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Title: Identification of structural relaxation in the dielectric response of water

Abstract

One century ago pioneering dielectric results obtained for water and n-alcohols triggered the advent of molecular rotation diffusion theory considered by Debye to describe the primary dielectric absorption in these liquids. Here, comparing dielectric, viscoelastic, and light scattering results, we unambiguously demonstrate that the structural relaxation appears only as a high-frequency shoulder in the dielectric spectra of water. In contrast, the main dielectric peak is related to a supramolecular structure, analogous to the Debye-like peak observed in monoalcohols.

Authors:
 [1];  [2];  [3];  [4]
  1. Roskilde Univ., Roskilde (Denmark)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
  4. Univ. of Tennessee, Knoxville, TN (United States); Technical Univ. of Dortmund, Dortmund (Germany)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1347335
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review Letters
Additional Journal Information:
Journal Volume: 116; Journal Issue: 23; Journal ID: ISSN 0031-9007
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS

Citation Formats

Hansen, Jesper S., Kisliuk, Alexander, Sokolov, Alexei P., and Gainaru, Catalin. Identification of structural relaxation in the dielectric response of water. United States: N. p., 2016. Web. doi:10.1103/PhysRevLett.116.237601.
Hansen, Jesper S., Kisliuk, Alexander, Sokolov, Alexei P., & Gainaru, Catalin. Identification of structural relaxation in the dielectric response of water. United States. doi:10.1103/PhysRevLett.116.237601.
Hansen, Jesper S., Kisliuk, Alexander, Sokolov, Alexei P., and Gainaru, Catalin. Thu . "Identification of structural relaxation in the dielectric response of water". United States. doi:10.1103/PhysRevLett.116.237601. https://www.osti.gov/servlets/purl/1347335.
@article{osti_1347335,
title = {Identification of structural relaxation in the dielectric response of water},
author = {Hansen, Jesper S. and Kisliuk, Alexander and Sokolov, Alexei P. and Gainaru, Catalin},
abstractNote = {One century ago pioneering dielectric results obtained for water and n-alcohols triggered the advent of molecular rotation diffusion theory considered by Debye to describe the primary dielectric absorption in these liquids. Here, comparing dielectric, viscoelastic, and light scattering results, we unambiguously demonstrate that the structural relaxation appears only as a high-frequency shoulder in the dielectric spectra of water. In contrast, the main dielectric peak is related to a supramolecular structure, analogous to the Debye-like peak observed in monoalcohols.},
doi = {10.1103/PhysRevLett.116.237601},
journal = {Physical Review Letters},
number = 23,
volume = 116,
place = {United States},
year = {2016},
month = {6}
}

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    Works referencing / citing this record:

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