Transition metal dissolution, ion migration, electrocatalytic reduction and capacity loss in Lithium-ion full cells
Abstract
Continuous operation of full cells with layered transition metal (TM) oxide positive electrodes (NCM523) leads to dissolution of TM ions and their migration and incorporation into the solid electrolyte interphase (SEI) of the graphite-based negative electrode. These processes correlate with cell capacity fade and accelerate markedly as the upper cutoff voltage (UCV) exceeds 4.30 V. At voltages ≥ 4.4 V there is enhanced fracture of the oxide during cycling that creates new surfaces and causes increased solvent oxidation and TM dissolution. Despite this deterioration, cell capacity fade still mainly results from lithium loss in the negative electrode SEI. Among TMs, Mn content in the SEI shows a better correlation with cell capacity loss than Co and Ni contents. As Mn ions become incorporated into the SEI, the kinetics of lithium trapping change from power to linear at the higher UCVs, indicating a large effect of these ions on SEI growth and implicating (electro)catalytic reactions. Lastly, we estimate that each MnII ion deposited in the SEI causes trapping of ~102 additional Li+ ions thereby hastening the depletion of cyclable lithium ions. Using these results, we sketch a mechanism for cell capacity fade, emphasizing the conceptual picture over the chemical detail.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1339642
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 164; Journal Issue: 2; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; NCA; NCM523 oxide; SEI; electrochemistry; graphite; high voltage; layered oxides; manganese; nickel
Citation Formats
Gilbert, James A., Shkrob, Ilya A., and Abraham, Daniel P. Transition metal dissolution, ion migration, electrocatalytic reduction and capacity loss in Lithium-ion full cells. United States: N. p., 2017.
Web. doi:10.1149/2.1111702jes.
Gilbert, James A., Shkrob, Ilya A., & Abraham, Daniel P. Transition metal dissolution, ion migration, electrocatalytic reduction and capacity loss in Lithium-ion full cells. United States. https://doi.org/10.1149/2.1111702jes
Gilbert, James A., Shkrob, Ilya A., and Abraham, Daniel P. Thu .
"Transition metal dissolution, ion migration, electrocatalytic reduction and capacity loss in Lithium-ion full cells". United States. https://doi.org/10.1149/2.1111702jes. https://www.osti.gov/servlets/purl/1339642.
@article{osti_1339642,
title = {Transition metal dissolution, ion migration, electrocatalytic reduction and capacity loss in Lithium-ion full cells},
author = {Gilbert, James A. and Shkrob, Ilya A. and Abraham, Daniel P.},
abstractNote = {Continuous operation of full cells with layered transition metal (TM) oxide positive electrodes (NCM523) leads to dissolution of TM ions and their migration and incorporation into the solid electrolyte interphase (SEI) of the graphite-based negative electrode. These processes correlate with cell capacity fade and accelerate markedly as the upper cutoff voltage (UCV) exceeds 4.30 V. At voltages ≥ 4.4 V there is enhanced fracture of the oxide during cycling that creates new surfaces and causes increased solvent oxidation and TM dissolution. Despite this deterioration, cell capacity fade still mainly results from lithium loss in the negative electrode SEI. Among TMs, Mn content in the SEI shows a better correlation with cell capacity loss than Co and Ni contents. As Mn ions become incorporated into the SEI, the kinetics of lithium trapping change from power to linear at the higher UCVs, indicating a large effect of these ions on SEI growth and implicating (electro)catalytic reactions. Lastly, we estimate that each MnII ion deposited in the SEI causes trapping of ~102 additional Li+ ions thereby hastening the depletion of cyclable lithium ions. Using these results, we sketch a mechanism for cell capacity fade, emphasizing the conceptual picture over the chemical detail.},
doi = {10.1149/2.1111702jes},
journal = {Journal of the Electrochemical Society},
number = 2,
volume = 164,
place = {United States},
year = {2017},
month = {1}
}
Web of Science
Works referenced in this record:
Recent progress in cathode materials research for advanced lithium ion batteries
journal, May 2012
- Xu, Bo; Qian, Danna; Wang, Ziying
- Materials Science and Engineering: R: Reports, Vol. 73, Issue 5-6
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Layered Li[Ni[sub x]Co[sub 1−2x]Mn[sub x]]O[sub 2] Cathode Materials for Lithium-Ion Batteries
journal, January 2001
- Lu, Zhonghua; MacNeil, D. D.; Dahn, J. R.
- Electrochemical and Solid-State Letters, Vol. 4, Issue 12
Layered Lithium Insertion Material of LiNi 1/2 Mn 1/2 O 2 : A Possible Alternative to LiCoO 2 for Advanced Lithium-Ion Batteries
journal, August 2001
- Ohzuku, Tsutomu; Makimura, Yoshinari
- Chemistry Letters, Vol. 30, Issue 8
Fundamental degradation mechanisms of layered oxide Li-ion battery cathode materials: Methodology, insights and novel approaches
journal, February 2015
- Hausbrand, R.; Cherkashinin, G.; Ehrenberg, H.
