Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia

Abstract

The atmospheric chemistry of isoprene contributes to the production of a substantial mass fraction of the particulate matter (PM) over tropical forests. Isoprene epoxydiols (IEPOX) produced in the gas phase by the oxidation of isoprene under HO2-dominant conditions are subsequently taken up by particles, thereby leading to production of secondary organic PM. The present study investigates possible perturbations to this pathway by urban pollution. The measurement site in central Amazonia was located 4 to 6 hours downwind of Manaus, Brazil. Measurements took place from February through March 2014 of the wet season, as part of the GoAmazon2014/5 experiment. Mass spectra of organic PM collected with an Aerodyne Aerosol Mass Spectrometer were analyzed by positive-matrix factorization. One resolved statistical factor (“IEPOX-SOA factor”) was associated with PM production by the IEPOX pathway. Loadings of this factor correlated with independently measured mass concentrations of tracers of IEPOX-derived PM, namely C5-alkene triols and 2-methyltetrols (R =0.96 and 0.78, respectively). Factor loading, as well as the ratio of the factor loading to organic PM mass concentration, decreased under polluted compared to background conditions. For the study period, sulfate concentration explained 37 % of the variability in the factor loading. After segregation of the data setmore » by NOy concentration, the sulfate concentration explained up to 75 % of the variability in factor loading within the NOy subsets. The sulfate-detrended IEPOX-SOA factor loading decreased by two- to three-fold for an increase in NOy concentration from 0.5 to 2 ppb. The suppressing effects of elevated NO dominated over the enhancing effects of higher sulfate with respect to the production of IEPOX-derived PM. Relative to background conditions, the Manaus pollution contributed more significantly to NOy than to sulfate. In this light, increased emissions of nitrogen oxides, as anticipated for some scenarios of Amazonian economic development, could significantly alter pathways of PM production that presently prevail over the tropical forest, implying changes to air quality and regional climate.« less

Authors:
 [1];  [2]; ORCiD logo [2]; ORCiD logo [2];  [3]; ORCiD logo [2]; ORCiD logo [4]; ORCiD logo [4];  [5]; ORCiD logo [6];  [6]; ORCiD logo [6]; ORCiD logo [4];  [7];  [8]; ORCiD logo [9]; ORCiD logo [10]; ORCiD logo [5]; ORCiD logo [5]; ORCiD logo [11] more »;  [3]; ORCiD logo [2];  [12] « less
+ Show Author Affiliations
  1. Harvard Univ., Cambridge, MA (United States). School of Engineering and Applied Sciences
  2. Univ. of Colorado, Boulder, CO (United States). Department. of Chemistry & Biochemistry. Cooperative Inst. for Research in Environmental Sciences
  3. Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab.
  4. Univ. of California, Berkeley, CA (United States). Dept. of Environmental Science, Policy, and Management
  5. Brookhaven National Lab. (BNL), Upton, NY (United States)
  6. Univ. of Sao Paulo (Brazil). Departamento de Física Aplicada
  7. Instituto Nacional de Pesquisas da Amazonia, Manaus, Amazonas (Brazil)
  8. Universidade do Estado do Amazonas, Manaus, Amazonas (Brazil). Escola Superior de Tecnologia
  9. Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Atmospheric Sciences and Global Change Division
  10. Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab.; Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Atmospheric Sciences and Global Change Division
  11. Univ. of North Carolina, Chapel Hill, NC (United States). Gillings School of Global Public Health. Dept. of Environmental Sciences and Engineering
  12. Harvard Univ., Cambridge, MA (United States). School of Engineering and Applied Sciences; Harvard Univ., Cambridge, MA (United States). Dept. of Earth and Planetary Sciences
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Biological and Environmental Research (BER)
OSTI Identifier:
1341692
Report Number(s):
BNL-113437-2017-JA; BNL-113437-2017-JAAM
R&D Project: 2016-BNL-EE630EECA-Budg; KP1701000
Grant/Contract Number:  
SC0012704; AC05-76RL01830
Resource Type:
Accepted Manuscript
Journal Name:
Atmospheric Chemistry and Physics: Discussions
Additional Journal Information:
Journal Volume: 17
Publisher:
European Geosciences Union
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES

