Modulation of hybrid organic–perovskite photovoltaic performance by controlling the excited dynamics of fullerenes
Abstract
Here, we present a synergistic approach to modulate organic–perovskite interfaces and their photovoltaic behaviors by tuning the properties of n-contact fullerenes layered atop of perovskite. Fullerenes with excited charge transfer are found to not only suppress fullerene photoluminescence, but also enhance molecular polarization and transport capabilities. This results in optimized perovskite–fullerene contact.
- Authors:
-
- Univ. of Washington, Seattle, WA (United States). Dept. of Materials Science and Engineering
- Univ. of Washington, Seattle, WA (United States). Dept. of Chemistry
- Univ. of Washington, Seattle, WA (United States). Dept. of Materials Science and Engineering; Univ. of Washington, Seattle, WA (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Univ. of Washington, Seattle, WA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE); AOARD; ONR; National Science Foundation (NSF); Boeing Foundation
- OSTI Identifier:
- 1343571
- Report Number(s):
- DOE-UW-Jen-7
Journal ID: ISSN 2051-6347; MHAOAL
- Grant/Contract Number:
- EE0006710; FA2386–11–1–4072; N00014-14-1-0170; N00014- 14-1-246; CHE-1265945; DMR-1215753; 2013118402
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Materials Horizons
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 4; Journal ID: ISSN 2051-6347
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY
Citation Formats
Li, Chang-Zhi, Liang, Po-Wei, Sulas, Dana B., Nguyen, Phu D., Li, Xiaosong, Ginger, David S., Schlenker, Cody W., and Jen, Alex K. -Y. Modulation of hybrid organic–perovskite photovoltaic performance by controlling the excited dynamics of fullerenes. United States: N. p., 2015.
Web. doi:10.1039/c5mh00026b.
Li, Chang-Zhi, Liang, Po-Wei, Sulas, Dana B., Nguyen, Phu D., Li, Xiaosong, Ginger, David S., Schlenker, Cody W., & Jen, Alex K. -Y. Modulation of hybrid organic–perovskite photovoltaic performance by controlling the excited dynamics of fullerenes. United States. https://doi.org/10.1039/c5mh00026b
Li, Chang-Zhi, Liang, Po-Wei, Sulas, Dana B., Nguyen, Phu D., Li, Xiaosong, Ginger, David S., Schlenker, Cody W., and Jen, Alex K. -Y. Thu .
"Modulation of hybrid organic–perovskite photovoltaic performance by controlling the excited dynamics of fullerenes". United States. https://doi.org/10.1039/c5mh00026b. https://www.osti.gov/servlets/purl/1343571.
@article{osti_1343571,
title = {Modulation of hybrid organic–perovskite photovoltaic performance by controlling the excited dynamics of fullerenes},
author = {Li, Chang-Zhi and Liang, Po-Wei and Sulas, Dana B. and Nguyen, Phu D. and Li, Xiaosong and Ginger, David S. and Schlenker, Cody W. and Jen, Alex K. -Y.},
abstractNote = {Here, we present a synergistic approach to modulate organic–perovskite interfaces and their photovoltaic behaviors by tuning the properties of n-contact fullerenes layered atop of perovskite. Fullerenes with excited charge transfer are found to not only suppress fullerene photoluminescence, but also enhance molecular polarization and transport capabilities. This results in optimized perovskite–fullerene contact.},
doi = {10.1039/c5mh00026b},
journal = {Materials Horizons},
number = 4,
volume = 2,
place = {United States},
year = {Thu Apr 02 00:00:00 EDT 2015},
month = {Thu Apr 02 00:00:00 EDT 2015}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 24 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
The role of spin in the kinetic control of recombination in organic photovoltaics
journal, August 2013
- Rao, Akshay; Chow, Philip C. Y.; Gélinas, Simon
- Nature, Vol. 500, Issue 7463
Low-temperature processed meso-superstructured to thin-film perovskite solar cells
journal, January 2013
- Ball, James M.; Lee, Michael M.; Hey, Andrew
- Energy & Environmental Science, Vol. 6, Issue 6
Metal-Oxide-Free Methylammonium Lead Iodide Perovskite-Based Solar Cells: the Influence of Organic Charge Transport Layers
journal, June 2014
- Malinkiewicz, Olga; Roldán-Carmona, Cristina; Soriano, Alejandra
- Advanced Energy Materials, Vol. 4, Issue 15
Electronic Properties of Meso-Superstructured and Planar Organometal Halide Perovskite Films: Charge Trapping, Photodoping, and Carrier Mobility
journal, June 2014
- Leijtens, Tomas; Stranks, Samuel D.; Eperon, Giles E.