- Materials Science and Engineering: B, Vol. 192
Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries
journal, August 2013
- Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun
- Advanced Energy Materials, Vol. 4, Issue 1
Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density
journal, January 2013
- Bettge, Martin; Li, Yan; Gallagher, Kevin
- Journal of The Electrochemical Society, Vol. 160, Issue 11
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010
- Verma, Pallavi; Maire, Pascal; Novák, Petr
- Electrochimica Acta, Vol. 55, Issue 22, p. 6332-6341
Li + -solvation/desolvation dictates interphasial processes on graphitic anode in Li ion cells
journal, August 2012
- Xu, Kang; von Wald Cresce, Arthur
- Journal of Materials Research, Vol. 27, Issue 18
Main aging mechanisms in Li ion batteries
journal, August 2005
- Broussely, M.; Biensan, Ph.; Bonhomme, F.
- Journal of Power Sources, Vol. 146, Issue 1-2
Failure Mechanism of Graphite/LiNi 0.5 Mn 1.5 O 4 Cells at High Voltage and Elevated Temperature
journal, January 2013
- Lu, Dongsheng; Xu, Mengqing; Zhou, Liu
- Journal of The Electrochemical Society, Vol. 160, Issue 5
Precision Measurements of the Coulombic Efficiency of Lithium-Ion Batteries and of Electrode Materials for Lithium-Ion Batteries
journal, January 2010
- Smith, A. J.; Burns, J. C.; Trussler, S.
- Journal of The Electrochemical Society, Vol. 157, Issue 2
Electrocatalysis Paradigm for Protection of Cathode Materials in High-Voltage Lithium-Ion Batteries
journal, July 2016
- Shkrob, Ilya A.; Abraham, Daniel P.
- The Journal of Physical Chemistry C, Vol. 120, Issue 28
First-Principles Modeling of the Initial Stages of Organic Solvent Decomposition on Li x Mn 2 O 4 (100) Surfaces
journal, April 2012
- Leung, Kevin
- The Journal of Physical Chemistry C, Vol. 116, Issue 18
Ageing mechanisms in lithium-ion batteries
journal, September 2005
- Vetter, J.; Novák, P.; Wagner, M. R.
- Journal of Power Sources, Vol. 147, Issue 1-2
Allotropic Control: How Certain Fluorinated Carbonate Electrolytes Protect Aluminum Current Collectors by Promoting the Formation of Insoluble Coordination Polymers
journal, August 2016
- Shkrob, Ilya A.; Pupek, Krzysztof Z.; Abraham, Daniel P.
- The Journal of Physical Chemistry C, Vol. 120, Issue 33
Current Collectors for Positive Electrodes of Lithium-Based Batteries
journal, January 2005
- Whitehead, Adam H.; Schreiber, Martha
- Journal of The Electrochemical Society, Vol. 152, Issue 11
Electrochemical behavior and passivation of current collectors in lithium-ion batteries
journal, January 2011
- Myung, Seung-Taek; Hitoshi, Yashiro; Sun, Yang-Kook
- Journal of Materials Chemistry, Vol. 21, Issue 27
Dissolution of Spinel Oxides and Capacity Losses in 4V Li / LixMn2O4 Cells
journal, January 1996
- Jang, Dong H.; Shin, Young J.; Oh, Seung M.
- Journal of The Electrochemical Society, Vol. 143, Issue 7, p. 2204-2211
Effect of Manganese Contamination on the Solid-Electrolyte-Interphase Properties in Li-Ion Batteries
journal, January 2013
- Delacourt, C.; Kwong, A.; Liu, X.
- Journal of The Electrochemical Society, Vol. 160, Issue 8
Multilayer electrolyte cell: A new tool for identifying electrochemical performances of high voltage cathode materials
journal, July 2013
- MahootcheianAsl, Nina; Kim, Jung-Hyun; Pieczonka, Nicholas P. W.
- Electrochemistry Communications, Vol. 32
Influence of manganese(II), cobalt(II), and nickel(II) additives in electrolyte on performance of graphite anode for lithium-ion batteries
journal, February 2002
- Komaba, Shinichi; Kumagai, Naoaki; Kataoka, Yoichi
- Electrochimica Acta, Vol. 47, Issue 8
Influence of Manganese Dissolution on the Degradation of Surface Films on Edge Plane Graphite Negative-Electrodes in Lithium-Ion Batteries
journal, January 2012
- Ochida, Manabu; Domi, Yasuhiro; Doi, Takayuki
- Journal of The Electrochemical Society, Vol. 159, Issue 7
Capacity Fading of Graphite Electrodes Due to the Deposition of Manganese Ions on Them in Li-Ion Batteries
journal, January 2002
- Tsunekawa, Hajime; Tanimoto,a, Satoshi; Marubayashi, Ryoji
- Journal of The Electrochemical Society, Vol. 149, Issue 10
Degradation of the solid electrolyte interphase induced by the deposition of manganese ions
journal, June 2015
- Shin, Hosop; Park, Jonghyun; Sastry, Ann Marie
- Journal of Power Sources, Vol. 284
Oxidation state of cross-over manganese species on the graphite electrode of lithium-ion cells
journal, January 2014
- Gowda, Sanketh R.; Gallagher, Kevin G.; Croy, Jason R.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 15
Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems
journal, September 2013
- Zhan, Chun; Lu, Jun; Jeremy Kropf, A.
