A combined salt–hard templating approach for synthesis of multi-modal porous carbons used for probing the simultaneous effects of porosity and electrode engineering on EDLC performance
Abstract
A novel approach, based on a combination of salt and hard templating for producing multi-modal porous carbons is demonstrated. The hard template, silica nanoparticles, generate mesopores (~22 nm), and in some cases borderline-macropores (~64 nm), resulting in high pore volume (~3.9 cm3/g) while the salt template, zinc chloride, generates borderline-mesopores (~2 nm), thus imparting high surface area (~2100 m2/g). The versatility of the proposed synthesis technique is demonstrated using: (i) dual salt templates with hard template resulting in magnetic, nanostructured-clay embedded (~27% clay content), high surface area (~1527 m2/g) bimodal carbons (~2 and 70 nm pores), (ii) multiple hard templates with salt template resulting in tri-modal carbons (~2, 12 and 28 nm pores), (iii) low temperature (450 °C) synthesis of bimodal carbons afforded by the presence of hygroscopic salt template, (iv) easy coupling with physical activation approaches. A selected set of thus synthesized carbons were used to evaluate, for the first time, the simultaneous effects of carbon porosity and pressure applied during electrode fabrication on EDLC performance. Electrode pressing was discovered to be more favorable for carbons containing hard-templated mesopores (~87% capacitance retention at current density of 40 A/g) as compared to those without (~54% capacitance retention).
- Authors:
-
- Cornell Univ., Ithaca, NY (United States)
- King Abdullah Univ. of Science and Technology (KAUST), Thuwal (Saudi Arabia)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Energy Materials Center at Cornell (EMC2)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1370405
- Alternate Identifier(s):
- OSTI ID: 1337523
- Grant/Contract Number:
- SC0001086
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Carbon
- Additional Journal Information:
- Journal Volume: 87; Journal Issue: C; Related Information: Emc2 partners with Cornell University (lead); Lawrence Berkeley National Laboratory; Journal ID: ISSN 0008-6223
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Bhandari, Nidhi, Dua, Rubal, Estevez, Luis, Sahore, Ritu, and Giannelis, Emmanuel P. A combined salt–hard templating approach for synthesis of multi-modal porous carbons used for probing the simultaneous effects of porosity and electrode engineering on EDLC performance. United States: N. p., 2015.
Web. doi:10.1016/j.carbon.2015.01.039.
Bhandari, Nidhi, Dua, Rubal, Estevez, Luis, Sahore, Ritu, & Giannelis, Emmanuel P. A combined salt–hard templating approach for synthesis of multi-modal porous carbons used for probing the simultaneous effects of porosity and electrode engineering on EDLC performance. United States. https://doi.org/10.1016/j.carbon.2015.01.039
Bhandari, Nidhi, Dua, Rubal, Estevez, Luis, Sahore, Ritu, and Giannelis, Emmanuel P. Sat .
"A combined salt–hard templating approach for synthesis of multi-modal porous carbons used for probing the simultaneous effects of porosity and electrode engineering on EDLC performance". United States. https://doi.org/10.1016/j.carbon.2015.01.039. https://www.osti.gov/servlets/purl/1370405.
