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Title: Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand

Here, a β-SiH functionalized benzyl anion [C(SiHMe 2) 2Ph]$-$s obtained by deprotonation of HC(SiHMe 2) 2Ph with KCH 2Ph or by reaction of KOtBu and (Me 2HSi) 3CPh; LnI 3(THF)n and three equivalents of this carbanion combine to provide homoleptic tris(alkyl)lanthanide compounds Ln{C(SiHMe 2) 2Ph} 3 (Ln = La, Ce, Pr, Nd) containing secondary metal–ligand interactions.
Authors:
 [1] ;  [1] ;  [1]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Chemistry
Publication Date:
Report Number(s):
IS-J-9147
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:
AC02-07CH11358
Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 53; Journal Issue: 4; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1342922

Boteju, Kasuni C., Ellern, Arkady, and Sadow, Aaron D.. Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand. United States: N. p., Web. doi:10.1039/C6CC09304C.
Boteju, Kasuni C., Ellern, Arkady, & Sadow, Aaron D.. Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand. United States. doi:10.1039/C6CC09304C.
Boteju, Kasuni C., Ellern, Arkady, and Sadow, Aaron D.. 2016. "Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand". United States. doi:10.1039/C6CC09304C. https://www.osti.gov/servlets/purl/1342922.
@article{osti_1342922,
title = {Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand},
author = {Boteju, Kasuni C. and Ellern, Arkady and Sadow, Aaron D.},
abstractNote = {Here, a β-SiH functionalized benzyl anion [C(SiHMe2)2Ph]$-$s obtained by deprotonation of HC(SiHMe2)2Ph with KCH2Ph or by reaction of KOtBu and (Me2HSi)3CPh; LnI3(THF)n and three equivalents of this carbanion combine to provide homoleptic tris(alkyl)lanthanide compounds Ln{C(SiHMe2)2Ph}3 (Ln = La, Ce, Pr, Nd) containing secondary metal–ligand interactions.},
doi = {10.1039/C6CC09304C},
journal = {ChemComm},
number = 4,
volume = 53,
place = {United States},
year = {2016},
month = {12}
}