Stress-induced charge-ordering process in LiMn 2 O 4

Chen, Yan; Yu, Dunji; An, Ke

doi:10.1080/21663831.2016.1197858

Title: Stress-induced charge-ordering process in LiMn ₂ O ₄

Abstract

In this letter we report the stress-induced Mn charge-ordering process in the LiMn₂O₄ spinel, evidenced by the lattice strain evolutions due to the Jahn–Teller effects. In situ neutron diffraction reveals the initial stage of this process at low stress, indicating the eg electron localization at the preferential Mn sites during the early phase transition as an underlying charge-ordering mechanism in the charge-frustrated LiMn₂O₄. The initial stage of this transition exhibits as a progressive lattice and charge evolution, without showing a first-order behavior.

Authors:

Chen, Yan ^[1]; Yu, Dunji ^[2]; An, Ke ^[1]

Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, TN, USA
Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, TN, USA, School of Chemical Engineering and Technology, Tianjin University, Tianjin, People’s Republic of China

Publication Date:: Mon Jul 25 00:00:00 EDT 2016

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1510148

Alternate Identifier(s):: OSTI ID: 1340435

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Published Article

Journal Name:: Materials Research Letters

Additional Journal Information:: Journal Name: Materials Research Letters Journal Volume: 5 Journal Issue: 2; Journal ID: ISSN 2166-3831

Publisher:: Informa UK Limited

Country of Publication:: United Kingdom

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Chen, Yan, Yu, Dunji, and An, Ke. Stress-induced charge-ordering process in LiMn 2 O 4.  United Kingdom: N. p., 2016. 
Web.  doi:10.1080/21663831.2016.1197858.

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                    Chen, Yan, Yu, Dunji, & An, Ke. Stress-induced charge-ordering process in LiMn 2 O 4.  United Kingdom.  https://doi.org/10.1080/21663831.2016.1197858

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                    Chen, Yan, Yu, Dunji, and An, Ke. Mon .  
"Stress-induced charge-ordering process in LiMn 2 O 4".  United Kingdom.  https://doi.org/10.1080/21663831.2016.1197858.

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@article{osti_1510148,

  title        = {Stress-induced charge-ordering process in LiMn 2 O 4},

  author       = {Chen, Yan and Yu, Dunji and An, Ke},

  abstractNote = {In this letter we report the stress-induced Mn charge-ordering process in the LiMn2O4 spinel, evidenced by the lattice strain evolutions due to the Jahn–Teller effects. In situ neutron diffraction reveals the initial stage of this process at low stress, indicating the eg electron localization at the preferential Mn sites during the early phase transition as an underlying charge-ordering mechanism in the charge-frustrated LiMn2O4. The initial stage of this transition exhibits as a progressive lattice and charge evolution, without showing a first-order behavior.},

  doi          = {10.1080/21663831.2016.1197858},

  journal      = {Materials Research Letters},

  number       = 2,

  volume       = 5,

  place        = {United Kingdom},

  year         = {Mon Jul 25 00:00:00 EDT 2016},

  month        = {Mon Jul 25 00:00:00 EDT 2016}

}

Copy to clipboard

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Figures / Tables:

Figure 1.: A schematic illustration of the in situ loading setup and the loading curve. The nonlinear loading curve with a large displacement includes the process of powder close packing. The nearly linear unloading curve presents the elastic deformation reversion, but the displacement is not fully recovered.

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Works referencing / citing this record:

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Title: Stress-induced charge-ordering process in LiMn 2 O 4

Abstract

Citation Formats

Figures / Tables:

LiMn 2 O 4 low-temperature phase: synchrotron and neutron diffraction study journal, December 1999

The charge order transition and elastic/anelastic properties of LiMn 2 O 4 journal, January 2003

Revealing the cyclic hardening mechanism of an austenitic stainless steel by real-time in situ neutron diffraction journal, October 2014

Stabilization of an orthorhombic phase in LiMnO by means of high pressure journal, February 2005

Issues and challenges facing rechargeable lithium batteries journal, November 2001

Electronic Crystallization in a Lithium Battery Material: Columnar Ordering of Electrons and Holes in the Spinel LiMn 2 O 4 journal, November 1998

EXPGUI , a graphical user interface for GSAS journal, April 2001

First In Situ Lattice Strains Measurements Under Load at VULCAN journal, October 2010

Local Lattice Distortion Caused by Short Range Charge Ordering in LiMn 2 O 4 journal, September 2013

Electrical transport properties in LiMn 2 O 4 journal, July 1998

Visualizing the Structural Evolution of LSM/xYSZ Composite Cathodes for SOFC by in-situ Neutron Diffraction journal, June 2014

A study of suppressed formation of low-conductivity phases in doped Li 7 La 3 Zr 2 O 12 garnets by in situ neutron diffraction journal, January 2015

Investigation of deformation dynamics in a wrought magnesium alloy journal, November 2014

High-pressure metaelastic properties of LixMn3−xO4 (x = 0.87, 0.94, 1.00) journal, January 2008

Lithium insertion into manganese spinels journal, April 1983

Magnetic properties of the chemically delithiated LixMn2O4 with 0.07≤x≤1 journal, May 2011