@article{osti_1370405,
title = {A combined salt–hard templating approach for synthesis of multi-modal porous carbons used for probing the simultaneous effects of porosity and electrode engineering on EDLC performance},
author = {Bhandari, Nidhi and Dua, Rubal and Estevez, Luis and Sahore, Ritu and Giannelis, Emmanuel P.},
abstractNote = {A novel approach, based on a combination of salt and hard templating for producing multi-modal porous carbons is demonstrated. The hard template, silica nanoparticles, generate mesopores (~22 nm), and in some cases borderline-macropores (~64 nm), resulting in high pore volume (~3.9 cm3/g) while the salt template, zinc chloride, generates borderline-mesopores (~2 nm), thus imparting high surface area (~2100 m2/g). The versatility of the proposed synthesis technique is demonstrated using: (i) dual salt templates with hard template resulting in magnetic, nanostructured-clay embedded (~27% clay content), high surface area (~1527 m2/g) bimodal carbons (~2 and 70 nm pores), (ii) multiple hard templates with salt template resulting in tri-modal carbons (~2, 12 and 28 nm pores), (iii) low temperature (450 °C) synthesis of bimodal carbons afforded by the presence of hygroscopic salt template, (iv) easy coupling with physical activation approaches. A selected set of thus synthesized carbons were used to evaluate, for the first time, the simultaneous effects of carbon porosity and pressure applied during electrode fabrication on EDLC performance. Electrode pressing was discovered to be more favorable for carbons containing hard-templated mesopores (~87% capacitance retention at current density of 40 A/g) as compared to those without (~54% capacitance retention).},
doi = {10.1016/j.carbon.2015.01.039},
journal = {Carbon},
number = C,
volume = 87,
place = {United States},
year = {Sat Jan 24 00:00:00 EST 2015},
month = {Sat Jan 24 00:00:00 EST 2015}
}
Web of Science
Works referenced in this record:
Controlling the Effective Surface Area and Pore Size Distribution of sp 2 Carbon Materials and Their Impact on the Capacitance Performance of These Materials
journal, April 2013
- Zhang, Long; Yang, Xi; Zhang, Fan
- Journal of the American Chemical Society, Vol. 135, Issue 15
Insights into the influence of pore size distribution and surface functionalities in the behaviour of carbon supercapacitors
journal, December 2012
- Vaquero, Susana; Díaz, Raul; Anderson, Marc
- Electrochimica Acta, Vol. 86
Role of textural properties and surface functionalities of selected carbons on the electrochemical behaviour of ionic liquid based-supercapacitors
journal, January 2012
- Jaramillo, Mauricio Mora; Mendoza, Alvaro; Vaquero, Susana
- RSC Advances, Vol. 2, Issue 22
A facile approach for the synthesis of monolithic hierarchical porous carbons – high performance materials for amine based CO2 capture and supercapacitor electrode
journal, January 2013
- Estevez, Luis; Dua, Rubal; Bhandari, Nidhi
- Energy & Environmental Science, Vol. 6, Issue 6
Ordered hierarchical mesoporous/microporous carbon with optimized pore structure for supercapacitors
journal, January 2013
- Zhou, Dan-Dan; Du, Yuan-Jin; Song, Yan-Fang
- J. Mater. Chem. A, Vol. 1, Issue 4
Ordered Hierarchical Mesoporous/Microporous Carbon Derived from Mesoporous Titanium-Carbide/Carbon Composites and its Electrochemical Performance in Supercapacitor
journal, September 2011
- Liu, Hai-Jing; Wang, Jie; Wang, Cong-Xiao
- Advanced Energy Materials, Vol. 1, Issue 6
Fabrication of hollow core carbon spheres with hierarchical nanoarchitecture for ultrahigh electrical charge storage
journal, January 2012
- Fang, Baizeng; Kim, Jung Ho; Kim, Min-Sik
- Journal of Materials Chemistry, Vol. 22, Issue 36
3D Aperiodic Hierarchical Porous Graphitic Carbon Material for High-Rate Electrochemical Capacitive Energy Storage
journal, January 2008
- Wang, Da-Wei; Li, Feng; Liu, Min
- Angewandte Chemie, Vol. 120, Issue 2
Fine tuning of the supercapacitive performance of nanoporous carbon electrodes with different pore diameters
journal, August 2012
- Dhawale, Dattatray S.; Benzigar, Mercy R.; Wahab, Mohammad A.
- Electrochimica Acta, Vol. 77
Tailoring Electrode/Electrolyte Interfacial Properties in Flexible Supercapacitors by Applying Pressure
journal, February 2012
- Masarapu, Charan; Wang, Lian-Ping; Li, Xin
- Advanced Energy Materials, Vol. 2, Issue 5
Electrochemical Behavior of Single-Walled Carbon Nanotube Supercapacitors under Compressive Stress
journal, September 2010
- Li, Xin; Rong, Jiepeng; Wei, Bingqing
- ACS Nano, Vol. 4, Issue 10
Strategies to reduce the resistance sources on Electrochemical Double Layer Capacitor electrodes
journal, September 2013
- Dsoke, Sonia; Tian, Xu; Täubert, Corina
- Journal of Power Sources, Vol. 238
Reduction of porous carbon/Al contact resistance for an electric double-layer capacitor (EDLC)
journal, March 2013
- Lei, Chunhong; Markoulidis, Foivos; Ashitaka, Zenya
- Electrochimica Acta, Vol. 92
Modification of Al current collector surface by sol–gel deposit for carbon–carbon supercapacitor applications
journal, March 2004
- Portet, C.; Taberna, P. L.; Simon, P.
