Magnetostriction-driven ground-state stabilization in 2H perovskites

Porter, D. G.; Senn, M. S.; Khalyavin, D. D.; Cortese, A.; Waterfield-Price, N.; Radaelli, P. G.; Manuel, P.; zur-Loye, H. -C.; Mazzoli, C.; Bombardi, A.

doi:10.1103/PhysRevB.94.134404

Title: Magnetostriction-driven ground-state stabilization in 2H perovskites

Abstract

In this paper, the magnetic ground state of Sr₃ARuO₆, with A =(Li,Na), is studied using neutron diffraction, resonant x-ray scattering, and laboratory characterization measurements of high-quality crystals. Combining these results allows us to observe the onset of long-range magnetic order and distinguish the symmetrically allowed magnetic models, identifying in-plane antiferromagnetic moments and a small ferromagnetic component along the c axis. While the existence of magnetic domains masks the particular in-plane direction of the moments, it has been possible to elucidate the ground state using symmetry considerations. We find that due to the lack of local anisotropy, antisymmetric exchange interactions control the magnetic order, first through structural distortions that couple to in-plane antiferromagnetic moments and second through a high-order magnetoelastic coupling that lifts the degeneracy of the in-plane moments. Finally, the symmetry considerations used to rationalize the magnetic ground state are very general and will apply to many systems in this family, such as Ca₃ARuO₆, with A = (Li,Na), and Ca₃LiOsO₆ whose magnetic ground states are still not completely understood.

Authors:

Porter, D. G. ^[1]; Senn, M. S. ^[2]; Khalyavin, D. D. ^[3]; Cortese, A. ^[4]; Waterfield-Price, N. ^[5]; Radaelli, P. G. ^[6]; Manuel, P. ^[3]; zur-Loye, H. -C. ^[4]; Mazzoli, C. ^[7]; Bombardi, A. ^[5]

Harwell Science and Innovation Campus, Didcot (United Kingdom). Diamond Light Source Ltd.
Harwell Science and Innovation Campus, Didcot (United Kingdom). Diamond Light Source Ltd.; Univ. of Oxford (United Kingdom). Inorganic Chemistry Lab.
Science and Technology Facilities Council (STFC), Chilton (United Kingdom). Rutherford Appleton Lab. (RAL). ISIS Facility
Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemistry and Biochemistry
Harwell Science and Innovation Campus, Didcot (United Kingdom). Diamond Light Source Ltd.; Univ. of Oxford (United Kingdom). Dept. of Physics
Univ. of Oxford (United Kingdom). Dept. of Physics
Polytechnic Univ. of Milan (Italy). Dept. of Physics; Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II

Publication Date:: Tue Oct 04 00:00:00 EDT 2016

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Harwell Science and Innovation Campus, Didcot (United Kingdom); Univ. of Oxford (United Kingdom)

Sponsoring Org.:: USDOE; National Science Foundation (NSF); European Union (EU)

Contributing Org.:: Science and Technology Facilities Council (STFC), Chilton (United Kingdom); Univ. of South Carolina, Columbia, SC (United States); Polytechnic Univ. of Milan (Italy)

OSTI Identifier:: 1341642

Report Number(s):: BNL-113361-2016-JA
Journal ID: ISSN 2469-9950; TRN: US1701578

Grant/Contract Number:: SC0012704; DMR-1301757; 645660

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review. B

Additional Journal Information:: Journal Volume: 94; Journal Issue: 13; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Porter, D. G., Senn, M. S., Khalyavin, D. D., Cortese, A., Waterfield-Price, N., Radaelli, P. G., Manuel, P., zur-Loye, H. -C., Mazzoli, C., and Bombardi, A. Magnetostriction-driven ground-state stabilization in 2H perovskites.  United States: N. p., 2016. 
Web.  doi:10.1103/PhysRevB.94.134404.

