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Title: Is Cu a stable electrode material in hybrid perovskite solar cells for a 30-year lifetime?

One grand challenge for long-lived perovskite solar cells is that the common electrode materials in solar cells, such as silver and aluminum or even gold, strongly react with hybrid perovskites. Here we report the evaluation of the potential of copper (Cu) as the electrode material in perovskite solar cells for long-term stability. In encapsulated devices which limit exposure to oxygen and moisture, Cu in direct contact with CH 3NH 3PbI 3 showed no reaction at laboratory time scales, and is predicted to be stable for almost 170 years at room temperature and over 22 years at the nominal operating cell temperature of 40 °C. No diffusion of Cu into CH 3NH 3PbI 3 has been observed after thermal annealing for over 100 hours at 80 °C, nor does Cu cause charge trap states in direct contact with CH 3NH 3PbI 3 after long-term thermal annealing or illumination. High performance devices with efficiency above 20% with Cu electrode retains 98% of the initial efficiency after 816 hours storage in ambient environment without encapsulation. Finally, the results indicate Cu is a promising low-cost electrode material for perovskite solar cells for long-term operation.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1]
  1. Univ. of Nebraska-Lincoln, Lincoln, NE (United States)
Publication Date:
Grant/Contract Number:
EE0006709
Type:
Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Volume: 9; Journal Issue: 12; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Research Org:
Univ. of Nebraska-Lincoln, Lincoln, NE (United States)
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE
OSTI Identifier:
1342623

Zhao, Jingjing, Zheng, Xiaopeng, Deng, Yehao, Li, Tao, Shao, Yuchuan, Gruverman, Alexei, Shield, Jeffrey, and Huang, Jinsong. Is Cu a stable electrode material in hybrid perovskite solar cells for a 30-year lifetime?. United States: N. p., Web. doi:10.1039/C6EE02980A.
Zhao, Jingjing, Zheng, Xiaopeng, Deng, Yehao, Li, Tao, Shao, Yuchuan, Gruverman, Alexei, Shield, Jeffrey, & Huang, Jinsong. Is Cu a stable electrode material in hybrid perovskite solar cells for a 30-year lifetime?. United States. doi:10.1039/C6EE02980A.
Zhao, Jingjing, Zheng, Xiaopeng, Deng, Yehao, Li, Tao, Shao, Yuchuan, Gruverman, Alexei, Shield, Jeffrey, and Huang, Jinsong. 2016. "Is Cu a stable electrode material in hybrid perovskite solar cells for a 30-year lifetime?". United States. doi:10.1039/C6EE02980A. https://www.osti.gov/servlets/purl/1342623.
@article{osti_1342623,
title = {Is Cu a stable electrode material in hybrid perovskite solar cells for a 30-year lifetime?},
author = {Zhao, Jingjing and Zheng, Xiaopeng and Deng, Yehao and Li, Tao and Shao, Yuchuan and Gruverman, Alexei and Shield, Jeffrey and Huang, Jinsong},
abstractNote = {One grand challenge for long-lived perovskite solar cells is that the common electrode materials in solar cells, such as silver and aluminum or even gold, strongly react with hybrid perovskites. Here we report the evaluation of the potential of copper (Cu) as the electrode material in perovskite solar cells for long-term stability. In encapsulated devices which limit exposure to oxygen and moisture, Cu in direct contact with CH3NH3PbI3 showed no reaction at laboratory time scales, and is predicted to be stable for almost 170 years at room temperature and over 22 years at the nominal operating cell temperature of 40 °C. No diffusion of Cu into CH3NH3PbI3 has been observed after thermal annealing for over 100 hours at 80 °C, nor does Cu cause charge trap states in direct contact with CH3NH3PbI3 after long-term thermal annealing or illumination. High performance devices with efficiency above 20% with Cu electrode retains 98% of the initial efficiency after 816 hours storage in ambient environment without encapsulation. Finally, the results indicate Cu is a promising low-cost electrode material for perovskite solar cells for long-term operation.},
doi = {10.1039/C6EE02980A},
journal = {Energy & Environmental Science},
number = 12,
volume = 9,
place = {United States},
year = {2016},
month = {10}
}

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