- ACS Nano, Vol. 8, Issue 7
Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells
journal, January 2014
- Juarez-Perez, Emilio J.; Wuβler, Michael; Fabregat-Santiago, Francisco
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 4, p. 680-685
Enhanced Open-Circuit Voltage in High Performance Polymer/Fullerene Bulk-Heterojunction Solar Cells by Cathode Modification with a C60 Surfactant
journal, December 2011
- O'Malley, Kevin M.; Li, Chang-Zhi; Yip, Hin-Lap
- Advanced Energy Materials, Vol. 2, Issue 1, p. 82-86
A Simple and Effective Way of Achieving Highly Efficient and Thermally Stable Bulk-Heterojunction Polymer Solar Cells Using Amorphous Fullerene Derivatives as Electron Acceptor
journal, July 2009
- Zhang, Yong; Yip, Hin-Lap; Acton, Orb
- Chemistry of Materials, Vol. 21, Issue 13, p. 2598-2600
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009
- Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
- Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
Organometal Perovskite Light Absorbers Toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell
journal, July 2013
- Park, Nam-Gyu
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 15, p. 2423-2429
Interface engineering of highly efficient perovskite solar cells
journal, July 2014
- Zhou, H.; Chen, Q.; Li, G.
- Science, Vol. 345, Issue 6196
Solution-Processible Highly Conducting Fullerenes
journal, March 2013
- Li, Chang-Zhi; Chueh, Chu-Chen; Yip, Hin-Lap
- Advanced Materials, Vol. 25, Issue 17, p. 2457-2461
Nanosecond Intersystem Crossing Times in Fullerene Acceptors: Implications for Organic Photovoltaic Diodes
journal, June 2014
- Chow, Philip C. Y.; Albert‐Seifried, Sebastian; Gélinas, Simon
- Advanced Materials, Vol. 26, Issue 28
Heterojunction Modification for Highly Efficient Organic–Inorganic Perovskite Solar Cells
journal, November 2014
- Wojciechowski, Konrad; Stranks, Samuel D.; Abate, Antonio
- ACS Nano, Vol. 8, Issue 12
Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells
journal, December 2014
- Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng
- Nature Communications, Vol. 5, Issue 1
Polymer Triplet Energy Levels Need Not Limit Photocurrent Collection in Organic Solar Cells
journal, November 2012
- Schlenker, Cody W.; Chen, Kung-Shih; Yip, Hin-Lap
- Journal of the American Chemical Society, Vol. 134, Issue 48
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
journal, October 2013
- Xing, G.; Mathews, N.; Sun, S.
- Science, Vol. 342, Issue 6156, p. 344-347
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013
- Stranks, S. D.; Eperon, G. E.; Grancini, G.
- Science, Vol. 342, Issue 6156, p. 341-344
Electro-optics of perovskite solar cells
journal, December 2014
- Lin, Qianqian; Armin, Ardalan; Nagiri, Ravi Chandra Raju
- Nature Photonics, Vol. 9, Issue 2
Large fill-factor bilayer iodine perovskite solar cells fabricated by a low-temperature solution-process
journal, January 2014
- Wang, Qi; Shao, Yuchuan; Dong, Qingfeng
- Energy Environ. Sci., Vol. 7, Issue 7
Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells
journal, March 2014
- Liang, Po-Wei; Liao, Chien-Yi; Chueh, Chu-Chen
- Advanced Materials, Vol. 26, Issue 22, p. 3748-3754
Organohalide lead perovskites for photovoltaic applications
journal, January 2014
- Gao, Peng; Grätzel, Michael; Nazeeruddin, Mohammad K.
- Energy Environ. Sci., Vol. 7, Issue 8
Suppressed Charge Recombination in Inverted Organic Photovoltaics via Enhanced Charge Extraction by Using a Conductive Fullerene Electron Transport Layer
journal, August 2014
- Li, Chang-Zhi; Chang, Chih-Yu; Zang, Yue
- Advanced Materials, Vol. 26, Issue 36
Facile synthesis of a 56π-electron 1,2-dihydromethano-[60]PCBM and its application for thermally stable polymer solar cells
journal, January 2011
- Li, Chang-Zhi; Chien, Shang-Chieh; Yip, Hin-Lap
- Chemical Communications, Vol. 47, Issue 36
High-Performance Perovskite-Polymer Hybrid Solar Cells via Electronic Coupling with Fullerene Monolayers
journal, June 2013
- Abrusci, Agnese; Stranks, Samuel D.; Docampo, Pablo
- Nano Letters, Vol. 13, Issue 7
Enhancement in the efficiency of an organic–inorganic hybrid solar cell with a doped P3HT hole-transporting layer on a void-free perovskite active layer
journal, January 2014
- Guo, Yunlong; Liu, Chao; Inoue, Kento
- J. Mater. Chem. A, Vol. 2, Issue 34
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015
- Nie, W.; Tsai, H.; Asadpour, R.
- Science, Vol. 347, Issue 6221, p. 522-525
Electronic Structures and Photoconversion Mechanism in Perovskite/Fullerene Heterojunctions
journal, December 2014
- Lo, Ming-Fai; Guan, Zhi-Qiang; Ng, Tsz-Wai
- Advanced Functional Materials, Vol. 25, Issue 8
Perovskite solar cells employing organic charge-transport layers
journal, December 2013
- Malinkiewicz, Olga; Yella, Aswani; Lee, Yong Hui
- Nature Photonics, Vol. 8, Issue 2
Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
journal, October 2013
- Snaith, Henry J.
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 21, p. 3623-3630