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                    Porter, D. G., Senn, M. S., Khalyavin, D. D., Cortese, A., Waterfield-Price, N., Radaelli, P. G., Manuel, P., zur-Loye, H. -C., Mazzoli, C., & Bombardi, A. Magnetostriction-driven ground-state stabilization in 2H perovskites.  United States.  https://doi.org/10.1103/PhysRevB.94.134404

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                    Porter, D. G., Senn, M. S., Khalyavin, D. D., Cortese, A., Waterfield-Price, N., Radaelli, P. G., Manuel, P., zur-Loye, H. -C., Mazzoli, C., and Bombardi, A. Tue .  
"Magnetostriction-driven ground-state stabilization in 2H perovskites".  United States.  https://doi.org/10.1103/PhysRevB.94.134404.  https://www.osti.gov/servlets/purl/1341642.

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@article{osti_1341642,

  title        = {Magnetostriction-driven ground-state stabilization in 2H perovskites},

  author       = {Porter, D. G. and Senn, M. S. and Khalyavin, D. D. and Cortese, A. and Waterfield-Price, N. and Radaelli, P. G. and Manuel, P. and zur-Loye, H. -C. and Mazzoli, C. and Bombardi, A.},

  abstractNote = {In this paper, the magnetic ground state of Sr3ARuO6, with A =(Li,Na), is studied using neutron diffraction, resonant x-ray scattering, and laboratory characterization measurements of high-quality crystals. Combining these results allows us to observe the onset of long-range magnetic order and distinguish the symmetrically allowed magnetic models, identifying in-plane antiferromagnetic moments and a small ferromagnetic component along the c axis. While the existence of magnetic domains masks the particular in-plane direction of the moments, it has been possible to elucidate the ground state using symmetry considerations. We find that due to the lack of local anisotropy, antisymmetric exchange interactions control the magnetic order, first through structural distortions that couple to in-plane antiferromagnetic moments and second through a high-order magnetoelastic coupling that lifts the degeneracy of the in-plane moments. Finally, the symmetry considerations used to rationalize the magnetic ground state are very general and will apply to many systems in this family, such as Ca3ARuO6, with A = (Li,Na), and Ca3LiOsO6 whose magnetic ground states are still not completely understood.},

  doi          = {10.1103/PhysRevB.94.134404},

  journal      = {Physical Review. B},

  number       = 13,

  volume       = 94,

  place        = {United States},

  year         = {Tue Oct 04 00:00:00 EDT 2016},

  month        = {Tue Oct 04 00:00:00 EDT 2016}

}

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Title: Magnetostriction-driven ground-state stabilization in 2H perovskites

Abstract

Citation Formats

X-ray Resonant Exchange Scattering: Polariztaion Dependence and Correlation Function journal, March 1996

Ferroelectricity in an Ising Chain Magnet journal, January 2008

High temperature flux growth, structural characterization, and magnetic properties of Ca3.15Li0.85IrO6, Sr3LiIrO6, Ca3LiRuO6 and Sr3LiRuO6 journal, March 2003

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Na Os O 3 : A high Neel temperature 5 d oxide journal, April 2014

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X-ray Resonant Exchange Scattering: Polariztaion Dependence and Correlation Function
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Ferroelectricity in an Ising Chain Magnet
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High temperature flux growth, structural characterization, and magnetic properties of Ca3.15Li0.85IrO6, Sr3LiIrO6, Ca3LiRuO6 and Sr3LiRuO6
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Refinement of obverse/reverse twins
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Diamond Beamline I16 (Materials & Magnetism)
conference, January 2010

Synthesis, crystal structure and magnetic properties of A3A′RuO6 (A = Ca, Sr; A′ = Li, Na)
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journal, May 2011

Magnetic structure of an incommensurate phase of La-doped ${BiFe}_{0.5} {Sc}_{0.5} O_{3}$ : Role of antisymmetric exchange interactions
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ISODISPLACE : a web-based tool for exploring structural distortions
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2H-perovskite related oxides: Synthesis, structures, and predictions
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Crystal Growth and Structure and Magnetic Properties of the 5d Oxide Ca ₃ LiOsO ₆ : Extended Superexchange Magnetic Interaction in Oxide
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