One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent
Abstract
A new material MIT-1 comprised of delaminated MWW zeolite nanosheets is synthesized in one-pot using a rationally designed organic structure-directing agent (OSDA). The OSDA is comprised of a hydrophilic head segment that resembles the OSDA used to synthesize the zeolite precursor MCM22(P), a hydrophobic tail segment that resembles the swelling agent used to swell MCM22(P), and a di-quaternary ammonium linker that connects both segments. MIT-1 features high crystallinity and surface areas exceeding 500 m2g-1, and can be synthesized over a wide synthesis window that includes Si/Al ratios ranging from 13 to 67. Characterization data reveal high mesoporosity and acid strength with no detectable amorphous silica phases. In conclusion, compared to MCM-22 and MCM-56, MIT-1 shows a three-fold increase in catalytic activity for the Friedel-Crafts alkylation of benzene with benzyl alcohol.
- Authors:
-
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Chemical Engineering
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Chemistry and Francis Bitter Magnet Lab.
- Publication Date:
- Research Org.:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Institutes of Health (NIH)
- OSTI Identifier:
- 1344503
- Grant/Contract Number:
- SC0008742
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 11; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Luo, Helen Y., Michaelis, Vladimir K., Hodges, Sydney, Griffin, Robert G., and Roman-Leshkov, Yuriy. One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent. United States: N. p., 2015.
Web. doi:10.1039/C5SC01912E.
Luo, Helen Y., Michaelis, Vladimir K., Hodges, Sydney, Griffin, Robert G., & Roman-Leshkov, Yuriy. One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent. United States. https://doi.org/10.1039/C5SC01912E
Luo, Helen Y., Michaelis, Vladimir K., Hodges, Sydney, Griffin, Robert G., and Roman-Leshkov, Yuriy. Wed .
"One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent". United States. https://doi.org/10.1039/C5SC01912E. https://www.osti.gov/servlets/purl/1344503.
@article{osti_1344503,
title = {One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent},
author = {Luo, Helen Y. and Michaelis, Vladimir K. and Hodges, Sydney and Griffin, Robert G. and Roman-Leshkov, Yuriy},
abstractNote = {A new material MIT-1 comprised of delaminated MWW zeolite nanosheets is synthesized in one-pot using a rationally designed organic structure-directing agent (OSDA). The OSDA is comprised of a hydrophilic head segment that resembles the OSDA used to synthesize the zeolite precursor MCM22(P), a hydrophobic tail segment that resembles the swelling agent used to swell MCM22(P), and a di-quaternary ammonium linker that connects both segments. MIT-1 features high crystallinity and surface areas exceeding 500 m2g-1, and can be synthesized over a wide synthesis window that includes Si/Al ratios ranging from 13 to 67. Characterization data reveal high mesoporosity and acid strength with no detectable amorphous silica phases. In conclusion, compared to MCM-22 and MCM-56, MIT-1 shows a three-fold increase in catalytic activity for the Friedel-Crafts alkylation of benzene with benzyl alcohol.},
doi = {10.1039/C5SC01912E},
journal = {Chemical Science},
number = 11,
volume = 6,
place = {United States},
year = {Wed Jul 22 00:00:00 EDT 2015},
month = {Wed Jul 22 00:00:00 EDT 2015}
}
Web of Science
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