Citation Formats

de Sá, Suzane S., Palm, Brett B., Campuzano-Jost, Pedro, Day, Douglas A., Newburn, Matthew K., Hu, Weiwei, Isaacman-VanWertz, Gabriel, Yee, Lindsay D., Thalman, Ryan, Brito, Joel, Carbone, Samara, Artaxo, Paulo, Goldstein, Allen H., Manzi, Antonio O., Souza, Rodrigo A.F., Mei, Fan, Shilling, John E., Springston, Stephen R., Wang, Jian, Surratt, Jason D., Alexander, M. Lizabeth, Jimenez, Jose L., and Martin, Scot T. Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia. United States: N. p., 2017. Web. doi:10.5194/acp-2016-1020.
Copy to clipboard
de Sá, Suzane S., Palm, Brett B., Campuzano-Jost, Pedro, Day, Douglas A., Newburn, Matthew K., Hu, Weiwei, Isaacman-VanWertz, Gabriel, Yee, Lindsay D., Thalman, Ryan, Brito, Joel, Carbone, Samara, Artaxo, Paulo, Goldstein, Allen H., Manzi, Antonio O., Souza, Rodrigo A.F., Mei, Fan, Shilling, John E., Springston, Stephen R., Wang, Jian, Surratt, Jason D., Alexander, M. Lizabeth, Jimenez, Jose L., & Martin, Scot T. Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia. United States. https://doi.org/10.5194/acp-2016-1020
Copy to clipboard
de Sá, Suzane S., Palm, Brett B., Campuzano-Jost, Pedro, Day, Douglas A., Newburn, Matthew K., Hu, Weiwei, Isaacman-VanWertz, Gabriel, Yee, Lindsay D., Thalman, Ryan, Brito, Joel, Carbone, Samara, Artaxo, Paulo, Goldstein, Allen H., Manzi, Antonio O., Souza, Rodrigo A.F., Mei, Fan, Shilling, John E., Springston, Stephen R., Wang, Jian, Surratt, Jason D., Alexander, M. Lizabeth, Jimenez, Jose L., and Martin, Scot T. Tue . "Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia". United States. https://doi.org/10.5194/acp-2016-1020. https://www.osti.gov/servlets/purl/1341692.
Copy to clipboard
@article{osti_1341692,
title = {Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia},
author = {de Sá, Suzane S. and Palm, Brett B. and Campuzano-Jost, Pedro and Day, Douglas A. and Newburn, Matthew K. and Hu, Weiwei and Isaacman-VanWertz, Gabriel and Yee, Lindsay D. and Thalman, Ryan and Brito, Joel and Carbone, Samara and Artaxo, Paulo and Goldstein, Allen H. and Manzi, Antonio O. and Souza, Rodrigo A.F. and Mei, Fan and Shilling, John E. and Springston, Stephen R. and Wang, Jian and Surratt, Jason D. and Alexander, M. Lizabeth and Jimenez, Jose L. and Martin, Scot T.},
abstractNote = {The atmospheric chemistry of isoprene contributes to the production of a substantial mass fraction of the particulate matter (PM) over tropical forests. Isoprene epoxydiols (IEPOX) produced in the gas phase by the oxidation of isoprene under HO2-dominant conditions are subsequently taken up by particles, thereby leading to production of secondary organic PM. The present study investigates possible perturbations to this pathway by urban pollution. The measurement site in central Amazonia was located 4 to 6 hours downwind of Manaus, Brazil. Measurements took place from February through March 2014 of the wet season, as part of the GoAmazon2014/5 experiment. Mass spectra of organic PM collected with an Aerodyne Aerosol Mass Spectrometer were analyzed by positive-matrix factorization. One resolved statistical factor (“IEPOX-SOA factor”) was associated with PM production by the IEPOX pathway. Loadings of this factor correlated with independently measured mass concentrations of tracers of IEPOX-derived PM, namely C5-alkene triols and 2-methyltetrols (R =0.96 and 0.78, respectively). Factor loading, as well as the ratio of the factor loading to organic PM mass concentration, decreased under polluted compared to background conditions. For the study period, sulfate concentration explained 37 % of the variability in the factor loading. After segregation of the data set by NOy concentration, the sulfate concentration explained up to 75 % of the variability in factor loading within the NOy subsets. The sulfate-detrended IEPOX-SOA factor loading decreased by two- to three-fold for an increase in NOy concentration from 0.5 to 2 ppb. The suppressing effects of elevated NO dominated over the enhancing effects of higher sulfate with respect to the production of IEPOX-derived PM. Relative to background conditions, the Manaus pollution contributed more significantly to NOy than to sulfate. In this light, increased emissions of nitrogen oxides, as anticipated for some scenarios of Amazonian economic development, could significantly alter pathways of PM production that presently prevail over the tropical forest, implying changes to air quality and regional climate.},
doi = {10.5194/acp-2016-1020},
journal = {Atmospheric Chemistry and Physics: Discussions},
number = ,
volume = 17,
place = {United States},
year = {Tue Jun 06 00:00:00 EDT 2017},
month = {Tue Jun 06 00:00:00 EDT 2017}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.5194/acp-2016-1020
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Organic aerosol formation from the reactive uptake of isoprene epoxydiols (IEPOX) onto non-acidified inorganic seeds
journal, January 2014

  • Nguyen, T. B.; Coggon, M. M.; Bates, K. H.
  • Atmospheric Chemistry and Physics, Vol. 14, Issue 7
  • DOI: 10.5194/acp-14-3497-2014

Effect of Acidity on Secondary Organic Aerosol Formation from Isoprene
journal, August 2007

  • Surratt, Jason D.; Lewandowski, Michael; Offenberg, John H.
  • Environmental Science & Technology, Vol. 41, Issue 15
  • DOI: 10.1021/es0704176

Seasonal characterization of submicron aerosol chemical composition and organic aerosol sources in the southeastern United States: Atlanta, Georgia,and Look Rock, Tennessee
journal, January 2016

  • Budisulistiorini, Sri Hapsari; Baumann, Karsten; Edgerton, Eric S.
  • Atmospheric Chemistry and Physics, Vol. 16, Issue 8
  • DOI: 10.5194/acp-16-5171-2016

Formation of Low Volatility Organic Compounds and Secondary Organic Aerosol from Isoprene Hydroxyhydroperoxide Low-NO Oxidation
journal, July 2015

