Thermodynamics of manganese oxides: Sodium, potassium, and calcium birnessite and cryptomelane

Birkner, Nancy; Navrotsky, Alexandra

doi:10.1073/pnas.1620427114

Title: Thermodynamics of manganese oxides: Sodium, potassium, and calcium birnessite and cryptomelane

Journal Article · 27 January 2017 · Proceedings of the National Academy of Sciences of the United States of America

DOI: https://doi.org/10.1073/pnas.1620427114 · OSTI ID:1341471

Birkner, Nancy ^[1]; Navrotsky, Alexandra ^[2]

Peter A. Rock Thermochemistry Laboratory, University of California, Davis, CA 95616,, Nanomaterials in the Environment, Agriculture, and Technology, University of California, Davis, CA 95616,, Pratt School of Engineering, Duke University, Durham NC 27708
Peter A. Rock Thermochemistry Laboratory, University of California, Davis, CA 95616,, Nanomaterials in the Environment, Agriculture, and Technology, University of California, Davis, CA 95616,

Significance Manganese oxides with layer and tunnel structures occur widely in the natural environment and inspire technological applications. In addition to having variable compositions, these structures often are found as small particles (nanophases). This study explores, using experimental thermochemistry, the role of composition, oxidation state, structure, and surface energy in the thermodynamic stability of synthetic birnessites and cryptomelane. These quantitative thermodynamic findings help explain and support qualitative observations of phase-transformation patterns gathered over the past five decades.

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Research Organization:: Univ. of California, Davis, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: FG02-97ER14749

OSTI ID:: 1341471

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Issue: 7 Vol. 114; ISSN 0027-8424

Publisher:: Proceedings of the National Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
birnessite
calorimetry
cryptomelane
manganese oxides
thermodynamics

Title: Thermodynamics of manganese oxides: Sodium, potassium, and calcium birnessite and cryptomelane

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