- Nature Communications, Vol. 4, Issue 1
Manganese in Graphite Anode and Capacity Fade in Li Ion Batteries
journal, October 2014
- Shkrob, Ilya A.; Kropf, A. Jeremy; Marin, Timothy W.
- The Journal of Physical Chemistry C, Vol. 118, Issue 42
The Formation Mechanism of Fluorescent Metal Complexes at the Li x Ni 0.5 Mn 1.5 O 4−δ /Carbonate Ester Electrolyte Interface
journal, March 2015
- Jarry, Angélique; Gottis, Sébastien; Yu, Young-Sang
- Journal of the American Chemical Society, Vol. 137, Issue 10
Study of Mn dissolution from LiMn2O4 spinel electrodes using in situ total reflection X-ray fluorescence analysis and fluorescence XAFS technique
journal, July 2001
- Terada, Yasuko; Nishiwaki, Yoshinori; Nakai, Izumi
- Journal of Power Sources, Vol. 97-98
Cycling Behavior of NCM523/Graphite Lithium-Ion Cells in the 3–4.4 V Range: Diagnostic Studies of Full Cells and Harvested Electrodes
journal, September 2016
- Gilbert, James A.; Bareño, Javier; Spila, Timothy
- Journal of The Electrochemical Society, Vol. 164, Issue 1
Review—Post-Mortem Analysis of Aged Lithium-Ion Batteries: Disassembly Methodology and Physico-Chemical Analysis Techniques
journal, January 2016
- Waldmann, Thomas; Iturrondobeitia, Amaia; Kasper, Michael
- Journal of The Electrochemical Society, Vol. 163, Issue 10
A High Precision Coulometry Study of the SEI Growth in Li/Graphite Cells
journal, January 2011
- Smith, A. J.; Burns, J. C.; Zhao, Xuemei
- Journal of The Electrochemical Society, Vol. 158, Issue 5
Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime Prediction
journal, December 2012
- Pinson, Matthew B.; Bazant, Martin Z.
- Journal of The Electrochemical Society, Vol. 160, Issue 2
Aging mechanism in Li ion cells and calendar life predictions
journal, July 2001
- Broussely, M.; Herreyre, S.; Biensan, P.
- Journal of Power Sources, Vol. 97-98
Solvent Diffusion Model for Aging of Lithium-Ion Battery Cells
journal, January 2004
- Ploehn, Harry J.; Ramadass, Premanand; White, Ralph E.
- Journal of The Electrochemical Society, Vol. 151, Issue 3
Conduction in Polymers: Dynamic Disorder Transport
journal, February 1994
- Nitzan, Abraham; Ratner, Mark A.
- The Journal of Physical Chemistry, Vol. 98, Issue 7
Electrode Behavior RE-Visited: Monitoring Potential Windows, Capacity Loss, and Impedance Changes in Li 1.03 (Ni 0.5 Co 0.2 Mn 0.3 ) 0.97 O 2 /Silicon-Graphite Full Cells
journal, January 2016
- Klett, Matilda; Gilbert, James A.; Trask, Stephen E.
- Journal of The Electrochemical Society, Vol. 163, Issue 6
Differential voltage analyses of high-power, lithium-ion cells
journal, January 2005
- Bloom, Ira; Jansen, Andrew N.; Abraham, Daniel P.
- Journal of Power Sources, Vol. 139, Issue 1-2
Differential voltage analyses of high-power lithium-ion cells
journal, January 2005
- Bloom, Ira; Christophersen, Jon; Gering, Kevin
- Journal of Power Sources, Vol. 139, Issue 1-2
Differential voltage analyses of high-power lithium-ion cells
journal, June 2006
- Bloom, Ira; Christophersen, Jon P.; Abraham, Daniel P.
- Journal of Power Sources, Vol. 157, Issue 1
Long-Term Low-Rate Cycling of LiCoO 2 /Graphite Li-Ion Cells at 55°C
journal, January 2012
- Smith, A. J.; Dahn, Hannah M.; Burns, J. C.
- Journal of The Electrochemical Society, Vol. 159, Issue 6
Observation of Microstructural Evolution in Li Battery Cathode Oxide Particles by In Situ Electron Microscopy
journal, May 2013
- Miller, Dean J.; Proff, Christian; Wen, J. G.
