Dynamic Scaling and Island Growth Kinetics in Pulsed Laser Deposition of
Abstract
We use real-time diffuse surface x-ray diffraction to probe the evolution of island size distributions and its effects on surface smoothing in pulsed laser deposition (PLD) of SrTiO3. We show that the island size evolution obeys dynamic scaling and two distinct regimes of island growth kinetics. Our data show that PLD film growth can persist without roughening despite thermally driven Ostwald ripening, the main mechanism for surface smoothing, being shut down. The absence of roughening is concomitant with decreasing island density, contradicting the prevailing view that increasing island density is the key to surface smoothing in PLD. We also report a previously unobserved crossover from diffusion-limited to attachment-limited island growth that reveals the influence of nonequilibrium atomic level surface transport processes on the growth modes in PLD. We show by direct measurements that attachment-limited island growth is the dominant process in PLD that creates step flowlike behavior or quasistep flow as PLD “self-organizes” local step flow on a length scale consistent with the substrate temperature and PLD parameters.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS) and X-Ray Science Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
- (BNL), Upton, NY (United States). Photon Sciences Division
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1341531
- Alternate Identifier(s):
- OSTI ID: 1331836; OSTI ID: 1393457
- Grant/Contract Number:
- AC05-00OR22725; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Letters
- Additional Journal Information:
- Journal Volume: 117; Journal Issue: 20; Journal ID: ISSN 0031-9007
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; pulsed laser deposition; surface x-ray diffraction; island growth; quasi step flow
Citation Formats
Eres, Gyula, Tischler, J. Z., Rouleau, C. M., Lee, Ho Nyung, Christen, H. M., Zschack, P., Brookhaven National Lab., and Larson, B. C. Dynamic Scaling and Island Growth Kinetics in Pulsed Laser Deposition of SrTiO3. United States: N. p., 2016.
Web. doi:10.1103/PhysRevLett.117.206102.
Eres, Gyula, Tischler, J. Z., Rouleau, C. M., Lee, Ho Nyung, Christen, H. M., Zschack, P., Brookhaven National Lab., & Larson, B. C. Dynamic Scaling and Island Growth Kinetics in Pulsed Laser Deposition of SrTiO3. United States. https://doi.org/10.1103/PhysRevLett.117.206102
Eres, Gyula, Tischler, J. Z., Rouleau, C. M., Lee, Ho Nyung, Christen, H. M., Zschack, P., Brookhaven National Lab., and Larson, B. C. Fri .
"Dynamic Scaling and Island Growth Kinetics in Pulsed Laser Deposition of SrTiO3". United States. https://doi.org/10.1103/PhysRevLett.117.206102. https://www.osti.gov/servlets/purl/1341531.
@article{osti_1341531,
title = {Dynamic Scaling and Island Growth Kinetics in Pulsed Laser Deposition of SrTiO3},
author = {Eres, Gyula and Tischler, J. Z. and Rouleau, C. M. and Lee, Ho Nyung and Christen, H. M. and Zschack, P. and Brookhaven National Lab. and Larson, B. C.},
abstractNote = {We use real-time diffuse surface x-ray diffraction to probe the evolution of island size distributions and its effects on surface smoothing in pulsed laser deposition (PLD) of SrTiO3. We show that the island size evolution obeys dynamic scaling and two distinct regimes of island growth kinetics. Our data show that PLD film growth can persist without roughening despite thermally driven Ostwald ripening, the main mechanism for surface smoothing, being shut down. The absence of roughening is concomitant with decreasing island density, contradicting the prevailing view that increasing island density is the key to surface smoothing in PLD. We also report a previously unobserved crossover from diffusion-limited to attachment-limited island growth that reveals the influence of nonequilibrium atomic level surface transport processes on the growth modes in PLD. We show by direct measurements that attachment-limited island growth is the dominant process in PLD that creates step flowlike behavior or quasistep flow as PLD “self-organizes” local step flow on a length scale consistent with the substrate temperature and PLD parameters.},
doi = {10.1103/PhysRevLett.117.206102},
journal = {Physical Review Letters},
number = 20,
volume = 117,
place = {United States},
year = {Fri Nov 11 00:00:00 EST 2016},
month = {Fri Nov 11 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Energetic Surface Smoothing of Complex Metal-Oxide Thin Films
journal, May 2006
- Willmott, P. R.; Herger, R.; Schlepütz, C. M.
- Physical Review Letters, Vol. 96, Issue 17
Epitaxial growth with pulsed deposition: Submonolayer scaling and Villain instability
journal, January 2003
- Hinnemann, Berit; Hinrichsen, Haye; Wolf, Dietrich E.
- Physical Review E, Vol. 67, Issue 1
Dynamic Scaling for Aggregation of Clusters
journal, May 1984
- Vicsek, Tamás; Family, Fereydoon
- Physical Review Letters, Vol. 52, Issue 19
High Island Densities in Pulsed Laser Deposition: Causes and Implications
journal, August 2009
- Schmid, M.; Lenauer, C.; Buchsbaum, A.
