Direct observation of electronic-liquid-crystal phase transitions and their microscopic origin in La1/3Ca2/3MnO3
Abstract
The ground-state electronic order in doped manganites is frequently associated with a lattice modulation, contributing to their many interesting properties. However, measuring the thermal evolution of the lattice superstructure with reciprocal-space probes alone can lead to ambiguous results with competing interpretations. Here, we provide direct observations of the evolution of the superstructure in La1/3Ca2/3MnO3 in real space, as well as reciprocal space, using transmission electron microscopic (TEM) techniques. We show that the transitions are the consequence of a proliferation of dislocations plus electronic phase separation. The resulting states are well described by the symmetries associated with electronic-liquid-crystal (ELC) phases. Furthermore, our results resolve the long-standing controversy over the origin of the incommensurate superstructure and suggest a new structural model that is consistent with recent theoretical calculations.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics & Materials Science Dept.
- Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Physics
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Shanghai JiaoTong Univ., Shanghai (China). Dept. of Physics & Astronomy
- National Univ. of Singapore (Singapore). Dept. of Materials Science and Engineering
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1427768
- Alternate Identifier(s):
- OSTI ID: 1342647
- Report Number(s):
- BNL-113462-2017-JA
Journal ID: ISSN 2045-2322; 141500
- Grant/Contract Number:
- AC02-06CH11357; SC0012704; ECCS-1307744
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE; Phase transitions and critical phenomena; Structure of solids and liquids
Citation Formats
Tao, J., Sun, K., Yin, W. -G., Wu, L., Xin, H., Wen, J. G., Luo, W., Pennycook, S. J., Tranquada, J. M., and Zhu, Y. Direct observation of electronic-liquid-crystal phase transitions and their microscopic origin in La1/3Ca2/3MnO3. United States: N. p., 2016.
Web. doi:10.1038/srep37624.
Tao, J., Sun, K., Yin, W. -G., Wu, L., Xin, H., Wen, J. G., Luo, W., Pennycook, S. J., Tranquada, J. M., & Zhu, Y. Direct observation of electronic-liquid-crystal phase transitions and their microscopic origin in La1/3Ca2/3MnO3. United States. https://doi.org/10.1038/srep37624
Tao, J., Sun, K., Yin, W. -G., Wu, L., Xin, H., Wen, J. G., Luo, W., Pennycook, S. J., Tranquada, J. M., and Zhu, Y. Tue .
"Direct observation of electronic-liquid-crystal phase transitions and their microscopic origin in La1/3Ca2/3MnO3". United States. https://doi.org/10.1038/srep37624. https://www.osti.gov/servlets/purl/1427768.
@article{osti_1427768,
title = {Direct observation of electronic-liquid-crystal phase transitions and their microscopic origin in La1/3Ca2/3MnO3},
author = {Tao, J. and Sun, K. and Yin, W. -G. and Wu, L. and Xin, H. and Wen, J. G. and Luo, W. and Pennycook, S. J. and Tranquada, J. M. and Zhu, Y.},
abstractNote = {The ground-state electronic order in doped manganites is frequently associated with a lattice modulation, contributing to their many interesting properties. However, measuring the thermal evolution of the lattice superstructure with reciprocal-space probes alone can lead to ambiguous results with competing interpretations. Here, we provide direct observations of the evolution of the superstructure in La1/3Ca2/3MnO3 in real space, as well as reciprocal space, using transmission electron microscopic (TEM) techniques. We show that the transitions are the consequence of a proliferation of dislocations plus electronic phase separation. The resulting states are well described by the symmetries associated with electronic-liquid-crystal (ELC) phases. Furthermore, our results resolve the long-standing controversy over the origin of the incommensurate superstructure and suggest a new structural model that is consistent with recent theoretical calculations.},
doi = {10.1038/srep37624},
journal = {Scientific Reports},
number = 1,
volume = 6,
place = {United States},
year = {Tue Nov 22 00:00:00 EST 2016},
month = {Tue Nov 22 00:00:00 EST 2016}
}
Web of Science
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