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Title: Synthesis and Characterization of Cerium(IV) Metallocenes

Abstract

In this study, by applying a salt metathesis approach between Ce(OtBu 3) 2(NO 3) 2(THF) 2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.

Authors:
 [1];  [2];  [3];  [1]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Chemistry Div. - Inorganic, Isotope and Actinide Chemistry (C-IIAC)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States). National Security Education Centre (NSEC)
  3. Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Materials Synthesis and Integrated Devices (MPA-11)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Laboratory Directed Research and Development (LDRD) Program
OSTI Identifier:
1337096
Report Number(s):
LA-UR-15-29339
Journal ID: ISSN 2304-6740; INORCW
Grant/Contract Number:  
AC52-06NA25396
Resource Type:
Accepted Manuscript
Journal Name:
Inorganics
Additional Journal Information:
Journal Volume: 3; Journal Issue: 4; Journal ID: ISSN 2304-6740
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; cerium; organometallic; cyclopentadiene; crystal structure

Citation Formats

Sutton, Andrew, Clark, David Lewis, Scott, Brian Lindley, and Gordon, John Cameron. Synthesis and Characterization of Cerium(IV) Metallocenes. United States: N. p., 2015. Web. doi:10.3390/inorganics3040589.
Sutton, Andrew, Clark, David Lewis, Scott, Brian Lindley, & Gordon, John Cameron. Synthesis and Characterization of Cerium(IV) Metallocenes. United States. doi:10.3390/inorganics3040589.
Sutton, Andrew, Clark, David Lewis, Scott, Brian Lindley, and Gordon, John Cameron. Fri . "Synthesis and Characterization of Cerium(IV) Metallocenes". United States. doi:10.3390/inorganics3040589. https://www.osti.gov/servlets/purl/1337096.
@article{osti_1337096,
title = {Synthesis and Characterization of Cerium(IV) Metallocenes},
author = {Sutton, Andrew and Clark, David Lewis and Scott, Brian Lindley and Gordon, John Cameron},
abstractNote = {In this study, by applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.},
doi = {10.3390/inorganics3040589},
journal = {Inorganics},
number = 4,
volume = 3,
place = {United States},
year = {2015},
month = {12}
}

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    Synthetic and structural studies of a series of soluble cerium(IV) alkoxide and alkoxide nitrate complexes
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    • DOI: 10.1021/ic802047u

    Facile Access to Tetravalent Cerium Compounds: One-Electron Oxidation Using Iodine(III) Reagents
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