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Title: Advanced electron microscopy characterization of nanomaterials for catalysis

Abstract

Transmission electron microscopy (TEM) has become one of the most powerful techniques in the fields of material science, inorganic chemistry and nanotechnology. In terms of resolutions, advanced TEM may reach a high spatial resolution of 0.05 nm, a high energy-resolution of 7 meV. In addition, in situ TEM can help researcher to image the process happened within 1 ms. This paper reviews the recent technical approaches of applying advanced TEM characterization on nanomaterials for catalysis. The text is organized according to the demanded information of nanocrystals from the perspective of application: for example, size, composition, phase, strain, and morphology. The electron beam induced effect and in situ TEM are also introduced. As a result, I hope this review can help the scientists in related fields to take advantage of advanced TEM to their own researches.

Authors:
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1352094
Alternate Identifier(s):
OSTI ID: 1345744
Report Number(s):
BNL-113586-2017-JA
Journal ID: ISSN 2468-0257; S2468025717300043; PII: S2468025717300043
Grant/Contract Number:  
SC0012704; SC00112704
Resource Type:
Published Article
Journal Name:
Green Energy & Environment
Additional Journal Information:
Journal Name: Green Energy & Environment; Journal ID: ISSN 2468-0257
Publisher:
Elsevier
Country of Publication:
China
Language:
English
Subject:
29 ENERGY PLANNING, POLICY, AND ECONOMY; TEM; nanomaterials; Center for Functional Nanomaterials

Citation Formats

Su, Dong. Advanced electron microscopy characterization of nanomaterials for catalysis. China: N. p., 2017. Web. doi:10.1016/j.gee.2017.02.001.
Su, Dong. Advanced electron microscopy characterization of nanomaterials for catalysis. China. https://doi.org/10.1016/j.gee.2017.02.001
Su, Dong. Wed . "Advanced electron microscopy characterization of nanomaterials for catalysis". China. https://doi.org/10.1016/j.gee.2017.02.001.
@article{osti_1352094,
title = {Advanced electron microscopy characterization of nanomaterials for catalysis},
author = {Su, Dong},
abstractNote = {Transmission electron microscopy (TEM) has become one of the most powerful techniques in the fields of material science, inorganic chemistry and nanotechnology. In terms of resolutions, advanced TEM may reach a high spatial resolution of 0.05 nm, a high energy-resolution of 7 meV. In addition, in situ TEM can help researcher to image the process happened within 1 ms. This paper reviews the recent technical approaches of applying advanced TEM characterization on nanomaterials for catalysis. The text is organized according to the demanded information of nanocrystals from the perspective of application: for example, size, composition, phase, strain, and morphology. The electron beam induced effect and in situ TEM are also introduced. As a result, I hope this review can help the scientists in related fields to take advantage of advanced TEM to their own researches.},
doi = {10.1016/j.gee.2017.02.001},
journal = {Green Energy & Environment},
number = ,
volume = ,
place = {China},
year = {Wed Feb 01 00:00:00 EST 2017},
month = {Wed Feb 01 00:00:00 EST 2017}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1016/j.gee.2017.02.001

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Works referenced in this record:

Three-dimensional coordinates of individual atoms in materials revealed by electron tomography
journal, September 2015

  • Xu, Rui; Chen, Chien-Chun; Wu, Li
  • Nature Materials, Vol. 14, Issue 11
  • DOI: 10.1038/nmat4426

Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts
journal, October 2012

  • Wang, Deli; Xin, Huolin L.; Hovden, Robert
  • Nature Materials, Vol. 12, Issue 1, p. 81-87
  • DOI: 10.1038/nmat3458

Direction-Specific Interactions Control Crystal Growth by Oriented Attachment
journal, May 2012


Electron microscopy of specimens in liquid
journal, October 2011

  • de Jonge, Niels; Ross, Frances M.
  • Nature Nanotechnology, Vol. 6, Issue 11, p. 695-704
  • DOI: 10.1038/nnano.2011.161

Electron tomography at 2.4-ångström resolution
journal, March 2012

  • Scott, M. C.; Chen, Chien-Chun; Mecklenburg, Matthew
  • Nature, Vol. 483, Issue 7390
  • DOI: 10.1038/nature10934

Shaping binary metal nanocrystals through epitaxial seeded growth
journal, July 2007

  • Habas, Susan E.; Lee, Hyunjoo; Radmilovic, Velimir
  • Nature Materials, Vol. 6, Issue 9
  • DOI: 10.1038/nmat1957

Controlling the Particle Size of ZrO 2 Nanoparticles in Hydrothermally Stable ZrO 2 /MWCNT Composites
journal, October 2012

  • Liu, Changchang; Lee, Sungchul; Su, Dong
  • Langmuir, Vol. 28, Issue 49
  • DOI: 10.1021/la303545y

