Exploring hardness enhancement in superhard tungsten tetraboride-based solid solutions using radial X-ray diffraction
Abstract
In this paper, we explore the hardening mechanisms in WB4-based solid solutions upon addition of Ta, Mn, and Cr using in situ radial X-ray diffraction techniques under nonhydrostatic pressure. By examining the lattice-supported differential strain, we provide insights into the mechanism for hardness increase in binary solid solutions at low dopant concentrations. Speculations on the combined effects of electronic structure and atomic size in ternary WB4 solid solutions containing Ta with Mn or Cr are also included to understand the extremely high hardness of these materials.
- Authors:
-
- UCLA, Los Angeles, CA (United States)
- UCLA, Los Angeles, CA (United States); Virginia Commonwealth Univ., Richmond, VA (United States)
- Publication Date:
- Research Org.:
- Carnegie Institution of Washington, Washington, D.C. (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1335839
- Alternate Identifier(s):
- OSTI ID: 1226779
- Grant/Contract Number:
- NA0002006; AC02-05CH11231; NA-00006
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Physics Letters
- Additional Journal Information:
- Journal Volume: 107; Journal Issue: 4; Journal ID: ISSN 0003-6951
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; diamond anvil cell; differential stress; hardness; in situ high-pressure; non-hydrostatic compression; radial diffraction; solid-solution hardening; superhard materials; tungsten tetraboride
Citation Formats
Xie, Miao, Mohammadi, Reza, Turner, Christopher L., Kaner, Richard B., Kavner, Abby, and Tolbert, Sarah H. Exploring hardness enhancement in superhard tungsten tetraboride-based solid solutions using radial X-ray diffraction. United States: N. p., 2015.
Web. doi:10.1063/1.4927596.
Xie, Miao, Mohammadi, Reza, Turner, Christopher L., Kaner, Richard B., Kavner, Abby, & Tolbert, Sarah H. Exploring hardness enhancement in superhard tungsten tetraboride-based solid solutions using radial X-ray diffraction. United States. https://doi.org/10.1063/1.4927596
Xie, Miao, Mohammadi, Reza, Turner, Christopher L., Kaner, Richard B., Kavner, Abby, and Tolbert, Sarah H. Wed .
"Exploring hardness enhancement in superhard tungsten tetraboride-based solid solutions using radial X-ray diffraction". United States. https://doi.org/10.1063/1.4927596. https://www.osti.gov/servlets/purl/1335839.
@article{osti_1335839,
title = {Exploring hardness enhancement in superhard tungsten tetraboride-based solid solutions using radial X-ray diffraction},
author = {Xie, Miao and Mohammadi, Reza and Turner, Christopher L. and Kaner, Richard B. and Kavner, Abby and Tolbert, Sarah H.},
abstractNote = {In this paper, we explore the hardening mechanisms in WB4-based solid solutions upon addition of Ta, Mn, and Cr using in situ radial X-ray diffraction techniques under nonhydrostatic pressure. By examining the lattice-supported differential strain, we provide insights into the mechanism for hardness increase in binary solid solutions at low dopant concentrations. Speculations on the combined effects of electronic structure and atomic size in ternary WB4 solid solutions containing Ta with Mn or Cr are also included to understand the extremely high hardness of these materials.},
doi = {10.1063/1.4927596},
journal = {Applied Physics Letters},
number = 4,
volume = 107,
place = {United States},
year = {Wed Jul 29 00:00:00 EDT 2015},
month = {Wed Jul 29 00:00:00 EDT 2015}
}
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Works referencing / citing this record:
Radial X‐Ray Diffraction Study of Superhard Early Transition Metal Dodecaborides under High Pressure
journal, April 2019
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Lattice strain and texture analysis of superhard Mo 0.9 W 1.1 BC and ReWC 0.8 via diamond anvil cell deformation
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Anomalous lattice stiffening in tungsten tetraboride solid solutions with manganese under compression
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