A magnesium–sodium hybrid battery with high operating voltage
Abstract
Here, we report a high performance magnesium-sodium hybrid battery utilizing a magnesium-sodium dual-salt electrolyte, a magnesium anode, and a Berlin green cathode. The cell delivers an average discharge voltage of 2.2 V and a reversible capacity of 143 mA h g–1. We also demonstrate the cell with an energy density of 135 W h kg–1 and a high power density of up to 1.67 kW kg–1.
- Authors:
-
- Univ. of Houston, Houston, TX (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sharp Lab. of America, Camas, WA (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- US Department of the Navy, Office of Naval Research (ONR); National Science Foundation (NSF); USDOE Office of Science (SC)
- OSTI Identifier:
- 1346732
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 52; Journal Issue: 53; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Dong, Hui, Li, Yifei, Liang, Yanliang, Li, Guosheng, Sun, Cheng -Jun, Ren, Yang, Lu, Yuhao, and Yao, Yan. A magnesium–sodium hybrid battery with high operating voltage. United States: N. p., 2016.
Web. doi:10.1039/c6cc03081e.
Dong, Hui, Li, Yifei, Liang, Yanliang, Li, Guosheng, Sun, Cheng -Jun, Ren, Yang, Lu, Yuhao, & Yao, Yan. A magnesium–sodium hybrid battery with high operating voltage. United States. https://doi.org/10.1039/c6cc03081e
Dong, Hui, Li, Yifei, Liang, Yanliang, Li, Guosheng, Sun, Cheng -Jun, Ren, Yang, Lu, Yuhao, and Yao, Yan. Fri .
"A magnesium–sodium hybrid battery with high operating voltage". United States. https://doi.org/10.1039/c6cc03081e. https://www.osti.gov/servlets/purl/1346732.
@article{osti_1346732,
title = {A magnesium–sodium hybrid battery with high operating voltage},
author = {Dong, Hui and Li, Yifei and Liang, Yanliang and Li, Guosheng and Sun, Cheng -Jun and Ren, Yang and Lu, Yuhao and Yao, Yan},
abstractNote = {Here, we report a high performance magnesium-sodium hybrid battery utilizing a magnesium-sodium dual-salt electrolyte, a magnesium anode, and a Berlin green cathode. The cell delivers an average discharge voltage of 2.2 V and a reversible capacity of 143 mA h g–1. We also demonstrate the cell with an energy density of 135 W h kg–1 and a high power density of up to 1.67 kW kg–1.},
doi = {10.1039/c6cc03081e},
journal = {ChemComm},
number = 53,
volume = 52,
place = {United States},
year = {Fri Jun 10 00:00:00 EDT 2016},
month = {Fri Jun 10 00:00:00 EDT 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 43 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Copper hexacyanoferrate battery electrodes with long cycle life and high power
journal, November 2011
- Wessells, Colin D.; Huggins, Robert A.; Cui, Yi
- Nature Communications, Vol. 2, Article No. 550
Prussian blue: a new framework of electrode materials for sodium batteries
journal, January 2012
- Lu, Yuhao; Wang, Long; Cheng, Jinguang
- Chemical Communications, Vol. 48, Issue 52, p. 6544-6546
Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries
journal, October 2014
- You, Ya; Yu, Xiqian; Yin, Yaxia
- Nano Research, Vol. 8, Issue 1
Single-crystal FeFe(CN)6 nanoparticles: a high capacity and high rate cathode for Na-ion batteries
journal, January 2013
- Wu, Xianyong; Deng, Wenwen; Qian, Jiangfeng
- Journal of Materials Chemistry A, Vol. 1, Issue 35
Rhombohedral Prussian White as Cathode for Rechargeable Sodium-Ion Batteries
journal, February 2015
- Wang, Long; Song, Jie; Qiao, Ruimin
- Journal of the American Chemical Society, Vol. 137, Issue 7
Microscopic properties of lithium, sodium, and magnesium battery anode materials related to possible dendrite growth
journal, November 2014
- Jäckle, Markus; Groß, Axel
- The Journal of Chemical Physics, Vol. 141, Issue 17
New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon
journal, August 2015
- Bommier, Clement; Surta, Todd Wesley; Dolgos, Michelle
- Nano Letters, Vol. 15, Issue 9
The Mechanisms of Lithium and Sodium Insertion in Carbon Materials
journal, January 2001
- Stevens, D. A.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 148, Issue 8
Prototype systems for rechargeable magnesium batteries
journal, October 2000
- Aurbach, D.; Lu, Z.; Schechter, A.
