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Title: Thermophysical properties of low cost lithium nitrate salts produced in northern Chile for thermal energy storage

In recent years, lithium containing salts have been studied for thermal energy storage (TES) applications because of their excellent thermophysical properties. In solar power plants, lithium is seen as a way to improve the properties of state-of-the art molten salts used today. Lithium nitrate is a good candidate for sensible heat storage, because of its ability to increase the salt mixture's working temperature range. In the present research, thermophysical properties characterization of lithium nitrate containing salts, produced in Chile, have been carried out. Corrosion evaluations at 390° and 565 °C for 1000 h were performed for low chromium steel T22 and stainless steels (AISI 430 and AISI 316), respectively. Chemical composition of the salts including identification of corrosion products and impurities was determined and an estimation of the Chilean production costs is reported. The study shows a loss of thermal properties after the corrosion tests. The heat capacity was reduced, possibly caused by the formation of oxides at high temperatures. As a result, the partial thermal decomposition of the salt was probably produced by the incorporation of corrosion products from the steel.
Authors:
ORCiD logo [1] ;  [2]
  1. Univ. of Antofagasta, Antofagasta (Chile); National Renewable Energy Lab. (NREL), Golden, CO (United States)
  2. National Renewable Energy Lab. (NREL), Golden, CO (United States)
Publication Date:
Report Number(s):
NREL/JA-5500-67720
Journal ID: ISSN 0960-1481
Grant/Contract Number:
AC36-08GO28308
Type:
Accepted Manuscript
Journal Name:
Renewable Energy
Additional Journal Information:
Journal Volume: 101; Journal Issue: C; Journal ID: ISSN 0960-1481
Publisher:
Elsevier
Research Org:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; molten salts; lithium nitrate; thermal energy storage; concentrated solar power
OSTI Identifier:
1339513
Alternate Identifier(s):
OSTI ID: 1359820

Fernández, Ángel G., and Gomez-Vidal, Judith C.. Thermophysical properties of low cost lithium nitrate salts produced in northern Chile for thermal energy storage. United States: N. p., Web. doi:10.1016/j.renene.2016.08.052.
Fernández, Ángel G., & Gomez-Vidal, Judith C.. Thermophysical properties of low cost lithium nitrate salts produced in northern Chile for thermal energy storage. United States. doi:10.1016/j.renene.2016.08.052.
Fernández, Ángel G., and Gomez-Vidal, Judith C.. 2016. "Thermophysical properties of low cost lithium nitrate salts produced in northern Chile for thermal energy storage". United States. doi:10.1016/j.renene.2016.08.052. https://www.osti.gov/servlets/purl/1339513.
@article{osti_1339513,
title = {Thermophysical properties of low cost lithium nitrate salts produced in northern Chile for thermal energy storage},
author = {Fernández, Ángel G. and Gomez-Vidal, Judith C.},
abstractNote = {In recent years, lithium containing salts have been studied for thermal energy storage (TES) applications because of their excellent thermophysical properties. In solar power plants, lithium is seen as a way to improve the properties of state-of-the art molten salts used today. Lithium nitrate is a good candidate for sensible heat storage, because of its ability to increase the salt mixture's working temperature range. In the present research, thermophysical properties characterization of lithium nitrate containing salts, produced in Chile, have been carried out. Corrosion evaluations at 390° and 565 °C for 1000 h were performed for low chromium steel T22 and stainless steels (AISI 430 and AISI 316), respectively. Chemical composition of the salts including identification of corrosion products and impurities was determined and an estimation of the Chilean production costs is reported. The study shows a loss of thermal properties after the corrosion tests. The heat capacity was reduced, possibly caused by the formation of oxides at high temperatures. As a result, the partial thermal decomposition of the salt was probably produced by the incorporation of corrosion products from the steel.},
doi = {10.1016/j.renene.2016.08.052},
journal = {Renewable Energy},
number = C,
volume = 101,
place = {United States},
year = {2016},
month = {9}
}