Frontiers of in situ electron microscopy
journal, January 2015

  • Zheng, Haimei; Meng, Ying Shirley; Zhu, Yimei
  • MRS Bulletin, Vol. 40, Issue 1
  • DOI: 10.1557/mrs.2014.305

The Impact of Nanoscience on Heterogeneous Catalysis
journal, March 2003


Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
journal, February 2014


New Approach to Fully Ordered fct-FePt Nanoparticles for Much Enhanced Electrocatalysis in Acid
journal, March 2015


Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte
journal, February 2014

  • Holtz, Megan E.; Yu, Yingchao; Gunceler, Deniz
  • Nano Letters, Vol. 14, Issue 3
  • DOI: 10.1021/nl404577c

Orbital angular momentum microlaser
journal, July 2016


Dynamic Visualization of the Electric Potential in an All-Solid-State Rechargeable Lithium Battery
journal, June 2010

  • Yamamoto, Kazuo; Iriyama, Yasutoshi; Asaka, Toru
  • Angewandte Chemie, Vol. 122, Issue 26
  • DOI: 10.1002/ange.200907319

Observation of Single Colloidal Platinum Nanocrystal Growth Trajectories
journal, June 2009


Atom-Resolved Imaging of Dynamic Shape Changes in Supported Copper Nanocrystals
journal, March 2002


Exploring the environmental transmission electron microscope
journal, November 2012


Stepwise Evolution of Spherical Seeds into 20-Fold Twinned Icosahedra
journal, August 2012


Seed-Mediated Synthesis of Core/Shell FePtM/FePt (M = Pd, Au) Nanowires and Their Electrocatalysis for Oxygen Reduction Reaction
journal, September 2013

  • Guo, Shaojun; Zhang, Sen; Su, Dong
  • Journal of the American Chemical Society, Vol. 135, Issue 37
  • DOI: 10.1021/ja406091p

Atomic-scale determination of surface facets in gold nanorods
journal, October 2012

  • Goris, Bart; Bals, Sara; Van den Broek, Wouter
  • Nature Materials, Vol. 11, Issue 11
  • DOI: 10.1038/nmat3462

Counting Au catalytic sites for the water–gas shift reaction
journal, September 2012


FePt Icosahedra with Magnetic Cores and Catalytic Shells
journal, February 2009

  • Wang, Rongming; Dmitrieva, Olga; Farle, Michael
  • The Journal of Physical Chemistry C, Vol. 113, Issue 11
  • DOI: 10.1021/jp811280k

Electron beam damage in oxides: a review
journal, December 2015


Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries
journal, January 2014


Fire up the atom forge
journal, November 2016

  • Kalinin, Sergei V.; Borisevich, Albina; Jesse, Stephen
  • Nature, Vol. 539, Issue 7630
  • DOI: 10.1038/539485a

In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode
journal, December 2010


Aberration corrected and monochromated environmental transmission electron microscopy: challenges and prospects for materials science
journal, November 2010


Complex structural dynamics of nanocatalysts revealed in Operando conditions by correlated imaging and spectroscopy probes
journal, June 2015

  • Li, Y.; Zakharov, D.; Zhao, S.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8583

Visualizing Gas Molecules Interacting with Supported Nanoparticulate Catalysts at Reaction Conditions
journal, January 2012


Formation of monatomic metallic glasses through ultrafast liquid quenching
journal, August 2014

  • Zhong, Li; Wang, Jiangwei; Sheng, Hongwei
  • Nature, Vol. 512, Issue 7513
  • DOI: 10.1038/nature13617

Origin of voltage decay in high-capacity layered oxide electrodes
journal, December 2014

  • Sathiya, M.; Abakumov, A. M.; Foix, D.
  • Nature Materials, Vol. 14, Issue 2
  • DOI: 10.1038/nmat4137

Three-dimensional imaging of dislocations in a nanoparticle at atomic resolution
journal, March 2013

  • Chen, Chien-Chun; Zhu, Chun; White, Edward R.
  • Nature, Vol. 496, Issue 7443
  • DOI: 10.1038/nature12009

Sodiation via Heterogeneous Disproportionation in FeF 2 Electrodes for Sodium-Ion Batteries
journal, June 2014

  • He, Kai; Zhou, Yongning; Gao, Peng
  • ACS Nano, Vol. 8, Issue 7
  • DOI: 10.1021/nn502284y

Developments in in situ Environmental Cell High-Resolution Electron Microscopy and Applications to Catalysis
journal, January 2002


Interfacial Effects in Iron-Nickel Hydroxide-Platinum Nanoparticles Enhance Catalytic Oxidation
journal, May 2014