  • Krechmer, Jordan E.; Coggon, Matthew M.; Massoli, Paola
  • Environmental Science & Technology, Vol. 49, Issue 17
  • DOI: 10.1021/acs.est.5b02031

The atmospheric sulfur cycle over the Amazon Basin: 2. Wet season
journal, January 1990

  • Andreae, M. O.; Berresheim, H.; Bingemer, H.
  • Journal of Geophysical Research, Vol. 95, Issue D10
  • DOI: 10.1029/JD095iD10p16813

Aqueous-Phase Secondary Organic Aerosol and Organosulfate Formation in Atmospheric Aerosols: A Modeling Study
journal, July 2012

  • McNeill, V. Faye; Woo, Joseph L.; Kim, Derek D.
  • Environmental Science & Technology, Vol. 46, Issue 15
  • DOI: 10.1021/es3002986

Aerosols, Climate, and the Hydrological Cycle
journal, December 2001

Ambient Gas-Particle Partitioning of Tracers for Biogenic Oxidation
journal, September 2016

  • Isaacman-VanWertz, Gabriel; Yee, Lindsay D.; Kreisberg, Nathan M.
  • Environmental Science & Technology, Vol. 50, Issue 18
  • DOI: 10.1021/acs.est.6b01674

Real-Time Continuous Characterization of Secondary Organic Aerosol Derived from Isoprene Epoxydiols in Downtown Atlanta, Georgia, Using the Aerodyne Aerosol Chemical Speciation Monitor
journal, May 2013

  • Budisulistiorini, Sri Hapsari; Canagaratna, Manjula R.; Croteau, Philip L.
  • Environmental Science & Technology, Vol. 47, Issue 11
  • DOI: 10.1021/es400023n

Atmospheric Fate of Methacrolein. 2. Formation of Lactone and Implications for Organic Aerosol Production
journal, February 2012

  • Kjaergaard, Henrik G.; Knap, Hasse C.; Ørnsø, Kristian B.
  • The Journal of Physical Chemistry A, Vol. 116, Issue 24
  • DOI: 10.1021/jp210853h

ATMOSPHERE: Enhanced: Air Pollution-Related Illness: Effects of Particles
journal, May 2005

A review of Secondary Organic Aerosol (SOA) formation from isoprene
journal, January 2009

  • Carlton, A. G.; Wiedinmyer, C.; Kroll, J. H.
  • Atmospheric Chemistry and Physics, Vol. 9, Issue 14
  • DOI: 10.5194/acp-9-4987-2009

Isoprene photochemistry over the Amazon rainforest
journal, May 2016

  • Liu, Yingjun; Brito, Joel; Dorris, Matthew R.
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 22
  • DOI: 10.1073/pnas.1524136113

Physical state and acidity of inorganic sulfate can regulate the production of secondary organic material from isoprene photooxidation products
journal, January 2015

  • Kuwata, Mikinori; Liu, Yingjun; McKinney, Karena
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 8
  • DOI: 10.1039/C4CP04942J

Production of methyl vinyl ketone and methacrolein via the hydroperoxyl pathway of isoprene oxidation
journal, January 2013

  • Liu, Y. J.; Herdlinger-Blatt, I.; McKinney, K. A.
  • Atmospheric Chemistry and Physics, Vol. 13, Issue 11
  • DOI: 10.5194/acp-13-5715-2013

Peroxy radical isomerization in the oxidation of isoprene
journal, January 2011

  • Crounse, John D.; Paulot, Fabien; Kjaergaard, Henrik G.
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 30
  • DOI: 10.1039/c1cp21330j

Effect of Organic Coatings, Humidity and Aerosol Acidity on Multiphase Chemistry of Isoprene Epoxydiols
journal, May 2016

  • Riva, Matthieu; Bell, David M.; Hansen, Anne-Maria Kaldal
  • Environmental Science & Technology, Vol. 50, Issue 11
  • DOI: 10.1021/acs.est.5b06050

Introduction: Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5)
journal, January 2016

  • Martin, S. T.; Artaxo, P.; Machado, L. A. T.
  • Atmospheric Chemistry and Physics, Vol. 16, Issue 8
  • DOI: 10.5194/acp-16-4785-2016

The Amazon basin in transition
journal, January 2012

  • Davidson, Eric A.; de Araújo, Alessandro C.; Artaxo, Paulo
  • Nature, Vol. 481, Issue 7381
  • DOI: 10.1038/nature10717

Secondary organic aerosol formation from isoprene photooxidation under high-NO x conditions : SOA FORMATION FROM ISOPRENE OXIDATION
journal, September 2005

  • Kroll, Jesse H.; Ng, Nga L.; Murphy, Shane M.
  • Geophysical Research Letters, Vol. 32, Issue 18
  • DOI: 10.1029/2005GL023637

The formation, properties and impact of secondary organic aerosol: current and emerging issues
journal, January 2009

  • Hallquist, M.; Wenger, J. C.; Baltensperger, U.
  • Atmospheric Chemistry and Physics, Vol. 9, Issue 14
  • DOI: 10.5194/acp-9-5155-2009

Aerosol formation in the photooxidation of isoprene and β-pinene
journal, January 1991