- Electrochimica Acta, Vol. 49, Issue 6
Electrode optimisation for carbon power supercapacitors
journal, May 1999
- Bonnefoi, L.; Simon, P.; Fauvarque, J. F.
- Journal of Power Sources, Vol. 79, Issue 1
Electric double layer capacitors based on a composite electrode of activated mesophase pitch and carbon nanotubes
journal, January 2012
- Huang, Cheng-Wei; Hsieh, Chien-Te; Kuo, Ping-Lin
- Journal of Materials Chemistry, Vol. 22, Issue 15
Volumetric capacitance of compressed activated microwave-expanded graphite oxide (a-MEGO) electrodes
journal, September 2013
- Murali, Shanthi; Quarles, Neil; Zhang, Li Li
- Nano Energy, Vol. 2, Issue 5
High-energy supercapacitors based on hierarchical porous carbon with an ultrahigh ion-accessible surface area in ionic liquid electrolytes
journal, January 2013
- Zhong, Hui; Xu, Fei; Li, Zenghui
- Nanoscale, Vol. 5, Issue 11
Hierarchically porous carbon derived from polymers and biomass: effect of interconnected pores on energy applications
journal, January 2014
- Dutta, Saikat; Bhaumik, Asim; Wu, Kevin C. -W.
- Energy Environ. Sci., Vol. 7, Issue 11
Three-dimensional flower-like and hierarchical porous carbon materials as high-rate performance electrodes for supercapacitors
journal, February 2014
- Wang, Qian; Yan, Jun; Wang, Yanbo
- Carbon, Vol. 67
Advanced Materials for Energy Storage
journal, February 2010
- Liu, Chang; Li, Feng; Ma, Lai-Peng
- Advanced Materials, Vol. 22, Issue 8
Effects of the mesostructural order on the electrochemical performance of hierarchical micro–mesoporous carbons
journal, January 2014
- Enterría, M.; Castro-Muñiz, A.; Suárez-García, F.
- J. Mater. Chem. A, Vol. 2, Issue 30
High-Performance Supercapacitors Based on Hierarchically Porous Graphite Particles
journal, June 2011
- Chen, Zheng; Wen, Jing; Yan, Chunzhu
- Advanced Energy Materials, Vol. 1, Issue 4
Effect of mesoporosity on specific capacitance of carbons
journal, May 2009
- Fernández, J. A.; Tennison, S.; Kozynchenko, O.
- Carbon, Vol. 47, Issue 6
Performance of templated mesoporous carbons in supercapacitors
journal, February 2007
- Sevilla, M.; Álvarez, S.; Centeno, T. A.
- Electrochimica Acta, Vol. 52, Issue 9
Energy storage in electrochemical capacitors: designing functional materials to improve performance
journal, January 2010
- Hall, Peter J.; Mirzaeian, Mojtaba; Fletcher, S. Isobel
- Energy & Environmental Science, Vol. 3, Issue 9
Block-Copolymer assisted synthesis of hierarchical carbon monoliths suitable as supercapacitor electrodes
journal, January 2010
- Carriazo, Daniel; Picó, Fernando; Gutiérrez, María C.