Atomic Structure of Au−Pd Bimetallic Alloyed Nanoparticles
journal, September 2010

  • Ding, Yong; Fan, Fengru; Tian, Zhongqun
  • Journal of the American Chemical Society, Vol. 132, Issue 35
  • DOI: 10.1021/ja105614q

The impacts of nanotechnology on catalysis by precious metal nanoparticles
journal, January 2012


Surface engineering of hierarchical platinum-cobalt nanowires for efficient electrocatalysis
journal, June 2016

  • Bu, Lingzheng; Guo, Shaojun; Zhang, Xu
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11850

Ordered bilayer ruthenium–platinum core-shell nanoparticles as carbon monoxide-tolerant fuel cell catalysts
journal, September 2013

  • Hsieh, Yu-Chi; Zhang, Yu; Su, Dong
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3466

Dynamic microscopy of nanoscale cluster growth at the solid–liquid interface
journal, July 2003

  • Williamson, M. J.; Tromp, R. M.; Vereecken, P. M.
  • Nature Materials, Vol. 2, Issue 8
  • DOI: 10.1038/nmat944

Do Eu dopants prefer the precipitated LaF 3 nanocrystals in glass ceramics?
journal, November 2012

  • Jiang, Nan; Zhou, Shifeng; Su, Dong
  • physica status solidi (RRL) - Rapid Research Letters, Vol. 6, Issue 12
  • DOI: 10.1002/pssr.201206476

Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts
journal, July 2013


Nanowire liquid pumps
journal, March 2013

  • Huang, Jian Yu; Lo, Yu-Chieh; Niu, Jun Jie
  • Nature Nanotechnology, Vol. 8, Issue 4
  • DOI: 10.1038/nnano.2013.41

Effects of elastic anisotropy on strain distributions in decahedral gold nanoparticles
journal, December 2007

  • Johnson, Craig L.; Snoeck, Etienne; Ezcurdia, Manex
  • Nature Materials, Vol. 7, Issue 2
  • DOI: 10.1038/nmat2083

Domain Dynamics During Ferroelectric Switching
journal, November 2011


Ternary PtSnRh–SnO2 nanoclusters: synthesis and electroactivity for ethanol oxidation fuel cell reaction
journal, January 2011

  • Du, Wenxin; Wang, Qi; LaScala, Carlo A.
  • Journal of Materials Chemistry, Vol. 21, Issue 24
  • DOI: 10.1039/c0jm04358c

Z-Contrast tomography: a technique in three-dimensional nanostructural analysis based on Rutherford scattering
journal, January 2001

  • Midgley, Paul A.; Weyland, Matthew; Thomas, John Meurig
  • Chemical Communications, Issue 10
  • DOI: 10.1039/b101819c

Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
journal, December 2008

  • Xia, Younan; Xiong, Yujie; Lim, Byungkwon
  • Angewandte Chemie International Edition, Vol. 48, Issue 1, p. 60-103
  • DOI: 10.1002/anie.200802248

Electron microscopy of gold nanoparticles at atomic resolution
journal, August 2014


Atom-by-atom structural and chemical analysis by annular dark-field electron microscopy
journal, March 2010

  • Krivanek, Ondrej L.; Chisholm, Matthew F.; Nicolosi, Valeria
  • Nature, Vol. 464, Issue 7288
  • DOI: 10.1038/nature08879

Impact of misfit dislocations on the polarization instability of epitaxial nanostructured ferroelectric perovskites
journal, January 2004

  • Chu, Ming-Wen; Szafraniak, Izabela; Scholz, Roland
  • Nature Materials, Vol. 3, Issue 2
  • DOI: 10.1038/nmat1057

Embedded Nanostructures Revealed in Three Dimensions
journal, September 2005


Sodiation Kinetics of Metal Oxide Conversion Electrodes: A Comparative Study with Lithiation
journal, August 2015


Remarkably Improved Electrode Performance of Bulk MnS by Forming a Solid Solution with FeS - Understanding the Li Storage Mechanism
journal, July 2014

  • Zhao, Liang; Yu, Xiqian; Yu, Juezhi
  • Advanced Functional Materials, Vol. 24, Issue 35
  • DOI: 10.1002/adfm.201400934

Basic questions related to electron-induced sputtering in the TEM
journal, July 2010


Real-Time Imaging of Pt3Fe Nanorod Growth in Solution
journal, May 2012


Studying the Kinetics of Crystalline Silicon Nanoparticle Lithiation with In Situ Transmission Electron Microscopy
journal, September 2012

  • McDowell, Matthew T.; Ryu, Ill; Lee, Seok Woo
  • Advanced Materials, Vol. 24, Issue 45
  • DOI: 10.1002/adma.201202744

Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis
journal, December 2016


Vibrational spectroscopy in the electron microscope
journal, October 2014

  • Krivanek, Ondrej L.; Lovejoy, Tracy C.; Dellby, Niklas
  • Nature, Vol. 514, Issue 7521
  • DOI: 10.1038/nature13870

Atomic-Scale Chemical Imaging of Composition and Bonding by Aberration-Corrected Microscopy
journal, February 2008


Performance and image analysis of the aberration-corrected Hitachi HD-2700C STEM
journal, March 2009

  • Inada, H.; Wu, L.; Wall, J.
  • Journal of Electron Microscopy, Vol. 58, Issue 3
  • DOI: 10.1093/jmicro/dfp011

In Situ Observation of Oscillatory Growth of Bismuth Nanoparticles
journal, February 2012

  • Xin, Huolin L.; Zheng, Haimei
  • Nano Letters, Vol. 12, Issue 3
  • DOI: 10.1021/nl2041854

Measurement of the displacement field of dislocations to 0.03 Å by electron microscopy
journal, May 2003

  • Hÿtch, Martin J.; Putaux, Jean-Luc; Pénisson, Jean-Michel
  • Nature, Vol. 423, Issue 6937
  • DOI: 10.1038/nature01638

3D structure of individual nanocrystals in solution by electron microscopy
journal, July 2015


High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction
journal, June 2015


In Situ Study of Lithiation and Delithiation of MoS 2 Nanosheets Using Electrochemical Liquid Cell Transmission Electron Microscopy
journal, July 2015


Engineering nano-composite Li4Ti5O12 anodes via scanning electron-probe fabrication
journal, May 2013


First Cross-Section Observation of an All Solid-State Lithium-Ion “Nanobattery” by Transmission Electron Microscopy
journal, March 2008

  • Brazier, A.; Dupont, L.; Dantras-Laffont, L.
  • Chemistry of Materials, Vol. 20, Issue 6
  • DOI: 10.1021/cm7033933

Carbon-Based Supercapacitors Produced by Activation of Graphene
journal, May 2011


Radiation damage in the TEM and SEM
journal, August 2004


Ultrafast Three-Dimensional Imaging of Lattice Dynamics in Individual Gold Nanocrystals
journal, May 2013


Facet development during platinum nanocube growth
journal, August 2014


Atomic-scale electron microscopy at ambient pressure
journal, August 2008


High-Resolution EM of Colloidal Nanocrystal Growth Using Graphene Liquid Cells
journal, April 2012


Electron energy-loss near-edge structure - a tool for the investigation of electronic structure on the nanometre scale
journal, August 2001


Direct Sub-Angstrom Imaging of a Crystal Lattice
journal, September 2004


Quantitative measurement of displacement and strain fields from HREM micrographs
journal, August 1998


Determination of the 3D shape of a nanoscale crystal with atomic resolution from a single image
journal, September 2014

  • Jia, C. L.; Mi, S. B.; Barthel, J.
  • Nature Materials, Vol. 13, Issue 11
  • DOI: 10.1038/nmat4087

Three-dimensional atomic imaging of crystalline nanoparticles
journal, February 2011

  • Van Aert, Sandra; Batenburg, Kees J.; Rossell, Marta D.
  • Nature, Vol. 470, Issue 7334
  • DOI: 10.1038/nature09741

Atom-by-atom spectroscopy at graphene edge
journal, December 2010


Structure Stabilization by Mixed Anions in Oxyfluoride Cathodes for High-Energy Lithium Batteries
journal, September 2015


Seeing atoms in three dimensions
journal, October 2012

  • Arslan, Ilke; Stach, Eric A.
  • Nature Materials, Vol. 11, Issue 11
  • DOI: 10.1038/nmat3472

Polyvinylpyrrolidone-induced anisotropic growth of gold nanoprisms in plasmon-driven synthesis
journal, July 2016

  • Zhai, Yueming; DuChene, Joseph S.; Wang, Yi-Chung
  • Nature Materials, Vol. 15, Issue 8
  • DOI: 10.1038/nmat4683

Visualization of Electrode–Electrolyte Interfaces in LiPF 6 /EC/DEC Electrolyte for Lithium Ion Batteries via in Situ TEM
journal, March 2014

  • Zeng, Zhiyuan; Liang, Wen-I; Liao, Hong-Gang
  • Nano Letters, Vol. 14, Issue 4
  • DOI: 10.1021/nl403922u

Platinum-based nanocages with subnanometer-thick walls and well-defined, controllable facets
journal, July 2015


Interfacial structure in epitaxial perovskite oxides on (001) Ge crystal
journal, January 2015

  • Shen, Xuan; Ahmadi-Majlan, K.; Ngai, Joseph H.
  • Applied Physics Letters, Vol. 106, Issue 3
  • DOI: 10.1063/1.4906430