Correlation between temperature variations of static and dynamic properties in glass-forming liquids
Abstract
In this detailed analysis of the static structure factor S(Q) in several glass-forming liquids we show that the temperature variations of the width of the main diffraction peak Q(T ) correlate with the fragility of these liquids. Our observation suggests a direct connection between rather subtle structural changes and sharp slowing down of structural relaxation in glass-forming liquids. We also show that this observation can be rationalized using the Adam-Gibbs approach, through a connection between temperature variations of structural correlation length, lc 2 /Q, and the size of cooperatively rearranging regions.
- Authors:
-
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Materials Science and Engineering
- Yale Univ., New Haven, CT (United States). Chemistry Dept.
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source
- Fukuoka Inst. of Technology (Japan). Dept. of Electrical Engineering
- (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
- Sponsoring Org.:
- USDOE; National Science Foundation (NSF)
- OSTI Identifier:
- 1347331
- Grant/Contract Number:
- AC05-00OR22725; DMR-1408811
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review E
- Additional Journal Information:
- Journal Volume: 94; Journal Issue: 6; Journal ID: ISSN 2470-0045
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Voylov, D. N., Griffin, P. J., Mercado, B., Keum, J. K., Nakanishi, M., Novikov, V. N., Sokolov, A. P., and Oak Ridge National Lab. Correlation between temperature variations of static and dynamic properties in glass-forming liquids. United States: N. p., 2016.
Web. doi:10.1103/PhysRevE.94.060603.
Voylov, D. N., Griffin, P. J., Mercado, B., Keum, J. K., Nakanishi, M., Novikov, V. N., Sokolov, A. P., & Oak Ridge National Lab. Correlation between temperature variations of static and dynamic properties in glass-forming liquids. United States. https://doi.org/10.1103/PhysRevE.94.060603
Voylov, D. N., Griffin, P. J., Mercado, B., Keum, J. K., Nakanishi, M., Novikov, V. N., Sokolov, A. P., and Oak Ridge National Lab. Thu .
"Correlation between temperature variations of static and dynamic properties in glass-forming liquids". United States. https://doi.org/10.1103/PhysRevE.94.060603. https://www.osti.gov/servlets/purl/1347331.
@article{osti_1347331,
title = {Correlation between temperature variations of static and dynamic properties in glass-forming liquids},
author = {Voylov, D. N. and Griffin, P. J. and Mercado, B. and Keum, J. K. and Nakanishi, M. and Novikov, V. N. and Sokolov, A. P. and Oak Ridge National Lab.},
abstractNote = {In this detailed analysis of the static structure factor S(Q) in several glass-forming liquids we show that the temperature variations of the width of the main diffraction peak Q(T ) correlate with the fragility of these liquids. Our observation suggests a direct connection between rather subtle structural changes and sharp slowing down of structural relaxation in glass-forming liquids. We also show that this observation can be rationalized using the Adam-Gibbs approach, through a connection between temperature variations of structural correlation length, lc 2 /Q, and the size of cooperatively rearranging regions.},
doi = {10.1103/PhysRevE.94.060603},
journal = {Physical Review E},
number = 6,
volume = 94,
place = {United States},
year = {Thu Dec 29 00:00:00 EST 2016},
month = {Thu Dec 29 00:00:00 EST 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 18 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Structure of vitreous and molten B2O3 measured by pulsed neutron total scattering
journal, June 1990
- Misawa, M.
- Journal of Non-Crystalline Solids, Vol. 122, Issue 1
X-ray scattering study and molecular simulation of glass forming liquids: Propylene carbonate and salol
journal, September 2000
- Eckstein, E.; Qian, J.; Hentschke, R.
- The Journal of Chemical Physics, Vol. 113, Issue 11
Translational diffusion in sucrose benzoate near the glass transition: Probe size dependence in the breakdown of the Stokes-Einstein equation
journal, June 2007
- Rajian, Justin Rajesh; Quitevis, Edward L.
- The Journal of Chemical Physics, Vol. 126, Issue 22
The liquid-glass transition in a strong network glass former investigated by neutron scattering
journal, July 1999
- Engberg, D.; Börjesson, L.; Swenson, J.
- Europhysics Letters (EPL), Vol. 47, Issue 2
Dynamics of glass‐forming liquids. I. Temperature‐derivative analysis of dielectric relaxation data
journal, April 1995
- Stickel, F.; Fischer, E. W.; Richert, R.
- The Journal of Chemical Physics, Vol. 102, Issue 15
Temperature dependence of local segmental motion in polystyrene and its variation with molecular weight
journal, July 2003
- Roland, C. M.; Casalini, R.
