Synthesis-driven, structure-dependent optical behavior in phase-tunable NaYF4:Yb,Er-based motifs and associated heterostructures
Abstract
Understanding the key parameters necessary for generating uniform Er,Yb co-activated NaYF4 possessing various selected phases (i.e. cubic or hexagonal) represents an important chemical strategy towards tailoring optical behavior in these systems. In this paper, we report on a straightforward hydrothermal synthesis in which the separate effects of reaction temperature, reaction time, and precursor stoichiometry in the absence of any surfactant were independently investigated. Interestingly, the presence and the concentration of NH4OH appear to be the most critical determinants of the phase and morphology. For example, with NH4OH as an additive, we have observed the formation of novel hierarchical nanowire bundles which possess overall lengths of ~5 μm and widths of ~1.5 μm but are composed of constituent component sub-units of long, ultrathin (~5 nm) nanowires. These motifs have yet to be reported as distinctive morphological manifestations of fluoride materials. The optical properties of as-generated structures have also been carefully analyzed. Specifically, we have observed tunable, structure-dependent energy transfer behavior associated with the formation of a unique class of NaYF4–CdSe quantum dot (QD) heterostructures, incorporating zero-dimensional (0D), one-dimensional (1D), and three-dimensional (3D) NaYF4 structures. Our results have demonstrated the key roles of the intrinsic morphology-specific physical surface area and porosity asmore »
- Authors:
-
- Stony Brook Univ., NY (United States). Dept. of Chemistry
- Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter of Physics and Materials Sciences Division
- Stony Brook Univ., NY (United States). Materials Science and Engineering Dept.
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
- Stony Brook Univ., NY (United States). Dept. of Chemistry; Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter of Physics and Materials Sciences Division
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1341646
- Report Number(s):
- BNL-113365-2016-JA
Journal ID: ISSN 1463-9076; R&D Project: PM037; KC0201030; TRN: US1701041
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP
- Additional Journal Information:
- Journal Volume: 19; Journal Issue: 3; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; NaYF4 nanocrystals; phase control; quantum dots; upconversion; energy transfer
Citation Formats
Liu, Haiqing, Han, Jinkyu, McBean, Coray, Lewis, Crystal S., Kumar Routh, Prahlad, Cotlet, Mircea, and Wong, Stanislaus S. Synthesis-driven, structure-dependent optical behavior in phase-tunable NaYF4:Yb,Er-based motifs and associated heterostructures. United States: N. p., 2017.
Web. doi:10.1039/C6CP07648C.
Liu, Haiqing, Han, Jinkyu, McBean, Coray, Lewis, Crystal S., Kumar Routh, Prahlad, Cotlet, Mircea, & Wong, Stanislaus S. Synthesis-driven, structure-dependent optical behavior in phase-tunable NaYF4:Yb,Er-based motifs and associated heterostructures. United States. https://doi.org/10.1039/C6CP07648C
Liu, Haiqing, Han, Jinkyu, McBean, Coray, Lewis, Crystal S., Kumar Routh, Prahlad, Cotlet, Mircea, and Wong, Stanislaus S. Tue .
"Synthesis-driven, structure-dependent optical behavior in phase-tunable NaYF4:Yb,Er-based motifs and associated heterostructures". United States. https://doi.org/10.1039/C6CP07648C. https://www.osti.gov/servlets/purl/1341646.