- Journal of Materials Chemistry, Vol. 20, Issue 4, p. 773-780
Pig bone derived hierarchical porous carbon and its enhanced cycling performance of lithium–sulfur batteries
journal, January 2011
- Wei, Shaochen; Zhang, Hao; Huang, Yaqin
- Energy & Environmental Science, Vol. 4, Issue 3
Simultaneous Formation of Ultrahigh Surface Area and Three-Dimensional Hierarchical Porous Graphene-Like Networks for Fast and Highly Stable Supercapacitors
journal, March 2013
- Li, Yunyong; Li, Zesheng; Shen, Pei Kang
- Advanced Materials, Vol. 25, Issue 17
Irreversible membrane fouling abatement through pre-deposited layer of hierarchical porous carbons
journal, November 2014
- Hamad, Juma Z.; Dua, Rubal; Kurniasari, Novita
- Water Research, Vol. 65
Electrochemical performance of graphitized carbide-derived-carbon with hierarchical micro- and meso-pores in alkaline electrolyte
journal, August 2014
- Xu, Jiang; Zhang, Ruijun; Wu, Chao
- Carbon, Vol. 74
Simple synthesis of hierarchically structured partially graphitized carbon by emulsion/block-copolymer co-template method for high power supercapacitors
journal, November 2013
- Mun, Yeongdong; Jo, Changshin; Hyeon, Taeghwan
- Carbon, Vol. 64
Hydrothermal nanocasting: Synthesis of hierarchically porous carbon monoliths and their application in lithium–sulfur batteries
journal, September 2013
- Yu, Linghui; Brun, Nicolas; Sakaushi, Ken
- Carbon, Vol. 61
Hierarchically porous N-doped carbon nanoflakes: Large-scale facile synthesis and application as an oxygen reduction reaction electrocatalyst with high activity
journal, November 2014
- Ning, Rui; Ge, Chenjiao; Liu, Qian
- Carbon, Vol. 78
A microporous–mesoporous carbon with graphitic structure for a high-rate stable sulfur cathode in carbonate solvent-based Li–S batteries
journal, January 2012
- Wang, Da-Wei; Zhou, Guangmin; Li, Feng
- Physical Chemistry Chemical Physics, Vol. 14, Issue 24
MOF-Derived Hierarchically Porous Carbon with Exceptional Porosity and Hydrogen Storage Capacity
journal, December 2011
- Yang, Seung Jae; Kim, Taehoon; Im, Ji Hyuk
- Chemistry of Materials, Vol. 24, Issue 3
Templated Nanocarbons for Energy Storage
journal, July 2012
- Nishihara, Hirotomo; Kyotani, Takashi
- Advanced Materials, Vol. 24, Issue 33, p. 4473-4498
One-pot endo/exotemplating of hierarchical micro-mesoporous carbons
journal, April 2013
- Enterría, M.; Suárez-García, F.; Martínez-Alonso, A.
- Carbon, Vol. 54
Ethanol-based synthesis of hierarchically porous carbon using nanocrystalline beta zeolite template for high-rate electrical double layer capacitor
journal, August 2013
- Kim, Kyoungsoo; Choi, Minkee; Ryoo, Ryong
- Carbon, Vol. 60
Hierarchical porous carbons prepared from direct coal liquefaction residue and coal for supercapacitor electrodes
journal, April 2013
- Zhang, Jianbo; Jin, Lijun; Cheng, Jie
- Carbon, Vol. 55
Fabrication of nitrogen-doped hierarchically porous carbons through a hybrid dual-template route for CO2 capture and haemoperfusion
journal, September 2014
- Liu, Rui-Lin; Ji, Wen-Juan; He, Tian
- Carbon, Vol. 76
Solvent evaporation mediated preparation of hierarchically porous metal organic framework-derived carbon with controllable and accessible large-scale porosity
journal, May 2014
- Yang, Seung Jae; Kim, Taeyoung; Lee, Kunsil
- Carbon, Vol. 71
Fabrication of New Nanoporous Carbons through Silica Templates and Their Application to the Adsorption of Bulky Dyes
journal, November 2000
- Han, Sangjin; Sohn, Kwonnam; Hyeon, Taeghwan
- Chemistry of Materials, Vol. 12, Issue 11
Hierarchically porous phenolic resin-based carbons obtained by block copolymer-colloidal silica templating and post-synthesis activation with carbon dioxide and water vapor
journal, January 2011
- Górka, Joanna; Jaroniec, Mietek
- Carbon, Vol. 49, Issue 1, p. 154-160
A comprehensive study on KOH activation of ordered mesoporous carbons and their supercapacitor application
journal, January 2012
- Lv, Yingying; Zhang, Fan; Dou, Yuqian
- J. Mater. Chem., Vol. 22, Issue 1
Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode
journal, January 2014
- Hao, Pin; Zhao, Zhenhuan; Tian, Jian
- Nanoscale, Vol. 6, Issue 20
Synthesis of ordered micro–mesoporous carbons by activation of SBA-15 carbon replicas
journal, March 2012
- Enterría, M.; Suárez-García, F.; Martínez-Alonso, A.
