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Title: Membrane-Based Gas Separation Accelerated by Hollow Nanosphere Architectures

Abstract

We report that the coupling of hollow carbon nanospheres with triblock copolymers is a promising strategy to fabricate mixed-matrix membranes, because the symmetric microporous shells combine with the hollow space to promote gas transport and the unique soft-rigid molecular structure of triblock copolymers can accommodate a high loading of fillers without a significant loss of mechanical strength.

Authors:
 [1];  [1];  [2];  [1];  [1];  [3];  [1];  [1];  [1];  [1];  [1];  [2]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
  2. (United States). Dept. of Chemistry
  3. (China)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1345787
Alternate Identifier(s):
OSTI ID: 1401722
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 29; Journal Issue: 4; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; mixed-matrix membranes; hollow nanosphere architectures; gas separation; triblock copolymer

Citation Formats

Zhang, Jinshui, Schott, Jennifer Ann, Univ. of Tennessee, Knoxville, TN, Li, Yunchao, Zhan, Wangcheng, East China Univ. of Science and Technology, Shanghai, Mahurin, Shannon M., Nelson, Kimberly, Sun, Xiao-Guang, Paranthaman, Mariappan Parans, Dai, Sheng, and Univ. of Tennessee, Knoxville, TN. Membrane-Based Gas Separation Accelerated by Hollow Nanosphere Architectures. United States: N. p., 2016. Web. doi:10.1002/adma.201603797.
Zhang, Jinshui, Schott, Jennifer Ann, Univ. of Tennessee, Knoxville, TN, Li, Yunchao, Zhan, Wangcheng, East China Univ. of Science and Technology, Shanghai, Mahurin, Shannon M., Nelson, Kimberly, Sun, Xiao-Guang, Paranthaman, Mariappan Parans, Dai, Sheng, & Univ. of Tennessee, Knoxville, TN. Membrane-Based Gas Separation Accelerated by Hollow Nanosphere Architectures. United States. doi:10.1002/adma.201603797.
Zhang, Jinshui, Schott, Jennifer Ann, Univ. of Tennessee, Knoxville, TN, Li, Yunchao, Zhan, Wangcheng, East China Univ. of Science and Technology, Shanghai, Mahurin, Shannon M., Nelson, Kimberly, Sun, Xiao-Guang, Paranthaman, Mariappan Parans, Dai, Sheng, and Univ. of Tennessee, Knoxville, TN. Tue . "Membrane-Based Gas Separation Accelerated by Hollow Nanosphere Architectures". United States. doi:10.1002/adma.201603797. https://www.osti.gov/servlets/purl/1345787.
@article{osti_1345787,
title = {Membrane-Based Gas Separation Accelerated by Hollow Nanosphere Architectures},
author = {Zhang, Jinshui and Schott, Jennifer Ann and Univ. of Tennessee, Knoxville, TN and Li, Yunchao and Zhan, Wangcheng and East China Univ. of Science and Technology, Shanghai and Mahurin, Shannon M. and Nelson, Kimberly and Sun, Xiao-Guang and Paranthaman, Mariappan Parans and Dai, Sheng and Univ. of Tennessee, Knoxville, TN},
abstractNote = {We report that the coupling of hollow carbon nanospheres with triblock copolymers is a promising strategy to fabricate mixed-matrix membranes, because the symmetric microporous shells combine with the hollow space to promote gas transport and the unique soft-rigid molecular structure of triblock copolymers can accommodate a high loading of fillers without a significant loss of mechanical strength.},
doi = {10.1002/adma.201603797},
journal = {Advanced Materials},
number = 4,
volume = 29,
place = {United States},
year = {2016},
month = {11}
}

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Cited by: 14 works
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