@article{osti_1341646,
title = {Synthesis-driven, structure-dependent optical behavior in phase-tunable NaYF4:Yb,Er-based motifs and associated heterostructures},
author = {Liu, Haiqing and Han, Jinkyu and McBean, Coray and Lewis, Crystal S. and Kumar Routh, Prahlad and Cotlet, Mircea and Wong, Stanislaus S.},
abstractNote = {Understanding the key parameters necessary for generating uniform Er,Yb co-activated NaYF4 possessing various selected phases (i.e. cubic or hexagonal) represents an important chemical strategy towards tailoring optical behavior in these systems. In this paper, we report on a straightforward hydrothermal synthesis in which the separate effects of reaction temperature, reaction time, and precursor stoichiometry in the absence of any surfactant were independently investigated. Interestingly, the presence and the concentration of NH4OH appear to be the most critical determinants of the phase and morphology. For example, with NH4OH as an additive, we have observed the formation of novel hierarchical nanowire bundles which possess overall lengths of ~5 μm and widths of ~1.5 μm but are composed of constituent component sub-units of long, ultrathin (~5 nm) nanowires. These motifs have yet to be reported as distinctive morphological manifestations of fluoride materials. The optical properties of as-generated structures have also been carefully analyzed. Specifically, we have observed tunable, structure-dependent energy transfer behavior associated with the formation of a unique class of NaYF4–CdSe quantum dot (QD) heterostructures, incorporating zero-dimensional (0D), one-dimensional (1D), and three-dimensional (3D) NaYF4 structures. Our results have demonstrated the key roles of the intrinsic morphology-specific physical surface area and porosity as factors in governing the resulting opto-electronic behavior. Finally and specifically, the trend in energy transfer efficiency correlates well with the corresponding QD loading within these heterostructures, thereby implying that the efficiency of FRET appears to be directly affected by the amount of QDs immobilized onto the external surfaces of the underlying fluoride host materials.},
doi = {10.1039/C6CP07648C},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 3,
volume = 19,
place = {United States},
year = {Tue Jan 03 00:00:00 EST 2017},
month = {Tue Jan 03 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Power scaling method for 2-μm diode-cladding-pumped Tm^3+-doped silica fiber lasers that uses Yb^3+ codoping
journal, January 2003
- Jackson, Stuart D.
- Optics Letters, Vol. 28, Issue 22
Upconverting nanoparticles for pre-clinical diffuse optical imaging, microscopy and sensing: Current trends and future challenges: Upconverting nanoparticles
journal, January 2013
- Xu, Can T.; Zhan, Qiuqiang; Liu, Haichun
- Laser & Photonics Reviews, Vol. 7, Issue 5
Controlled synthesis and morphology dependent upconversion luminescence of NaYF 4 :Yb, Er nanocrystals
journal, June 2007
- Sun, Yajuan; Chen, Yue; Tian, Lijin
- Nanotechnology, Vol. 18, Issue 27
Morphology-Dependent Energy Transfer Dynamics in Fluorene-Based Amphiphile Nanoparticles
journal, May 2012
- Stevens, Amy L.; Kaeser, Adrien; Schenning, Albertus P. H. J.
- ACS Nano, Vol. 6, Issue 6
Tailoring the Morphology and Structure of Nanosized Zn 2 SiO 4 : Mn 2+ Phosphors Using the Hydrothermal Method and Their Luminescence Properties
journal, May 2010
- An, Jae-Sul; Noh, Jun Hong; Cho, In-Sun
- The Journal of Physical Chemistry C, Vol. 114, Issue 23
Synthesis of a NaYF 4 :Yb,Er upconversion film on a silicon substrate and its tribological behavior
journal, January 2015
- Wang, Chuanying; Cheng, Xianhua
- RSC Advances, Vol. 5, Issue 115
One-dimensional hexagonal-phase NaYF4: Controlled synthesis, self-assembly, and morphology-dependent up-conversion luminescence properties
journal, January 2010
- Ma, Dekun; Yang, Dongpeng; Jiang, Jinlu
- CrystEngComm, Vol. 12, Issue 5
A New Cubic Phase for a NaYF 4 Host Matrix Offering High Upconversion Luminescence Efficiency
journal, August 2015
- Wang, Limin; Li, Xiyu; Li, Zhengquan
- Advanced Materials, Vol. 27, Issue 37
Controlled synthesis and luminescence properties from cubic to hexagonal NaYF4:Ln3+ (Ln=Eu and Yb/Tm) microcrystals
journal, May 2009
- Wang, Guofeng; Qin, Weiping; Zhang, Jisen
- Journal of Alloys and Compounds, Vol. 475, Issue 1-2
Biosorption of cadmium and nickel by functionalized husk of Lathyrus sativus
journal, April 2008
- Panda, G. C.; Das, S. K.; Guha, A. K.
