrid single ion-conducting electrolytes for lithium batteries
journal, December 2015
- Villaluenga, Irune; Wujcik, Kevin H.; Tong, Wei
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 1
Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode
journal, March 2016
- Liu, Yayuan; Lin, Dingchang; Liang, Zheng
- Nature Communications, Vol. 7, Issue 1
Hierarchically Porous Graphene as a Lithium–Air Battery Electrode
journal, November 2011
- Xiao, Jie; Mei, Donghai; Li, Xiaolin
- Nano Letters, Vol. 11, Issue 11
Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating
journal, February 2016
- Liang, Zheng; Lin, Dingchang; Zhao, Jie
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 11
Free-Standing Copper Nanowire Network Current Collector for Improving Lithium Anode Performance
journal, June 2016
- Lu, Lei-Lei; Ge, Jin; Yang, Jun-Nan
- Nano Letters, Vol. 16, Issue 7
Mastering the interface for advanced all-solid-state lithium rechargeable batteries
journal, November 2016
- Li, Yutao; Zhou, Weidong; Chen, Xi
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 47
Synthesis, Characterization, and Structural Modeling of High-Capacity, Dual Functioning MnO 2 Electrode/Electrocatalysts for Li-O 2 Cells
journal, July 2012
- Trahey, Lynn; Karan, Naba K.; Chan, Maria K. Y.
- Advanced Energy Materials, Vol. 3, Issue 1
Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices
journal, August 2008
- Guo, Yu-Guo; Hu, Jin-Song; Wan, Li-Jun
- Advanced Materials, Vol. 20, Issue 15
Nanostructured sulfur cathodes
journal, January 2013
- Yang, Yuan; Zheng, Guangyuan; Cui, Yi
- Chemical Society Reviews, Vol. 42, Issue 7, p. 3018-3032
Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications
journal, July 2016
- Zhu, Hongli; Luo, Wei; Ciesielski, Peter N.
- Chemical Reviews, Vol. 116, Issue 16
Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes
journal, August 2015
- Yang, Chun-Peng; Yin, Ya-Xia; Zhang, Shuai-Feng
- Nature Communications, Vol. 6, Issue 1
Spatially heterogeneous carbon-fiber papers as surface dendrite-free current collectors for lithium deposition
journal, February 2012
- Ji, Xiulei; Liu, De-Yu; Prendiville, Daniel G.
- Nano Today, Vol. 7, Issue 1
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Advances in Li–S batteries
journal, January 2010
- Ji, Xiulei; Nazar, Linda F.
- Journal of Materials Chemistry, Vol. 20, Issue 44, p. 9821-9826
Metallic anodes for next generation secondary batteries
journal, January 2013
- Kim, Hansu; Jeong, Goojin; Kim, Young-Ugk
- Chemical Society Reviews, Vol. 42, Issue 23
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013
- Ding, Fei; Xu, Wu; Graff, Gordon L.
- Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456
Optimization of Air Electrode for Li/Air Batteries
journal, January 2010
- Xiao, Jie; Wang, Donghai; Xu, Wu
- Journal of The Electrochemical Society, Vol. 157, Issue 4
Ionic shield for polysulfides towards highly-stable lithium–sulfur batteries
journal, January 2014
- Huang, Jia-Qi; Zhang, Qiang; Peng, Hong-Jie
- Energy Environ. Sci., Vol. 7, Issue 1
Stabilized Lithium–Metal Surface in a Polysulfide-Rich Environment of Lithium–Sulfur Batteries
journal, July 2014
- Zu, Chenxi; Manthiram, Arumugam
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 15
Functional Organosulfide Electrolyte Promotes an Alternate Reaction Pathway to Achieve High Performance in Lithium-Sulfur Batteries
journal, February 2016
- Chen, Shuru; Dai, Fang; Gordin, Mikhail L.
- Angewandte Chemie International Edition, Vol. 55, Issue 13
Honeycomb Carbon: A Review of Graphene
journal, January 2010
- Allen, Matthew J.; Tung, Vincent C.; Kaner, Richard B.
- Chemical Reviews, Vol. 110, Issue 1, p. 132-145
Li–O2 and Li–S batteries with high energy storage
journal, January 2012
- Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
- Nature Materials, Vol. 11, Issue 1, p. 19-29
Making Li-Air Batteries Rechargeable: Material Challenges
journal, May 2012
- Shao, Yuyan; Ding, Fei; Xiao, Jie
- Advanced Functional Materials, Vol. 23, Issue 8
A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles
journal, December 2015
- Choudhury, Snehashis; Mangal, Rahul; Agrawal, Akanksha
- Nature Communications, Vol. 6, Issue 1
Lithium metal anodes for rechargeable batteries
journal, January 2014
- Xu, Wu; Wang, Jiulin; Ding, Fei
- Energy Environ. Sci., Vol. 7, Issue 2
Manipulating surface reactions in lithium–sulphur batteries using hybrid anode structures
journal, January 2014
- Huang, Cheng; Xiao, Jie; Shao, Yuyan
- Nature Communications, Vol. 5, Issue 1, Article No. 3015
Conductive Nanostructured Scaffolds Render Low Local Current Density to Inhibit Lithium Dendrite Growth
journal, January 2016
- Zhang, Rui; Cheng, Xin-Bing; Zhao, Chen-Zi
- Advanced Materials, Vol. 28, Issue 11
Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes
journal, March 2016
- Lin, Dingchang; Liu, Yayuan; Liang, Zheng
- Nature Nanotechnology, Vol. 11, Issue 7
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009
- Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
- Nature Materials, Vol. 8, Issue 6, p. 500-506
Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014
- Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng
- Nature Nanotechnology, Vol. 9, Issue 8
Real-time 3D imaging of microstructure growth in battery cells using indirect MRI
journal, September 2016
- Ilott, Andrew J.; Mohammadi, Mohaddese; Chang, Hee Jung
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 39
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes
journal, August 2014
- Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A.
- Nature Materials, Vol. 13, Issue 10