- Advanced Energy Materials, Vol. 3, Issue 8
Microstructural Evolution in Transition-metal-oxide Cathode Materials for Lithium-Ion Batteries
journal, July 2016
- Miller, Dean J.; Sheng, Huaping; Wang, Lifen
- Microscopy and Microanalysis, Vol. 22, Issue S3
Understanding Transition-Metal Dissolution Behavior in LiNi 0.5 Mn 1.5 O 4 High-Voltage Spinel for Lithium Ion Batteries
journal, July 2013
- Pieczonka, Nicholas P. W.; Liu, Zhongyi; Lu, Peng
- The Journal of Physical Chemistry C, Vol. 117, Issue 31
Consequences of Electrolyte Degradation for the Electrochemical Performance of Li 1+x (Ni a Co b Mn 1-a-b ) 1-x O 2
journal, January 2015
- Peng, H. -J.; Urbonaite, S.; Villevieille, C.
- Journal of The Electrochemical Society, Vol. 162, Issue 13
First-Principles Modeling of Mn(II) Migration above and Dissolution from Li x Mn 2 O 4 (001) Surfaces
journal, November 2016
- Leung, Kevin
- Chemistry of Materials, Vol. 29, Issue 6
Microscopy and Spectroscopy of Lithium Nickel Oxide-Based Particles Used in High Power Lithium-Ion Cells
journal, January 2003
- Abraham, D. P.; Twesten, R. D.; Balasubramanian, M.
- Journal of The Electrochemical Society, Vol. 150, Issue 11
Surface changes on LiNi0.8Co0.2O2 particles during testing of high-power lithium-ion cells
journal, August 2002
- Abraham, D. P.; Twesten, R. D.; Balasubramanian, M.
- Electrochemistry Communications, Vol. 4, Issue 8
Reduction of Carbonate Electrolytes and the Formation of Solid-Electrolyte Interface (SEI) in Lithium-Ion Batteries. 1. Spectroscopic Observations of Radical Intermediates Generated in One-Electron Reduction of Carbonates
journal, September 2013
- Shkrob, Ilya A.; Zhu, Ye; Marin, Timothy W.
- The Journal of Physical Chemistry C, Vol. 117, Issue 38, p. 19255-19269
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004
- Xu, Kang
- Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418
Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014
- Xu, Kang
- Chemical Reviews, Vol. 114, Issue 23
Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy
journal, January 2013
- Nie, Mengyun; Chalasani, Dinesh; Abraham, Daniel P.
- The Journal of Physical Chemistry C, Vol. 117, Issue 3, p. 1257-1267
Reduction of Carbonate Electrolytes and the Formation of Solid-Electrolyte Interface (SEI) in Lithium-Ion Batteries. 2. Radiolytically Induced Polymerization of Ethylene Carbonate
journal, September 2013
- Shkrob, Ilya A.; Zhu, Ye; Marin, Timothy W.
- The Journal of Physical Chemistry C, Vol. 117, Issue 38, p. 19270-19279
Mass Spectrometry Investigations on Electrolyte Degradation Products for the Development of Nanocomposite Electrodes in Lithium Ion Batteries
journal, June 2006
- Gireaud, Laurent; Grugeon, Sylvie; Pilard, Serge
- Analytical Chemistry, Vol. 78, Issue 11
Deciphering the multi-step degradation mechanisms of carbonate-based electrolyte in Li batteries
journal, March 2008
- Gachot, Gregory; Grugeon, Sylvie; Armand, Michel
- Journal of Power Sources, Vol. 178, Issue 1
Identification of Li Battery Electrolyte Degradation Products Through Direct Synthesis and Characterization of Alkyl Carbonate Salts
journal, January 2005
- Gireaud, L.; Grugeon, S.; Laruelle, S.