- The Journal of Chemical Physics, Vol. 119, Issue 3
Structure of liquid and glassy
journal, September 2010
- Zeidler, Anita; Salmon, Philip S.; Martin, Richard A.
- Physical Review B, Vol. 82, Issue 10
Universal relation between viscous flow and fast dynamics in glass-forming materials
journal, March 2010
- Scopigno, T.; Cangialosi, D.; Ruocco, G.
- Physical Review B, Vol. 81, Issue 10
Liquid structure: Is it directly correlative to glass-forming ability?
journal, July 2007
- Zhao, Yan; Bian, Xiufang; Qin, Xubo
- Physics Letters A, Vol. 367, Issue 4-5
Anomalous structural evolution and liquid fragility signatures in Cu–Zr and Cu–Hf liquids and glasses
journal, November 2013
- Mauro, N. A.; Vogt, Adam J.; Johnson, Mark L.
- Acta Materialia, Vol. 61, Issue 19
Structural changes in sodium tetrasilicate glass around the liquid-glass transition: a neutron diffraction study
journal, December 1998
- Zotov, N.; Delaplane, R. G.; Keppler, H.
- Physics and Chemistry of Minerals, Vol. 26, Issue 2
Intermediate-range order in binary chalcogenide glasses: The first sharp diffraction peak
journal, December 1988
- Susman, S.; Price, D. L.; Volin, K. J.
- Journal of Non-Crystalline Solids, Vol. 106, Issue 1-3
Neutron scattering studies of the model glass former ortho -terphenyl
journal, October 2001
- Tölle, Albert
- Reports on Progress in Physics, Vol. 64, Issue 11
A structural signature of liquid fragility
journal, August 2014
- Mauro, N. A.; Blodgett, M.; Johnson, M. L.
- Nature Communications, Vol. 5, Issue 1
Theoretical perspective on the glass transition and amorphous materials
journal, June 2011
- Berthier, Ludovic; Biroli, Giulio
- Reviews of Modern Physics, Vol. 83, Issue 2
Correlation between dynamic fragility and glass transition temperature for different classes of glass forming liquids
journal, August 2006
- Qin, Qian; McKenna, Gregory B.
- Journal of Non-Crystalline Solids, Vol. 352, Issue 28-29
Structure and Dynamics of Poly( n -decyl methacrylate) below and above the Glass Transition
journal, October 1998
- Floudas, G.; Štepánek, P.
- Macromolecules, Vol. 31, Issue 20
A neutron diffraction study of Ca0.4K0.6(NO3)1.4 from the glass to liquid state
journal, June 1997
- Tengroth, C.; Swenson, J.; Börjesson, L.
- Physica B: Condensed Matter, Vol. 234-236
Structural studies of an organic liquid through the glass transition
journal, November 1996
- Leheny, Robert L.; Menon, Narayanan; Nagel, Sidney R.
- The Journal of Chemical Physics, Vol. 105, Issue 17
Thermodynamic signature of growing amorphous order in glass-forming liquids
journal, August 2008
- Biroli, G.; Bouchaud, J. -P.; Cavagna, A.
- Nature Physics, Vol. 4, Issue 10
Topological versus chemical ordering in network glasses at intermediate and extended length scales
journal, May 2005
- Salmon, Philip S.; Martin, Richard A.; Mason, Philip E.
- Nature, Vol. 435, Issue 7038
Temperature-dependent structure of methyltributylammonium bis(trifluoromethylsulfonyl)amide: X ray scattering and simulations
journal, February 2011
- Santos, Cherry S.; Annapureddy, Harsha V. R.; Murthy, N. Sanjeeva
- The Journal of Chemical Physics, Vol. 134, Issue 6
Supercooled liquids and the glass transition
journal, March 2001
- Debenedetti, Pablo G.; Stillinger, Frank H.
- Nature, Vol. 410, Issue 6825
Network Topology and the Fragility of Tetrahedral Glass-Forming Liquids
journal, October 2009
- Wilson, Mark; Salmon, Philip S.
- Physical Review Letters, Vol. 103, Issue 15
Molecular Weight Dependence of Fragility in Polystyrene
journal, July 1998
- Santangelo, P. G.; Roland, C. M.
- Macromolecules, Vol. 31, Issue 14
Structural evolution in Ni–Nb and Ni–Nb–Ta liquids and glasses — A measure of liquid fragility?
journal, February 2013
- Mauro, N. A.; Johnson, M. L.; Bendert, J. C.