  • Pandis, Spyros N.; Paulson, Suzanne E.; Seinfeld, John H.
  • Atmospheric Environment. Part A. General Topics, Vol. 25, Issue 5-6
  • DOI: 10.1016/0960-1686(91)90141-S

Field-Deployable, High-Resolution, Time-of-Flight Aerosol Mass Spectrometer
journal, December 2006

  • DeCarlo, Peter F.; Kimmel, Joel R.; Trimborn, Achim
  • Analytical Chemistry, Vol. 78, Issue 24
  • DOI: 10.1021/ac061249n

Uptake and release of gaseous species accompanying the reactions of isoprene photo-oxidation products with sulfate particles
journal, January 2016

  • Liu, Yingjun; Kuwata, Mikinori; McKinney, Karena A.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 3
  • DOI: 10.1039/C5CP04551G

Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols
journal, January 2016

  • Riedel, T. P.; Lin, Y. -H.; Zhang, Z.
  • Atmospheric Chemistry and Physics, Vol. 16, Issue 3
  • DOI: 10.5194/acp-16-1245-2016

Reactive Uptake of an Isoprene-Derived Epoxydiol to Submicron Aerosol Particles
journal, September 2014

  • Gaston, Cassandra J.; Riedel, Theran P.; Zhang, Zhenfa
  • Environmental Science & Technology, Vol. 48, Issue 19
  • DOI: 10.1021/es5034266

Evidence for Organosulfates in Secondary Organic Aerosol
journal, January 2007

  • Surratt, Jason D.; Kroll, Jesse H.; Kleindienst, Tadeusz E.
  • Environmental Science & Technology, Vol. 41, Issue 2
  • DOI: 10.1021/es062081q

Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene
journal, August 2006

  • Surratt, Jason D.; Murphy, Shane M.; Kroll, Jesse H.
  • The Journal of Physical Chemistry A, Vol. 110, Issue 31
  • DOI: 10.1021/jp061734m

Kinetics of the reactions of isoprene-derived hydroxynitrates: gas phase epoxide formation and solution phase hydrolysis
journal, January 2014

  • Jacobs, M. I.; Burke, W. J.; Elrod, M. J.
  • Atmospheric Chemistry and Physics, Vol. 14, Issue 17
  • DOI: 10.5194/acp-14-8933-2014

Impact of Manaus City on the Amazon Green Ocean atmosphere: ozone production, precursor sensitivity and aerosol load
journal, January 2010

  • Kuhn, U.; Ganzeveld, L.; Thielmann, A.
  • Atmospheric Chemistry and Physics, Vol. 10, Issue 19
  • DOI: 10.5194/acp-10-9251-2010

Light-Absorbing Oligomer Formation in Secondary Organic Aerosol from Reactive Uptake of Isoprene Epoxydiols
journal, October 2014

  • Lin, Ying-Hsuan; Budisulistiorini, Sri Hapsari; Chu, Kevin
  • Environmental Science & Technology, Vol. 48, Issue 20
  • DOI: 10.1021/es503142b

Isoprene Forms Secondary Organic Aerosol through Cloud Processing:  Model Simulations
journal, June 2005

  • Lim, Ho-Jin; Carlton, Annmarie G.; Turpin, Barbara J.
  • Environmental Science & Technology, Vol. 39, Issue 12
  • DOI: 10.1021/es048039h

Rainforest Aerosols as Biogenic Nuclei of Clouds and Precipitation in the Amazon
journal, September 2010

Health Effects of Fine Particulate Air Pollution: Lines that Connect
journal, June 2006

Chemical Characterization of Secondary Organic Aerosol from Oxidation of Isoprene Hydroxyhydroperoxides
journal, September 2016

  • Riva, Matthieu; Budisulistiorini, Sri H.; Chen, Yuzhi
  • Environmental Science & Technology, Vol. 50, Issue 18
  • DOI: 10.1021/acs.est.6b02511

Submicron particle mass concentrations and sources in the Amazonian wet season (AMAZE-08)
journal, January 2015

  • Chen, Q.; Farmer, D. K.; Rizzo, L. V.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 7
  • DOI: 10.5194/acp-15-3687-2015

The DOE ARM Aerial Facility
journal, May 2014

  • Schmid, B.; Tomlinson, J. M.; Hubbe, J. M.
  • Bulletin of the American Meteorological Society, Vol. 95, Issue 5
  • DOI: 10.1175/BAMS-D-13-00040.1

Atmospheric oxidation of isoprene and 1,3-butadiene: influence of aerosol acidity and relative humidity on secondary organic aerosol
journal, January 2015

  • Lewandowski, M.; Jaoui, M.; Offenberg, J. H.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 7
  • DOI: 10.5194/acp-15-3773-2015

Observational Insights into Aerosol Formation from Isoprene
journal, September 2013

  • Worton, David R.; Surratt, Jason D.; LaFranchi, Brian W.
  • Environmental Science & Technology, Vol. 47, Issue 20
  • DOI: 10.1021/es4011064

A missing sink for gas-phase glyoxal in Mexico City: Formation of secondary organic aerosol
journal, January 2007

  • Volkamer, Rainer; San Martini, Federico; Molina, Luisa T.
  • Geophysical Research Letters, Vol. 34, Issue 19
  • DOI: 10.1029/2007GL030752