- Colloids and Surfaces B: Biointerfaces, Vol. 62, Issue 2
Amine-Assisted Facetted Etching of CdSe Nanocrystals
journal, March 2005
- Li, Rongfu; Lee, Jeunghoon; Yang, Baocheng
- Journal of the American Chemical Society, Vol. 127, Issue 8
Salt-assisted rapid transformation of NaYF 4 :Yb 3+ ,Er 3+ nanocrystals from cubic to hexagonal
journal, January 2014
- Yin, Bangda; Zhou, Wenli; Long, Qian
- CrystEngComm, Vol. 16, Issue 36
Enhanced Performance of Dye-Sensitized Solar Cells by Utilization of an External, Bifunctional Layer Consisting of Uniform β-NaYF 4 :Er 3+ /Yb 3+ Nanoplatelets
journal, August 2011
- Shan, Guo-Bin; Assaaoudi, Hassane; Demopoulos, George P.
- ACS Applied Materials & Interfaces, Vol. 3, Issue 9
Visible Quantum Cutting in LiGdF 4 :Eu 3+ Through Downconversion
journal, January 1999
- Wegh, René T.; Donker, Harry; Oskam, Koenraad D.
- Science, Vol. 283, Issue 5402
Synthesis and Upconversion Luminescence of Hexagonal-Phase NaYF4:Yb, Er3+ Phosphors of Controlled Size and Morphology
journal, September 2005
- Zeng, J. -H.; Su, J.; Li, Z. -H.
- Advanced Materials, Vol. 17, Issue 17
Upconversion induced enhancement of dye sensitized solar cells based on core–shell structured β-NaYF 4 :Er 3+ , Yb 3+ @SiO 2 nanoparticles
journal, January 2014
- Zhou, Ziyao; Wang, Jiahong; Nan, Fan
- Nanoscale, Vol. 6, Issue 4
Hexagonal Sodium Yttrium Fluoride Based Green and Blue Emitting Upconversion Phosphors
journal, April 2004
- Krämer, Karl W.; Biner, Daniel; Frei, Gabriela
- Chemistry of Materials, Vol. 16, Issue 7
Shape, Size, and Phase-Controlled Rare-Earth Fluoride Nanocrystals with Optical Up-Conversion Properties
journal, September 2009
- Zhang, Fan; Li, Jing; Shan, Jiong
- Chemistry - A European Journal, Vol. 15, Issue 41
Effect of surface area and crystallite size on luminescent intensity of Y2O3:Eu phosphor prepared by spray pyrolysis
journal, August 2005
- Jung, Kyeong Youl; Lee, Chang Hee; Kang, Yun Chan
- Materials Letters, Vol. 59, Issue 19-20
Control of Photoluminescence Properties of CdSe Nanocrystals in Growth
journal, March 2002
- Qu, Lianhua; Peng, Xiaogang
- Journal of the American Chemical Society, Vol. 124, Issue 9
Absolute quantum yield measurements of colloidal NaYF4: Er3+, Yb3+ upconverting nanoparticles
journal, January 2010
- Boyer, John-Christopher; van Veggel, Frank C. J. M.
- Nanoscale, Vol. 2, Issue 8
Synthesis and photoluminescence properties of hexagonal Lanthanide(iii)-doped NaYF4 microprisms
journal, January 2010
- Tao, Feng; Pan, Feng; Wang, Zhijun
- CrystEngComm, Vol. 12, Issue 12
Energy transfer in lanthanide upconversion studies for extended optical applications
journal, January 2015
- Dong, Hao; Sun, Ling-Dong; Yan, Chun-Hua
- Chemical Society Reviews, Vol. 44, Issue 6
Two-Photon Absorption in CdSe Colloidal Quantum Dots Compared to Organic Molecules
journal, November 2014
- Makarov, Nikolay S.; Lau, Pick Chung; Olson, Christopher
- ACS Nano, Vol. 8, Issue 12
β-NaYF 4 :Yb 3+ , Er 3+ upconversion microcrystals with both high emission intensity and controlled morphology: β-NaYF 4 :Yb, 3+ , Er 3+ Upconversion Crystals with both High Emission Intensity and Controlled Morphology
journal, February 2014
- Suli, Wu; Ye, Liu; Jie, Chang
- Laser & Photonics Reviews, Vol. 8, Issue 4
Magnetic and upconverted luminescent properties of multifunctional lanthanide doped cubic KGdF4 nanocrystals
journal, January 2010
- Yang, L. W.; Zhang, Y. Y.; Li, J. J.