- Journal of The Electrochemical Society, Vol. 152, Issue 5
Dynamics and morphology of solid electrolyte interphase (SEI)
journal, January 2016
- Single, Fabian; Horstmann, Birger; Latz, Arnulf
- Physical Chemistry Chemical Physics, Vol. 18, Issue 27
Failure and Stabilization Mechanisms of Graphite Electrodes
journal, March 1997
- Aurbach, Doron; Levi, Mikhail D.; Levi, Elena
- The Journal of Physical Chemistry B, Vol. 101, Issue 12
Direct Calculation of Li-Ion Transport in the Solid Electrolyte Interphase
journal, September 2012
- Shi, Siqi; Lu, Peng; Liu, Zhongyi
- Journal of the American Chemical Society, Vol. 134, Issue 37
Computational Exploration of the Li-Electrode|Electrolyte Interface in the Presence of a Nanometer Thick Solid-Electrolyte Interphase Layer
journal, September 2016
- Li, Yunsong; Leung, Kevin; Qi, Yue
- Accounts of Chemical Research, Vol. 49, Issue 10
Interfacial Structure and Dynamics of the Lithium Alkyl Dicarbonate SEI Components in Contact with the Lithium Battery Electrolyte
journal, July 2014
- Borodin, Oleg; Bedrov, Dmitry
- The Journal of Physical Chemistry C, Vol. 118, Issue 32
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling
journal, August 2016
- An, Seong Jin; Li, Jianlin; Daniel, Claus
- Carbon, Vol. 105
Silicon Solid Electrolyte Interphase (SEI) of Lithium Ion Battery Characterized by Microscopy and Spectroscopy
journal, June 2013
- Nie, Mengyun; Abraham, Daniel P.; Chen, Yanjing
- The Journal of Physical Chemistry C, Vol. 117, Issue 26
A New Perspective on the Formation and Structure of the Solid Electrolyte Interface at the Graphite Anode of Li-Ion Cells
journal, January 1999
- Ein-Eli, Yair
- Electrochemical and Solid-State Letters, Vol. 2, Issue 5
Modeling detailed chemistry and transport for solid-electrolyte-interface (SEI) films in Li–ion batteries
journal, December 2011
- Colclasure, Andrew M.; Smith, Kandler A.; Kee, Robert J.
- Electrochimica Acta, Vol. 58
Formation and Growth Mechanisms of Solid-Electrolyte Interphase Layers in Rechargeable Batteries
journal, November 2015
- Soto, Fernando A.; Ma, Yuguang; Martinez de la Hoz, Julibeth M.
- Chemistry of Materials, Vol. 27, Issue 23
In Situ and Quantitative Characterization of Solid Electrolyte Interphases
journal, February 2014
- Cresce, Arthur v.; Russell, Selena M.; Baker, David R.
- Nano Letters, Vol. 14, Issue 3
Chemistry, Impedance, and Morphology Evolution in Solid Electrolyte Interphase Films during Formation in Lithium Ion Batteries
journal, December 2013
- Lu, Peng; Li, Chen; Schneider, Eric W.
- The Journal of Physical Chemistry C, Vol. 118, Issue 2
Ab initio molecular dynamics simulations of the initial stages of solid–electrolyte interphase formation on lithium ion battery graphitic anodes
journal, January 2010
- Leung, Kevin; Budzien, Joanne L.
- Physical Chemistry Chemical Physics, Vol. 12, Issue 25
Molecular Dynamics Simulations of Lithium Alkyl Carbonates
journal, November 2006
- Borodin, Oleg; Smith, Grant D.; Fan, Peng
- The Journal of Physical Chemistry B, Vol. 110, Issue 45
Molecular Dynamics Simulations and Experimental Study of Lithium Ion Transport in Dilithium Ethylene Dicarbonate
journal, April 2013
- Borodin, Oleg; Zhuang, Guorong V.; Ross, Philip N.
- The Journal of Physical Chemistry C, Vol. 117, Issue 15
Solubility of Lithium Salts Formed on the Lithium-Ion Battery Negative Electrode Surface in Organic Solvents
journal, January 2009
- Tasaki, Ken; Goldberg, Alex; Lian, Jian-Jie
- Journal of The Electrochemical Society, Vol. 156, Issue 12
Solvent Decompositions and Physical Properties of Decomposition Compounds in Li-Ion Battery Electrolytes Studied by DFT Calculations and Molecular Dynamics Simulations
journal, February 2005
- Tasaki, Ken
- The Journal of Physical Chemistry B, Vol. 109, Issue 7
Understanding Long-Term Cycling Performance of Li 1.2 Ni 0.15 Mn 0.55 Co 0.1 O 2 –Graphite Lithium-Ion Cells
journal, January 2013
- Li, Y.; Bettge, M.; Polzin, B.