Budgets of reactive nitrogen, hydrocarbons, and ozone over the Amazon forest during the wet season
journal, January 1990

  • Jacob, Daniel J.; Wofsy, Steven C.
  • Journal of Geophysical Research, Vol. 95, Issue D10
  • DOI: 10.1029/JD095iD10p16737

Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies
journal, January 2011

  • Ervens, B.; Turpin, B. J.; Weber, R. J.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 21
  • DOI: 10.5194/acp-11-11069-2011

The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions
journal, January 2012

  • Guenther, A. B.; Jiang, X.; Heald, C. L.
  • Geoscientific Model Development, Vol. 5, Issue 6
  • DOI: 10.5194/gmd-5-1471-2012

Efficient Isoprene Secondary Organic Aerosol Formation from a Non-IEPOX Pathway
journal, September 2016

  • Liu, Jiumeng; D’Ambro, Emma L.; Lee, Ben H.
  • Environmental Science & Technology, Vol. 50, Issue 18
  • DOI: 10.1021/acs.est.6b01872

Effects of anthropogenic emissions on aerosol formation from isoprene and monoterpenes in the southeastern United States
journal, December 2014

  • Xu, Lu; Guo, Hongyu; Boyd, Christopher M.
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 1
  • DOI: 10.1073/pnas.1417609112

A satellite view of aerosols in the climate system
journal, September 2002

  • Kaufman, Yoram J.; Tanré, Didier; Boucher, Olivier
  • Nature, Vol. 419, Issue 6903
  • DOI: 10.1038/nature01091

Epoxide as a precursor to secondary organic aerosol formation from isoprene photooxidation in the presence of nitrogen oxides
journal, April 2013

  • Lin, Y. -H.; Zhang, H.; Pye, H. O. T.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 17
  • DOI: 10.1073/pnas.1221150110

Seasonal variation of ozone deposition to a tropical rain forest in southwest Amazonia
journal, January 2007

  • Rummel, U.; Ammann, C.; Kirkman, G. A.
  • Atmospheric Chemistry and Physics, Vol. 7, Issue 20
  • DOI: 10.5194/acp-7-5415-2007

The Amazon Tall Tower Observatory (ATTO): overview of pilot measurements on ecosystem ecology, meteorology, trace gases, and aerosols
journal, January 2015

  • Andreae, M. O.; Acevedo, O. C.; Araùjo, A.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 18
  • DOI: 10.5194/acp-15-10723-2015

Volatility and lifetime against OH heterogeneous reaction of ambient isoprene-epoxydiols-derived secondary organic aerosol (IEPOX-SOA)
journal, January 2016

  • Hu, Weiwei; Palm, Brett B.; Day, Douglas A.
  • Atmospheric Chemistry and Physics, Vol. 16, Issue 18
  • DOI: 10.5194/acp-16-11563-2016

Molecular Composition and Volatility of Organic Aerosol in the Southeastern U.S.: Implications for IEPOX Derived SOA
journal, February 2016

  • Lopez-Hilfiker, F. D.; Mohr, C.; D’Ambro, E. L.
  • Environmental Science & Technology, Vol. 50, Issue 5
  • DOI: 10.1021/acs.est.5b04769

Uptake of Epoxydiol Isomers Accounts for Half of the Particle-Phase Material Produced from Isoprene Photooxidation via the HO 2 Pathway
journal, December 2014

  • Liu, Yingjun; Kuwata, Mikinori; Strick, Benjamin F.
  • Environmental Science & Technology, Vol. 49, Issue 1
  • DOI: 10.1021/es5034298

Maximum efficiency in the hydroxyl-radical-based self-cleansing of the troposphere
journal, July 2014

  • Rohrer, Franz; Lu, Keding; Hofzumahaus, Andreas
  • Nature Geoscience, Vol. 7, Issue 8
  • DOI: 10.1038/ngeo2199

Evidence for a significant proportion of Secondary Organic Aerosol from isoprene above a maritime tropical forest
journal, January 2011

  • Robinson, N. H.; Hamilton, J. F.; Allan, J. D.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 3
  • DOI: 10.5194/acp-11-1039-2011

Sub-micrometre particulate matter is primarily in liquid form over Amazon rainforest
journal, December 2015

  • Bateman, Adam P.; Gong, Zhaoheng; Liu, Pengfei
  • Nature Geoscience, Vol. 9, Issue 1
  • DOI: 10.1038/ngeo2599

Kinetics and Products of the Reaction of the First-Generation Isoprene Hydroxy Hydroperoxide (ISOPOOH) with OH
journal, September 2015

  • St. Clair, Jason M.; Rivera-Rios, Jean C.; Crounse, John D.
  • The Journal of Physical Chemistry A, Vol. 120, Issue 9
  • DOI: 10.1021/acs.jpca.5b06532

Organic aerosol and global climate modelling: a review
journal, January 2005

  • Kanakidou, M.; Seinfeld, J. H.; Pandis, S. N.
  • Atmospheric Chemistry and Physics, Vol. 5, Issue 4
  • DOI: 10.5194/acp-5-1053-2005

Reactive intermediates revealed in secondary organic aerosol formation from isoprene
journal, December 2009

  • Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 15
  • DOI: 10.1073/pnas.0911114107

Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements
journal, January 2015

  • Hu, W. W.; Campuzano-Jost, P.; Palm, B. B.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 20
  • DOI: 10.5194/acp-15-11807-2015

Evolution of Organic Aerosols in the Atmosphere
journal, December 2009

Interpretation of organic components from Positive Matrix Factorization of aerosol mass spectrometric data
journal, January 2009

  • Ulbrich, I. M.; Canagaratna, M. R.; Zhang, Q.
  • Atmospheric Chemistry and Physics, Vol. 9, Issue 9
  • DOI: 10.5194/acp-9-2891-2009

Chemical and microphysical characterization of ambient aerosols with the aerodyne aerosol mass spectrometer
journal, January 2007

  • Canagaratna, M. R.; Jayne, J. T.; Jimenez, J. L.
  • Mass Spectrometry Reviews, Vol. 26, Issue 2
  • DOI: 10.1002/mas.20115

Characterization of oxygenated derivatives of isoprene related to 2-methyltetrols in Amazonian aerosols using trimethylsilylation and gas chromatography/ion trap mass spectrometry
journal, January 2005

  • Wang, Wu; Kourtchev, Ivan; Graham, Bim
  • Rapid Communications in Mass Spectrometry, Vol. 19, Issue 10
  • DOI: 10.1002/rcm.1940

Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene
journal, February 2004

Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere
journal, January 2015

  • Nguyen, Tran B.; Bates, Kelvin H.; Crounse, John D.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 27
  • DOI: 10.1039/C5CP02001H

The Arm Climate Research Facility: A Review of Structure and Capabilities
journal, March 2013

  • Mather, James H.; Voyles, Jimmy W.
  • Bulletin of the American Meteorological Society, Vol. 94, Issue 3
  • DOI: 10.1175/BAMS-D-11-00218.1

Isoprene Epoxydiols as Precursors to Secondary Organic Aerosol Formation: Acid-Catalyzed Reactive Uptake Studies with Authentic Compounds
journal, November 2011

  • Lin, Ying-Hsuan; Zhang, Zhenfa; Docherty, Kenneth S.
  • Environmental Science & Technology, Vol. 46, Issue 1
  • DOI: 10.1021/es202554c

Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the southeast United States and co-benefit of SO 2 emission controls
journal, January 2016

  • Marais, E. A.; Jacob, D. J.; Jimenez, J. L.
  • Atmospheric Chemistry and Physics, Vol. 16, Issue 3
  • DOI: 10.5194/acp-16-1603-2016

Photochemical processing of organic aerosol at nearby continental sites: contrast between urban plumes and regional aerosol
journal, January 2011

  • Slowik, J. G.; Brook, J.; Chang, R. Y. -W.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 6
  • DOI: 10.5194/acp-11-2991-2011

Variations of OH radical in an urban plume inferred from NO 2 column measurements : NO2 COLUMN AND VARIATIONS OF OH RADICAL
journal, May 2013

  • Valin, L. C.; Russell, A. R.; Cohen, R. C.
  • Geophysical Research Letters, Vol. 40, Issue 9
  • DOI: 10.1002/grl.50267

Tropospheric nitric oxide measurements over the Amazon Basin
journal, January 1988

An overview of the Amazonian Aerosol Characterization Experiment 2008 (AMAZE-08)
journal, January 2010

  • Martin, S. T.; Andreae, M. O.; Althausen, D.
  • Atmospheric Chemistry and Physics, Vol. 10, Issue 23
  • DOI: 10.5194/acp-10-11415-2010

The lifetime of nitrogen oxides in an isoprene-dominated forest
journal, January 2016

  • Romer, Paul S.; Duffey, Kaitlin C.; Wooldridge, Paul J.
  • Atmospheric Chemistry and Physics, Vol. 16, Issue 12
  • DOI: 10.5194/acp-16-7623-2016

Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene
journal, August 2009

Real-Time Continuous Characterization of Secondary Organic Aerosol Derived from Isoprene Epoxydiols in Downtown Atlanta, Georgia, Using the Aerodyne Aerosol Chemical Speciation Monitor
journal, May 2013

  • Budisulistiorini, Sri Hapsari; Canagaratna, Manjula R.; Croteau, Philip L.
  • Environmental Science & Technology, Vol. 47, Issue 11
  • DOI: 10.1021/es400023n

Observational Insights into Aerosol Formation from Isoprene
journal, September 2013

  • Worton, David R.; Surratt, Jason D.; LaFranchi, Brian W.
  • Environmental Science & Technology, Vol. 47, Issue 20
  • DOI: 10.1021/es4011064

Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene
journal, August 2006

  • Surratt, Jason D.; Murphy, Shane M.; Kroll, Jesse H.
  • The Journal of Physical Chemistry A, Vol. 110, Issue 31
  • DOI: 10.1021/jp061734m

Global budgets of atmospheric glyoxal and methylglyoxal, and implications for formation of secondary organic aerosols
journal, January 2008

  • Fu, Tzung-May; Jacob, Daniel J.; Wittrock, Folkard
  • Journal of Geophysical Research, Vol. 113, Issue D15
  • DOI: 10.1029/2007jd009505

Emission of nitric oxide (NO) from tropical forest soils and exchange of NO between the forest canopy and atmospheric boundary layers
journal, January 1990

