Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy
Abstract
Hybrid lead perovskites containing a mixture of organic and inorganic cations and anions have lead to solar cell devices with better performance and stability than their single halide analogs. Here, 207Pb solid-state nuclear magnetic resonance and single particle photoluminescence spectroscopies show that the structure and composition of mixed-halide and—likely—other hybrid lead perovskites is much more complex than previously thought and is highly dependent on their synthesis. While a majority of reports in the area focus on the construction of photovoltaic devices, this perspective focuses instead on achieving a better understanding of the fundamental chemistry and photophysics of these materials, as this will aid not only in constructing improved devices, but also in generating new uses for these unique materials.
- Authors:
-
- Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States
- Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States, US DOE Ames Laboratory, Ames, Iowa 50011, United States
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1352099
- Alternate Identifier(s):
- OSTI ID: 1347410; OSTI ID: 1508006
- Report Number(s):
- IS-J-9164
Journal ID: ISSN 2380-8195
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Published Article
- Journal Name:
- ACS Energy Letters
- Additional Journal Information:
- Journal Name: ACS Energy Letters Journal Volume: 2 Journal Issue: 4; Journal ID: ISSN 2380-8195
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; 36 MATERIALS SCIENCE
Citation Formats
Rosales, Bryan A., Hanrahan, Michael P., Boote, Brett W., Rossini, Aaron J., Smith, Emily A., and Vela, Javier. Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy. United States: N. p., 2017.
Web. doi:10.1021/acsenergylett.6b00674.
Rosales, Bryan A., Hanrahan, Michael P., Boote, Brett W., Rossini, Aaron J., Smith, Emily A., & Vela, Javier. Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy. United States. https://doi.org/10.1021/acsenergylett.6b00674
Rosales, Bryan A., Hanrahan, Michael P., Boote, Brett W., Rossini, Aaron J., Smith, Emily A., and Vela, Javier. Tue .
"Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy". United States. https://doi.org/10.1021/acsenergylett.6b00674.
@article{osti_1352099,
title = {Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy},
author = {Rosales, Bryan A. and Hanrahan, Michael P. and Boote, Brett W. and Rossini, Aaron J. and Smith, Emily A. and Vela, Javier},
abstractNote = {Hybrid lead perovskites containing a mixture of organic and inorganic cations and anions have lead to solar cell devices with better performance and stability than their single halide analogs. Here, 207Pb solid-state nuclear magnetic resonance and single particle photoluminescence spectroscopies show that the structure and composition of mixed-halide and—likely—other hybrid lead perovskites is much more complex than previously thought and is highly dependent on their synthesis. While a majority of reports in the area focus on the construction of photovoltaic devices, this perspective focuses instead on achieving a better understanding of the fundamental chemistry and photophysics of these materials, as this will aid not only in constructing improved devices, but also in generating new uses for these unique materials.},
doi = {10.1021/acsenergylett.6b00674},
journal = {ACS Energy Letters},
number = 4,
volume = 2,
place = {United States},
year = {Tue Mar 28 00:00:00 EDT 2017},
month = {Tue Mar 28 00:00:00 EDT 2017}
}
https://doi.org/10.1021/acsenergylett.6b00674
Web of Science
Figures / Tables:
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