skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Elucidation of the surface characteristics and electrochemistry of high-performance LiNiO2

Abstract

Phase pure LiNiO2 was prepared using a solid-state method and the optimal synthesis conditions led to a remarkably high capacity of 200 mA h g$-$1 with excellent retention. The combination of bulk and surface characterization elucidated an essential role of the excess Li in phase formation during synthesis and the subsequent electrochemical performance.

Authors:
 [1];  [1];  [2];  [3];  [4];  [5];  [1];  [1]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  2. SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Sustainable Energy Technologies
  5. Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1342627
Alternate Identifier(s):
OSTI ID: 1378755
Report Number(s):
BNL-112702-2016-JA
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:  
SC0012704; AC02-05CH11231; AC02-76SF00515
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 52; Journal Issue: 22; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE

Citation Formats

Xu, Jing, Lin, Feng, Nordlund, Dennis, Crumlin, Ethan J., Wang, Feng, Bai, Jianming, Doeff, Marca M., and Tong, Wei. Elucidation of the surface characteristics and electrochemistry of high-performance LiNiO2. United States: N. p., 2016. Web. doi:10.1039/c5cc09434h.
Xu, Jing, Lin, Feng, Nordlund, Dennis, Crumlin, Ethan J., Wang, Feng, Bai, Jianming, Doeff, Marca M., & Tong, Wei. Elucidation of the surface characteristics and electrochemistry of high-performance LiNiO2. United States. doi:10.1039/c5cc09434h.
Xu, Jing, Lin, Feng, Nordlund, Dennis, Crumlin, Ethan J., Wang, Feng, Bai, Jianming, Doeff, Marca M., and Tong, Wei. Thu . "Elucidation of the surface characteristics and electrochemistry of high-performance LiNiO2". United States. doi:10.1039/c5cc09434h. https://www.osti.gov/servlets/purl/1342627.
@article{osti_1342627,
title = {Elucidation of the surface characteristics and electrochemistry of high-performance LiNiO2},
author = {Xu, Jing and Lin, Feng and Nordlund, Dennis and Crumlin, Ethan J. and Wang, Feng and Bai, Jianming and Doeff, Marca M. and Tong, Wei},
abstractNote = {Phase pure LiNiO2 was prepared using a solid-state method and the optimal synthesis conditions led to a remarkably high capacity of 200 mA h g$-$1 with excellent retention. The combination of bulk and surface characterization elucidated an essential role of the excess Li in phase formation during synthesis and the subsequent electrochemical performance.},
doi = {10.1039/c5cc09434h},
journal = {ChemComm},
number = 22,
volume = 52,
place = {United States},
year = {2016},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 13 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Soft Chemistry Synthesis and Characterization of Layered Li1-xNi1-yCoyO2-δ (0 ≤ x ≤ 1 and 0 ≤ y ≤ 1)
journal, September 2001

  • Chebiam, R. V.; Prado, F.; Manthiram, A.
  • Chemistry of Materials, Vol. 13, Issue 9, p. 2951-2957
  • DOI: 10.1021/cm0102537

Positive Electrode Materials for Li-Ion and Li-Batteries
journal, February 2010

  • Ellis, Brian L.; Lee, Kyu Tae; Nazar, Linda F.
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm902696j

Cathode materials modified by surface coating for lithium ion batteries
journal, May 2006


Cobalt-Free Nickel Rich Layered Oxide Cathodes for Lithium-Ion Batteries
journal, October 2013

  • Sun, Yang-Kook; Lee, Dong-Ju; Lee, Yun Jung
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 21
  • DOI: 10.1021/am403684z

Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li 2 MnO 3 −LiCo 1/3 Ni 1/3 Mn 1/3 O 2
journal, March 2011

  • Yabuuchi, Naoaki; Yoshii, Kazuhiro; Myung, Seung-Taek
  • Journal of the American Chemical Society, Vol. 133, Issue 12
  • DOI: 10.1021/ja108588y

Atomic subshell photoionization cross sections and asymmetry parameters: 1 ⩽ Z ⩽ 103
journal, January 1985


Influence of synthesis conditions on the surface passivation and electrochemical behavior of layered cathode materials
journal, January 2014

  • Lin, Feng; Nordlund, Dennis; Pan, Taijun
  • J. Mater. Chem. A, Vol. 2, Issue 46
  • DOI: 10.1039/C4TA04497E

Electrochemistry and Structural Chemistry of LiNiO[sub 2] (R3m) for 4 Volt Secondary Lithium Cells
journal, January 1993

  • Ohzuku, Tsutomu
  • Journal of The Electrochemical Society, Vol. 140, Issue 7
  • DOI: 10.1149/1.2220730

Reaction mechanism and kinetics analysis of lithium nickel oxide during solid-state reaction
journal, January 2000

  • Lu, Chung-Hsin; Wei-Cheng, Lee
  • Journal of Materials Chemistry, Vol. 10, Issue 6
  • DOI: 10.1039/a909130k

Surface Characterization of Electrodes from High Power Lithium-Ion Batteries
journal, January 2002

  • Andersson, A. M.; Abraham, D. P.; Haasch, R.
  • Journal of The Electrochemical Society, Vol. 149, Issue 10
  • DOI: 10.1149/1.1505636

Role of Mn Content on the Electrochemical Properties of Nickel-Rich Layered LiNi 0.8– x Co 0.1 Mn 0.1+ x O 2 (0.0 ≤ x ≤ 0.08) Cathodes for Lithium-Ion Batteries
journal, March 2015

  • Zheng, Jianming; Kan, Wang Hay; Manthiram, Arumugam
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 12
  • DOI: 10.1021/acsami.5b00788

Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries
journal, January 2014

  • Lin, Feng; Nordlund, Dennis; Markus, Isaac M.
  • Energy & Environmental Science, Vol. 7, Issue 9
  • DOI: 10.1039/C4EE01400F

Higher, Stronger, Better…︁ A Review of 5 Volt Cathode Materials for Advanced Lithium-Ion Batteries
journal, June 2012


Final states after Ni2p photoemission in the nickel—oxygen system
journal, January 1991

  • Oku, Masaoki; Tokuda, Hajime; Hirokawa, Kichinosuke
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 53, Issue 4
  • DOI: 10.1016/0368-2048(91)85039-V

Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries
journal, March 2014

  • Lin, Feng; Markus, Isaac M.; Nordlund, Dennis
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4529

    Works referencing / citing this record:

    Catalytic Activity of Ni1-xLi2xWO4 Particles for Carbon Dioxide Photoreduction
    journal, May 2019


    There and Back Again-The Journey of LiNiO 2 as a Cathode Active Material
    journal, May 2019

    • Bianchini, Matteo; Roca-Ayats, Maria; Hartmann, Pascal
    • Angewandte Chemie International Edition, Vol. 58, Issue 31
    • DOI: 10.1002/anie.201812472

    There and Back Again-The Journey of LiNiO 2 as a Cathode Active Material
    journal, May 2019

    • Bianchini, Matteo; Roca-Ayats, Maria; Hartmann, Pascal
    • Angewandte Chemie International Edition, Vol. 58, Issue 31
    • DOI: 10.1002/anie.201812472

    Catalytic Activity of Ni1-xLi2xWO4 Particles for Carbon Dioxide Photoreduction
    journal, May 2019