  • Bakwin, Peter S.; Wofsy, Steven C.; Fan, Song-Miao
  • Journal of Geophysical Research, Vol. 95, Issue D10
  • DOI: 10.1029/jd095id10p16755

Reactive intermediates revealed in secondary organic aerosol formation from isoprene
journal, December 2009

  • Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 15
  • DOI: 10.1073/pnas.0911114107

Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene
journal, August 2009

Evidence for a significant proportion of Secondary Organic Aerosol from isoprene above a maritime tropical forest
journal, January 2011

  • Robinson, N. H.; Hamilton, J. F.; Allan, J. D.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 3
  • DOI: 10.5194/acp-11-1039-2011

Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements
journal, January 2015

  • Hu, W. W.; Campuzano-Jost, P.; Palm, B. B.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 20
  • DOI: 10.5194/acp-15-11807-2015

Submicron particle mass concentrations and sources in the Amazonian wet season (AMAZE-08)
journal, January 2015

  • Chen, Q.; Farmer, D. K.; Rizzo, L. V.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 7
  • DOI: 10.5194/acp-15-3687-2015

Atmospheric oxidation of isoprene and 1,3-butadiene: influence of aerosol acidity and relative humidity on secondary organic aerosol
journal, January 2015

  • Lewandowski, M.; Jaoui, M.; Offenberg, J. H.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 7
  • DOI: 10.5194/acp-15-3773-2015

Introduction: Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5)
journal, January 2016

  • Martin, S. T.; Artaxo, P.; Machado, L. A. T.
  • Atmospheric Chemistry and Physics, Vol. 16, Issue 8
  • DOI: 10.5194/acp-16-4785-2016

The lifetime of nitrogen oxides in an isoprene-dominated forest
journal, January 2016

  • Romer, Paul S.; Duffey, Kaitlin C.; Wooldridge, Paul J.
  • Atmospheric Chemistry and Physics, Vol. 16, Issue 12
  • DOI: 10.5194/acp-16-7623-2016

Power plant fuel switching and air quality in a tropical, forested environment
journal, January 2017

  • Medeiros, Adan S. S.; Calderaro, Gisele; Guimarães, Patricia C.
  • Atmospheric Chemistry and Physics, Vol. 17, Issue 14
  • DOI: 10.5194/acp-17-8987-2017

Organic aerosol and global climate modelling: a review
journal, January 2004

  • Kanakidou, M.; Seinfeld, J. H.; Pandis, S. N.
  • Atmospheric Chemistry and Physics Discussions, Vol. 4, Issue 5
  • DOI: 10.5194/acpd-4-5855-2004
    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Chemical composition of ultrafine aerosol particles in central Amazonia during the wet season
    journal, January 2019

    • Glicker, Hayley S.; Lawler, Michael J.; Ortega, John
    • Atmospheric Chemistry and Physics, Vol. 19, Issue 20
    • DOI: 10.5194/acp-19-13053-2019

    Multi-year statistical and modeling analysis of submicrometer aerosol number size distributions at a rain forest site in Amazonia
    journal, January 2018

    • Varanda Rizzo, Luciana; Roldin, Pontus; Brito, Joel
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 14
    • DOI: 10.5194/acp-18-10255-2018

    Ground-based observation of clusters and nucleation-mode particles in the Amazon
    journal, January 2018

    • Wimmer, Daniela; Buenrostro Mazon, Stephany; Manninen, Hanna Elina
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 17
    • DOI: 10.5194/acp-18-13245-2018

    Isoprene photo-oxidation products quantify the effect of pollution on hydroxyl radicals over Amazonia
    journal, April 2018

    Urban pollution greatly enhances formation of natural aerosols over the Amazon rainforest
    journal, March 2019

    Evaluation of the new capture vaporizer for aerosol mass spectrometers (AMS) through field studies of inorganic species
    journal, February 2017

    Aircraft observations of the chemical composition and aging of aerosol in the Manaus urban plume during GoAmazon 2014/5
    journal, January 2018

    • Shilling, John E.; Pekour, Mikhail S.; Fortner, Edward C.
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 14
    • DOI: 10.5194/acp-18-10773-2018

    Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia
    journal, January 2018

    • Palm, Brett B.; de Sá, Suzane S.; Day, Douglas A.
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 1
    • DOI: 10.5194/acp-18-467-2018

    Development of a hydrophilic interaction liquid chromatography (HILIC) method for the chemical characterization of water-soluble isoprene epoxydiol (IEPOX)-derived secondary organic aerosol
    journal, January 2018

    • Cui, Tianqu; Zeng, Zhexi; dos Santos, Erickson O.
    • Environmental Science: Processes & Impacts, Vol. 20, Issue 11
    • DOI: 10.1039/c8em00308d

    Observations of sesquiterpenes and their oxidation products in central Amazonia during the wet and dry seasons
    journal, January 2018

    • Yee, Lindsay D.; Isaacman-VanWertz, Gabriel; Wernis, Rebecca A.
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 14
    • DOI: 10.5194/acp-18-10433-2018

    Assessing the role of anthropogenic and biogenic sources on PM1 over southern West Africa using aircraft measurements
    journal, January 2018