- Journal of The Electrochemical Society, Vol. 160, Issue 5
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, December 2004
- Xu, Kang
- ChemInform, Vol. 35, Issue 50
Ab initio Molecular Dynamics Simulations of the Initial Stages of Solid-electrolyte Interphase Formation on Lithium Ion Battery Graphitic Anodes
text, January 2010
- Leung, Kevin; Budzien, Joanne
- arXiv
First Principles Modeling of the Initial Stages of Organic Solvent Decomposition on Li(x)Mn(2)O(4) (100) Surfaces
text, January 2012
- Leung, Kevin
- arXiv
First Principles Modeling of Mn(II) Migration above and Dissolution from Li(x)Mn(2)O(4) (001) Surfaces
text, January 2017
- Leung, Kevin
- arXiv
Works referencing / citing this record:
Scavenging Materials to Stabilize LiPF 6 ‐Containing Carbonate‐Based Electrolytes for Li‐Ion Batteries
journal, November 2018
- Han, Jung‐Gu; Kim, Koeun; Lee, Yongwon
- Advanced Materials, Vol. 31, Issue 20
Chemical, Structural, and Electronic Aspects of Formation and Degradation Behavior on Different Length Scales of Ni‐Rich NCM and Li‐Rich HE‐NCM Cathode Materials in Li‐Ion Batteries
journal, April 2019
- de Biasi, Lea; Schwarz, Björn; Brezesinski, Torsten
- Advanced Materials, Vol. 31, Issue 26
Composition and Impedance Heterogeneity in Oxide Electrode Cross-Sections Detected by Raman Spectroscopy
journal, February 2018
- Gilbert, James A.; Maroni, Victor A.; Cui, Yanjie
- Advanced Materials Interfaces, Vol. 5, Issue 9
Surface/Interface Structure Degradation of Ni‐Rich Layered Oxide Cathodes toward Lithium‐Ion Batteries: Fundamental Mechanisms and Remedying Strategies
journal, December 2019
- Liang, Longwei; Zhang, Wenheng; Zhao, Fei
- Advanced Materials Interfaces, Vol. 7, Issue 3
Deciphering the Cathode-Electrolyte Interfacial Chemistry in Sodium Layered Cathode Materials
journal, October 2018
- Mu, Linqin; Feng, Xu; Kou, Ronghui
- Advanced Energy Materials, Vol. 8, Issue 34
Interphases in Electroactive Suspension Systems: Where Chemistry Meets Mesoscale Physics
journal, April 2019
- Shukla, Garima; Franco, Alejandro A.
- Batteries & Supercaps, Vol. 2, Issue 7
New Insights for the Abuse Tolerance Behavior of LiMn 2 O 4 under High Cut‐Off Potential Conditions
journal, September 2018
- Zhang, Feilong; Geng, Tongtong; Peng, Fengfeng
- ChemElectroChem, Vol. 6, Issue 3
Identifying rate limitation and a guide to design of fast‐charging Li‐ion battery
journal, December 2019
- Zhang, Sheng S.
- InfoMat, Vol. 2, Issue 5
The State and Challenges of Anode Materials Based on Conversion Reactions for Sodium Storage
journal, March 2018
- Wu, Chao; Dou, Shi-Xue; Yu, Yan
- Small, Vol. 14, Issue 22
Recent Progress of Layered Transition Metal Oxide Cathodes for Sodium‐Ion Batteries
journal, February 2019
- Liu, Qiannan; Hu, Zhe; Chen, Mingzhe
- Small, Vol. 15, Issue 32
Investigation of various layered lithium ion battery cathode materials by plasma- and X-ray-based element analytical techniques
journal, October 2018
- Evertz, Marco; Kasnatscheew, Johannes; Winter, Martin
- Analytical and Bioanalytical Chemistry, Vol. 411, Issue 1
Ion Chromatography with Post-column Reaction and Serial Conductivity and Spectrophotometric Detection Method Development for Quantification of Transition Metal Dissolution in Lithium Ion Battery Electrolytes
journal, May 2018
- Vortmann-Westhoven, Britta; Diehl, Marcel; Winter, Martin
- Chromatographia, Vol. 81, Issue 7
Lattice doping regulated interfacial reactions in cathode for enhanced cycling stability
journal, August 2019
- Zou, Lianfeng; Li, Jianyu; Liu, Zhenyu
- Nature Communications, Vol. 10, Issue 1
Spatial quantification of dynamic inter and intra particle crystallographic heterogeneities within lithium ion electrodes
journal, January 2020
- Finegan, Donal P.; Vamvakeros, Antonis; Tan, Chun
- Nature Communications, Vol. 11, Issue 1
High-nickel layered oxide cathodes for lithium-based automotive batteries
journal, January 2020
- Li, Wangda; Erickson, Evan M.; Manthiram, Arumugam
- Nature Energy, Vol. 5, Issue 1
Understanding ageing in Li-ion batteries: a chemical issue
journal, January 2018
- Palacín, M. Rosa
- Chemical Society Reviews, Vol. 47, Issue 13
Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review
journal, January 2018
- Zhan, Chun; Wu, Tianpin; Lu, Jun
- Energy & Environmental Science, Vol. 11, Issue 2
Empowering multicomponent cathode materials for sodium ion batteries by exploring three-dimensional compositional heterogeneities
journal, January 2018
- Rahman, Muhammad Mominur; Xu, Yahong; Cheng, Hao
- Energy & Environmental Science, Vol. 11, Issue 9
Structural analysis of the initial lithiation of NiO thin film electrodes
journal, January 2019
- Evmenenko, Guennadi; Fister, Timothy T.; Castro, Fernando C.
- Physical Chemistry Chemical Physics, Vol. 21, Issue 17
Use of Asymmetric Average Charge- and Average Discharge- Voltages as an Indicator of the Onset of Unwanted Lithium Deposition in Lithium-Ion Cells
journal, January 2018
- Harlow, J. E.; Glazier, S. L.; Li, Jing
- Journal of The Electrochemical Society, Vol. 165, Issue 16
How Transition Metals Enable Electron Transfer through the SEI: Part II. Redox-Cycling Mechanism Model and Experiment
journal, August 2019
- Harris, Oliver C.; Leung, Kevin; Tang, Maureen H.
- Journal of The Electrochemical Society, Vol. 167, Issue 1
Minimized Metal Dissolution from High-Energy Nickel Cobalt Manganese Oxide Cathodes with Al 2 O 3 Coating and Its Effects on Electrolyte Decomposition on Graphite Anodes
journal, January 2019
- Jurng, Sunhyung; Heiskanen, Satu Kristiina; Chandrasiri, K. W. D. Kaveendi
- Journal of The Electrochemical Society, Vol. 166, Issue 13
Electrochemomechanical Fatigue: Decoupling Mechanisms of Fracture-Induced Performance Degradation in Li X Mn 2 O 4
journal, January 2018
- McGrogan, Frank P.; Raja, Shilpa N.; Chiang, Yet-Ming
- Journal of The Electrochemical Society, Vol. 165, Issue 11
Li 1.2 Mn 0.55 Ni 0.15 Co 0.1 O 2 (LMR-NMC)-Carbon Coated-LiMnPO 4 Blended Electrodes for High Performance Lithium Ion Batteries
journal, January 2018
- Kumar, S. Krishna; Martha, Surendra K.
- Journal of The Electrochemical Society, Vol. 165, Issue 3
Electrochemical Kinetics of SEI Growth on Carbon Black: Part I. Experiments
journal, January 2019
- Attia, Peter M.; Das, Supratim; Harris, Stephen J.
- Journal of The Electrochemical Society, Vol. 166, Issue 4
Importance of Capacity Balancing on The Electrochemical Performance of Li[Ni 0.8 Co 0.1 Mn 0.1 ]O 2 (NCM811)/Silicon Full Cells
journal, January 2019
- Reuter, Florian; Baasner, Anne; Pampel, Jonas
- Journal of The Electrochemical Society, Vol. 166, Issue 14
Dependence of Cell Failure on Cut-Off Voltage Ranges and Observation of Kinetic Hindrance in LiNi 0.8 Co 0.15 Al 0.05 O 2
journal, January 2018
- Li, Jing; Harlow, Jessie; Stakheiko, Nikolai
- Journal of The Electrochemical Society, Vol. 165, Issue 11
Electrolyte and SEI Decomposition Reactions of Transition Metal Ions Investigated by On-Line Electrochemical Mass Spectrometry
journal, January 2018
- Solchenbach, Sophie; Hong, Gloria; Freiberg, Anna Teresa Sophie
- Journal of The Electrochemical Society, Vol. 165, Issue 14
Review—Multifunctional Separators: A Promising Approach for Improving the Durability and Performance of Li-Ion Batteries
journal, January 2019
- Banerjee, Anjan; Ziv, Baruch; Shilina, Yuliya
- Journal of The Electrochemical Society, Vol. 166, Issue 3
Comparative Measurements of Side-Reaction Currents of Li[Li 1/3 Ti 5/3 ]O 4 and Li[Li 0.1 Al 0.1 Mn 1.8 ]O 4 Electrodes in Lithium-Ion Cells and Symmetric Cells
journal, January 2019
- Ariyoshi, Kingo; Fukunishi, Yuki; Yamada, Yusuke
- Journal of The Electrochemical Society, Vol. 166, Issue 14
Preformed Anodes for High-Voltage Lithium-Ion Battery Performance: Fluorinated Electrolytes, Crosstalk, and the Origins of Impedance Rise
journal, January 2018
- Tornheim, Adam; Sahore, Ritu; He, Meinan
- Journal of The Electrochemical Society, Vol. 165, Issue 14
One Law to Rule Them All: Stretched Exponential Master Curve of Capacity Fade for Li-Ion Batteries
journal, January 2019
- Cuervo-Reyes, Eduardo; Flückiger, Reto
- Journal of The Electrochemical Society, Vol. 166, Issue 8
Quantifying Changes to the Electrolyte and Negative Electrode in Aged NMC532/Graphite Lithium-Ion Cells
journal, January 2018
- Thompson, L. M.; Stone, W.; Eldesoky, A.
