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Title: Local structural effects in Sr 3NiRhO 6 across magnetic transitions

Here, we investigate the temperature dependence of the structural parameters of quasi-one-dimensional Sr 3NiRhO 6 across the region of magnetic phase transitions using Ni K-edge and Sr K-edge x-ray absorption spectroscopy (XAS). The features in the x-ray absorption near-edge region are identified using multiple scattering calculations. The temperature-dependent extended x-ray absorption fine structure (EXAFS) studies show that the setting of the intra-chain super exchange interaction starts at ~200 K, which is well above the first transition temperature (45 K) revealed by magnetic susceptibility studies. The onset of the inter-chain super–super exchange interaction appears to be at ~125 K. Interestingly, the role played by direct exchange interaction between the Ni 3d and Rh 4d states in stabilising the magnetic interaction is less significant. The present results shed light on the generic features exhibited by isostructural compounds and may help in identifying the magnetic exchange pathways useful for understanding the unusual properties exhibited by such compounds.
Authors:
 [1] ;  [2] ;  [1]
  1. Indian Institute of Technology Mandi, Himachal Pradesh (India)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Report Number(s):
BNL-108435-2015-JA
Journal ID: ISSN 2053-1591; R&D Project: LS001
Grant/Contract Number:
SC00112704
Type:
Accepted Manuscript
Journal Name:
Materials Research Express (Online)
Additional Journal Information:
Journal Name: Materials Research Express (Online); Journal Volume: 3; Journal Issue: 4; Journal ID: ISSN 2053-1591
Publisher:
IOP Publishing
Research Org:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; quasi-one-dimensional system; x-ray absorption spectroscopy; strongly correlated electron systems
OSTI Identifier:
1341505

Singh, Navneet, Khalid, S., and Bindu, R.. Local structural effects in Sr3NiRhO6 across magnetic transitions. United States: N. p., Web. doi:10.1088/2053-1591/3/4/046301.
Singh, Navneet, Khalid, S., & Bindu, R.. Local structural effects in Sr3NiRhO6 across magnetic transitions. United States. doi:10.1088/2053-1591/3/4/046301.
Singh, Navneet, Khalid, S., and Bindu, R.. 2016. "Local structural effects in Sr3NiRhO6 across magnetic transitions". United States. doi:10.1088/2053-1591/3/4/046301. https://www.osti.gov/servlets/purl/1341505.
@article{osti_1341505,
title = {Local structural effects in Sr3NiRhO6 across magnetic transitions},
author = {Singh, Navneet and Khalid, S. and Bindu, R.},
abstractNote = {Here, we investigate the temperature dependence of the structural parameters of quasi-one-dimensional Sr3NiRhO6 across the region of magnetic phase transitions using Ni K-edge and Sr K-edge x-ray absorption spectroscopy (XAS). The features in the x-ray absorption near-edge region are identified using multiple scattering calculations. The temperature-dependent extended x-ray absorption fine structure (EXAFS) studies show that the setting of the intra-chain super exchange interaction starts at ~200 K, which is well above the first transition temperature (45 K) revealed by magnetic susceptibility studies. The onset of the inter-chain super–super exchange interaction appears to be at ~125 K. Interestingly, the role played by direct exchange interaction between the Ni 3d and Rh 4d states in stabilising the magnetic interaction is less significant. The present results shed light on the generic features exhibited by isostructural compounds and may help in identifying the magnetic exchange pathways useful for understanding the unusual properties exhibited by such compounds.},
doi = {10.1088/2053-1591/3/4/046301},
journal = {Materials Research Express (Online)},
number = 4,
volume = 3,
place = {United States},
year = {2016},
month = {4}
}