    • Brito, Joel; Freney, Evelyn; Dominutti, Pamela
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 2
    • DOI: 10.5194/acp-18-757-2018

    Urban influence on the concentration and composition of submicron particulate matter in central Amazonia
    journal, January 2018

    • de Sá, Suzane S.; Palm, Brett B.; Campuzano-Jost, Pedro
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 16
    • DOI: 10.5194/acp-18-12185-2018

    CCN activity and organic hygroscopicity of aerosols downwind of an urban region in central Amazonia: seasonal and diel variations and impact of anthropogenic emissions
    journal, January 2017

    • Thalman, Ryan; de Sá, Suzane S.; Palm, Brett B.
    • Atmospheric Chemistry and Physics, Vol. 17, Issue 19
    • DOI: 10.5194/acp-17-11779-2017

    Contributions of biomass-burning, urban, and biogenic emissions to the concentrations and light-absorbing properties of particulate matter in central Amazonia during the dry season
    journal, January 2019

    • de Sá, Suzane S.; Rizzo, Luciana V.; Palm, Brett B.
    • Atmospheric Chemistry and Physics, Vol. 19, Issue 12
    • DOI: 10.5194/acp-19-7973-2019

    Regional Similarities and NO x ‐Related Increases in Biogenic Secondary Organic Aerosol in Summertime Southeastern United States
    journal, September 2018

    • Liu, Jun; Russell, Lynn M.; Ruggeri, Giulia
    • Journal of Geophysical Research: Atmospheres, Vol. 123, Issue 18
    • DOI: 10.1029/2018jd028491

    Contributions of mobile, stationary and biogenic sources to air pollution in the Amazon rainforest: a numerical study with the WRF-Chem model
    journal, January 2017

    • Abou Rafee, Sameh A.; Martins, Leila D.; Kawashima, Ana B.
    • Atmospheric Chemistry and Physics, Vol. 17, Issue 12
    • DOI: 10.5194/acp-17-7977-2017

    Aircraft-based observations of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) in the tropical upper troposphere over the Amazon region
    journal, January 2018

    • Schulz, Christiane; Schneider, Johannes; Amorim Holanda, Bruna
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 20
    • DOI: 10.5194/acp-18-14979-2018

    African volcanic emissions influencing atmospheric aerosols over the Amazon rain forest
    journal, January 2018

    • Saturno, Jorge; Ditas, Florian; Penning de Vries, Marloes
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 14
    • DOI: 10.5194/acp-18-10391-2018

    Anthropogenic influences on the physical state of submicron particulate matter over a tropical forest
    journal, January 2017

    • Bateman, Adam P.; Gong, Zhaoheng; Harder, Tristan H.
    • Atmospheric Chemistry and Physics, Vol. 17, Issue 3
    • DOI: 10.5194/acp-17-1759-2017

    Organosulfates in aerosols downwind of an urban region in central Amazon
    journal, January 2018

    • Glasius, Marianne; Bering, Mads S.; Yee, Lindsay D.
    • Environmental Science: Processes & Impacts, Vol. 20, Issue 11
    • DOI: 10.1039/c8em00413g

    Isoprene photo-oxidation products quantify the effect of pollution on hydroxyl radicals over Amazonia
    journal, April 2018

    Elemental Mixing State of Aerosol Particles Collected in Central Amazonia during GoAmazon2014/15
    journal, September 2017

    • Fraund, Matthew; Pham, Don; Bonanno, Daniel
    • Atmosphere, Vol. 8, Issue 12
    • DOI: 10.3390/atmos8090173

    African volcanic emissions influencing atmospheric aerosols over the Amazon rain forest
    journal, January 2018

    • Saturno, Jorge; Ditas, Florian; Penning de Vries, Marloes
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 14
    • DOI: 10.5194/acp-18-10391-2018

    Ground-based observation of clusters and nucleation-mode particles in the Amazon
    journal, January 2018

    • Wimmer, Daniela; Buenrostro Mazon, Stephany; Manninen, Hanna Elina
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 17
    • DOI: 10.5194/acp-18-13245-2018

    Aircraft-based observations of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) in the tropical upper troposphere over the Amazon region
    journal, January 2018

    • Schulz, Christiane; Schneider, Johannes; Amorim Holanda, Bruna
    • Atmospheric Chemistry and Physics, Vol. 18, Issue 20
    • DOI: 10.5194/acp-18-14979-2018

    Chemical composition of ultrafine aerosol particles in central Amazonia during the wet season
    journal, January 2019

    • Glicker, Hayley S.; Lawler, Michael J.; Ortega, John
    • Atmospheric Chemistry and Physics, Vol. 19, Issue 20
    • DOI: 10.5194/acp-19-13053-2019

    Mixing states of Amazon basin aerosol particles transported over long distances using transmission electron microscopy
    journal, January 2020

    • Adachi, Kouji; Oshima, Naga; Gong, Zhaoheng
    • Atmospheric Chemistry and Physics, Vol. 20, Issue 20
    • DOI: 10.5194/acp-20-11923-2020

    Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A
    journal, May 2020

    • Mouchel-Vallon, Camille; Lee-Taylor, Julia; Hodzic, Alma
    • Atmospheric Chemistry and Physics, Vol. 20, Issue 10
    • DOI: 10.5194/acp-20-5995-2020
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: