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Title: Ultrafast Relaxation Dynamics of Photoexcited Zinc-Porphyrin: Electronic-Vibrational Coupling

Cyclic tetrapyrroles are the active core of compounds with crucial roles in living systems, such as hemoglobin and chlorophyll, and in technology as photocatalysts and light absorbers for solar energy conversion. Zinc-tetraphenylporphyrin (Zn-TPP) is a prototypical cyclic tetrapyrrole that has been intensely studied in past decades. Because of its importance for photochemical processes the optical properties are of particular interest, and, accordingly, numerous studies have focused on light absorption and excited-state dynamics of Zn-TPP. Relaxation after photoexcitation in the Soret band involves internal conversion that is preceded by an ultrafast process. This relaxation process has been observed by several groups. Until now, it has not been established if it involves a higher lying ”dark” state or vibrational relaxation in the excited S 2 state. Here we combine high time resolution electronic and vibrational spectroscopy to show that this process constitutes vibrational relaxation in the anharmonic 2 potential.
Authors:
 [1] ;  [2] ;  [1]
  1. Univ. of Delaware, Newark, DE (United States). Dept. of Chemistry and Biochemistry
  2. Univ. of Delaware, Newark, DE (United States). Dept. of Physics and Astronomy
Publication Date:
Grant/Contract Number:
SC0016288
Type:
Accepted Manuscript
Journal Name:
Journal of Physical Chemistry Letters
Additional Journal Information:
Journal Volume: 7; Journal Issue: 16; Journal ID: ISSN 1948-7185
Publisher:
American Chemical Society
Research Org:
Univ. of Delaware, Newark, DE (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 14 SOLAR ENERGY
OSTI Identifier:
1345807

Abraham, Baxter, Nieto-Pescador, Jesus, and Gundlach, Lars. Ultrafast Relaxation Dynamics of Photoexcited Zinc-Porphyrin: Electronic-Vibrational Coupling. United States: N. p., Web. doi:10.1021/acs.jpclett.6b01439.
Abraham, Baxter, Nieto-Pescador, Jesus, & Gundlach, Lars. Ultrafast Relaxation Dynamics of Photoexcited Zinc-Porphyrin: Electronic-Vibrational Coupling. United States. doi:10.1021/acs.jpclett.6b01439.
Abraham, Baxter, Nieto-Pescador, Jesus, and Gundlach, Lars. 2016. "Ultrafast Relaxation Dynamics of Photoexcited Zinc-Porphyrin: Electronic-Vibrational Coupling". United States. doi:10.1021/acs.jpclett.6b01439. https://www.osti.gov/servlets/purl/1345807.
@article{osti_1345807,
title = {Ultrafast Relaxation Dynamics of Photoexcited Zinc-Porphyrin: Electronic-Vibrational Coupling},
author = {Abraham, Baxter and Nieto-Pescador, Jesus and Gundlach, Lars},
abstractNote = {Cyclic tetrapyrroles are the active core of compounds with crucial roles in living systems, such as hemoglobin and chlorophyll, and in technology as photocatalysts and light absorbers for solar energy conversion. Zinc-tetraphenylporphyrin (Zn-TPP) is a prototypical cyclic tetrapyrrole that has been intensely studied in past decades. Because of its importance for photochemical processes the optical properties are of particular interest, and, accordingly, numerous studies have focused on light absorption and excited-state dynamics of Zn-TPP. Relaxation after photoexcitation in the Soret band involves internal conversion that is preceded by an ultrafast process. This relaxation process has been observed by several groups. Until now, it has not been established if it involves a higher lying ”dark” state or vibrational relaxation in the excited S2 state. Here we combine high time resolution electronic and vibrational spectroscopy to show that this process constitutes vibrational relaxation in the anharmonic 2 potential.},
doi = {10.1021/acs.jpclett.6b01439},
journal = {Journal of Physical Chemistry Letters},
number = 16,
volume = 7,
place = {United States},
year = {2016},
month = {8}
}