- Physical Review Letters, Vol. 103, Issue 7
Interlayer Mass Transport in Homoepitaxial and Heteroepitaxial Metal Growth
journal, July 1995
- Bromann, Karsten; Brune, Harald; Röder, Holger
- Physical Review Letters, Vol. 75, Issue 4
Steps on surfaces: experiment and theory
journal, September 1999
- Jeong, Hyeong-Chai; Williams, Ellen D.
- Surface Science Reports, Vol. 34, Issue 6-8
Nonequilibrium Interlayer Transport in Pulsed Laser Deposition
journal, June 2006
- Tischler, J. Z.; Eres, Gyula; Larson, B. C.
- Physical Review Letters, Vol. 96, Issue 22
Atomistic Processes in the Early Stages of Thin-Film Growth
journal, April 1997
- Zhang, Z.
- Science, Vol. 276, Issue 5311
Ostwald ripening of two-dimensional islands on Si(001)
journal, October 1996
- Bartelt, N. C.; Theis, W.; Tromp, R. M.
- Physical Review B, Vol. 54, Issue 16
Critical island size for layer-by-layer growth
journal, January 1994
- Tersoff, J.; Denier van der Gon, A. W.; Tromp, R. M.
- Physical Review Letters, Vol. 72, Issue 2
Kinetic and Monte Carlo models of thin film coarsening: Cross over from diffusion-coalescence to Ostwald growth modes
journal, January 2000
- Lo, Alan; Skodje, Rex T.
- The Journal of Chemical Physics, Vol. 112, Issue 4
Ostwald ripening of two-dimensional homoepitaxial islands
journal, July 2005
- Haußer, Frank; Voigt, Axel
- Physical Review B, Vol. 72, Issue 3
Kinetic pathways leading to layer-by-layer growth from hyperthermal atoms: A multibillion time step molecular dynamics study
journal, September 2007
- Adamović, D.; Chirita, V.; Münger, E. P.
- Physical Review B, Vol. 76, Issue 11
Measurements of Surface Diffusivity and Coarsening during Pulsed Laser Deposition
journal, December 2009
- Ferguson, J. D.; Arikan, G.; Dale, D. S.
- Physical Review Letters, Vol. 103, Issue 25
Emergent phenomena at oxide interfaces
journal, January 2012
- Hwang, H. Y.; Iwasa, Y.; Kawasaki, M.
- Nature Materials, Vol. 11, Issue 2
Persistent Step-Flow Growth of Strained Films on Vicinal Substrates
journal, August 2005
- Hong, Wei; Lee, Ho Nyung; Yoon, Mina
- Physical Review Letters, Vol. 95, Issue 9
Kinetic-energy induced smoothening and delay of epitaxial breakdown in pulsed-laser deposition
journal, August 2007
- Shin, Byungha; Aziz, Michael J.
- Physical Review B, Vol. 76, Issue 8
Initial Stages of Thin Film Growth in the Presence of Island-Edge Barriers
journal, January 1997
- Kandel, Daniel
- Physical Review Letters, Vol. 78, Issue 3
Quantitative determination of energy enhanced interlayer transport in pulsed laser deposition of SrTiO
journal, November 2011
- Eres, Gyula; Tischler, J. Z.; Rouleau, C. M.
- Physical Review B, Vol. 84, Issue 19
How “Hot Precursors” Modify Island Nucleation: A Rate-Equation Model
journal, December 2014
- Morales-Cifuentes, Josue R.; Einstein, T. L.; Pimpinelli, A.
- Physical Review Letters, Vol. 113, Issue 24
Capture numbers in the presence of repulsive adsorbate interactions
journal, November 2002
- Venables, J. A.; Brune, H.
- Physical Review B, Vol. 66, Issue 19
Time-resolved study of SrTiO3 homoepitaxial pulsed-laser deposition using surface x-ray diffraction
journal, May 2002
- Eres, G.; Tischler, J. Z.; Yoon, M.
- Applied Physics Letters, Vol. 80, Issue 18
Recent advances in pulsed-laser deposition of complex oxides
journal, June 2008
- Christen, H. M.; Eres, G.
- Journal of Physics: Condensed Matter, Vol. 20, Issue 26
Role of Cluster Transient Mobility in Pulsed Laser Deposition-Type Growth Kinetics
journal, January 2007
- Vasco, E.; Sacedón, J. L.
- Physical Review Letters, Vol. 98, Issue 3
Works referencing / citing this record:
Picoscale materials engineering
journal, September 2017
- Ismail-Beigi, Sohrab; Walker, Frederick J.; Disa, Ankit S.
- Nature Reviews Materials, Vol. 2, Issue 11
In situ growth of ultra-smooth or super-rough thin films by suppression of vertical or horizontal growth of surface mounds
journal, January 2020
- Hu, Chaoquan; Cai, Jize; Li, Yuankai
- Journal of Materials Chemistry C, Vol. 8, Issue 9
Experimental setup combining in situ hard X-ray photoelectron spectroscopy and real-time surface X-ray diffraction for characterizing atomic and electronic structure evolution during complex oxide heterostructure growth
journal, September 2019
- Eres, Gyula; Rouleau, C. M.; Lu, Q.
- Review of Scientific Instruments, Vol. 90, Issue 9