- Nanoscale, Vol. 2, Issue 12
Highly Efficient Multicolour Upconversion Emission in Transparent Colloids of Lanthanide-Doped NaYF 4 Nanocrystals
journal, December 2004
- Heer, S.; Kömpe, K.; Güdel, H. -U.
- Advanced Materials, Vol. 16, Issue 23-24
Controlled synthesis of NaYF4: Yb, Er nanocrystals with upconversion fluorescence via a facile hydrothermal procedure in aqueous solution
journal, January 2011
- Wang, Yuhui; Cai, Ruxiu; Liu, Zhihong
- CrystEngComm, Vol. 13, Issue 6
Two-photon absorption and two-photon assisted excited-state absorption in CdSe 0.3 S 0.7 quantum dots
journal, March 2009
- Wu, Feng; Zhang, Guilan; Tian, Wei
- Journal of Optics A: Pure and Applied Optics, Vol. 11, Issue 6
Bright White Light through Up-Conversion of a Single NIR Source from Sol−Gel-Derived Thin Film Made with Ln 3+ -Doped LaF 3 Nanoparticles
journal, September 2005
- Sivakumar, Sri; van Veggel, Frank C. J. M.; Raudsepp, Mati
- Journal of the American Chemical Society, Vol. 127, Issue 36
Synthesis of Hexagonal-Phase NaYF4:Yb,Er and NaYF4:Yb,Tm Nanocrystals with Efficient Up-Conversion Fluorescence
journal, December 2006
- Yi, G. S.; Chow, G. M.
- Advanced Functional Materials, Vol. 16, Issue 18, p. 2324-2329
Morphology-Dependent Energy Transfer of Polyfluorene Nanoparticles Decorating InGaN/GaN Quantum-Well Nanopillars
journal, August 2013
- Erdem, Talha; Ibrahimova, Vusala; Jeon, Dae-Woo
- The Journal of Physical Chemistry C, Vol. 117, Issue 36
Analysing the effect of the crystal structure on upconversion luminescence in Yb 3+ ,Er 3+ -co-doped NaYF 4 nanomaterials
journal, January 2015
- Klier, D. T.; Kumke, M. U.
- Journal of Materials Chemistry C, Vol. 3, Issue 42
Uniform Nanostructured Arrays of Sodium Rare-Earth Fluorides for Highly Efficient Multicolor Upconversion Luminescence
journal, October 2007
- Zhang, Fan; Wan, Ying; Yu, Ting
- Angewandte Chemie International Edition, Vol. 46, Issue 42
Near-IR Photoresponse in New Up-Converting CdSe/NaYF 4 :Yb,Er Nanoheterostructures
journal, July 2010
- Yan, Chenglin; Dadvand, Afshin; Rosei, Federico
- Journal of the American Chemical Society, Vol. 132, Issue 26
Enhanced photovoltaic performance of dye-sensitized solar cells based on NaYF4:Yb3+, Er3+-incorporated nanocrystalline TiO2 electrodes
journal, August 2015
- Zhu, Guang; Wang, Hongyan; Zhang, Quanxin
- Journal of Colloid and Interface Science, Vol. 451
Synthesis and Fluorescence of Neodymium-Doped Barium Fluoride Nanoparticles
journal, July 2000
- Bender, Christopher M.; Burlitch, James M.; Barber, Duane
- Chemistry of Materials, Vol. 12, Issue 7
Enhancing the performance of solar cells via luminescent down-shifting of the incident spectrum: A review
journal, August 2009
- Klampaftis, Efthymios; Ross, David; McIntosh, Keith R.