- Journal of The Electrochemical Society, Vol. 165, Issue 11
Effect of Choices of Positive Electrode Material, Electrolyte, Upper Cut-Off Voltage and Testing Temperature on the Life Time of Lithium-Ion Cells
journal, January 2018
- Li, Jing; Glazier, Stephen L.; Nelson, Kathlyne
- Journal of The Electrochemical Society, Vol. 165, Issue 13
Development of Electrolytes for Single Crystal NMC532/Artificial Graphite Cells with Long Lifetime
journal, January 2018
- Li, Jing; Li, Hongyang; Stone, Will
- Journal of The Electrochemical Society, Vol. 165, Issue 3
Nickel, Manganese, and Cobalt Dissolution from Ni-Rich NMC and Their Effects on NMC622-Graphite Cells
journal, January 2019
- Jung, Roland; Linsenmann, Fabian; Thomas, Rowena
- Journal of The Electrochemical Society, Vol. 166, Issue 2
A Guide to Full Coin Cell Making for Academic Researchers
journal, January 2019
- Murray, Vivian; Hall, David S.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 166, Issue 2
Advancing Lithium- and Manganese-Rich Cathodes through a Combined Electrolyte Additive/Surface Treatment Strategy
journal, January 2019
- Gutierrez, Arturo; He, Meinan; Yonemoto, Bryan T.
- Journal of The Electrochemical Society, Vol. 166, Issue 16
Degradation and Aging Routes of Ni-Rich Cathode Based Li-Ion Batteries
journal, January 2020
- Teichert, Philipp; Eshetu, Gebrekidan Gebresilassie; Jahnke, Hannes
- Batteries, Vol. 6, Issue 1
Mn versus Al in Layered Oxide Cathodes in Lithium-Ion Batteries: A Comprehensive Evaluation on Long-Term Cyclability
journal, February 2018
- Li, Wangda; Liu, Xiaoming; Celio, Hugo
- Advanced Energy Materials, Vol. 8, Issue 15
High-Voltage Li-Ion Full-Cells with Ultralong Term Cycle Life at Elevated Temperature
journal, October 2018
- Qiao, Yu; He, Yibo; Jiang, Kezhu
- Advanced Energy Materials, Vol. 8, Issue 33
Improvement of Cycleability and Rate‐Capability of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Materials Coated with Lithium Boron Oxide by an Antisolvent Precipitation Method
journal, August 2019
- Hashigami, Satoshi; Yoshimi, Kei; Kato, Yukihiro
- ChemistrySelect, Vol. 4, Issue 29
Composite‐Structure Materials for Na‐Ion Batteries
journal, October 2018
- Su, Heng; Yu, Haijun
- Small Methods, Vol. 3, Issue 4
Single-crystal based studies for correlating the properties and high-voltage performance of Li[Ni x Mn y Co 1−x−y ]O 2 cathodes
journal, January 2019
- Zhu, Jian; Chen, Guoying
- Journal of Materials Chemistry A, Vol. 7, Issue 10
How Transition Metals Enable Electron Transfer through the SEI: Part I. Experiments and Butler-Volmer Modeling
journal, August 2019
- Harris, Oliver C.; Lin, Yuxiao; Qi, Yue
- Journal of The Electrochemical Society, Vol. 167, Issue 1
Fast Charging of Li-Ion Cells: Part II. Nonlinear Contributions to Cell and Electrode Polarization
journal, January 2019
- Shkrob, Ilya A.; Rodrigues, Marco-Tulio Fonseca; Dees, Dennis W.
- Journal of The Electrochemical Society, Vol. 166, Issue 14
Communication—Ligand-Dependent Electrochemical Activity for Mn 2+ in Lithium-Ion Electrolyte Solutions
journal, January 2019
- Tornheim, Adam; Kirner, Joel; Sahore, Ritu
- Journal of The Electrochemical Society, Vol. 166, Issue 10
Comparison of Single Crystal and Polycrystalline LiNi 0.5 Mn 0.3 Co 0.2 O 2 Positive Electrode Materials for High Voltage Li-Ion Cells
journal, January 2017
- Li, Jing; Cameron, Andrew R.; Li, Hongyang
- Journal of The Electrochemical Society, Vol. 164, Issue 7
Degradation and Aging Routes of Ni-Rich Cathode Based Li-Ion Batteries
text, January 2020
- Teichert, Philipp; Eshetu, Gebrekidan Gebresilassie; Jahnke, Hannes
- RWTH Aachen University
Chemical, Structural, and Electronic Aspects of Formation and Degradation Behavior on Different Length Scales of Ni‐Rich NCM and Li‐Rich HE‐NCM Cathode Materials in Li‐Ion Batteries
text, January 2019
- De Biasi, Lea; Schwarz, Björn; Brezesinski, Torsten
- Karlsruhe
Interphases in Electroactive Suspension Systems: Where Chemistry Meets Mesoscale Physics
journal, July 2019
- Shukla, Garima; Franco, Alejandro A.
- Batteries & Supercaps, Vol. 2, Issue 7
A highly stabilized nickel-rich cathode material by nanoscale epitaxy control for high-energy lithium-ion batteries
journal, January 2018
- Kim, Junhyeok; Ma, Hyunsoo; Cha, Hyungyeon
- Energy & Environmental Science, Vol. 11, Issue 6
One law to rule them all: Stretched exponential master curve of capacity fade for Li-ion batteries
preprint, January 2019
- Cuervo-Reyes, Eduardo; Flueckiger, Reto
- arXiv