- Nature, Vol. 407, Issue 6805, p. 724-727
Interlayer-Expanded Molybdenum Disulfide Nanocomposites for Electrochemical Magnesium Storage
journal, February 2015
- Liang, Yanliang; Yoo, Hyun Deog; Li, Yifei
- Nano Letters, Vol. 15, Issue 3
Improved Electrolyte Solutions for Rechargeable Magnesium Batteries
journal, January 2006
- Gofer, Yosef; Chusid, Orit; Gizbar, Haim
- Electrochemical and Solid-State Letters, Vol. 9, Issue 5
A concept of dual-salt polyvalent-metal storage battery
journal, January 2014
- Yagi, Shunsuke; Ichitsubo, Tetsu; Shirai, Yoshimasa
- J. Mater. Chem. A, Vol. 2, Issue 4
High performance batteries based on hybrid magnesium and lithium chemistry
journal, January 2014
- Cheng, Yingwen; Shao, Yuyan; Zhang, Ji-Guang
- Chem. Commun., Vol. 50, Issue 68
Efficient and Inexpensive Sodium–Magnesium Hybrid Battery
journal, October 2015
- Walter, Marc; Kravchyk, Kostiantyn V.; Ibáñez, Maria
- Chemistry of Materials, Vol. 27, Issue 21
Elucidating the structure of the magnesium aluminum chloride complex electrolyte for magnesium-ion batteries
journal, January 2015
- Canepa, Pieremanuele; Jayaraman, Saivenkataraman; Cheng, Lei
- Energy & Environmental Science, Vol. 8, Issue 12
Electrochemically stable cathode current collectors for rechargeable magnesium batteries
journal, January 2014
- Cheng, Yingwen; Liu, Tianbiao; Shao, Yuyan
- J. Mater. Chem. A, Vol. 2, Issue 8
A high performance hybrid battery based on aluminum anode and LiFePO 4 cathode
journal, January 2016
- Sun, Xiao-Guang; Bi, Zhonghe; Liu, Hansan
- Chemical Communications, Vol. 52, Issue 8
An Efficient Halogen-Free Electrolyte for Use in Rechargeable Magnesium Batteries
journal, May 2015
- Tutusaus, Oscar; Mohtadi, Rana; Arthur, Timothy S.
- Angewandte Chemie International Edition, Vol. 54, Issue 27
Combining In Situ Synchrotron X-Ray Diffraction and Absorption Techniques with Transmission Electron Microscopy to Study the Origin of Thermal Instability in Overcharged Cathode Materials for Lithium-Ion Batteries
journal, June 2012
- Nam, Kyung-Wan; Bak, Seong-Min; Hu, Enyuan
- Advanced Functional Materials, Vol. 23, Issue 8
A Superior Low-Cost Cathode for a Na-Ion Battery
journal, January 2013
- Wang, Long; Lu, Yuhao; Liu, Jue
- Angewandte Chemie International Edition, Vol. 52, Issue 7
High energy density hybrid Mg 2+ /Li + battery with superior ultra-low temperature performance
journal, January 2016
- Zhang, Zhonghua; Xu, Huimin; Cui, Zili
- Journal of Materials Chemistry A, Vol. 4, Issue 6
High Areal Capacity Hybrid Magnesium–Lithium-Ion Battery with 99.9% Coulombic Efficiency for Large-Scale Energy Storage
journal, March 2015
- Yoo, Hyun Deog; Liang, Yanliang; Li, Yifei
- ACS Applied Materials & Interfaces, Vol. 7, Issue 12
Dual-Salt Mg-Based Batteries with Conversion Cathodes
journal, November 2015
- Zhang, Ye; Xie, Junjie; Han, Yanlin
- Advanced Functional Materials, Vol. 25, Issue 47
Works referencing / citing this record:
High Rate Magnesium-Sulfur Battery with Improved Cyclability Based on Metal-Organic Framework Derivative Carbon Host
journal, January 2018
- Zhou, Xuejun; Tian, Jing; Hu, Jiulin
- Advanced Materials, Vol. 30, Issue 7
KTi 2 (PO 4 ) 3 with Large Ion Diffusion Channel for High-Efficiency Sodium Storage
journal, May 2017
- Sheng, Jinzhi; Peng, Chen; Xu, Yanan
- Advanced Energy Materials, Vol. 7, Issue 17
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review
journal, January 2019
- Ma, Zheng; MacFarlane, Douglas R.; Kar, Mega
- Batteries & Supercaps, Vol. 2, Issue 2
Four decades of electrochemical investigation of Prussian blue
journal, November 2019
- Ivanov, Vladimir D.
- Ionics, Vol. 26, Issue 2
A critical review of cathodes for rechargeable Mg batteries
journal, January 2018
- Mao, Minglei; Gao, Tao; Hou, Singyuk
- Chemical Society Reviews, Vol. 47, Issue 23
Exploring the Synergy of LiBH 4 /NaBH 4 Additives with Mg(BH 4 ) 2 Electrolyte Using Density Functional Theory
journal, January 2018
- Deetz, Joshua D.; Cao, Fenglei; Sun, Huai
- Journal of The Electrochemical Society, Vol. 165, Issue 11
Communication—Mg(TFSI) 2 -Based Hybrid Magnesium-Sodium Electrolyte: Case Study with NaTi 2 (PO 4 ) 3 //Mg Cell
journal, January 2018
- Rudola, Ashish; Azmansah, Siti Aishah Bte; Balaya, Palani
- Journal of The Electrochemical Society, Vol. 165, Issue 5
Rechargeable Mg–Li hybrid batteries: status and challenges
journal, September 2016
- Cheng, Yingwen; Chang, Hee Jung; Dong, Hui
- Journal of Materials Research, Vol. 31, Issue 20
Magnesium-Sodium Hybrid Battery With High Voltage, Capacity and Cyclability
journal, December 2018
- Zhang, Ruigang; Tutusaus, Oscar; Mohtadi, Rana
- Frontiers in Chemistry, Vol. 6