- Solar Energy Materials and Solar Cells, Vol. 93, Issue 8
Highly Luminescent NIR-to-Visible Upconversion Thin Films and Monoliths Requiring No High-Temperature Treatment
journal, July 2009
- Lin, Cuikun; Berry, Mary T.; Anderson, Robert
- Chemistry of Materials, Vol. 21, Issue 14
Observation of Photoinduced Charge Transfer in Novel Luminescent CdSe Quantum Dot–CePO 4 :Tb Metal Oxide Nanowire Composite Heterostructures
journal, March 2014
- Han, Jinkyu; Wang, Lei; Wong, Stanislaus S.
- The Journal of Physical Chemistry C, Vol. 118, Issue 11
Monodispersed β-NaYF 4 Mesocrystals: In Situ Ion Exchange and Multicolor Up- and Down-Conversions
journal, April 2013
- Zhuang, Jianle; Yang, Xianfeng; Fu, Junxiang
- Crystal Growth & Design, Vol. 13, Issue 6
White Emission by Frequency Up-Conversion in Yb 3+ -Ho 3+ -Tm 3+ Triply Doped Hexagonal NaYF 4 Nanorods
journal, October 2009
- Yang, L. W.; Han, H. L.; Zhang, Y. Y.
- The Journal of Physical Chemistry C, Vol. 113, Issue 44
Dependence of the Up-Conversion Properties of NaYF 4 :Yb 3+ /Er 3+ Nanopowders on the Structure and Particle Size
journal, November 2012
- Kwon, Seok Hun; Lee, Jun Seong; Kim, Young Jin
- Journal of Nanoscience and Nanotechnology, Vol. 12, Issue 11
Up-conversion FRET from Er 3+ /Yb 3+ :NaYF 4 Nanophosphor to CdSe Quantum Dots
journal, September 2010
- Bednarkiewicz, Artur; Nyk, Marcin; Samoc, Marek
- The Journal of Physical Chemistry C, Vol. 114, Issue 41
Morphology and dopant-dependent optical characteristics of novel composite 1D and 3D-based heterostructures of CdSe nanocrystals and LaPO 4 :Re (Re = Eu, Ce, Tb) metal phosphate nanowires
journal, January 2014
- Han, Jinkyu; Wang, Lei; Wong, Stanislaus S.
- RSC Adv., Vol. 4, Issue 66
Synthesis of upconversion NaYF 4 :Yb 3+ ,Er 3+ particles with enhanced luminescent intensity through control of morphology and phase
journal, January 2014
- Lin, Min; Zhao, Ying; Liu, Ming
- J. Mater. Chem. C, Vol. 2, Issue 19
Upconverter solar cells: materials and applications
journal, January 2011
- de Wild, J.; Meijerink, A.; Rath, J. K.
- Energy & Environmental Science, Vol. 4, Issue 12
NaYF4:Yb,Tm/CdS composite as a novel near-infrared-driven photocatalyst
journal, October 2010
- Li, Chuanhao; Wang, Feng; Zhu, Jian
- Applied Catalysis B: Environmental, Vol. 100, Issue 3-4
Tuning upconversion through energy migration in core–shell nanoparticles
journal, October 2011
- Wang, Feng; Deng, Renren; Wang, Juan
- Nature Materials, Vol. 10, Issue 12
Upconversion enhancement of lanthanide-doped NaYF4 for quantum dot-sensitized solar cells
journal, February 2015
- Wang, Kefeng; Jiang, Jiaqiao; Wan, Sijie
- Electrochimica Acta, Vol. 155
Crystal Symmetry, Lattice Vibrations and Optical Spectroscopy of Solids: A Group Theoretical Approach
book, July 2014
- Di Bartolo, Baldassare; Powell, Richard C.
Characterization of the biosorption of cadmium, lead and copper with the brown alga Fucus vesiculosus
journal, October 2008
- Mata, Y. N.; Blázquez, M. L.; Ballester, A.