- Journal of Non-Crystalline Solids, Vol. 362
The structure of vitreous and liquid GeSe2: a neutron diffraction study
journal, November 1990
- Susman, Sherman; Volin, Kenneth J.; Montague, Daniel G.
- Journal of Non-Crystalline Solids, Vol. 125, Issue 1-2
Viscous flow in silica and binary liquid silicates
journal, January 1955
- Bockris, J. O'M.; Mackenzie, J. D.; Kitchener, J. A.
- Transactions of the Faraday Society, Vol. 51
Spectroscopy simulation and scattering, and the medium range order problem in glass
journal, August 1985
- Angell, C. A.
- Journal of Non-Crystalline Solids, Vol. 73, Issue 1-3
Medium-Range Order in Silica, the Canonical Network Glass
journal, January 1996
- Gaskell, P. H.; Wallis, D. J.
- Physical Review Letters, Vol. 76, Issue 1
Thermodynamics, Structure, and Dynamics in Room Temperature Ionic Liquids: The Case of 1-Butyl-3-methyl Imidazolium Hexafluorophosphate ([bmim][PF 6 ])
journal, October 2006
- Triolo, Alessandro; Mandanici, Andrea; Russina, Olga
- The Journal of Physical Chemistry B, Vol. 110, Issue 42
On the Temperature Dependence of Cooperative Relaxation Properties in Glass‐Forming Liquids
journal, July 1965
- Adam, Gerold; Gibbs, Julian H.
- The Journal of Chemical Physics, Vol. 43, Issue 1
Fifth-order susceptibility unveils growth of thermodynamic amorphous order in glass-formers
journal, June 2016
- Albert, S.; Bauer, T.; Michl, M.
- Science, Vol. 352, Issue 6291
Medium-range order in glasses: Comparison of Raman and diffraction measurements
journal, September 1992
- Sokolov, A. P.; Kisliuk, A.; Soltwisch, M.
- Physical Review Letters, Vol. 69, Issue 10
Nonexponential relaxations in strong and fragile glass formers
journal, September 1993
- Böhmer, R.; Ngai, K. L.; Angell, C. A.
- The Journal of Chemical Physics, Vol. 99, Issue 5
Cooperativity and the Freezing of Molecular Motion at the Glass Transition
journal, November 2013
- Bauer, Th.; Lunkenheimer, P.; Loidl, A.
- Physical Review Letters, Vol. 111, Issue 22
Are polymers standard glass-forming systems? The role of intramolecular barriers on the glass-transition phenomena of glass-forming polymers
journal, January 2015
- Colmenero, J.
- Journal of Physics: Condensed Matter, Vol. 27, Issue 10
Evolution of the dynamic susceptibility in molecular glass formers: Results from light scattering, dielectric spectroscopy, and NMR
journal, March 2013
- Petzold, N.; Schmidtke, B.; Kahlau, R.
- The Journal of Chemical Physics, Vol. 138, Issue 12
Formation of Glasses from Liquids and Biopolymers
journal, March 1995
- Angell, C. A.
- Science, Vol. 267, Issue 5206
Anomalous structural evolution in Cu 50 Zr 50 glass-forming liquids
journal, July 2013
- Mauro, Nicholas A.; Vogt, Adam J.; Johnson, Mark L.
- Applied Physics Letters, Vol. 103, Issue 2
Glassy Aging Dynamics
journal, July 2005
- Lunkenheimer, P.; Wehn, R.; Schneider, U.
- Physical Review Letters, Vol. 95, Issue 5
Through the Glass Lightly
journal, March 1995
- Vogelstein, B.; Kinzler, K. W.
- Science, Vol. 267, Issue 5204
Non-exponential relaxations in strong and fragile glass-formers
text, January 1993
- Böhmer, Roland; Ngai, K. L.; Angell, C. A.
- The American Institute of Physics
Thermodynamic signature of growing amorphous order in glass-forming liquids
text, January 2008
- Biroli, G.; Bouchaud, J. -P.; Cavagna, A.
- arXiv
Theoretical perspective on the glass transition and amorphous materials
text, January 2010
- Berthier, Ludovic; Biroli, Giulio
- arXiv
Works referencing / citing this record:
The role of local-geometrical-orders on the growth of dynamic-length-scales in glass-forming liquids
journal, January 2018
- Wong, Kaikin; Krishnan, Rithin P.; Chen, Changjiu
- Scientific Reports, Vol. 8, Issue 1
Local Density Correlations in Liquids
journal, February 2020
- Egami, Takeshi
- Frontiers in Physics, Vol. 8