Interrelationship between Li + diffusion, charge, and magnetism in Li 7 Mn 2 O 4 and Li 7 1.1 Mn 1.9 O 4 spinels: Elastic, inelastic, and quasielastic neutron scattering journal, March 2011

Charge order and three-site distortions in the Verwey structure of magnetite journal, December 2011

Electrodes for lithium batteries journal, March 1993

Charge and spin ordering in LiMn 2 O 4 journal, August 2001

In-situ neutron diffraction of LaCoO 3 perovskite under uniaxial compression. I. Crystal structure analysis and texture development journal, July 2014

Low-Temperature Structure and Magnetic Properties of the Spinel LiMn 2 O 4 : A Frustrated Antiferromagnet and Cathode Material journal, June 1999

Jahn-Teller structural phase transition around 280K in LiMn2O4 journal, June 1995

Phase-specific deformation behavior of a relatively tough NiAl–Cr(Mo) lamellar composite journal, August 2014

A first-principles study on phase transition induced by charge ordering of in spinel journal, August 2010

Bond-length fluctuation in the orthorhombic 3 x 3 x 1 superstructure of LiMn2O4 spinel journal, August 2014

X-ray Study of the Spinel LiMn 2 O 4 at Low Temperatures journal, December 1999

Electronic Conduction of Magnetite (Fe3O4) and its Transition Point at Low Temperatures journal, August 1939

Porous Carbon-Based Nanocomposites Containing Fe2P Nanoparticles as Promising Materials for Supercapacitor Electrodes journal, November 2019

Tracing Phase Transformation and Lattice Evolution in a TRIP Sheet Steel under High-Temperature Annealing by Real-Time In Situ Neutron Diffraction journal, September 2018

Title: Stress-induced charge-ordering process in LiMn ₂ O ₄

LiMn ₂ O ₄ low-temperature phase: synchrotron and neutron diffraction study
journal, December 1999

The charge order transition and elastic/anelastic properties of LiMn ₂ O ₄
journal, January 2003

Revealing the cyclic hardening mechanism of an austenitic stainless steel by real-time in situ neutron diffraction
journal, October 2014

Stabilization of an orthorhombic phase in LiMnO by means of high pressure
journal, February 2005

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

Electronic Crystallization in a Lithium Battery Material: Columnar Ordering of Electrons and Holes in the Spinel ${LiMn}_{2} O_{4}$
journal, November 1998

EXPGUI , a graphical user interface for GSAS
journal, April 2001

First In Situ Lattice Strains Measurements Under Load at VULCAN
journal, October 2010

Local Lattice Distortion Caused by Short Range Charge Ordering in LiMn ₂ O ₄
journal, September 2013

Electrical transport properties in LiMn ₂ O ₄
journal, July 1998

Visualizing the Structural Evolution of LSM/xYSZ Composite Cathodes for SOFC by in-situ Neutron Diffraction
journal, June 2014

A study of suppressed formation of low-conductivity phases in doped Li ₇ La ₃ Zr ₂ O ₁₂ garnets by in situ neutron diffraction
journal, January 2015

Investigation of deformation dynamics in a wrought magnesium alloy
journal, November 2014

High-pressure metaelastic properties of LixMn3−xO4 (x = 0.87, 0.94, 1.00)
journal, January 2008

Lithium insertion into manganese spinels
journal, April 1983

Magnetic properties of the chemically delithiated LixMn2O4 with 0.07≤x≤1
journal, May 2011

Interrelationship between Li $^{+}$ diffusion, charge, and magnetism in ${}^{7}{Li}$ Mn $_{2}$ O $_{4}$ and ${}^{7}{Li}$ $_{1.1}$ Mn $_{1.9}$ O $_{4}$ spinels: Elastic, inelastic, and quasielastic neutron scattering
journal, March 2011

Charge order and three-site distortions in the Verwey structure of magnetite
journal, December 2011

Electrodes for lithium batteries
journal, March 1993

Charge and spin ordering in ${LiMn}_{2} O_{4}$
journal, August 2001

In-situ neutron diffraction of LaCoO ₃ perovskite under uniaxial compression. I. Crystal structure analysis and texture development
journal, July 2014

Low-Temperature Structure and Magnetic Properties of the Spinel LiMn ₂ O ₄ : A Frustrated Antiferromagnet and Cathode Material
journal, June 1999

Jahn-Teller structural phase transition around 280K in LiMn2O4
journal, June 1995

Phase-specific deformation behavior of a relatively tough NiAl–Cr(Mo) lamellar composite
journal, August 2014

A first-principles study on phase transition induced by charge ordering of in spinel
journal, August 2010

Bond-length fluctuation in the orthorhombic 3 x 3 x 1 superstructure of LiMn2O4 spinel
journal, August 2014

X-ray Study of the Spinel LiMn ₂ O ₄ at Low Temperatures
journal, December 1999

Electronic Conduction of Magnetite (Fe3O4) and its Transition Point at Low Temperatures
journal, August 1939

Porous Carbon-Based Nanocomposites Containing Fe2P Nanoparticles as Promising Materials for Supercapacitor Electrodes
journal, November 2019

Tracing Phase Transformation and Lattice Evolution in a TRIP Sheet Steel under High-Temperature Annealing by Real-Time In Situ Neutron Diffraction
journal, September 2018