- Journal of Hazardous Materials, Vol. 158, Issue 2-3
Interaction Between Y 3+ and Oleate Ions for the Cubic-to-Hexagonal Phase Transformation of NaYF 4 Nanocrystals
journal, January 2012
- Sui, Yunqi; Tao, Ke; Tian, Qing
- The Journal of Physical Chemistry C, Vol. 116, Issue 2
Different Microstructures of β-NaYF 4 Fabricated by Hydrothermal Process: Effects of pH Values and Fluoride Sources
journal, October 2007
- Li, Chunxia; Yang, Jun; Quan, Zewei
- Chemistry of Materials, Vol. 19, Issue 20
Multiplexed near-infrared in vivo imaging complementarily using quantum dots and upconverting NaYF4:Yb3+,Tm3+ nanoparticles
journal, January 2011
- Jeong, Sanghwa; Won, Nayoun; Lee, Jinsik
- Chemical Communications, Vol. 47, Issue 28
Simultaneous morphology manipulation and upconversion luminescence enhancement of β-NaYF4:Yb3+/Er3+ microcrystals by simply tuning the KF dosage
journal, August 2015
- Ding, Mingye; Chen, Daqin; Yin, Shilong
- Scientific Reports, Vol. 5, Issue 1
Performance optimization in dye-sensitized solar cells with β -NaYF 4 :Er 3+ /Yb 3+ and graphene multi-functional layer hybrid composite photoanodes
journal, August 2015
- Luoshan, Mengdai; Li, Meiya; Liu, Xiaolian
- Journal of Power Sources, Vol. 287
Multifunctional core–shell upconversion nanoparticles for targeted tumor cells induced by near-infrared light
journal, January 2013
- Yang, Xiaojun; Xiao, Qianqian; Niu, Caixia
- Journal of Materials Chemistry B, Vol. 1, Issue 21
Upconversion and Anti-Stokes Processes with f and d Ions in Solids
journal, January 2004
- Auzel, François
- Chemical Reviews, Vol. 104, Issue 1
Plasmon-Enhanced Two-Photon Absorption in Photoluminescent Semiconductor Nanocrystals
journal, March 2016
- Marin, Brandon C.; Hsu, Su-Wen; Chen, Li
- ACS Photonics, Vol. 3, Issue 4
Preparation of Monodisperse Iron Oxide Nanoparticles via the Synthesis and Decomposition of Iron Fatty Acid Complexes
journal, July 2009
- Chen, Chih-Jung; Lai, Hsin-Yi; Lin, Chee-Cheng
- Nanoscale Research Letters, Vol. 4, Issue 11
Simultaneous phase and size control of upconversion nanocrystals through lanthanide doping
journal, February 2010
- Wang, Feng; Han, Yu; Lim, Chin Seong
- Nature, Vol. 463, Issue 7284
Nano- and Submicron Sized Europium Activated Silicate Phosphors Prepared by a Modified Co-Precipitation Method
journal, January 2012
- Han, J. K.; Hannah, M. E.; Piquette, A.
- ECS Journal of Solid State Science and Technology, Vol. 1, Issue 3
Multifunctional Hybrid Nanomaterials from Water Dispersible CaF 2 :Eu 3+ , Mn 2+ and Fe 3 O 4 for Luminescence and Hyperthermia Application
journal, July 2014
- Singh, Laishram Priyobarta; Srivastava, Sri Krishna; Mishra, Ratikant
- The Journal of Physical Chemistry C, Vol. 118, Issue 31
Works referencing / citing this record:
Metal chalcogenide quantum dot-sensitized 1D-based semiconducting heterostructures for optical-related applications
journal, January 2019
- Yue, Shiyu; Li, Luyao; McGuire, Scott C.
- Energy & Environmental Science, Vol. 12, Issue 5
LSPR effects in a magnetic–luminescent heterostructure for efficient enhanced luminescence performance
journal, January 2019
- Peng, Hongxia; He, Yi; Tian, Xiuying
- New Journal of Chemistry, Vol. 43, Issue 1
Novel sol–gel fabrication of Yb 3+ /Tm 3+ co-doped β-NaYF 4 thin films and investigation of their upconversion properties
journal, January 2018
- Pellegrino, Anna L.; Catalano, Maria R.; Cortelletti, Paolo
- Photochemical & Photobiological Sciences, Vol. 17, Issue 9