- Microporous and Mesoporous Materials, Vol. 151
Avoiding structure degradation during activation of ordered mesoporous carbons
journal, August 2012
- Enterría, Marina; Suárez-García, Fabián; Martínez-Alonso, Amelia
- Carbon, Vol. 50, Issue 10
Synthesis of functionalized 3D hierarchical porous carbon for high-performance supercapacitors
journal, January 2013
- Qie, Long; Chen, Weimin; Xu, Henghui
- Energy & Environmental Science, Vol. 6, Issue 8
From dead leaves to high energy density supercapacitors
journal, January 2013
- Biswal, Mandakini; Banerjee, Abhik; Deo, Meenal
- Energy & Environmental Science, Vol. 6, Issue 4, p. 1249-1259
Synthesis of mesoporous carbons for supercapacitors from coal tar pitch by coupling microwave-assisted KOH activation with a MgO template
journal, November 2012
- He, Xiaojun; Li, Ruchun; Qiu, Jieshan
- Carbon, Vol. 50, Issue 13
“Salt Templating”: A Simple and Sustainable Pathway toward Highly Porous Functional Carbons from Ionic Liquids
journal, October 2012
- Fechler, Nina; Fellinger, Tim-Patrick; Antonietti, Markus
- Advanced Materials, Vol. 25, Issue 1
Moderating Black Powder Chemistry for the Synthesis of Doped and Highly Porous Graphene Nanoplatelets and Their Use in Electrocatalysis
journal, August 2013
- Liu, Xiaofeng; Antonietti, Markus
- Advanced Materials, Vol. 25, Issue 43
Salt and sugar: direct synthesis of high surface area carbon materials at low temperatures via hydrothermal carbonization of glucose under hypersaline conditions
journal, January 2013
- Fechler, Nina; Wohlgemuth, Stephanie-Angelika; Jäker, Philipp
- Journal of Materials Chemistry A, Vol. 1, Issue 33
A Facile Molten-Salt Route to Graphene Synthesis
journal, July 2013
- Liu, Xiaofeng; Giordano, Cristina; Antonietti, Markus
- Small, Vol. 10, Issue 1
Simple silica-particle template synthesis of mesoporous carbons
journal, January 1999
- Han, Sangjin; Hyeon, Taeghwan
- Chemical Communications, Issue 19
Spontaneous Phase Separation Mediated Synthesis of 3D Mesoporous Carbon with Controllable Cage and Window Size
journal, April 2011
- Lee, Hyung Ik; Stucky, Galen D.; Kim, Jin Hoe
- Advanced Materials, Vol. 23, Issue 20
Preparation of activated carbon cloths from viscous rayon. Part II: physical activation processes
journal, January 2000
- Rodrı́guez-Reinoso, F.; Pastor, A. C.; Marsh, H.
- Carbon, Vol. 38, Issue 3
Works referencing / citing this record:
Ordered Mesoporous Carbons Loading on Graphene after Different Molten Salt Activations for Supercapacitor Applications
journal, October 2018
- Chen, Peng; Lu, Suhui; Yang, Chao
- Energy Technology, Vol. 6, Issue 11
Synthesis and electrochemical performance of high surface area hierarchical porous carbon with ultrahigh mesoporosity for high-performance supercapacitors
journal, June 2019
- Ma, Chang; Xu, Jiankang; Fan, Qingchao
- Journal of Solid State Electrochemistry, Vol. 23, Issue 7
Designing Carbon Based Supercapacitors with High Energy Density: A Summary of Recent Progress
journal, February 2018
- Han, Yi; Lai, Zhengzhe; Wang, Zifan
- Chemistry – A European Journal, Vol. 24, Issue 29