Gate-opening effect in ZIF-8: the first experimental proof using inelastic neutron scattering
Abstract
In order to understand the behavior of industrial molecular separations, the gate-opening phenomenon in ZIFs are of paramount importance. We show for the first time using in situ inelastic neutron scattering (INS) the swinging of the -CH3 groups and the imidazolate linkers in the prototypical ZIF-8 and ZIF-8@AC hybrid materials upon exposure to mild N2 pressure.
- Authors:
-
- Univ. of Alicante, San Vicente del Raspeig (Spain). Univ. Inst. of Materials.
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Division
- Univ. of Cambridge (United Kingdom). Dept. of Chemcial Engineering and Biotechnology
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1342663
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 52; Journal Issue: 18; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Casco, M. E., Cheng, Y. Q., Daemen, L. L., Fairen-Jimenez, D., Ramos-Fernández, E. V., Ramirez-Cuesta, A. J., and Silvestre-Albero, J. Gate-opening effect in ZIF-8: the first experimental proof using inelastic neutron scattering. United States: N. p., 2016.
Web. doi:10.1039/C5CC10222G.
Casco, M. E., Cheng, Y. Q., Daemen, L. L., Fairen-Jimenez, D., Ramos-Fernández, E. V., Ramirez-Cuesta, A. J., & Silvestre-Albero, J. Gate-opening effect in ZIF-8: the first experimental proof using inelastic neutron scattering. United States. https://doi.org/10.1039/C5CC10222G
Casco, M. E., Cheng, Y. Q., Daemen, L. L., Fairen-Jimenez, D., Ramos-Fernández, E. V., Ramirez-Cuesta, A. J., and Silvestre-Albero, J. Thu .
"Gate-opening effect in ZIF-8: the first experimental proof using inelastic neutron scattering". United States. https://doi.org/10.1039/C5CC10222G. https://www.osti.gov/servlets/purl/1342663.
@article{osti_1342663,
title = {Gate-opening effect in ZIF-8: the first experimental proof using inelastic neutron scattering},
author = {Casco, M. E. and Cheng, Y. Q. and Daemen, L. L. and Fairen-Jimenez, D. and Ramos-Fernández, E. V. and Ramirez-Cuesta, A. J. and Silvestre-Albero, J.},
abstractNote = {In order to understand the behavior of industrial molecular separations, the gate-opening phenomenon in ZIFs are of paramount importance. We show for the first time using in situ inelastic neutron scattering (INS) the swinging of the -CH3 groups and the imidazolate linkers in the prototypical ZIF-8 and ZIF-8@AC hybrid materials upon exposure to mild N2 pressure.},
doi = {10.1039/C5CC10222G},
journal = {ChemComm},
number = 18,
volume = 52,
place = {United States},
year = {Thu Jan 28 00:00:00 EST 2016},
month = {Thu Jan 28 00:00:00 EST 2016}
}
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